Material Safety Data Sheet
Nexicor
8485 Broadwell Road
Version: 1.9
Cincinnati, Ohio 45208 08/07/2008
N080W-CRTRG(1 .1 LBS-0.485KG)
ACRYLIC CAULK
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Manufactured By: Daytona Plant
703 South Street
New Smyrna Beach FL 32168
08/07/2008
Revised:
Preparer: PRODUCT STEWARDSHIP COMPLIANCE AND STANDARDS
CHEMTREC 1-800-424-9300
Chemical Family/Use: Acrylic Latex Caulk
Formula: Mixture
HMIS
Flammability: 1 Reactivity: 0 Health: 2
NFPA
Flammability: 1 Reactivity: 0 Health: 2
2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
WARNING! Irritating to eyes, respiratory system and skin. Harmful by inhalation, in contact with skin and if
swallowed. May cause allergic skin reaction. May cause central nervous system depression. Refer to other
MSDS sections for detailed information.
Form: Solid Color: White Odor: Trace Ammonia
POTENTIAL HEALTH EFFECTS
INGESTION
May be harmful if swallowed. Irritation of the mouth, throat, and stomach. May cause kidney damage.
May cause headache, dizziness, nausea, vomiting, gastrointestinal irritation and central nervous
system depression.
SKIN
May be absorbed through skin and produce effects as listed under "Ingestion". Can cause irritation
and reddening of the skin.
INHALATION
Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting. Can irritate
mucous membranes and respiratory tract with coughing and shortness of breath. Avoid inhalation of
vapour or mist.
EYES
Contact can cause severe irritation and conjunctivitis (redness and swelling).
MEDICAL CONDITIONS AGGRAVATED
Central nervous system disorders. Pre-existing skin or respiratory diseases. Kidney disorders
Page 1/3
Nexicor
8485 Broadwell Road
Material Safety Data Sheet
Cincinnati, Ohio 45208
Version: 1.9
08/07/2008
N080W 12C-CRTRG(1 .1 LBS-0.485KG)
ACRYLIC CAULK
SUBCHRONIC (TARGET ORGAN )
Respiratory system; Kidney; Central nervous system
CHRONIC EFFECTS / CARCINOGENICITY
This product or one of its ingredients present at 0.1% or more is NOT listed as a carcinogen or
suspected carcinogen by NTP, IARC, or OSHA.
ROUTES OF EXPOSURE
Inhalation; Dermal; Eyes; Ingestion
3. COMPOSITION / INFORMATION ON INGREDIENTS
PRODUCT COMPOSITION CAS REG NO. WGT. %
A. HA ZARDOUS
Ethylene Glycol 107-21-1 <1%
Diisoheptyl phthalate 71888-89-6 0% - 10 %
Butyl benzyl phthalate 85-68-7 0% - 10 %
STODDARD SOLVENT 8052-41-3 1-5%
B. NON-HAZARDOUS
Limestone 471-34-1 30 - 60 %
Water 7732-18-5 10 - 30 %
2-Propenoic acid, Butyl ester,- 25067-01-0 10 - 30 %
Polymer with Ethenyl Acetate
2-propenoic acid, polymer 52640-81-0 1-5%
4. FIRST AID MEASURES
INGESTION
Immediate medical attention is required. Do NOT induce vomiting. If victim is conscious, give 2-4
glasses of water.
SKIN
Wash off with soap and water. Remove and wash contaminated clothing before re-use. Get
medical attention if irritation or symptoms from Section 3 develop. Flush skin with large amounts
of water for at least 15 minutes until no evidence of chemical remains.
INHALATION
Get medical attention if irritation or symptoms from Section 3 develop. If not breathing, begin
artificial respiration using a barrier device. Because of chemical properties, do not use mouth-to-
Page 2/3
Material Safety Data Sheet
Nexicor
8485 Broadwell Road
Version: 1.9
Cincinnati, Ohio 45208 08/07/2008
N080W 12C-CRTRG(1 .1 LBS-0.485KG)
ACRYLIC CAULK
mouth contact. Remove to fresh air.
EYES
In case of contact, immediately flush eyes with plenty of water for at least 15 minutes and get
medical attention if irritation persists.
NOTE TO PHYSICIAN
Treatment is symptomatic and supportive.
5. FIRE-FIGHTING MEASURES
FLASH POINT: > 93.3 癈; 200 癋. estimated
IGNITION TEMPERATURE: Unknown
FLAMMABLE LIMITS IN AIR - LOWER (%): Unknown
FLAMMABLE LIMITS IN AIR - UPPER (%): Unknown
SENSITIVITY TO MECHANICAL IMPACT: No
SENSITIVITY TO STATIC DISCHARGE
Sensitivity to static discharge is not expected.
EXTINGUISHING MEDIA
All standard extinguishing agents are suitable.
SPECIAL FIRE FIGHTING PROCEDURES
Firefighters must wear NIOSH/MSHA approved positive pressure self-contained breathing
apparatus with full face mask and full protective clothing.
6. ACCIDENTAL RELEASE MEASURES
ACTION TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED
Wipe, scrape or soak up in an inert material and put in a container for disposal. Wash walking
surfaces with detergent and water to reduce slipping hazard. Wear proper protective equipment as
specified in the protective equipment section. Keep out of water supplies and sewers.
7. HANDLING AND STORAGE
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE
Avoid contact with skin and eyes. Remove and wash contaminated clothing before re-use. Keep away
from children. Keep container tightly closed. Keep container dry. Do not inhale vapors. Avoid
accidental ingestion of this material. Wash hands and face before eating, drinking, smoking, using
toilet facilities, or applying cosmetics. Store between 40 F and 120 F. Product releases formaldehyde
during curing.
Page 3/3
Material Safety Data Sheet
Nexicor
8485 Broadwell Road
Version: 1.9
Cincinnati, Ohio 45208 08/07/2008
N080W 12C-CRTRG(1 .1 LBS-0.485KG)
ACRYLIC CAULK
8.EXPOSURE CONTROLS / PERSONAL PROTECTION
ENGINEERING CONTROLS
Eyewash stations; Showers
RESPIRATORY PROTECTION
If exposure limits are exceeded or respiratory irritation is experienced, NIOSH/MSHA approved
respiratory protection should be worn. Supplied air respirators may be required for non-routine or
emergency situations. Respiratory protection must be provided in accordance with OSHA regulations
(see 29CFR 1910.134).
PROTECTIVE GLOVES
Impermeable or chemical resistant gloves.
EYE AND FACE PROTECTION
Safety glasses with side-shields; Monogoggles.
OTHER PROTECTIVE EQUIPMENT
Wear suitable protective clothing and eye/face protection.
Exposure Guidelines
Component CAS RN Source Value
STODDARD 8052-41-3 ACGIH, TWA 100 ppm
SOLVENT
STODDARD 8052-41-3 OSHA Z1, PEL 500 ppm; 2,900 mg/m3
SOLVENT
Absence of values indicates none found
PEL - OSHA Permissible Exposure Limit; TLV - ACGIH Threshold Limit Value; TWA - Time Weighted Average
OSHA revoked the Final Rule Limits of January 19, 1989 in response to the 11th Circuit Court of Appeals decision (AFL-CIO v. OSHA)
effective June 30, 1993. See 29 CFR 1910.1000 (58 FR 35338).
