Page 1/10
Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 01/22/2008 Reviewed on 01/22/2008
1 Identification of substance
?Product details
?Trade name: 41377 Body Sealant
?Article number: 41377
?Manufacturer/Supplier:
SEM Products Inc.
651 Michael Wylie Dr.
Charlotte, NC 28217
(704)522-1006
?Information department:
labsupport@sem.ws : SEM Products 651 Michael Wylie Dr. Charlotte, NC 28217 : phone 1-704-522-1006, M -
TH 7am - 4pm EDT
?Emergency information: 24 HR EMERGENCY CHEMTREC 1-800-424-9300
2 Composition/Data on components
?Chemical characterization
?Description: Mixture of the substances listed below with nonhazardous additions.
?Dangerous components:
ALIPHATIC AMINE (PROPRIETARY) 25-50%
Danger: 3.1.O/3, 3.1.I/4, 3.4.S/1, 3.8/3; 3.4.R/1; 3.2/1B
25068-38-6 bisphenolA(chloro)oxirane polymer 10-25%
Warning: 3.2/2, 3.3/2A, 3.4.S/1
15625-89-5 2,2-bis(acryloyloxymethyl)butyl acrylate 10-25%
Warning: 3.2/2, 3.3/2A, 3.4.S/1
14807-96-6 Talc (Mg3H2(SiO3)4) 10-25%
Warning: 3.2/2, 3.3/2A, 3.8/3
67762-90-7 FUMED SILICA 2.5-10%
Warning: 3.3/2A, 3.8/3
26142-30-3 POLYMER OF EPICHLOROHYDRIN-POLYGLYCOL 2.5-10%
Warning: 3.2/2, 3.3/2A, 3.8/3
ACRYLATE ESTERS (PROPRIETARY) 1-2.5%
Danger: 3.4.R/1, 3.4.S/1; 3.3/1, 3.2/2
Warning: 3.8/3
3 Hazards identification
?Hazard description:
Toxic
?WHMIS-symbols:
D2A - Very toxic material causing other toxic effects
E - Corrosive material
(Contd. on page 2)
CDN
DR
Page 2/10
Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 01/22/2008 Reviewed on 01/22/2008
Trade name: 41377 Body Sealant
(Contd. of page 1)
?Information pertaining to particular dangers for man and environment:
The product has to be labelled due to the calculation procedure of international guidelines.
Harmful by inhalation and if swallowed.
Causes burns.
Irritating to respiratory system.
Danger of very serious irreversible effects.
May cause sensitisation by inhalation and skin contact.
Contains epoxy constituents. See information supplied by the manufacturer.
?Classification system:
The classification was made according to the latest editions of international substances lists, and expanded upon
from company and literature data.
?NFPA ratings (scale 0 - 4)
Health = 3
1 Fire = 1
3 0 Reactivity = 0
?HMIS-ratings (scale 0 - 4)
HEALTH *3 Health = *3
Fire = 1
FIRE 1
Reactivity = 0
REACTIVITY 0
?GHS label elements
Danger
3.4/1 - May cause allergy or asthma symptoms or breathing difficulties if inhaled.
3.8/1 - Causes damage to organs.
3.4/1 - May cause an allergic skin reaction.
Danger
3.2/1B - Causes severe skin burns and eye damage.
Warning
3.1/4 - Harmful if swallowed.
3.1/4 - Harmful if inhaled.
?Prevention:
Do not breathe dust/fume/gas/mist/vapours/spray.
Avoid breathing dust/fume/gas/mist/vapours/spray.
Wash thoroughly after handling.
Do not eat, drink or smoke when using this product.
Use only outdoors or in a well-ventilated area.
Contaminated work clothing should not be allowed out of the workplace.
Wear protective gloves/protective clothing/eye protection/face protection.
(Contd. on page 3)
CDN
DR
Page 3/10
Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 01/22/2008 Reviewed on 01/22/2008
Trade name: 41377 Body Sealant
(Contd. of page 2)
In case of inadequate ventilation wear respiratory protection.
?Response:
IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
IF ON SKIN: Wash with plenty of soap and water.
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
IF INHALED: If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for
breathing.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
IF exposed: Call a POISON CENTER or doctor/physician.
Immediately call a POISON CENTER or doctor/physician.
Call a POISON CENTER or doctor/physician if you feel unwell.
Specific treatment (see label).
Rinse mouth.
If skin irritation or rash occurs: Get medical advice/attention.
If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician.
Wash contaminated clothing before reuse.
?Storage:
Store locked up.
?Disposal:
Dispose of contents/container in accordance with local/regional/national/international regulations.
4 First aid measures
?General information:
Immediately remove any clothing soiled by the product.
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours
after the accident.
?After inhalation:
Supply fresh air and to be sure call for a doctor.
In case of unconsciousness place patient stably in side position for transportation.
?After skin contact: Immediately wash with water and soap and rinse thoroughly.
?After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor.
?After swallowing:
Immediately call a doctor.
