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MSDS Material Safety Data Sheet
CAS

108-01-0 460-73-1 107-21-1 123-91-1 75-21-8

File Name: 108-01-0_460-73-1_107-21-1_123-91-1_75-21-8.asp

                              Material Safety Data Sheet

FL 2000 - Polyol
1. Substance/preparation and company identification

Company 24 Hour Emergency Response Information
LaPolla Coatings, Inc. CHEMTREC: (800) 424 -9300
15402 Vantage Parkway E #322 (800) 888-3342
Houston, Texas 77032

Chemical family: resin
Synonyms: Urethane System Resin Component


2. Composition/information on ingredients

CAS Number Content (W/W) Chemical name
< 85.0 % Polyol
< 7.0 % Flame Retardant
108-01-0 < 5.0 % 2-dimethylaminoethanol
< 2.0 % Surfactant
< 5.0 % Catalyst
460-73-1 < 10.0 % 1,1,1,3,3-pentafluoropropane

3. Hazard identification

Emergency overview

CAUTION: MAY CAUSE EYE, SKIN AND RESPIRATORY TRACT IRRITATION.
CORROSIVE TO SKIN.
SEVERELY IRRITATING TO EYES, SKIN, RESPIRATORY TRACT.
SENSITIZER.

Potential health effects

Primary routes of exposure
Routes of entry for solids and liquids include eye and skin contact, ingestion and inhalation. Routes of entry
for gases include inhalation and eye contact. Skin contact may be a route of entry for liquified gases.

Acute toxicity:
Ingestion may cause gastrointestinal disturbances.
Information on: Fluorocarbons
At levels above the recommended exposure limit, the fluorocarbon acts as a weak narcotic. Acute
overexposure causes tremors, confusion, irritation, suffocation, and may result in cardiac
sensitization.

Information on: Dimethylaminoethanol
Dimethylaminoethanol is extremely irritating to the skin and eyes. Direct contact with the liquid is
corrosive. Acute inhalation exposures at high concentrations have been known to produce
respiratory difficulties, loss of coordination and decreased motor activity in rats.




MSDS ?FL 2000 Polyol 1
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Cont'd

Irritation:
Irritating to respirator y system.
Information on: Polyol
Contact with the eyes and skin may result in irritation.
Information on: Dimethylaminoethanol
Contact with dimethylaminoethanol may result in severe irritation. Burns and permanent injury may
result.

Repeated dose toxicity:
No other known chronic effects.
Information on: Dimethylaminoethanol
Repeated skin contact with dimethylaminoethanol may result in sensitization. Repeated inhalation
has been known to produce effects on the eyes and nasal mucosa as well as respiratory and
olfactory lesions in experimental animals. Exposure to dimethylaminoethanol has been associated
with visual and ocular changes and is reversible upon significantly reduced or ceased exposure.

4. First-aid measures

General advice:
Remove contaminated clothing.

If inhaled:
Remove the affected individual into fresh air and keep the person calm. Assist in breathing if necessary.
Immediate medical attention required.

If on skin:
Wash affected areas thoroughly with soap and water. Immediate medical attention required.

If in eyes:
In case of contact with the eyes, rinse immediately for at least 15 minutes with plenty of water. Immediate
medical attention required.

If swallowed:
Rinse mouth and then drink plenty of water. Induce vomiting. Never induce vomiting or give anything by
mouth if the victim is unconscious or having convulsions. Immediate medical attention required.

5. Fire-fighting measures

Flash point: > 200 癈 (closed cup)
Autoignition: No data available.

Suitable extinguishing media:
water, dry extinguishing media, carbon dioxide, foam

Hazards during fire-fighting:

No particular hazards known.

Protective equipment for fire-fighting:
Firefighters should be equipped with self-contained breathing apparatus and turn-out gear.




MSDS ?FL 2000 Polyol 2
MSDS- FL 2000 - Polyol
Cont'd

6. Accidental release measures

Cleanup:
Spills should be contained, solidified, and placed in suitable containers for disposal.


7. Handling and storage

Handling

General advice:
Product should not be mixed with air above atmospheric pressure for leak testing or any other purpose. Use
dry nitrogen to transfer or leak test equipment pressurized with product.

Protection against fire and explosion:
No explosion proofing necessary.

Storage

General advice:
Product that is frozen and/or tending to sedimentation can be liquified or homogenized by careful application
of indirect heat (do not use flames or direct contact with a heat source). Protect from direct sunlight. Keep in
a cool, well-ventilated place. Avoid extreme heat. Store protected against freezing. Stored and transported in
a cylinder under pressure. Must not be repacked by the customer.

Storage stability:
Storage temperature: 70 - 80 癋
Protect against moisture. Store in unopened original containers in a cool and dry place.


