MATERIAL SAFETY DATA SHEET
MATERIAL IDENTITY: -35癋 Splash Ultimate Windshield Washer Fluid
SECTION 1 - MANUFACTURER'S INFORMATION
Manufacturer: SuperClean Brands, Inc. Telephone: (651) 489-8211
51 East Maryland Avenue
St. Paul, MN 55117-4615 Facsimile: (651) 489-8247
Transportation Emergency (for immediate information about a chemical or to seek assistance from a
manufacturer): 1-800-535-5053
Date Updated: December 12, 2007
SECTION 2 - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION
Common Name: Windshield Washer Fluid Product Use: Used for cleaning windshields
Product Identification: Windshield Washer Fluid
NFPA HAZARD RATINGS
HEALTH - 1
FLAMMABILITY - 3
REACTIVITY - 0
OTHER - NOT APPLICABLE
Hazardous Component * Approxima OSHA NIOSH REL ACGIH Threshold IDLH
te Permissible Limit Value (NIOSH)
Compositi Exposure
on Limit **
3
Methanol (Methyl Alcohol) 34 percent 200 ppm (260 200 ppm (260 200 ppm (260 mg/m ) 6,000 ppm
3) 3
- CAS 67-56-1 (by weight) mg/m 8-hour mg/m ) 8-hour 8-Hour TWA (0.6 percent
- UN 1230 (DOT Guide 28) TWA (Skin) TWA in air)
3
250 ppm (310 mg/m )
250 ppm (310 Short-term Exposure
3
mg/m ) Ceiling Limit (15-minute
(Skin) TWA)
(Skin)
3 3
Ethelene Gylcol <3% 50 ppm (125 mg/m ) 50 ppm (125 mg/m )
- CAS 107-21-1 (by weight)
3 3
100 ppm mg/m 100 ppm mg/m
*With the exception of ethylene oxide, the hazardous components listed are not a known or suspected human carcinogen as listed or
determined by the National Agency for Research on Cancer, National Toxicological Program "NTP Seventh Annual Report on Carcinogens," or
International Agency for Research on Cancer (IARC) monograph reviews. In addition, they are not considered a carcinogen by the
Occupational Safety and Health Administration (OSHA) or the National Institute for Occupational Safety and Health (NIOSH).
th
Ethylene oxide is listed as a carcinogen by OSHA, NIOSH, the ACGIH, and the NTP 7 Annual Report on Carcinogens. International Agency
for Research on Cancer (IARC) Review: Group 2A IMEMDT 7,205,87; Animal Inadequate Evidence IMEMDT 11,157,76; Human Inadequate
Evidence IMEMDT 36,189,85; Animal Sufficient Evidence IMEMDT 36,189,85. Community Right-To-Know List. EPA Extremely Hazardous
Substances List. Reported to EPA TSCA Inventory. EPA Genetic Toxicology Program.
**This MSDS contains the 1989 PEL's and from the June 1993 Air Contaminants Final Rule, specified in Tables Z-1, Z-2, and Z-3 (Federal
Register; 58(124):35338-35351; June 30, 1993).
MSDS -35癋 Splash Ultimate Windshield Washer Fluid Page 1 of 4
MATERIAL SAFETY DATA SHEET
MATERIAL IDENTITY: -35癋 Splash Ultimate Windshield Washer Fluid
SECTION 3 - PHYSICAL/CHEMICAL CHARACTERISTICS
o o
Boiling Point: Approximately 170 F (for product) Flash Point: 90 F
o
Solubility in Water: Soluble Vapor Pressure: 100mm @ 21.2 (methanol)
Vapor Density: 1.11 (methanol) Ionization Potential: 10.84 eV (methanol)
o
Freezing Point: -35 F
Appearance and Odor: The windshield washer is purple, and it has a mild characteristic pungent odor from the
methanol. The odor threshold for methanol is 10 ppm.
SECTION 4 - FIRE AND EXPLOSION HAZARD DATA
Flammable Limits: UEL - 36 percent for methanol LEL - 6 percent for methanol
o
Autoignition Temperature: 878 F for methanol
Extinguishing Media for Methanol:
Small Fires: Dry chemical, carbon dioxide, water spray or alcohol resistant foam.
Large Fires: Water spray, fog or alcohol-resistant foam.
Special Fire Fighting Procedures: Move container away from fire area if you can do so without risk. Dike fire
control water for later disposal; do not scatter the material. Apply cooling water to the sides of containers exposed
to flames until well after the fire is out.
Unusual Fire and Explosion Hazards for Methanol: Flammable/combustible material; may be ignited by heat,
spark or flame. Vapors may travel to a source of ignition and flash back. Container may explode in heat of fire.
Vapor explosion and poison hazard indoors, outdoors, or in sewers. Runoff to sewer may create fire or explosion
hazard.
SECTION 5 - REACTIVITY DATA
Stability/Polymerization: In a closed container, methyl alcohol is stable at room temperature and it is stable
under routine handling and storage. Hazardous polymerization will not occur.
Incompatibility (Material to Avoid): Incompatible with beryllium dihydride; metals; oxidants; potassium tert-
butoxide; carbon tetrachloride + metals; dichloromethane. Can react vigorously with oxidizing materials. Explosive
reaction with chloroform + sodium methoxide; diethyl zinc. Violent reaction with alkyl aluminum salts; acetyle
bromide; chloroform + sodium hydroxide; CrO3; cyanuric chloride; (I + ethanol + HgO); Pb(CIO4)2; HCIO4; P2O3;
1
(KOH + CHC12); nitric acid.