9.PHYSICAL AND CHEMICAL PROPERTIES
BOILING POINT - C & F: 100.00 癈; 212 癋
VAPOR PRESSURE (20 C) (MM HG): Unknown
VAPOR DENSITY (AIR=1): No data available
FREEZING POINT: Unknown
MELTING POINT: Unknown
PHYSICAL STATE: Solid
ODOR: Trace Ammonia
COLOR: White
EVAPORATION RATE (BUTYL ACETATE=1): Unknown
Page 4/4
Material Safety Data Sheet
Nexicor
8485 Broadwell Road
Version: 1.9
Cincinnati, Ohio 45208 08/07/2008
N080W 12C-CRTRG(1 .1 LBS-0.485KG)
ACRYLIC CAULK
SPECIFIC GRAVITY (WATER=1): 1.61
DENSITY: Unknown
pH: ca. 8.0
VOLATILE ORGANIC CONTENT (VOL): 17.47 %(m)
SOLUBILITY IN WATER (20 C): Unknown
SOLUBILITY IN ORGANIC SOLVENT (STATE Unknown
SOLVENT):
VOC EXCL. H2O & EXEMPTS (G/L): 60.90
10. STABILITY AND REACTIVITY
STABILITY
Stable
HAZARDOUS POLYMERIZATION
Will not occur
HAZARDOUS THERMAL DECOMPOSITION / COMBUSTION PRODUCTS
Carbon dioxide (CO2); Carbon monoxide; Oxides of nitrogen.; Toxic monomer fumes.
INCOMPATIBILITY (MATERIALS TO AVOID)
None known.
CONDITIONS TO AVOID
Unknown
11. TOXICOLOGICAL INFORMATION
ACUTE ORAL
Remarks: Unknown
ACUTE DERMAL
Remarks: Unknown
ACUTE INHALATION
Remarks: Unknown
OTHER
This product contains ethylene glycol. Ethylene glycol produces birth defects in laboratory animals.
There is currently no evidence that ethylene glycol has caused birth defects in humans. The major
route for producing developmental toxicity is perorally. Exposure to high aerosol concentrations is
marginally effective at most. Cutaneous application of ethylene glycol is ineffective in producing
developmental toxicity in laboratory animals.
SENSITIZATION
No data available
Page 5/5
Material Safety Data Sheet
Nexicor
8485 Broadwell Road
Version: 1.9
Cincinnati, Ohio 45208 08/07/2008
N080W 12C-CRTRG(1 .1 LBS-0.485KG)
ACRYLIC CAULK
SKIN IRRITATION
No data available
EYE IRRITATION
No data available
MUTAGENICITY
Unknown
OTHER EFFECTS OF OVEREXPOSURE
This product contains butyl benzyl phthalate. Adverse reproductive effects have been reported in
animals exposed to butyl benzyl phthalate through chronic feeding studies. Additionally, chronically
fed rats exhibited leukemia and lymphomas, including Hodgkin's disease.
12. ECOLOGICAL INFORMATION
ECOTOXICITY
No data available
DISTRIBUTION
No data available
CHEMICAL FATE
No data available
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD
Disposal should be made in accordance with federal, state and local regulations.
14. TRANSPORT INFORMATION
Further Information: This product is not regarded as dangerous goods according to the
national and international regulations on the transport of dangerous
goods.
15. REGULATORY INFORMATION
Inventories
Page 6/6
Material Safety Data Sheet
Nexicor
8485 Broadwell Road
Version: 1.9
Cincinnati, Ohio 45208 08/07/2008
N080W 12C-CRTRG(1 .1 LBS-0.485KG)
ACRYLIC CAULK
TSCA list y (Positive listing)
Philippines Inventory of n (Negative listing)
Chemicals and Chemical
Substances (PICCS)
Canada NDSL Inventory n (Negative listing)
EU list of existing chemical n (Negative listing)
substances
Australia Inventory of Chemical n (Negative listing)
Substances (AICS)
Canada DSL Inventory y (Positive listing)
Korea Existing Chemicals n (Negative listing)
Inventory (KECI)
Japan Inventory of Existing & n (Negative listing)
New Chemical Substances
(ENCS)
China Inventory of Existing n (Negative listing)
Chemical Substances
For inventories that are marked as quantity restricted or special cases, please contact Momentive.
US Regulatory Information
SARA (311,312) HAZARD CLASS
Acute Health Hazard; Chronic Health Hazard
SARA (313) CHEMICALS
107-13-1, Acrylonitrile1 08-05-4, Vinyl Acetate79-06-1, Acrylamide50-00-0, Formaldehyde75-21 -8,
Ethylene Oxide
CALIFORNIA PROPOSITION 65
WARNING! This product contains a chemical known in the State of California to cause cancer.
108-88-3, Toluene. 140-88-5, Ethyl Acrylate. 107-13-1, . 7439-92-1, Lead. 79-06-1, 2-Propenamide.
123-91-1, 1 ,4-Dioxane. 7440-02-0, Nickel. 50-00-0, Formaldehyde. 75-21-8, Ethylene Oxide.
Canadian Regulatory Information
WHMIS HAZARD CLASS
D2A VERY TOXIC MATERIALS, D2B TOXIC MATERIALS
Other
SCHDLE B/HTSUS: 3214.10.00.10 Mastic based on rubber
ECCN: EAR99
Page 7/7
Material Safety Data Sheet
Nexicor
8485 Broadwell Road
Version: 1.9
Cincinnati, Ohio 45208 08/07/2008
N080W 12C-CRTRG(1 .1 LBS-0.485KG)
ACRYLIC CAULK
16. OTHER INFORMATION
OTHER
C = ceiling limit NEGL = negligible EST = estimated NF = none found NA = not
applicable UNKN = unknown NE = none established REC = recommended ND = none
determined V = recommended by vendor SKN = skin TS = trade secret R =
recommended MST = mist NT = not tested STEL = short term exposure limit ppm =
parts per million ppb = parts per billion By-product= reaction by-product, TSCA inventory status
not required under 40 CFR part 720.30(h-2)., These data are offered in good faith as typical values
and not as product specifications. No warranty, either expressed or implied, is made. The
recommended industrial hygiene and safe handling procedures are believed to be generally
applicable. However, each user should review these recommendations in the specific context of the
intended use and determine whether they are appropriate.
Page 8/8
Material Safety Data Sheet
Nexicor
8485 Broadwell Road
Version: 1.8
Cincinnati, Ohio 45244 07/13/2008
N181W 12C-Crtrg (1.1 Lbs-0.482 Kg)
ACRYLIC CAULK
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Manufactured By: Euless Plant
10950 S. Pipeline Rd
Euless TX 76040
03/13/2008
Revised:
Preparer: PRODUCT STEWARDSHIP COMPLIANCE AND STANDARDS
CHEMTREC 1-800-424-9300
Chemical Family/Use: Sealant
Formula: Mixture
HMIS
Flammability: 0 Reactivity: 0 Health: 1
NFPA
Flammability: 0 Reactivity: 0 Health: 1
2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
WARNING! Harmful if swallowed, inhaled, or absorbed through the skin. Irritating to eyes, respiratory
system and skin. May cause allergic skin reaction. May cause adverse liver, kidney, and CNS effects. May
cause adverse cardiac effects. Adverse reproductive effects reported in animals.
Form: Solid Color: White Odor: Ammonia
POTENTIAL HEALTH EFFECTS
INGESTION
Harmful if swallowed. May cause gastrointestinal irritation, nausea, vomiting, and diarrhea. May
cause central nervous system effects. May cause tingling and numbness in the hands and feet. May
cause pneumonitis as a result of aspiration. Liver and kidney injuries may occur. May cause
cardiopulmonary effects and possible hemorrhaging. May cause reproductive effects based on results
of animal studies.
SKIN
Harmful if absorbed through the skin. May be absorbed through the skin and contribute to the
symptoms listed under "Ingestion". Causes skin irritation. May cause skin defatting with prolonged
exposure. May cause allergic skin reaction.
INHALATION
Harmful if inhaled. Causes irritation of the mouth, nose, and throat. Symptoms of overexposure may
be headache, dizziness, tiredness, nausea and vomiting. May cause central nervous system effects.
May affect the heart and cardiovascular system. May also cause other effects as listed under
"Ingestion".