Drink copious amounts of water and provide fresh air. Immediately call a doctor.
5 Fire fighting measures
?Suitable extinguishing agents: Use fire fighting measures that suit the environment.
?Protective equipment: Mouth respiratory protective device.
6 Accidental release measures
?Person-related safety precautions: Wear protective equipment. Keep unprotected persons away.
?Measures for environmental protection: Do not allow to enter sewers/ surface or ground water.
?Measures for cleaning/collecting:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
(Contd. on page 4)
CDN
DR
Page 4/10
Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 01/22/2008 Reviewed on 01/22/2008
Trade name: 41377 Body Sealant
(Contd. of page 3)
Use neutralizing agent.
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
7 Handling and storage
?Handling:
?Information for safe handling:
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
?Information about protection against explosions and fires: No special measures required.
?Storage:
?Requirements to be met by storerooms and receptacles: No special requirements.
?Information about storage in one common storage facility: Not required.
?Further information about storage conditions: Keep receptacle tightly sealed.
8 Exposure controls and personal protection
?Additional information about design of technical systems: No further data; see item 7.
?Components with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be monitored at
the workplace.
?Additional information: The lists that were valid during the creation were used as basis.
?Personal protective equipment:
?General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
?Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use
respiratory protective device that is independent of circulating air.
?Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
?Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance
of the glove material can not be calculated in advance and has therefore to be checked prior to the application.
?Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be
observed.
(Contd. on page 5)
CDN
DR
Page 5/10
Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 01/22/2008 Reviewed on 01/22/2008
Trade name: 41377 Body Sealant
(Contd. of page 4)
?Eye protection:
Tightly sealed goggles
9 Physical and chemical properties
?General Information
Liquid
Form:
According to product specification
Color:
Characteristic
Odor:
?Change in condition
Melting point/Melting range: Undetermined.
Boiling point/Boiling range: 261癈
121癈
?Flash point:
Product is not selfigniting.
?Auto igniting:
Product does not present an explosion hazard.
?Danger of explosion:
In use, may form flammable/explosive vapour-air mixture.
1.17 g/cm?br>
?Density at 20癈:
?Solubility in / Miscibility with
Not miscible or difficult to mix.
Water:
?Solvent content:
0.0 %
Organic solvents:
0.2 %
VOC content:
3.0 g/l / 0.03 lb/gl
99.8 %
?Solids content:
10 Stability and reactivity
?Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
?Dangerous reactions No dangerous reactions known.
?Dangerous products of decomposition: No dangerous decomposition products known.
11 Toxicological information
?Acute toxicity:
?Primary irritant effect:
?on the skin: Caustic effect on skin and mucous membranes.
?on the eye: Strong caustic effect.
?Sensitization:
Sensitization possible through inhalation.
Sensitization possible through skin contact.
(Contd. on page 6)
CDN
DR
Page 6/10
Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 01/22/2008 Reviewed on 01/22/2008
Trade name: 41377 Body Sealant
(Contd. of page 5)
?Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations:
Harmful
Corrosive
Irritant
Swallowing will lead to a strong caustic effect on mouth and throat and to the danger of perforation of esophagus
and stomach.
12 Ecological information
?General notes:
Water hazard class 2 (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Must not reach bodies of water or drainage ditch undiluted or unneutralized.
Danger to drinking water if even small quantities leak into the ground.
13 Disposal considerations
?Product:
?Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
?Uncleaned packagings:
?Recommendation: Disposal must be made according to official regulations.
14 Transport information
?DOT regulations:
8
?Hazard class:
UN3267
?Identification number:
III
?Packing group:
?Proper shipping name (technical name): CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S. (ALIPHATIC
AMINE (PROPRIETARY), 3-aminopropyltriethoxysilane)
8
?Label
ORM-D 49CFR ?173.154 b) Limited Quantities of Class 8
?Remarks:
?TDG (Transport dangerous goods):
8 Corrosive substances
?TDG class:
3267
?UN-Number:
III
?Packaging group:
(Contd. on page 7)
CDN
DR
Page 7/10
Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 01/22/2008 Reviewed on 01/22/2008
Trade name: 41377 Body Sealant
(Contd. of page 6)
8
?Label:
3267 CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S. (ALIPHATIC
?Description of goods:
AMINE (PROPRIETARY), 3-aminopropyltriethoxysilane)
?Maritime transport IMDG:
8
?IMDG Class:
3267
?UN Number:
8
?Label
III
?Packaging group:
F-A,S-B
?EMS Number:
No
?Marine pollutant:
CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S. (ALIPHATIC
?Propper shipping name:
AMINE (PROPRIETARY), 3-aminopropyltriethoxysilane)
?Air transport ICAO-TI and IATA-DGR:
8
?ICAO/IATA Class:
3267
?UN/ID Number:
8
?Label
III
?Packaging group:
CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S. (ALIPHATIC
?Propper shipping name:
AMINE (PROPRIETARY), 3-aminopropyltriethoxysilane)
?UN "Model Regulation": UN3267; CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S.; 8; III
15 Regulations
?Sara
?Section 355 (extremely hazardous substances):
None of the ingredient is listed.