8. Exposure controls and personal protection

Advice on system design:
Provide local exhaust ventilation to control vapours/mists.

Personal protective equipment

Respiratory protection:
Wear a NIOSH-certified (or equivalent) organic vapour/particulate respirator as needed.

Hand protection:
Chemical resistant protective gloves

Eye protection:
Wear face shield or tightly fitting safety goggles (chemical goggles) if splashing hazard exists.

General safety and hygiene measures:
Avoid contact with skin. Handle in accordance with good industrial hygiene and safety practice. Wear
protective clothing as necessary to prevent contact. Avoid inhalation of vapours/mists. Wash soiled clothing
immediately.




MSDS ?FL 2000 Polyol 3
MSDS- FL 2000 - Polyol
Cont'd

9. Physical and chemical properties

Form: liquid
Odour: amine-like
Colour: brown
pH value: >= 7
Bulk density: 9.60 - 9.83 lb/USg ( 25 癈)
Viscosity, dynamic: 800 - 1,000 mPa.s ( 23 癈)
Miscibility with water: slightly soluble


10. Stability and reactivity

Conditions to avoid:
> 80 degrees Fahrenheit
Avoid moisture. Avoid direct sunlight. Avoid excessive temperatures.

Hazardous reactions:
The product is chemically stable.

Decomposition products:
Hazardous decomposition products: carbon monoxide, Carbon dioxide

Thermal decomposition:
No data available.


11. Toxicological information

12. Ecological information

13. Disposal considerations

Waste disposal of substance:
Incinerate in a licensed facility.
Dispose of in a licensed facility.
Do not discharge substance/product into sewer system.

Container disposal:
Steel drums must be emptied and can be sent to a licensed drum reconditioner for reuse, a scrap metal
dealer or an approved landfill. Refer to 40 CFR ?261.7 (residues of hazardous waste in empty containers).
Decontaminate containers prior to disposal. Recommend crushing, puncturing or other means to prevent
unauthorized use of used containers.


14. Transport information

Reference Bill of Lading




MSDS ?FL 2000 Polyol 4
MSDS- FL 2000 - Polyol
Cont'd

15. Regulatory information

Federal Regulations

Registration status:
TSCA, US released / listed
TSCA 12B released / listed
No data available.
OSHA hazard category:

CERCLA RQ CAS Number Chemical name
5,000 LBS 107-21-1 ethylene glycol
100 LBS 123-91-1 1,4-dioxane
10 LBS 75-21-8 Ethylene Oxide

SARA hazard categories (EPCRA 311/312): Not hazardous

State regulations

CA Prop. 65:
THIS PRODUCT CONTAINS A CHEMICAL(S) KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER AND BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.


16. Other information

HMIS III rating
Health: 1 Flammability: 1 Physical hazard: 1

HMIS uses a numbering scale ranging from 0 to 4 to indicate the degree of hazard. A value of zero means that the
substance possesses essentially no hazard; a rating of four indicates high hazard.

Local contact information
1-877-6-FOAM-IT


IMPORTANT: WHILE THE DESCRIPTIONS, DESIGNS, DATA AND INFORMATION CONTAINED HEREIN
ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE , IT IS PROVIDED FOR YOUR
GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT PROCESSING OR APPLICATION/USE,
WE RECOMMEND THAT YOU MAKE TESTS TO DETERMINE THE SUITABILITY OF A PRODUCT FOR
YOUR PARTICULAR PURPOSE PRIOR TO USE. NO WARRANTIES OF ANY KIND, EITHER
EXPRESSED OR IMPLIED, INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A
PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED OR DESIGNS, DATA OR
INFORMATION SET FORTH, OR THAT THE PRODUCTS, DESIGNS, DATA OR INFORMATION MAY BE
USED WITHOUT INFRINGING THE INTELLECTUAL PROPERTY RIGHTS OF OTHERS. IN NO CASE
SHALL THE DESCRIPTIONS, INFORMATION, DATA OR DESIGNS PROVIDED BE CONSIDERED A
PART OF OUR TERMS AND CONDITIONS OF SALE. FURTHER, YOU EXPRESSLY UNDERSTAND AND
AGREE THAT THE DESCRIPTIONS, DESIGNS, DATA, AND INFORMATION FURNISHED BY FOAM
ENTERPRISES LLC HEREUNDER ARE GIVEN GRATIS AND FOAM ENTERPRISES LLC ASSUMES NO
OBLIGATION OR LIABILITY FOR THE DESCRIPTION, DESIGNS, DATA AND INFORMATION GIVEN OR
RESULTS OBTAINED, ALL SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK.
END OF DATA SHEET




MSDS ?FL 2000 Polyol 5

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