EYES
Irritation with redness, swelling, pain, and tearing.
Page 1/8
Material Safety Data Sheet
Nexicor
8485 Broadwell Road
Version: 1.8
Cincinnati, Ohio 45244 07/13/2008
N181W 12C-Crtrg (1.1 Lbs-0.482 Kg)
ACRYLIC CAULK
MEDICAL CONDITIONS AGGRAVATED
Respiratory disorder Central nervous system disorders. Skin disorders. Cardiovascular disorders.
Pre-existing liver or kidney disorders.
SUBCHRONIC (TARGET ORGAN )
Skin; Liver; Kidney; Central nervous system; Heart effects.; Bone marrow and hematopoietic
(blood forming) system
CHRONIC EFFECTS / CARCINOGENICITY
This product contains stoddard solvent or mineral spirits. Chronic and repeated overexposure
may result in adverse liver and kidney effects, bone marrow hyperplasia, and intracerebral
hemorrhage.
ROUTES OF EXPOSURE
Dermal; Inhalation; Ingestion
3. COMPOSITION / INFORMATION ON INGREDIENTS
PRODUCT COMPOSITION CAS REG NO. WGT. %
A. HA ZARDOUS
ETHANEDIOL 107-21-1 <1%
Diisoheptyl phthalate 71888-89-6 5 - 10 %
STODDARD SOLVENT 8052-41-3 1-5%
Butyl benzyl phthalate 85-68-7 >= 5% - <= 10 %
B. NON-HAZARDOUS
Limestone 471-34-1 30 - 60 %
Water 7732-18-5 10 - 30 %
2-propenoic acid, polymer 52640-81-0 10 - 30 %
2-Propenoic acid, Butyl ester,- 25067-01 -0 1-5%
Polymer with Ethenyl Acetate
4. FIRST AID MEASURES
INGESTION
Do NOT induce vomiting. To avoid aspiration should vomiting occur, have the person lean
forward. Immediate medical attention is required. If victim is conscious, give 2-4 glasses of water.
Never induce vomiting unless specifically directed by qualified medical personnel. Never give
anything by mouth to an unconscious person.
Page 2/8
Material Safety Data Sheet
Nexicor
8485 Broadwell Road
Version: 1.8
Cincinnati, Ohio 45244 07/13/2008
N181W 12C-Crtrg (1.1 Lbs-0.482 Kg)
ACRYLIC CAULK
SKIN
Flush skin with large amounts of water for at least 15 minutes until no evidence of chemical
remains. Wash with soap and water. Get medical attention if irritation or symptoms from Section
3 develop.
INHALATION
Move to fresh air. If not breathing, begin artificial respiration using a barrier device. Because of
chemical properties, do not use mouth-to-mouth contact.
EYES
In case of contact, immediately flush eyes with plenty of water for at least 15 minutes and get
medical attention if irritation persists.
NOTE TO PHYSICIAN
Treatment is symptomatic and supportive.
5. FIRE-FIGHTING MEASURES
FLASH POINT: > 93.3 癈; 200 癋
METHOD: estimated
IGNITION TEMPERATURE: Not applicable
FLAMMABLE LIMITS IN AIR - LOWER (%): Not applicable
FLAMMABLE LIMITS IN AIR - UPPER (%): Not applicable
SENSITIVITY TO MECHANICAL IMPACT: No
SENSITIVITY TO STATIC DISCHARGE
Sensitivity to static discharge is not expected.
EXTINGUISHING MEDIA
All standard extinguishing agents are suitable.None
SPECIAL FIRE FIGHTING PROCEDURES
Firefighters must wear NIOSH/MSHA approved positive pressure self-contained breathing
apparatus with full face mask and full protective clothing.
6. ACCIDENTAL RELEASE MEASURES
ACTION TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED
Wipe, scrape or soak up in an inert material and put in a container for disposal. Wash walking
surfaces with detergent and water to reduce slipping hazard. Wear proper protective equipment as
specified in the protective equipment section. Keep out of water supplies and sewers.
Page 3/8
Material Safety Data Sheet
Nexicor
8485 Broadwell Road
Version: 1.8
Cincinnati, Ohio 45244 07/13/2008
N181W 12C-Crtrg (1.1 Lbs-0.482 Kg)
ACRYLIC CAULK
7.HANDLING AND STORAGE
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE
Avoid contact with skin and eyes. Use only in well-ventilated areas. Avoid accidental ingestion of this
material. Wash hands and face before eating, drinking, smoking, using toilet facilities, or applying
cosmetics. Keep container closed when not in use. Keep away from children.
STORAGE
Store away from heat, sources of ignition, and incompatibles.
8.EXPOSURE CONTROLS / PERSONAL PROTECTION
ENGINEERING CONTROLS
Showers; Eyewash stations; Ventilation and other forms of engineering controls are preferred for
controlling exposures. Respiratory protection may be needed for non-routine or emergency situations.
RESPIRATORY PROTECTION
If exposure limits are exceeded or respiratory irritation is experienced, NIOSH/MSHA approved
respiratory protection should be worn. Supplied air respirators may be required for non-routine or
emergency situations. Respiratory protection must be provided in accordance with OSHA regulations
(see 29CFR 1910.134).
PROTECTIVE GLOVES
Neoprene
EYE AND FACE PROTECTION
Monogoggles.; Safety glasses with side-shields
OTHER PROTECTIVE EQUIPMENT
Wear suitable protective clothing and eye/face protection.
Exposure Guidelines
Component CAS RN Source Value
STODDARD 8052-41-3 ACGIH, TWA 100 ppm
SOLVENT
STODDARD 8052-41-3 OSHA Z1, PEL 500 ppm; 2,900 mg/m3
SOLVENT
Titanium Dioxide 13463-67-7 ACGIH, TWA 10 mg/m3
Titanium Dioxide 13463-67-7 OSHA Z1, PEL Total dust. 15 mg/m3
QUARTZ 14808-60-7 OSHA Z1, PEL Respirable fraction. 5 mg/m3
QUARTZ 14808-60-7 OSHA Z1, PEL Total dust. 15 mg/m3
QUARTZ 14808-60-7 ACGIH, TWA Respirable fraction. 0.025 mg/m3
STODDARD 8052-41-3 ACGIH, TWA 100 ppm
Page 4/8
Material Safety Data Sheet
Nexicor
8485 Broadwell Road
Version: 1.8
Cincinnati, Ohio 45244 07/13/2008
N181W 12C-Crtrg (1.1 Lbs-0.482 Kg)
ACRYLIC CAULK
SOLVENT
STODDARD 8052-41-3 OSHA Z1, PEL 500 ppm; 2,900 mg/m3
SOLVENT
Absence of values indicates none found
PEL - OSHA Permissible Exposure Limit; TLV - ACGIH Threshold Limit Value; TWA - Time Weighted Average
OSHA revoked the Final Rule Limits of January 19, 1989 in response to the 11th Circuit Court of Appeals decision (AFL-CIO v. OSHA)
effective June 30, 1993. See 29 CFR 1910.1000 (58 FR 35338).
9. PHYSICAL AND CHEMICAL PROPERTIES
BOILING POINT - C & F: Not applicable
VAPOR PRESSURE (20 C) (MM HG): Not applicable
VAPOR DENSITY (AIR=1): Not applicable
FREEZING POINT: Not applicable
MELTING POINT: Not applicable
PHYSICAL STATE: Solid
ODOR: Ammonia
COLOR: White
SPECIFIC GRAVITY (WATER=1): Unknown
DENSITY: Unknown
ACID / ALKALINITY (MEQ/G): Not applicable
pH: Unknown
VOLATILE ORGANIC CONTENT (VOL): 16.56 %(m)
SOLUBILITY IN WATER (20 C): Unknown
SOLUBILITY IN ORGANIC SOLVENT (STATE Unknown
SOLVENT):
VOC EXCL. H2O & EXEMPTS (G/L): 64.60
10. STABILITY AND REACTIVITY
STABILITY
Stable
HAZARDOUS POLYMERIZATION
Will not occur
HAZARDOUS THERMAL DECOMPOSITION / COMBUSTION PRODUCTS
Carbon dioxide (CO2); Carbon monoxide; Oxides of nitrogen.; Toxic monomer fumes.
