Material Safety Data
Sheet
1. PRODUCT AND COMPANY IDENTIFICATION
DTG TEXTILE 2 INK LIGHT Magenta
Revision date: 04/26/2005
Supplier Colman & Company, Inc. 5409
S. West Shore Blvd. Tampa, FL
33611
For non-emergency information contact: 1-800-891-1094
Emergency telephone number
Non-Emergency / Colman & Co 1-800-891-1094 (9am-5pm M-F, USA -
EST)
Emergency / CHEMTREC 1-800-424-9300 (24 hours, USA)
2. COMPOSITION/INFORMATION ON INGREDIENTS
Component CAS-No. Concentration
Acrylic polymer(s) Not Hazardous 5.0 - 8.0%
C.I. Pigment Red 122 980-26-7 0.5 - 2.0%
Residual monomers Not Required < 500.0PPM
Aqua ammonia 1336-21-6 <= 0.2%
Ammonium Nitrate 6484-52-2 0.1 - 2.0%
Anionic / nonionic surfactant(s) Trade Secret 1.0 - 2.0%
Pyrrolidone 616-45-5 8.0 - 10.0%
Diethylene glycol 111-46-6 10.0 - 13.0%
Water 7732-18-5 66.0 - 69.0%
3. HAZARDS IDENTIFICATION
Emergency Overview
Appearance
Form Translucent liquid
Colour Magenta
Odour ammonia
Hazard Summary Warning! Inhalation of vapor or mist can cause headache, nausea and
irritation of the nose, throat and lungs. Causes severe eye irritation. Prolonged or repeated
overexposure to the solvent(s) in this material can cause the following: liver damage kidney
damage embryofetotoxic effects
Potential Health Effects
Primary Routes of Entry: Inhalation Eye contact Skin contact
Eyes: Direct contact with material can cause the following:
severe irritation
tearing
reddening
Skin: Material can cause the following:
slight irritation
Ingestion: Material is possibly harmful if swallowed.
Material can cause the following:
abdominal pain
vomiting
nausea
depression
diarrhea
gastrointestinal irritation
dizziness
Inhalation: Inhalation of solvent vapor or mist can cause the following:
irritation of nose, throat, and lungs
headache
nausea
Chronic Exposure: Prolonged or repeated overexposure to the solvent(s) in this material can
cause the following:
kidney damage
liver damage
embryofetotoxic effects
4. FIRST AID MEASURES
Inhalation: Move to fresh air. Give artificial respiration if breathing has stopped. Consult a
physician.
Skin contact: Wash with water and soap as a precaution. If skin irritation persists, call a
physician. Wash contaminated clothing before reuse.
Eye contact: Immediately flush eye(s) with plenty of water. Get prompt medical attention.
Ingestion: Drink 1 or 2 glasses of water. Consult a physician. Never give anything by mouth to
an unconscious person. If vomiting occurs spontaneously, keep airway clear.
5. FIRE-FIGHTING MEASURES
Flash point Noncombustible
Lower explosion limit not applicable
Upper explosion limit not applicable
Thermal decomposition Combustion generates toxic fumes of the following:, nitrogen oxides
(NOx), Carbon oxides
Suitable extinguishing media: Use the following extinguishing media when fighting fires
involving this material: polar solvent (alcohol) foam water spray dry chemical carbon dioxide
(CO2)
Specific hazards during fire fighting: Dried product can burn. Material can splatter above
100C/212F.
Special protective equipment for fire-fighters: Wear self-contained breathing apparatus and
protective suit.
Further information: Remain upwind.
Avoid breathing smoke.
Use water spray to cool unopened containers.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions
Appropriate protective equipment must be worn when handling a spill of this material. See
SECTION 8, Exposure Controls/Personal Protection, for recommendations.
If exposed to material during clean-up operations, see SECTION 4, First Aid Measures, for
actions to follow.
Methods for cleaning up
Keep spectators away.
Floor may be slippery; use care to avoid falling.
Avoid breathing vapor.
Ventilate the area.
Contain spills immediately with inert materials (e.g., sand, earth).
Transfer liquids and solid diking material to separate suitable containers for recovery or disposal.
CAUTION: Keep spills and cleaning runoff out of municipal sewers and open bodies of water.