Hazardous Decomposition or By-products: When methanol is heated to decomposition, carbon dioxide and
carbon monoxide may be produced, as well as formaldehyde may be produced, and it emits acrid smoke and
irritating fumes.
1
Lewis, Richard J., Sr.: Sax's Dangerous Properties of Industrial Materials, Eighth Edition. New York,
New York: Van Nostrand Reinhold, 1992.
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MATERIAL SAFETY DATA SHEET
MATERIAL IDENTITY: -35癋 Splash Ultimate Windshield Washer Fluid
SECTION 6 - HEALTH HAZARD DATA
Routes of Entry (Methanol): The primary routes of entry are inhalation, ingestion, and absorption.
Health Hazards and Signs and Symptoms of Exposure (Methanol): Irritant to eyes, skin, and upper respiratory
system. Headaches, drowsiness, dizziness, vertigo, light-headed, nausea, and vomiting. Visual disturbance, optic
nerve damage, and blindness. Skin exposure hazard.
Target Organs (Methanol): Central nervous system, digestive tract, eyes, and skin.
Acute Effects (Methanol): Eye irritation. Inhalation can result nose irritation, headache, fatigue, nausea, visual
impairment or complete and possible blindness, acidosis, convulsions, circulatory collapse, respiratory fatigue, and
death. Ingestion can cause gastrointestinal (GI) irritation followed by the symptoms described for inhalation and
possible kidney impairment. Skin contact results in a cold sensation, dryness, and cracking, possible leading to
dermatitis. Methyl alcohol may be absorbed through the skin and may cause headache, fatigue and visual
disturbances. Eye contact results in irritation with lacrimation, inflamed lids, and photophobia.
Chronic Effects (Methanol): Chronic exposure may result in visual impairment or blindness.
Medical Conditions Generally Aggravated by Exposure (Methanol): Ocular, respiratory, or dermal disorders
may be aggravated by methanol exposure.
Emergency and First Aid Procedures:
Eyes: Rinse with water 15 to 20 minutes, seek medical assistance.
Skin: Flush with water for 15 minutes.
Inhalation: Remove from source to fresh air, provide respiratory support as needed.
Ingestion: Call Physician , hospital emergency room or Poison Control Center immediately .
GET PROMPT MEDICAL ATTENTION
SECTION 7 - PRECAUTIONS FOR SAFE HANDLING AND USE
Steps to be Taken in Case Material is Released or Spilled:
?Keep unnecessary people away; isolate hazard area and deny entry.
?Stay upwind; keep out of low areas.
?Shut off ignition sources; no flares, smoking or flames in hazard area.
?Positive pressure self-contained breathing apparatus and chemical protective clothing is recommended
for personnel involved in clean-up procedures with no fire.
?Do not walk through spilled material; stop leak if it can be done without risk.
?Water spray may reduce vapor; but it will not prevent ignition in closed spaces.
Waste Disposal Method: Dispose of in accordance with federal, state and local regulations.
EPA Designations:
RCRA Hazardous Waste (40 CFR 261.33): Hazardous Waste No. U154
CERCLA Hazardous Substance (40 CFR 302.4): Not Listed
SARA Extremely Hazardous Substance (40 CFR 355): Not Listed
SARA Toxic Chemical (40 CFR 372.65): Not Listed
MSDS -35癋 Splash Ultimate Windshield Washer Fluid Page 3 of 4
MATERIAL SAFETY DATA SHEET
MATERIAL IDENTITY: -35癋 Splash Ultimate Windshield Washer Fluid
SECTION 8 - SPECIAL PROTECTION INFORMATION
Respiratory Protection: Under normal use conditions (outdoor windshield cleaning), respiratory protection is not
justified.
Protective Eye Wear: Splash goggles are recommended when handling the solution. Contact lens use is not
recommended.
Protective Clothing: The selection of protective clothing and gloves is dependent upon anticipated exposure. As
reported by the manufacturer, Best Glove style 725R (PVC) offers excellent protection for up to 240 minutes of
complete immersion
SECTION 9 - OTHER HAZARDOUS INFORMATION AND DEFINITIONS
OSHA PEL: The Occupational Safety and Health Administration's Permissible Exposure Limit, which is defined as
the maximum concentration of contaminant to which a normal healthy individual may be exposed 8-hours per day,
40-hours per week, without experiencing adverse health effects over a working lifetime.
ACGIH TLV: American Conference of Governmental Industrial Hygienist's Threshold Limit Value, similar to the
OSHA PEL but not considered a legal standard.
SECTION 10 ?TRANSPORTATION INFORMATION
DOT HAZARD DESCRIPTION:
In inner packaging not over 5 L (1.3 gallons) Consumer commodity, ORM-D
Per 49 CFR 173.150 (b) (3) & 173.150 (c)
MSDS Prepared by: Maxim Technologies, Inc.
Judgements as to the suitability herein for the user's purposes are necessarily the user's responsibility. Therefore,
although reasonable care has been taken in the preparation of such information, Maxim Technologies, Inc.,
extends no warranties, makes no representations, and assumes no responsibility as to the accuracy or suitability of
such information for application to the intended purposes or for the consequences of its use.
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