INCOMPATIBILITY (MATERIALS TO AVOID)
None known.
CONDITIONS TO AVOID
Unknown
Page 5/8
Material Safety Data Sheet
Nexicor
8485 Broadwell Road
Version: 1.8
Cincinnati, Ohio 45244 07/13/2008
N181W 12C-Crtrg (1.1 Lbs-0.482 Kg)
ACRYLIC CAULK
11. TOXICOLOGICAL INFORMATION
ACUTE ORAL
Remarks: Unknown
ACUTE DERMAL
Remarks: Unknown
ACUTE INHALATION
Remarks: Unknown
OTHER
None.
SENSITIZATION
No data available
SKIN IRRITATION
No data available
EYE IRRITATION
No data available
MUTAGENICITY
Unknown
OTHER EFFECTS OF OVEREXPOSURE
This product contains butyl benzyl phthalate. Adverse reproductive effects have been reported in
animals exposed to butyl benzyl phthalate through chronic feeding studies. Additionally, chronically
fed rats exhibited leukemia and lymphomas, including Hodgkin's disease.
12. ECOLOGICAL INFORMATION
ECOTOXICITY
Ecotoxicological data for this product is not available.
DISTRIBUTION
No data available
CHEMICAL FATE
No data available
Page 6/8
Material Safety Data Sheet
Nexicor
8485 Broadwell Road
Version: 1.8
Cincinnati, Ohio 45244 07/13/2008
N181W 12C-Crtrg (1.1 Lbs-0.482 Kg)
ACRYLIC CAULK
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD
Disposal should be made in accordance with federal, state and local regulations.
14. TRANSPORT INFORMATION
Further Information: This product is not regarded as dangerous goods according to the
national and international regulations on the transport of dangerous
goods.
15. REGULATORY INFORMATION
Inventories
TSCA list y (Positive listing)
Philippines Inventory of n (Negative listing)
Chemicals and Chemical
Substances (PICCS)
Canada NDSL Inventory n (Negative listing)
EU list of existing chemical n (Negative listing)
substances
Australia Inventory of Chemical n (Negative listing)
Substances (AICS)
Canada DSL Inventory y (Positive listing)
Korea Existing Chemicals n (Negative listing)
Inventory (KECI)
For inventories that are marked as quantity restricted or special cases, please contact Momentive.
US Regulatory Information
SARA (311,312) HAZARD CLASS
Acute Health Hazard; Chronic Health Hazard
SARA (313) CHEMICALS
107-13-1, Acrylonitrile1 08-05-4, Vinyl Acetate79-06-1, Acrylamide50-00-0, Formaldehyde75-21 -8,
Ethylene Oxide
CALIFORNIA PROPOSITION 65
WARNING! This product contains a chemical known in the State of California to cause cancer.
140-88-5, Ethyl Acrylate. 107-13-1, . 7439-92-1, Lead. 79-06-1, 2-Propenamide. 123-91-1, 1,4-
Dioxane. 50-00-0, Formaldehyde. 75-21-8, Ethylene Oxide.
Page 7/8
Material Safety Data Sheet
Version: 1.8
07/13/2008
N181W 12C-Crtrg (1.1 Lbs-0.482 Kg)
ACRYLIC CAULK
Canadian Regulatory Information
WHMIS HAZARD CLASS
D2B TOXIC MATERIALS
Other
ECCN: EAR99
16. OTHER INFORMATION
OTHER
These data are offered in good faith as typical values and not as product specifications. No warranty,
either expressed or implied, is made. The recommended industrial hygiene and safe handling
procedures are believed to be generally applicable. However, each user should review these
recommendations in the specific context of the intended use and determine whether they are
appropriate., C = ceiling limit NEGL = negligible EST = estimated NF = none found
NA = not applicable UNKN = unknown NE = none established REC = recommended ND =
none determined V = recommended by vendor SKN = skin TS = trade secret R =
recommended MST = mist NT = not tested STEL = short term exposure limit ppm =
parts per million ppb = parts per billion By-product= reaction by-product, TSCA inventory status
not required under 40 CFR part 720.30(h-2).
Page 8/8
Material Safety Data Sheet
Nexicor
8485 Broadwell Road
Version: 1.7
Cincinnati, Ohio 45244 8/12/2008
N183C 12C-Crtrg (0.730 Lbs-0.331 Kg)
Silicone Rubber Sealant
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Manufactured By: Waterford Plant
260 Hudson River Rd
Waterford NY 12188
8/12/2008
Revised:
Preparer: PRODUCT STEWARDSHIP COMPLIANCE AND STANDARDS
CHEMTREC 1-800-424-9300
Chemical Family/Use: Sealant
Formula: Mixture
HMIS
Flammability: 1 Reactivity: 0 Health: 1
NFPA
Flammability: 1 Reactivity: 0 Health: 1
2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
WARNING! May be harmful if swallowed, inhaled or absorbed through skin. Irritating to eyes, respiratory
system and skin. May cause central nervous system depression.
Form: Solid Color: Translucent Odor: Acetic acid
POTENTIAL HEALTH EFFECTS
INGESTION
May be harmful if swallowed. May cause central nervous system effects. May cause gastrointestinal
irritation, nausea, vomiting, and diarrhea.
SKIN
Uncured product contact will irritate lips, gums and tongue. Skin irritation is possible after contact with
the uncured product. May be absorbed through skin and produce effects as listed under "Ingestion".
INHALATION
Causes mild respiratory tract irritation. Applies in uncured state. May also cause other effects as listed
under "Ingestion".
EYES
Eye irritation on contact with the uncured product.
MEDICAL CONDITIONS AGGRAVATED
Pre-existing skin or respiratory diseases.
SUBCHRONIC (TARGET ORGAN )
Central nervous system; Skin
Page 1/7
Material Safety Data Sheet
Nexicor
8485 Broadwell Road
Version: 1.7
Cincinnati, Ohio 45244 8/12/2008
N183C 12C-Crtrg (0.730 Lbs-0.331 Kg)
Silicone Rubber Sealant
CHRONIC EFFECTS / CARCINOGENICITY
This product or one of its ingredients present at 0.1% or more is NOT listed as a carcinogen or
suspected carcinogen by NTP, IARC, or OSHA.
ROUTES OF EXPOSURE
Inhalation; Eyes; Dermal; Oral.
3. COMPOSITION / INFORMATION ON INGREDIENTS
PRODUCT COMPOSITION CAS REG NO. WGT. %
A. HA ZARDOUS
DISTILLATES, 64742-47-8 10 - 30 %
PETROLEUM,HYDROTREATED
METHYLTRIACETOXYSILANE 4253-34-3 1-5%
B. NON-HAZARDOUS
Dimethylpolysiloxane 70131-67-8 60 - 90 %
Treated Filler 68611-44-9 5 - 10 %
4. FIRST AID MEASURES
INGESTION
Do not induce vomiting. If victim is conscious, give 1-3 glasses of water to drink. Never give
anything by mouth to an unconscious person. Get medical attention if irritation persists.
SKIN
Wash with soap and water. Get medical attention if irritation or symptoms from Section 3
develop.
INHALATION
If inhaled, remove to fresh air. If not breathing give artificial respiration using a barrier device. If
breathing is difficult give oxygen. Get medical attention.
EYES
In case of contact, immediately flush eyes with plenty of water for at least 15 minutes and get
medical attention if irritation persists.
