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MATERIAL SAFETY DATA SHEET
Date Issued: 11/08/2006
MSDS No: F-80 PART B
Date-Revised: 02/09/2010
Revision No: 1
F-80 PART B
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: F-80 PART B
GENERAL USE: Polyurethane curing agent
CHEMICAL FAMILY: Aromatic diamine-glycol mixture
MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS
CHEMTREC (US Transportation): (800) 424-9300
BJB Enterprises, Inc.
14791 Franklin Avenue or (703) 527-3887
Tustin, CA 92780
Customer Service Number: (714) 734-8450
Fax: (714) 734-8929
2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
PHYSICAL APPEARANCE AND ODOR: Pale yellow viscous liquid with a slight sulfur odor.
IMMEDIATE CONCERNS: Avoid eye and skin contact. Avoid breathing vapors. May cause eye and skin irritation. Use in well
ventilated areas.
POTENTIAL HEALTH EFFECTS
EYES: May cause irritation.
SKIN: May cause irritation and possible allergic sensitivity with repeated contact.
INGESTION: Slightly hazardous in case of ingestion.
INHALATION: May result in respiratory irritation.
MEDICAL CONDITIONS AGGRAVATED: No data is available.
ROUTES OF ENTRY: Eye and skin contact, inhalation of vapors, or accidental ingestion.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name Wt.% CAS
Polyether polyol mixture 80 - 100 Proprietary
Di-(methylthio)toluenediamine 5 - 10 106264-79-3
Phenyl mercuric neodecanoate (35% as Hg) 0.1033 26545-49-3
Acrylonitrile 0.002 107-13-1
4. FIRST AID MEASURES
EYES: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15
minutes. Consult a physician.
SKIN: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical attention if symptoms
occur. Wash clothing before reuse.
INGESTION: If swallowed, call a physician immediately. Remove stomach contents by gastric suction or induce vomiting only as
directed by medical personnel. Never give anything by mouth to an unconscious person.
INHALATION: Remove to fresh air. If not breathing, give artificial respiration or give oxygen by trained personnel. Seek
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F-80 PART B
immediate medical attention.
NOTES TO PHYSICIAN: Symptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be
monitored for at least 48 hours.
5. FIRE FIGHTING MEASURES
FLASHPOINT AND METHOD: 107癈 (225癋) Pensky-Martens CC
EXTINGUISHING MEDIA: Water spray, carbon dioxide, dry chemical, or foam.
FIRE FIGHTING PROCEDURES: Cool fire exposed containers with water spray. Remove containers from the fire area if
possible. Do not release runoff from fire control methods to sewers or waterways.
FIRE FIGHTING EQUIPMENT: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and
consider use of unmanned hose holders or monitor nozzles for fighting large fires.
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide, nitrogen oxides and sulfur.
6. ACCIDENTAL RELEASE MEASURES
SMALL SPILL: Evacuate the area. Clean-up should only be performed by trained personnel. People dealing with a major spill
should wear full protective clothing including appropriate respiratory protection. Prevent product spill from entering sewers or
waterways. Neutralize small spills with a decontaminant.
LARGE SPILL: Contain and absorb large spills onto an inert, non-flammable adsorbent carrier (such as earth or sand). Shovel into
open-top drums or plastic bags for further decontamination, if necessary. Wash the spill area clean with a liquid decontaminant.
Remove and properly dispose of residues. Notify applicable government authorities if release is reportable. (See CERCLA in
Section 15).
RELEASE NOTES: US regulations require reporting spills of this material that could reach any surface waters. The toll free
number for the US Coast Guard National Response Center is (800) 424-8802.
7. HANDLING AND STORAGE
GENERAL PROCEDURES: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing
vapor over open containers. Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
HANDLING: Use appropriate personal protective equipment as specified in Section 8. Handle in a well ventilated area. Handle and
use in a manner consistent with good industrial/manufacturing techniques and practices.
STORAGE: Store in a cool, dry place, away from excessive heat, in original or similar container. Avoid unnecessary contact.
