Safety data sheet in accordance with 2001/58/EC
Page 1
Antifrogen N
Substance key: SXR024717 Revision Date: 06.03.2007
Version : 1 - 35 / EU Date of printing : 06.03.2007
1. Identification of the substance/preparation and company
Trade name
Antifrogen N
Use of the substance/preparation.
Industry sector : Functional Fluids
Type of use : Brine for refrigeration
Identification of the company
Clariant Produkte (Deutschland) GmbH
CM-Deutschland
Brueningstr. 50
65929 Frankfurt am Main
Telephone no. : +49 6196 757 60
Information about the substance/preparation
Division Functional Chemicals
++49(0)69-305-2092/15315/32251
Emergency telephone number : +49 69 305 6418
2. Composition/information on ingredients
Chemical characterization
Monoethylene glycol (1,2-ethane diol) with inhibitors
Hazardous ingredients
Ethanediol
Concentration : 90 - 95 %
CAS number : 107-21-1
EINECS number : 203-473-3
Hazard symbols Xn
R phrases 22
Sodium nitrite
Concentration : < 0,5 %
CAS number : 7632-00-0
EINECS number : 231-555-9
Hazard symbols O T N
R phrases 8 25 50
Potassium nitrite
Concentration : < 0,2 %
CAS number : 7758-09-0
EINECS number : 231-832-4
Hazard symbols O T N
R phrases 8 25 50
3. Hazards identification
Harmful if swallowed.
Safety data sheet in accordance with 2001/58/EC
Page 2
Antifrogen N
Substance key: SXR024717 Revision Date: 06.03.2007
Version : 1 - 35 / EU Date of printing : 06.03.2007
4. First aid measures
General information
Remove soiled or soaked clothing immediately
After inhalation
In the event of symptoms seek medical advice.
After contact with skin
In case of contact with skin wash off immediately with plenty of water
After contact with eyes
In case of contact with eyes rinse thoroughly with plenty of water and seek medical advice
After ingestion
Summon a doctor immediately.
5. Fire-fighting measures
Suitable extinguishing media
water spray jet
alcohol-resistant foam
carbon dioxide
dry powder
Special hazards from the substance itself, its combustion products or from its vapours
In case of fires, hazardous combustion gases are formed: Carbon monoxide (CO)
Nitrous gases (NOx)
Special protective equipment for firefighting
Use self-contained breathing apparatus
6. Accidental release measures
Personal precautions
Ensure adequate ventilation.
Wear suitable personal protective equipment.
Environmental precautions
Do not allow to enter drains or waterways
Methods for cleaning up/taking up
Pick up with absorbent material (eg sand, kieselgur, acid binder, universal binder, sawdust).
Dispose of as prescribed
7. Handling and storage
Advice on safe handling
Open and handle container with care.
Provide good ventilation of working area (local exhaust ventilation if necessary).
Advice on protection against fire and explosion
Observe the general rules of industrial fire protection
Safety data sheet in accordance with 2001/58/EC
Page 3
Antifrogen N
Substance key: SXR024717 Revision Date: 06.03.2007
Version : 1 - 35 / EU Date of printing : 06.03.2007
Advice on storage compatibility
Do not store with alkalies
Do not store with strong oxidizing agents
8. Exposure controls/personal protection
Ingredients with occupational exposure limits to be monitored
ETHYLENE GLYCOL
CAS number : 107-21-1
EU. Indicative Exposure and Directives relating to the protection of risks related to work
exposure to chemical, physical, and biological agents.
EU Exposure Limit Values Data
Revision : 07 2000
Time Weighted Average (TWA):
Values: 52 mg/m3 20 ppm
ETHYLENE GLYCOL
CAS number : 107-21-1
EU. Indicative Exposure and Directives relating to the protection of risks related to work
exposure to chemical, physical, and biological agents.
EU Exposure Limit Values Data
Revision : 07 2000
Skin designation:
Can be absorbed through the skin.
General protective measures
Do not inhale vapours
Avoid contact with eyes and skin
Hygiene measures
Keep away from foodstuffs and beverages.
Use respiratory protection in case of insufficient exhaust
Respiratory protection :
ventilation or prolonged exposure
Full mask to standard DIN EN 136
Filter A (organic gases and vapours) to standard DIN EN 141
The use of filter apparatus presupposes that the environment
atmosphere contains at least 17% oxygen by volume, and
does not exceed the maximum gas concentration, usually
0.5% by volume. Relevant guidelines to be considered
include EN 136/141/143/371/372 as well as other national
regulations.
For long-term exposure:
Hand protection :
Butyl rubber gloves
Minimum breakthrough time / gloves : 480 min
Minimum thickness / gloves 0,7 mm
For short-term exposure (splash protection):
Nitrile rubber gloves.