NOTE TO PHYSICIAN
Treatment is symptomatic and supportive.
Page 2/7
Material Safety Data Sheet
Nexicor
8485 Broadwell Road
Version: 1.7
Cincinnati, Ohio 45244 8/12/2008
N183C 12C-Crtrg (0.730 Lbs-0.331 Kg)
Silicone Rubber Sealant
5. FIRE-FIGHTING MEASURES
FLASH POINT: > 93.3 癈; 200 癋
METHOD: estimated
IGNITION TEMPERATURE: No data available
FLAMMABLE LIMITS IN AIR - LOWER (%): Unknown
FLAMMABLE LIMITS IN AIR - UPPER (%): Unknown
SENSITIVITY TO MECHANICAL IMPACT: No
SENSITIVITY TO STATIC DISCHARGE
Sensitivity to static discharge is not expected.
EXTINGUISHING MEDIA
All standard extinguishing agents are suitable.
SPECIAL FIRE FIGHTING PROCEDURES
Firefighters must wear NIOSH/MSHA approved positive pressure self-contained breathing
apparatus with full face mask and full protective clothing.
6. ACCIDENTAL RELEASE MEASURES
ACTION TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED
Wipe, scrape or soak up in an inert material and put in a container for disposal. Wash walking
surfaces with detergent and water to reduce slipping hazard. Wear proper protective equipment as
specified in the protective equipment section.
7. HANDLING AND STORAGE
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE
Keep container closed when not in use. Avoid contact with skin, eyes and clothing. Keep away from
children. Remove contact lenses before using sealant. Do not handle lenses until all sealant has been
cleaned from the fingertips, nails and cuticles. Residual sealant may remain on fingers for several
days and transfer to lenses and cause severe eye irritation. Product releases acetic acid during
application and curing.
STORAGE
Store at room temperature in the original container. Keep container closed.
Page 3/7
Material Safety Data Sheet
Nexicor
8485 Broadwell Road
Version: 1.7
Cincinnati, Ohio 45244 8/12/2008
N183C 12C-Crtrg (0.730 Lbs-0.331 Kg)
Silicone Rubber Sealant
8.EXPOSURE CONTROLS / PERSONAL PROTECTION
ENGINEERING CONTROLS
Eyewash stations; Showers; Exhaust ventilation
RESPIRATORY PROTECTION
If exposure limits are exceeded or respiratory irritation is experienced, NIOSH/MSHA approved
respiratory protection should be worn. Supplied air respirators may be required for non-routine or
emergency situations. Respiratory protection must be provided in accordance with OSHA regulations
(see 29CFR 1910.134).
PROTECTIVE GLOVES
Cloth gloves.
EYE AND FACE PROTECTION
Safety glasses with side-shields
OTHER PROTECTIVE EQUIPMENT
Wear suitable protective clothing and eye/face protection.
Exposure Guidelines
Component CAS RN Source Value
Absence of values indicates none found
PEL - OSHA Permissible Exposure Limit; TLV - ACGIH Threshold Limit Value; TWA - Time Weighted Average
OSHA revoked the Final Rule Limits of January 19, 1989 in response to the 11th Circuit Court of Appeals decision (AFL-CIO v. OSHA)
effective June 30, 1993. See 29 CFR 1910.1000 (58 FR 35338).
9.PHYSICAL AND CHEMICAL PROPERTIES
BOILING POINT - C & F: Not applicable
VAPOR PRESSURE (20 C) (MM HG): Unknown
VAPOR DENSITY (AIR=1): No data available
FREEZING POINT: Not applicable
MELTING POINT: Not applicable
PHYSICAL STATE: Solid
ODOR: Acetic acid
COLOR: Translucent
EVAPORATION RATE (BUTYL ACETATE=1): <1
SPECIFIC GRAVITY (WATER=1): ca. 1.05
DENSITY: ca. 1.050 g/cm3
ACID / ALKALINITY (MEQ/G): No data available
pH: Not applicable
VOLATILE ORGANIC CONTENT (VOL): 2.8 %(m)
SOLUBILITY IN WATER (20 C): Insoluble
SOLUBILITY IN ORGANIC SOLVENT (STATE Soluble in toluene
Page 4/7
Material Safety Data Sheet
Nexicor
8485 Broadwell Road
Version: 1.7
Cincinnati, Ohio 8/12/2008
N183C 12C-Crtrg (0.730 Lbs-0.331 Kg)
Silicone Rubber Sealant
SOLVENT):
VOC EXCL. H2O & EXEMPTS (G/L): ca. 36
10. STABILITY AND REACTIVITY
STABILITY
Stable
HAZARDOUS POLYMERIZATION
Will not occur.
HAZARDOUS THERMAL DECOMPOSITION / COMBUSTION PRODUCTS
Carbon dioxide (CO2); Carbon monoxide; Silicon dioxide.; Acetic acid; This product contains
methylpolysiloxanes which can generate formaldehyde at approximately 300 degrees Fahrenheit
(150'C) and above, in atmospheres which contain oxygen. Formaldehyde is a skin and respiratory
sensitizer, eye and throat irritant, acute toxicant, and potential cancer hazard.
INCOMPATIBILITY (MATERIALS TO AVOID)
None known.
CONDITIONS TO AVOID
None known.
11. TOXICOLOGICAL INFORMATION
ACUTE ORAL
Remarks: Unknown
ACUTE DERMAL
Remarks: Unknown
ACUTE INHALATION
Remarks: Unknown
OTHER
No data available
SENSITIZATION
No data available
SKIN IRRITATION
No data available
EYE IRRITATION
No data available
Page 5/7
Material Safety Data Sheet
Nexicor
8485 Broadwell Road
Version: 1.7
Cincinnati, Ohio 45244 8/12/2008
N183C 12C-Crtrg (0.730 Lbs-0.331 Kg)
Silicone Rubber Sealant
MUTAGENICITY
Unknown
OTHER EFFECTS OF OVEREXPOSURE
Acetic acid released during curing.
12. ECOLOGICAL INFORMATION
ECOTOXICITY
No data available
DISTRIBUTION
No data available
CHEMICAL FATE
No data available
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD
Disposal should be made in accordance with federal, state and local regulations.
14. TRANSPORT INFORMATION
Further Information: This product is not regarded as dangerous goods according to the
national and international regulations on the transport of dangerous
goods.
15. REGULATORY INFORMATION
Inventories
Canada NDSL Inventory n (Negative listing)
TSCA list y (Positive listing)
Japan Inventory of Existing & y (Positive listing)
New Chemical Substances
(ENCS)
y (Positive listing)
Korea Existing Chemicals
Inventory (KECI)
y (Positive listing)
Australia Inventory of Chemical
Substances (AICS)
Page 6/7
Material Safety Data Sheet
Version: 1.7
8/12/2008
N183C 12C-Crtrg (0.730 Lbs-0.331 Kg)
Silicone Rubber Sealant
EU list of existing chemical y (Positive listing)
substances
China Inventory of Existing y (Positive listing)
Chemical Substances
Philippines Inventory of y (Positive listing)
Chemicals and Chemical
Substances (PICCS)
Canada DSL Inventory q (quantity restricted)
For inventories that are marked as quantity restricted or special cases, please contact Momentive.