Protect from freezing. Containers should be tightly sealed to prevent contamination with foreign materials.
SHELF LIFE: 6 months from date of shipment under manufacturers recommended storage conditions.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
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F-80 PART B
EXPOSURE GUIDELINES
OSHA HAZARDOUS COMPONENTS (29 CFR1910.1200)
EXPOSURE LIMITS
OSHA PEL ACGIH TLV SupplierOEL
mg/m3 mg/m3 mg/m3
Chemical Name ppm ppm ppm
TWA NE NE NE NE NE NE
Polyether polyol mixture
STEL NE NE NE NE NE NE
TWA NE NE NE NE NE NE
Di-(methylthio)toluenediamine
STEL NE NE NE NE NE NE
TWA NE NE NE NE NE NE
Phenyl mercuric neodecanoate (35% as Hg)
STEL NE NE NE NE NE NE
[1] [1]
TWA 10 25 10 25 1 2.17
Acrylonitrile
STEL NE NE NE NE NE NE
OSHA TABLE COMMENTS:
1. NIOSH REL
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne
levels below recommended exposure limits.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection
to protect against possible splashing or spraying of material. ANSI Z87.1 or approved equivalent.
SKIN: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be used to prevent
contact with eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer
maximum protection.
RESPIRATORY: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH
approved) may be necessary for certain applications. Consider the type of application, environmental concentrations, and other
materials being used concurrently when determining respirator use and selection. Observe OSHA regulations for respirator use
(29 CFR 1910.134).
PROTECTIVE CLOTHING: Protective clothing should be selected and used in accordance with 'Guidelines for the Selection
of Chemical Protective Clothing' published by ACGIH.
WORK HYGIENIC PRACTICES: Contaminated clothing should be changed and washed before reuse. Eating, drinking and
smoking in immediate work area should be prohibited. Wash hands before eating.
OTHER USE PRECAUTIONS: Facilities storing or utilizing this material should be equipped with an eyewash facility and a
safety shower. Training is important. Follow all label precautions.
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: Viscous liquid
ODOR: Slight sulfur
APPEARANCE: Opaque
COLOR: Pale yellow
pH: < 8
PERCENT VOLATILE: 1
VAPOR PRESSURE: < 0.1 mmHg at 20癈 (68癋)
VAPOR DENSITY: Not Established
BOILING POINT: Not Established
FLASHPOINT AND METHOD: 107癈 (225癋) Pensky-Martens CC
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F-80 PART B
SPECIFIC GRAVITY: 1.060 (water=1) at 25癈 (77癋)
VISCOSITY: 2000 Centipoise at 25癈 (77癋)
VOC (Volatile Organic Compound): 10.600 g/l Calculated. Theoretical VOC minus water and exempt solvents.
10. STABILITY AND REACTIVITY
STABILITY: This product is stable under normal ambient conditions of temperature and pressure.
POLYMERIZATION: Product will not undergo polymerization.
CONDITIONS TO AVOID: High temperatures, moisture, and freezing conditions.
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, Carbon dioxide, nitrogen oxides and sulfur.
INCOMPATIBLE MATERIALS: Isocyanates, oxidizing agents, and strong mineral acids.
11. TOXICOLOGICAL INFORMATION
TOXICITY TO ANIMALS
ORAL LD50 DERMAL LD50 INHALATION
Chemical Name
(rat) (rabbit) LC50 (rat)
Polyether polyol mixture Not Established Not Established Not Established
Di-(methylthio)toluenediamine 1515 mg/kg > 2000 mg/kg Not Established
Phenyl mercuric neodecanoate (35% as Hg) 25 to 200 mg/kg Not Established Not Established
Acrylonitrile Not Established Not Established Not Established
CARCINOGENICITY
NTP IARC OSHA
Chemical Name
Status Status Status
Acrylonitrile 2 2B X
IARC: This product contains substances that are classified as possible carcinogens to humans.
12. ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION: Mercury has toxic effects on bacteria, daphnia magna, fish, and other aquatic
organisms. Mercury can accumulate in organisms, danger of bioaccumulation.
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: The generation of waste should be avoided or minimized wherever possible. Disposal should be in
accordance with local, state, provincial or national regulations.
EMPTY CONTAINER: Containers must be emptied (as defined by RCRA, 40 CFR Section 261.7 or state regulations that may be
more stringent) and either passed to an approved recycler or destroyed.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION) LAND
NOTE: Not Regulated
AIR (ICAO/IATA): Not Regulated
VESSEL (IMO/IMDG): Not Regulated
15. REGULATORY INFORMATION
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT)
311/312 HAZARD CATEGORIES: Acute health hazard. Chronic health hazard
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F-80 PART B
313 REPORTABLE INGREDIENTS: This product contains the following substances subject to the reporting requirements
of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372:
EPCRA SECTION 313 SUPPLIER NOTIFICATION
Chemical Name Wt.% CAS Comments
Phenyl mercuric neodecanoate (35% as Hg) 0.1033 26545-49-3 Mercury Compounds (Category Code N458)
CERCLA (COMPREHENSIVE RESPONSE, COMPENSATION, AND LIABILITY ACT)
CERCLA REGULATORY: For this/these chemicals, release of more than the Reportable Quantity to the environment in a
24-hour period requires notification to the National Response Center (800-424-8802 or 202-426-2675):
CERCLA
Chemical Name Wt.%
RQ
Phenyl mercuric neodecanoate (35% as Hg) 0.1033 100 lbs.
Acrylonitrile 0.002 100 lbs.
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA STATUS: This product or its components are listed in or exempt from the TSCA inventory requirements.
CLEAN AIR ACT
Chemical Name Wt.% CAS
Acrylonitrile 0.002 107-13-1
OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA)
29 CFR1910.119---PROCESS SAFETY MANAGEMENT OF HIGHLY HAZARDOUS CHEMICALS: None of the
chemicals in this product are considered highly hazardous by OSHA.
REGULATIONS
STATE REGULATIONS: California Proposition 65: This product contains chemical(s) which are known to the State of
California to cause cancer, birth defects or other reproductive harm, and may be subject to the requirements of California
Proposition 65 (CA Health & Safety Code Section 25249.5):
CALIFORNIA PROPOSITION 65
Chemical Name Wt.% Listed
Phenyl mercuric neodecanoate (35% as Hg) 0.1033 Developmental Toxicity
Acrylonitrile 0.002 Cancer
OSHA HAZARD COMM. RULE: The contents of the MSDS comply with the OSHA Hazard Communication Standard 29 CFR
1910.1200.
16. OTHER INFORMATION
REASON FOR ISSUE: Revised format
APPROVED BY: Michael Rose TITLE: R & D Manager
PREPARED BY: Gus Alidad
REVISION SUMMARY: Revision # 1. Any changes in information are as follows: In Section 2: Physical AppearanceIn Section 5:
Explosion Hazards, Hazardous DecompositionIn Section 8: Engineering Controls, Skin Protection, Eyes-Face Protection, Work
Hygienic PracticesIn Section 9: Color, VOC Method, (VOC) (wt%) (Operator), VOC (From)In Section 10: Hazardous
Decomposition ProductsIn Section 11: IARCIn Section 15: SARA 311/312 Hazard Categories, CERCLA RegulatoryIn Section 16:
HMIS Health (chronic '*')
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F-80 PART B
HMIS RATING NFPA CODES
* 2
HEALTH:
1
1
FLAMMABILITY:
2 0
0
PHYSICAL HAZARD:
X
PERSONAL PROTECTION:
HMIS RATINGS NOTES: Personal Protection: See Section 8
MANUFACTURER DISCLAIMER: This information is furnished without warranty, expressed or implied, except that is accurate
to the best knowledge of BJB Enterprises, Inc. The data on this sheet relates only to the specific material designated herein. BJB
Enterprises, Inc. assumes no legal responsibility for use or reliance upon this data.
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