7. Handling and storage
Handling
Keep from freezing - product stability may be affected. Avoid contact with skin, eyes and
clothing. Wash thoroughly after handling. Keep container tightly closed. Store in a cool, dry, well
ventilated place.
Storage
Storage temperature: 5 - 25 癈 (41 - 77 癋)
Other data: NOTE: Formaldehyde will be generated under acidic conditions. Maintain adequate
ventilation under these conditions to prevent exposure to formaldehyde above the Rohm and
Haas Co. recommended ceiling of 0.3 ppm.
Further information:
Monomer vapors can be evolved when material is heated during processing operations. See
SECTION 8, for types of ventilation required.
Improper disposal or re-use of this container may be dangerous and illegal. Refer to applicable
local, state and federal regulations.
Dispose empty container in a sanitary landfill or by incineration as allowed by state and local
authorities.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure limit(s)
Exposure limits are listed below, if they exist.
Component Regulation Type of listing Value
Aqua ammonia DTG TWA 25 ppm
DTG STEL 35 ppm
ACGIH TWA 17 mg/m3
25 ppm
ACGIH STEL 24
mg/m3 35 ppm
OSHA_TRANS PEL 35
mg/m3 50 ppm
Component Regulation Type of listing Value
Pyrrolidone DTG TWA 40 ppm
DTG STEL 120 ppm
Component Regulation Type of listing Value
Diethylene glycol DTG TWA 84 mg/m3
Eye protection: Use chemical splash goggles (ANSI Z87.1 or approved equivalent). Eye
protection worn must be compatible with respiratory protection system employed.
Hand protection: Chemical-resistant gloves should be worn whenever this material is handled.
The glove(s) listed below may provide protection against permeation. (Gloves of other chemically
resistant materials may not provide adequate protection): Neoprene gloves Gloves should be
removed and replaced immediately if there is any indication of degradation or chemical
breakthrough. Rinse and remove gloves immediately after use. Wash hands with soap and
water.
Skin and body protection: Use chemically resistant apron or other impervious clothing to avoid
prolonged or repeated skin contact.
Respiratory protection: A respiratory protection program meeting OSHA 1910.134 and ANSI
Z88.2 requirements or equivalent must be followed whenever workplace conditions warrant a
respirator's use. None required if airborne concentrations are maintained below the exposure
limit listed in Exposure Limit Information. Up to 10 times the exposure limit: Wear a properly
fitted NIOSH approved (or equivalent) half-mask, air-purifying respirator. Up to 1000 ppm organic
vapor: Wear a properly fitted NIOSH approved (or equivalent) full-facepiece, air-purifying
respirator, OR full-facepiece, airline respirator in the pressure demand mode. Above 1000 ppm
organic vapor or Unknown: Wear a properly fitted NIOSH approved (or equivalent) self-contained
breathing appartus in the pressure demand mode, OR full-facepiece, airline respirator in the
pressure demand mode with emergency escape provision. Air-purifying respirators should be
equipped with NIOSH approved (or equivalent) organic vapor cartridges and R95 or P95 filters.
Protective measures: Facilities storing or utilizing this material should be equipped with an
eyewash facility and a safety shower.
Engineering measures: Use local exhaust ventilation with a minimum capture velocity of 100
ft/min. (0.5 m/sec.) at the point of vapor evolution. Refer to the current edition of Industrial
Ventilation: A Manual of Recommended Practice published by the American Conference of
Governmental Industrial Hygienists for information on the design, installation, use, and
maintenance of exhaust systems.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
Form Translucent liquid
Colour Magenta
Odour ammonia
pH 7.5 - 9.5
Boiling point/range 100 癈 (212.00 癋) Water
Melting point/range 0 癈 (32 癋) Water
Flash point Noncombustible
Lower explosion limit not applicable
Upper explosion limit not applicable
Vapour pressure 17.0 mmHg at 20 癈 (68.00 癋) Water
Vapour pressure 22.6648 Pa at 20 癈 (68.00 癋) Water
Relative vapour density <1.0Water
Water solubility Dilutable
Relative density 0.95 - 1.05
Viscosity, dynamic 2.200 - 4.000 mPa.s
Viscosity, dynamic 2.200 - 4.000 mPa.s
Evaporation rate <1.00 Water
Percent volatility 66 - 69 % water
NOTE: The physical data presented above are typical values and should not be construed as a
specification.