US Regulatory Information
SARA (311,312) HAZARD CLASS
Acute Health Hazard; Chronic Health HazardAcute Health Hazard
SARA (313) CHEMICALS
58-36-6, 10, 1 0'-oxybisphenoxarsine
Canadian Regulatory Information
WHMIS HAZARD CLASS
D2B TOXIC MATERIALS
Other
SCHDLE B/HTSUS: 3214.10.00.10 Mastic based on rubber
ECCN: EAR99
16. OTHER INFORMATION
OTHER
These data are offered in good faith as typical values and not as product specifications. No warranty,
either expressed or implied, is made. The recommended industrial hygiene and safe handling
procedures are believed to be generally applicable. However, each user should review these
recommendations in the specific context of the intended use and determine whether they are
appropriate., C = ceiling limit NEGL = negligible EST = estimated NF = none found
NA = not applicable UNKN = unknown NE = none established REC = recommended ND =
none determined V = recommended by vendor SKN = skin TS = trade secret R =
recommended MST = mist NT = not tested STEL = short term exposure limit ppm =
parts per million ppb = parts per billion By-product= reaction by-product, TSCA inventory status
not required under 40 CFR part 720.30(h-2).
Page 7/7
Material Safety Data Sheet
Nexicor
8485 Broadwell Road
Version: 1.3
Cincinnati, Ohio 45244 07/24/2008
N184A 5TG-TUBE(0.439LBS-0.199KG)
Acrylic Caulk
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Manufactured By: Daytona Plant
703 South Street
New Smyrna Beach FL 32168
04/24/2008
Revised:
Preparer: PRODUCT STEWARDSHIP COMPLIANCE AND STANDARDS
CHEMTREC 1-800-424-9300
Chemical Family/Use: Acrylic Latex Caulk
Formula: Mixture
HMIS
Flammability: 0 Reactivity: 0 Health: 1
NFPA
Flammability: 0 Reactivity: 0 Health: 1
2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
CAUTION! Irritating to eyes, respiratory system and skin. May cause adverse nerve and muscular effects.
Refer to other MSDS sections for detailed information.
Form: Solid Color: White Odor: Ammonia
POTENTIAL HEALTH EFFECTS
INGESTION
May cause gastrointestinal irritation, nausea, vomiting, and diarrhea.
SKIN
Can cause irritation and reddening of the skin.
INHALATION
Avoid inhalation of vapour or mist. Can irritate mucous membranes and respiratory tract with coughing
and shortness of breath. Symptoms of overexposure may be headache, dizziness, tiredness, nausea
and vomiting.
EYES
Causes eye irritation.
MEDICAL CONDITIONS AGGRAVATED
None known.
SUBCHRONIC (TARGET ORGAN )
None known.
Page 1/7
Material Safety Data Sheet
Nexicor
8485 Broadwell Road
Version: 1.3
Cincinnati, Ohio 45244 07/24/2008
N184A 5TG-TUBE(0.439LBS-0.199KG)
Acrylic Caulk
CHRONIC EFFECTS / CARCINOGENICITY
This product or one of its ingredients present at 0.1% or more is NOT listed as a carcinogen or
suspected carcinogen by NTP, IARC, or OSHA.
ROUTES OF EXPOSURE
Inhalation; Dermal; Eyes
3. COMPOSITION / INFORMATION ON INGREDIENTS
PRODUCT COMPOSITION CAS REG NO. WGT. %
A. HA ZARDOUS
2-(2-Methoxyethoxy)ethanol, 111-77-3 1-5%
B. NON-HAZARDOUS
Water 7732-18-5 30 - 60 %
Vendor Trade secret-Acrylic - 10 - 30 %
Polymer
Limestone 471-34-1 10 - 30 %
Styrene, Butyl Acrylate, 2-Ethyl- 82539-93-3 10 - 30 %
Hexyl Acrylate, Methyl
Methacrylate
4. FIRST AID MEASURES
INGESTION
Do not induce vomiting. If victim is conscious, give 1-3 glasses of water to drink. Never give
anything by mouth to an unconscious person. Get medical attention if irritation persists.
SKIN
Wash off with soap and water. Get medical attention if irritation or symptoms from Section 3
develop.
INHALATION
If inhaled, remove to fresh air. If not breathing give artificial respiration using a barrier device. If
breathing is difficult give oxygen. Get medical attention.
EYES
In case of contact, immediately flush eyes with plenty of water for at least 15 minutes and get
medical attention if irritation persists.
Page 2/7
Material Safety Data Sheet
Nexicor
8485 Broadwell Road
Version: 1.3
Cincinnati, Ohio 45244 07/24/2008
N184A 5TG-TUBE(0.439LBS-0.199KG)
Acrylic Caulk
NOTE TO PHYSICIAN
Treatment is symptomatic and supportive.
5. FIRE-FIGHTING MEASURES
FLASH POINT: > 93.3 癈; 200 癋
METHOD: estimated
IGNITION TEMPERATURE: Unknown
FLAMMABLE LIMITS IN AIR - LOWER (%): Unknown
FLAMMABLE LIMITS IN AIR - UPPER (%): Unknown
SENSITIVITY TO MECHANICAL IMPACT: No
SENSITIVITY TO STATIC DISCHARGE
Sensitivity to static discharge is not expected.
EXTINGUISHING MEDIA
All standard extinguishing agents are suitable.
SPECIAL FIRE FIGHTING PROCEDURES
Firefighters must wear NIOSH/MSHA approved positive pressure self-contained breathing
apparatus with full face mask and full protective clothing.
6. ACCIDENTAL RELEASE MEASURES
ACTION TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED
Wipe, scrape or soak up in an inert material and put in a container for disposal. Wash walking
surfaces with detergent and water to reduce slipping hazard. Wear proper protective equipment as
specified in the protective equipment section. Keep out of water supplies and sewers.
7. HANDLING AND STORAGE
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE
Do not inhale vapors. Avoid contact with skin and eyes. Avoid accidental ingestion of this material.
Wash hands and face before eating, drinking, smoking, using toilet facilities, or applying cosmetics.
Keep container tightly closed. Keep away from children.
Page 3/7
Material Safety Data Sheet
Nexicor
8485 Broadwell Road
Version: 1.3
Cincinnati, Ohio 45244 07/24/2008
N184A 5TG-TUBE(0.439LBS-0.199KG)
Acrylic Caulk
8.EXPOSURE CONTROLS / PERSONAL PROTECTION
ENGINEERING CONTROLS
Eyewash stations; Showers
RESPIRATORY PROTECTION
If exposure limits are exceeded or respiratory irritation is experienced, NIOSH/MSHA approved
respiratory protection should be worn. Supplied air respirators may be required for non-routine or
emergency situations. Respiratory protection must be provided in accordance with OSHA regulations
(see 29CFR 1910.134).
PROTECTIVE GLOVES
Neoprene
EYE AND FACE PROTECTION
Safety glasses with side-shields; Monogoggles.
OTHER PROTECTIVE EQUIPMENT
Wear suitable protective clothing and eye/face protection.
Exposure Guidelines
Component CAS RN Source Value
Absence of values indicates none found
PEL - OSHA Permissible Exposure Limit; TLV - ACGIH Threshold Limit Value; TWA - Time Weighted Average; INTL REL - Internal
Recommended Exposure Limit
OSHA revoked the Final Rule Limits of January 19, 1989 in response to the 11th Circuit Court of Appeals decision (AFL-CIO v. OSHA)
effective June 30, 1993. See 29 CFR 1910.1000 (58 FR 35338).