?Section 313 (Specific toxic chemical listings):
14807-96-6 Talc (Mg3H2(SiO3)4)
107-21-1 ethanediol
?TSCA (Toxic Substances Control Act):
25068-38-6 bisphenolA(chloro)oxirane polymer
15625-89-5 2,2-bis(acryloyloxymethyl)butyl acrylate
14807-96-6 Talc (Mg3H2(SiO3)4)
13463-67-7 titanium dioxide
919-30-2 3-aminopropyltriethoxysilane
107-21-1 ethanediol
7631-86-9 silicon dioxide, chemically prepared
(Contd. on page 8)
CDN
DR
Page 8/10
Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 01/22/2008 Reviewed on 01/22/2008
Trade name: 41377 Body Sealant
(Contd. of page 7)
21645-51-2 aluminium hydroxide
64-17-5 ethanol
?Proposition 65
?Chemicals known to cause cancer:
25068-38-6 bisphenolA(chloro)oxirane polymer
ACRYLATE ESTERS (PROPRIETARY)
107-21-1 ethanediol
?Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
?Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
?Chemicals known to cause developmental toxicity:
64-17-5 ethanol
?Cancerogenity categories
?EPA (Environmental Protection Agency)
None of the ingredients is listed.
?IARC (International Agency for Research on Cancer)
14807-96-6 Talc (Mg3H2(SiO3)4) 3
13463-67-7 titanium dioxide 3
7631-86-9 silicon dioxide, chemically prepared 3
?NTP (National Toxicology Program)
None of the ingredients is listed.
?TLV (Threshold Limit Value established by ACGIH)
14807-96-6 Talc (Mg3H2(SiO3)4) A4
13463-67-7 titanium dioxide A4
107-21-1 ethanediol A4
64-17-5 ethanol A4
?NIOSH-Ca (National Institute for Occupational Safety and Health)
13463-67-7 titanium dioxide
?OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
?Canadian substance listings:
?Canadian Domestic Substances List (DSL)
25068-38-6 bisphenolA(chloro)oxirane polymer
15625-89-5 2,2-bis(acryloyloxymethyl)butyl acrylate
14807-96-6 Talc (Mg3H2(SiO3)4)
67762-90-7 FUMED SILICA
26142-30-3 POLYMER OF EPICHLOROHYDRIN-POLYGLYCOL
13463-67-7 titanium dioxide
919-30-2 3-aminopropyltriethoxysilane
107-21-1 ethanediol
7631-86-9 silicon dioxide, chemically prepared
(Contd. on page 9)
CDN
DR
Page 9/10
Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 01/22/2008 Reviewed on 01/22/2008
Trade name: 41377 Body Sealant
(Contd. of page 8)
51274-00-1 YELLOW IRON OXIDE
21645-51-2 aluminium hydroxide
64-17-5 ethanol
?Canadian Ingredient Disclosure list (limit 0.1%)
None of the ingredients is listed.
?Canadian Ingredient Disclosure list (limit 1%)
None of the ingredients is listed.
?Product related hazard informations:
The product has been classified and marked in accordance with directives on hazardous materials.
?Hazard symbols:
Toxic
?Hazard-determining components of labelling:
ALIPHATIC AMINE (PROPRIETARY)
bisphenolA(chloro)oxirane polymer
2,2-bis(acryloyloxymethyl)butyl acrylate
ACRYLATE ESTERS (PROPRIETARY)
?Risk phrases:
Harmful by inhalation and if swallowed.
Causes burns.
Irritating to respiratory system.
Danger of very serious irreversible effects.
May cause sensitisation by inhalation and skin contact.
?Safety phrases:
Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
Wear suitable protective clothing, gloves and eye/face protection.
In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
This material and its container must be disposed of as hazardous waste.
?Special labeling of certain preparations:
Contains epoxy constituents. See information supplied by the manufacturer.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
?Department issuing MSDS: Environment protection department.
?Contact: Steve Gaver
?Abbreviations and acronyms:
ADR: Accord europ閑n sur le transport des marchandises Dangereuses par Route (European Agreement concerning the International
Carriage of Dangerous Goods by Road)
RID: Reglement internationale concernent le transport des merchandises dangereuses par chemin de fer (Regulations Concerning the
International Transport of Dangerous Goods by Rail)
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
IATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA)
ICAO: International Civil Aviation Organization
ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO)
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
(Contd. on page 10)
CDN
DR
Page 10/10
Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 01/22/2008 Reviewed on 01/22/2008
Trade name: 41377 Body Sealant
(Contd. of page 9)
ACGIH: American Conference of Governmental Industrial Hygienists
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
WHMIS: Workplace Hazardous Materials Information System (Canada)
GefStoffV: Gefahrstoffverordnung (Ordinance on Hazardous Substances, Germany)
VOC: Volatile Organic Compounds (USA, EU)
CDN
DR
|