10. STABILITY AND REACTIVITY
Hazardous reactions This material is considered stable. However, avoid temperatures above
177C/350F, the onset of polymer decomposition. Thermal decomposition is dependent on time
and temperature.
Materials to avoid Avoid contact with acids, alkalies and strong oxidizing agents.
Hazardous decomposition products Thermal decomposition may yield acrylic monomers.,
polymerization Product will not undergo polymerization.
11. TOXICOLOGICAL INFORMATION
The following toxicological data shown are those obtained from tests on products of similar
composition.
Skin irritation rabbit slight irritation
Sensitization Patch test on human volunteers did not demonstrate sensitization properties.
Component: Aqua ammonia
Acute oral toxicity LD50 rat 350 mg/kg
Component: Aqua ammonia
Acute oral toxicity LDLo human 43 mg/kg
Component: Ammonium Nitrate
Acute oral toxicity LD50 rat 2,217 mg/kg
Component: 2,2'-oxybisethanol diethylene glycol
Acute oral toxicity LD50 rat 10,000 mg/kg
Component: 2,2'-oxybisethanol diethylene glycol
Acute dermal toxicity LD50 rabbit 10,000 mg/kg
12. ECOLOGICAL INFORMATION
There is no data available for this product.
2,2'-oxybisethanol diethylene glycol
Ecotoxicity effects
Toxicity to fish LC50 >100 mg/l
Toxicity to aquatic invertebrates EC50 Daphnia magna 100 mg/l
13. DISPOSAL CONSIDERATIONS
Disposal
Waste Classification: When a decision is made to discard this material as supplied, it does not
meet RCRA's characteristic definition of ignitability, corrosivity, or reactivity, and is not listed in 40
CFR 261.33. The toxicity characteristic (TC), however, has not been evaluated by the Toxicity
Characteristic Leaching Procedure (TCLP).
Incinerate liquid and contaminated solids in accordance with local, state, and federal regulations.
14. TRANSPORT INFORMATION
DOT
Not regulated for transport
IMO/IMDG
Not regulated (Not dangerous for transport)
Transportation classifications may vary by container volume and may be influenced by regional or
country variations in regulations
15. REGULATORY INFORMATION
Workplace Classification
This product is considered hazardous under the OSHA Hazard Communication Standard (29
CFR 1910.1200).
This product is a 'controlled product' under the Canadian Workplace Hazardous Materials
Information System (WHMIS).
SARA Title III: Section 311/312 Categorizations (40CFR370): Chronic Health Hazard
Acute Health Hazard
SARA Title III: Section 313 Information (40CFR372)
This product does not contain a chemical which is listed in Section 313 at or above de minimis
concentrations.
CERCLA Information (40CFR302.4)
Releases of this material to air, land, or water are not reportable to the National Response Center
under the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA)
or to state and local emergency planning committees under the Superfund Amendments and
Reauthorization Act (SARA) Title III Section 304.
US. Toxic Substances Control Act (TSCA) All components of this product are in
compliance with the inventory listing requirements of the U.S. Toxic Substances Control Act
(TSCA) Chemical Substance Inventory.
Pennsylvania
Any material listed as "Not Hazardous" in the CAS REG NO. column of SECTION 2,
Composition/Information On Ingredients, of this MSDS is a trade secret under the provisions of
the Pennsylvania Worker and Community Right-to-Know Act.
California (Proposition 65)
This product contains trace levels of a component or components known to the state of California
to cause cancer:
Components: Acrylonitrile 107-13-1
Ethyl acrylate 140-88-5
16. OTHER INFORMATION
Hazard Rating
Health Fire Reactivity
2* 0 0
HMIS
Legend
ACGIH American Conference of Governmental Industrial Hygienists
BAc Butyl acetate
OSHA Occupational Safety and Health Administration
PEL Permissible Exposure Limit
STEL Short Term Exposure Limit (STEL):
TLV Threshold Limit Value
TWA Time Weighted Average (TWA):
| Bar denotes a revision from prior MSDS.
The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information given is designed only as a
guidance for safe handling, use, processing, storage, transportation, disposal and release and is
not to be considered a warranty or quality specification. The information relates only to the
specific material designated and may not be valid for such material used in combination with any
other materials or in any process, unless specified in the text.
Version: 1.6
Print Date: 04/27/2005
Layout 371379
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