9.PHYSICAL AND CHEMICAL PROPERTIES
BOILING POINT - C & F: 100.00 癈; 212 癋
VAPOR PRESSURE (20 C) (MM HG): Unknown
FREEZING POINT: Unknown
MELTING POINT: Unknown
PHYSICAL STATE: Solid
ODOR: Ammonia
COLOR: White
SPECIFIC GRAVITY (WATER=1): ca. 1.22
DENSITY: ca. 1.227 g/cm3
ACID / ALKALINITY (MEQ/G): Unknown
pH: 7.7 - 8.1
VOLATILE ORGANIC CONTENT (VOL): Unknown
SOLUBILITY IN WATER (20 C): Unknown
SOLUBILITY IN ORGANIC SOLVENT (STATE Unknown
SOLVENT):
Page 4/7
Material Safety Data Sheet
Nexicor
8485 Broadwell Road
Version: 1.3
Cincinnati, Ohio 45244 07/24/2008
N184A 5TG-TUBE(0.439LBS-0.199KG)
Acrylic Caulk
VOC EXCL. H2O & EXEMPTS (G/L): 32.95
10. STABILITY AND REACTIVITY
STABILITY
Stable
HAZARDOUS POLYMERIZATION
Will not occur
HAZARDOUS THERMAL DECOMPOSITION / COMBUSTION PRODUCTS
Carbon dioxide (CO2); Carbon monoxide; Oxides of nitrogen.; Toxic monomer fumes.; This product
contains methylpolysiloxanes which can generate formaldehyde at approximately 300 degrees
Fahrenheit (150'C) and above, in atmospheres which contain oxygen. Formaldehyde is a skin and
respiratory sensitizer, eye and throat irritant, acute toxicant, and potential cancer hazard. A MSDS for
formaldehyde is available from Momentive.
INCOMPATIBILITY (MATERIALS TO AVOID)
None known.
CONDITIONS TO AVOID
Unknown
11. TOXICOLOGICAL INFORMATION
ACUTE ORAL
Remarks: NONE FOUND
ACUTE DERMAL
Remarks: NONE FOUND
ACUTE INHALATION
Remarks: NONE FOUND
OTHER
None.
MUTAGENICITY
Unknown
OTHER EFFECTS OF OVEREXPOSURE
None known.
Page 5/7
Material Safety Data Sheet
Nexicor
8485 Broadwell Road
Version: 1.3
Cincinnati, Ohio 45244 07/24/2008
N184A 5TG-TUBE(0.439LBS-0.199KG)
Acrylic Caulk
12. ECOLOGICAL INFORMATION
ECOTOXICITY
No data available
CHEMICAL FATE
No data available
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD
Disposal should be made in accordance with federal, state and local regulations.
14. TRANSPORT INFORMATION
Further Information: This product is not regarded as dangerous goods according to the
national and international regulations on the transport of dangerous
goods.
15. REGULATORY INFORMATION
Inventories
TSCA list y (Positive listing)
Philippines Inventory of y (Positive listing)
Chemicals and Chemical
Substances (PICCS)
Canada DSL Inventory y (Positive listing)
China Inventory of Existing n (Negative listing)
Chemical Substances
Canada NDSL Inventory n (Negative listing)
n (Negative listing)
Japan Inventory of Existing &
New Chemical Substances
(ENCS)
n (Negative listing)
Korea Existing Chemicals
Inventory (KECI)
n (Negative listing)
Australia Inventory of Chemical
Substances (AICS)
For inventories that are marked as quantity restricted or special cases, please contact Momentive .
Page 6/7
Material Safety Data Sheet
Version: 1.3
07/24/2008
N184A 5TG-TUBE(0.439LBS-0.199KG)
Acrylic Caulk
US Regulatory Information
CERCLA
Reportable quantity: 1233 lbs
PRODUCT COMPOSITION Chemical CERCLA Reportable Quantity
10605-21-7 Reportable quantity: 1 LBS
SARA (311,312) HAZARD CLASS
Acute Health Hazard; Chronic Health Hazard
SARA (313) CHEMICALS
CALIFORNIA PROPOSITION 65
Warning! This product contains a chemical known to the State of California to cause cancer, birth
defects or other reproductive harm.
79-06-1, 2-Propenamide. 7439-92-1, Lead. 140-88-5, Ethyl Acrylate. 872-50-4, N-METHYL
PYRROLI DIN ONE. 108-88-3, Toluene. 75-21-8, Ethylene Oxide. 50-00-0, Formaldehyde. 71-43-2,
Benzene. 7440-02-0, Nickel. 123-91 -1, 1,4-Dioxane.
Canadian Regulatory Information
WHMIS HAZARD CLASS
D2B TOXIC MATERIALS
Other
SCHDLE B/HTSUS: 3214.10.00.10 Mastic based on rubber
16. OTHER INFORMATION
OTHER
These data are offered in good faith as typical values and not as product specifications. No warranty,
either expressed or implied, is made. The recommended industrial hygiene and safe handling
procedures are believed to be generally applicable. However, each user should review these
recommendations in the specific context of the intended use and determine whether they are
appropriate., C = ceiling limit NEGL = negligible EST = estimated NF = none found
NA = not applicable UNKN = unknown NE = none established REC = recommended ND =
none determined V = recommended by vendor SKN = skin TS = trade secret R =
recommended MST = mist NT = not tested STEL = short term exposure limit ppm =
parts per million ppb = parts per billion By-product= reaction by-product, TSCA inventory status
not required under 40 CFR part 720.30(h-2).
Page 7/7
Material Safety Data Sheet
Nexicor
8485 Broadwell Road
Version: 1.3
Cincinnati, Ohio 45244 07/24/2008
N184W 5TG-TUBE(0.439LBS-0.199KG)
Acrylic Caulk
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Manufactured By: Daytona Plant
703 South Street
New Smyrna Beach FL 32168
04/24/2008
Revised:
Preparer: PRODUCT STEWARDSHIP COMPLIANCE AND STANDARDS
CHEMTREC 1-800-424-9300
Chemical Family/Use: Acrylic Latex Caulk
Formula: Mixture
HMIS
Flammability: 0 Reactivity: 0 Health: 1
NFPA
Flammability: 0 Reactivity: 0 Health: 1
2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
CAUTION! Irritating to eyes, respiratory system and skin. May cause adverse nerve and muscular effects.
Refer to other MSDS sections for detailed information.
Form: Solid Color: White Odor: Ammonia
POTENTIAL HEALTH EFFECTS
INGESTION
May cause gastrointestinal irritation, nausea, vomiting, and diarrhea.
SKIN
Can cause irritation and reddening of the skin.
INHALATION
Avoid inhalation of vapour or mist. Can irritate mucous membranes and respiratory tract with coughing
and shortness of breath. Symptoms of overexposure may be headache, dizziness, tiredness, nausea
and vomiting.
EYES
Causes eye irritation.
MEDICAL CONDITIONS AGGRAVATED
None known.
SUBCHRONIC (TARGET ORGAN )
None known.
Page 1/7
Material Safety Data Sheet
Nexicor
8485 Broadwell Road
Version: 1.3
Cincinnati, Ohio 45244 07/24/2008
N184W 5TG-TUBE(0.439LBS-0.199KG)
Acrylic Caulk
CHRONIC EFFECTS / CARCINOGENICITY
This product or one of its ingredients present at 0.1% or more is NOT listed as a carcinogen or
suspected carcinogen by NTP, IARC, or OSHA.
ROUTES OF EXPOSURE
Inhalation; Dermal; Eyes
3. COMPOSITION / INFORMATION ON INGREDIENTS
PRODUCT COMPOSITION CAS REG NO. WGT. %
A. HA ZARDOUS
2-(2-Methoxyethoxy)ethanol, 111-77-3 1-5%
B. NON-HAZARDOUS
Water 7732-18-5 30 - 60 %
Vendor Trade secret-Acrylic - 10 - 30 %
Polymer
Limestone 471-34-1 10 - 30 %
Styrene, Butyl Acrylate, 2-Ethyl- 82539-93-3 10 - 30 %
Hexyl Acrylate, Methyl
Methacrylate
4. FIRST AID MEASURES
INGESTION
Do not induce vomiting. If victim is conscious, give 1-3 glasses of water to drink. Never give
anything by mouth to an unconscious person. Get medical attention if irritation persists.
SKIN
Wash off with soap and water. Get medical attention if irritation or symptoms from Section 3
develop.
INHALATION
If inhaled, remove to fresh air. If not breathing give artificial respiration using a barrier device. If
breathing is difficult give oxygen. Get medical attention.