Minimum breakthrough time / gloves : 30 min
Minimum thickness / gloves 0,4 mm
Safety data sheet in accordance with 2001/58/EC
Page 4
Antifrogen N
Substance key: SXR024717 Revision Date: 06.03.2007
Version : 1 - 35 / EU Date of printing : 06.03.2007
These types of protective gloves are offered by various
manufacturers. Please note the manufacturers?detailed
statements, especially about the minimum thickness and the
minimum breakthrough time. Consider also the particular
working conditions under which the gloves are being used.
safety glasses
Eye protection :
9. Physical and chemical properties
Form : Liquid
Colour : light yellow
Odour : perceptible
approx. -70 癈
Pourpoint :
Method : DIN 51583
approx. 170 癈 ( 1.013 mbar)
Boiling temperature :
Method : ASTM D 1120
approx. 120 癈
Flash point :
Method : DIN 51758 (closed cup)
approx. 410 癈
Ignition temperature :
Method : DIN 51794
Not applicable
Oxidizing properties :
not self-igniting
Self-ignition temperature :
3 %(V)
Lower explosion limit :
not tested.
Upper explosion limit :
not tested.
Evaporation rate :
< 0,1 mbar (20 癈)
Vapour pressure :
Method : Calculated by Syracuse.
approx. 1,14 g/cm3 (20 癈)
Density :
Method : DIN 51757
Not applicable
Bulk density :
not tested.
Vapour density in relation to
air :
(20 癈)
Solubility in water :
miscible in all proportions
fat
Soluble in ... :
not tested.
8 - 9 (20 癈, 300 g/l)
pH value :
Method : DIN EN 1262
Not applicable
Octanol/water partition
coefficient (log Pow) :
Safety data sheet in accordance with 2001/58/EC
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Antifrogen N
Substance key: SXR024717 Revision Date: 06.03.2007
Version : 1 - 35 / EU Date of printing : 06.03.2007
26 - 29 mm2/s ( 20 癈)
Viscosity (kinematic) :
Method : DIN 51562
Not applicable
Combustion number :
Further information
The product is hygroscopic.
10. Stability and reactivity
approx. 260 癈
Thermal decomposition :
Method : DSC
Hazardous reactions
Reactions with alkalies.
Reactions with oxidising agents.
11. Toxicological information
LD50 4.000 mg/kg (rat)
Acute oral toxicity :
Source : IUCLID
Information based on the main component.
not tested.
Acute inhalation toxicity :
not tested.
Acute dermal toxicity :
non-irritant
Irritant effect on skin :
slightly irritant
Irritant effect on eyes :
not tested.
Sensitization :
not tested.
Mutagenicity :
Remarks
Vapours and mists cause irritation/burns to eyes and the respiratory tract
There is a possibility of kidney damage
Poisoning affects the central nervous system
12. Ecological information
90 %
Biodegradability :
good degradability
Method : Zahn-Wellens test
LC50 1.500 mg/l (golden orfe)
Fish toxicity :
Remarks
If handled correctly it causes no disturbance in treatment plants.
13. Disposal considerations
Safety data sheet in accordance with 2001/58/EC
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Antifrogen N
Substance key: SXR024717 Revision Date: 06.03.2007
Version : 1 - 35 / EU Date of printing : 06.03.2007
Product
In accordance with local authority regulations, take to special waste incineration plant
14. Transport information
not restricted
ADR
not restricted
ADNR
not restricted
RID
not restricted
IATA
not restricted
IMDG
15. Regulatory information
Labelling in accordance with EC-Directives
hazard warning labelling compulsory
Classification according to the calculation procedure of the Dangerous Preparations Directive
(1999/45/EC).
Hazard symbols
Xn Harmful
Hazardous component(s) to be indicated on label
Ethanediol
R phrases
22 Harmful if swallowed.
S phrases
2 Keep out of the reach of children.
24/25 Avoid contact with skin and eyes.
16. Other information
Text of the R-phrases which are allocated to the ingredients/components mentioned
in section 2 of this Safety Data Sheet.
22 Harmful if swallowed.
25 Toxic if swallowed.
50 Very toxic to aquatic organisms.
8 Contact with combustible material may cause fire.
Decimal notation: "Thousands" places are identified with a dot (example: 2.000 mg/kg
means "two thousand mg/kg"). Decimal places are identified with a comma (example: 1,35
g/cm3).
The data are based on the current state of our knowledge, and are intended to describe the
product with regard to the requirements of safety. The data should not be taken to imply any
guarantee of a particular or general specification. It is the responsibility of the user of the
product to ensure to his satisfaction that the product is suitable for the intended purpose and
Safety data sheet in accordance with 2001/58/EC
Page 7
Antifrogen N
Substance key: SXR024717 Revision Date: 06.03.2007
Version : 1 - 35 / EU Date of printing : 06.03.2007
method of use. We do not accept responsibility for any harm caused by the use of this
information. In all cases, our general conditions of sale apply.
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