EYES
In case of contact, immediately flush eyes with plenty of water for at least 15 minutes and get
medical attention if irritation persists.
Page 2/7
Material Safety Data Sheet
Nexicor
8485 Broadwell Road
Version: 1.3
Cincinnati, Ohio 45244 07/24/2008
N184W 5TG-TUBE(0.439LBS-0.199KG)
Acrylic Caulk
NOTE TO PHYSICIAN
Treatment is symptomatic and supportive.
5. FIRE-FIGHTING MEASURES
FLASH POINT: > 93.3 癈; 200 癋
METHOD: estimated
IGNITION TEMPERATURE: Unknown
FLAMMABLE LIMITS IN AIR - LOWER (%): Unknown
FLAMMABLE LIMITS IN AIR - UPPER (%): Unknown
SENSITIVITY TO MECHANICAL IMPACT: No
SENSITIVITY TO STATIC DISCHARGE
Sensitivity to static discharge is not expected.
EXTINGUISHING MEDIA
All standard extinguishing agents are suitable.
SPECIAL FIRE FIGHTING PROCEDURES
Firefighters must wear NIOSH/MSHA approved positive pressure self-contained breathing
apparatus with full face mask and full protective clothing.
6. ACCIDENTAL RELEASE MEASURES
ACTION TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED
Wipe, scrape or soak up in an inert material and put in a container for disposal. Wash walking
surfaces with detergent and water to reduce slipping hazard. Wear proper protective equipment as
specified in the protective equipment section. Keep out of water supplies and sewers.
7. HANDLING AND STORAGE
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE
Do not inhale vapors. Avoid contact with skin and eyes. Avoid accidental ingestion of this material.
Wash hands and face before eating, drinking, smoking, using toilet facilities, or applying cosmetics.
Keep container tightly closed. Keep away from children.
Page 3/7
Material Safety Data Sheet
Nexicor
8485 Broadwell Road
Version: 1.3
Cincinnati, Ohio 45244 07/24/2008
N184W 5TG-TUBE(0.439LBS-0.199KG)
Acrylic Caulk
8.EXPOSURE CONTROLS / PERSONAL PROTECTION
ENGINEERING CONTROLS
Eyewash stations; Showers
RESPIRATORY PROTECTION
If exposure limits are exceeded or respiratory irritation is experienced, NIOSH/MSHA approved
respiratory protection should be worn. Supplied air respirators may be required for non-routine or
emergency situations. Respiratory protection must be provided in accordance with OSHA regulations
(see 29CFR 1910.134).
PROTECTIVE GLOVES
Neoprene
EYE AND FACE PROTECTION
Safety glasses with side-shields; Monogoggles.
OTHER PROTECTIVE EQUIPMENT
Wear suitable protective clothing and eye/face protection.
Exposure Guidelines
Component CAS RN Source Value
Absence of values indicates none found
PEL - OSHA Permissible Exposure Limit; TLV - ACGIH Threshold Limit Value; TWA - Time Weighted Average; INTL REL - Internal
Recommended Exposure Limit
OSHA revoked the Final Rule Limits of January 19, 1989 in response to the 11th Circuit Court of Appeals decision (AFL-CIO v. OSHA)
effective June 30, 1993. See 29 CFR 1910.1000 (58 FR 35338).
9.PHYSICAL AND CHEMICAL PROPERTIES
BOILING POINT - C & F: 100.00 癈; 212 癋
VAPOR PRESSURE (20 C) (MM HG): Unknown
FREEZING POINT: Unknown
MELTING POINT: Unknown
PHYSICAL STATE: Solid
ODOR: Ammonia
COLOR: White
SPECIFIC GRAVITY (WATER=1): ca. 1.22
DENSITY: ca. 1.227 g/cm3
ACID / ALKALINITY (MEQ/G): Unknown
pH: 7.7 - 8.1
VOLATILE ORGANIC CONTENT (VOL): Unknown
SOLUBILITY IN WATER (20 C): Unknown
SOLUBILITY IN ORGANIC SOLVENT (STATE Unknown
SOLVENT):
Page 4/7
Material Safety Data Sheet
Nexicor
8485 Broadwell Road
Version: 1.3
Cincinnati, Ohio 45244 07/24/2008
N184W 5TG-TUBE(0.439LBS-0.199KG)
Acrylic Caulk
VOC EXCL. H2O & EXEMPTS (G/L): 32.95
10. STABILITY AND REACTIVITY
STABILITY
Stable
HAZARDOUS POLYMERIZATION
Will not occur
HAZARDOUS THERMAL DECOMPOSITION / COMBUSTION PRODUCTS
Carbon dioxide (CO2); Carbon monoxide; Oxides of nitrogen.; Toxic monomer fumes.; This product
contains methylpolysiloxanes which can generate formaldehyde at approximately 300 degrees
Fahrenheit (150'C) and above, in atmospheres which contain oxygen. Formaldehyde is a skin and
respiratory sensitizer, eye and throat irritant, acute toxicant, and potential cancer hazard. A MSDS for
formaldehyde is available from Momentive.
INCOMPATIBILITY (MATERIALS TO AVOID)
None known.
CONDITIONS TO AVOID
Unknown
11. TOXICOLOGICAL INFORMATION
ACUTE ORAL
Remarks: NONE FOUND
ACUTE DERMAL
Remarks: NONE FOUND
ACUTE INHALATION
Remarks: NONE FOUND
OTHER
None.
MUTAGENICITY
Unknown
OTHER EFFECTS OF OVEREXPOSURE
None known.
Page 5/7
Material Safety Data Sheet
Nexicor
8485 Broadwell Road
Version: 1.3
Cincinnati, Ohio 45244 07/24/2008
N184W 5TG-TUBE(0.439LBS-0.199KG)
Acrylic Caulk
12. ECOLOGICAL INFORMATION
ECOTOXICITY
No data available
CHEMICAL FATE
No data available
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD
Disposal should be made in accordance with federal, state and local regulations.
14. TRANSPORT INFORMATION
Further Information: This product is not regarded as dangerous goods according to the
national and international regulations on the transport of dangerous
goods.
15. REGULATORY INFORMATION
Inventories
TSCA list y (Positive listing)
Philippines Inventory of y (Positive listing)
Chemicals and Chemical
Substances (PICCS)
Canada DSL Inventory y (Positive listing)
China Inventory of Existing n (Negative listing)
Chemical Substances
Canada NDSL Inventory n (Negative listing)
n (Negative listing)
Japan Inventory of Existing &
New Chemical Substances
(ENCS)
n (Negative listing)
Korea Existing Chemicals
Inventory (KECI)
n (Negative listing)
Australia Inventory of Chemical
Substances (AICS)
For inventories that are marked as quantity restricted or special cases, please contact Momentive .
Page 6/7
Material Safety Data Sheet
Version: 1.3
07/24/2008
N184W 5TG-TUBE(0.439LBS-0.199KG)
Acrylic Caulk
US Regulatory Information
CERCLA
Reportable quantity: 1233 lbs
PRODUCT COMPOSITION Chemical CERCLA Reportable Quantity
10605-21-7 Reportable quantity: 1 LBS
SARA (311,312) HAZARD CLASS
Acute Health Hazard; Chronic Health Hazard
SARA (313) CHEMICALS
CALIFORNIA PROPOSITION 65
Warning! This product contains a chemical known to the State of California to cause cancer, birth
defects or other reproductive harm.
79-06-1, 2-Propenamide. 7439-92-1, Lead. 140-88-5, Ethyl Acrylate. 872-50-4, N-METHYL
PYRROLI DIN ONE. 108-88-3, Toluene. 75-21-8, Ethylene Oxide. 50-00-0, Formaldehyde. 71-43-2,
Benzene. 7440-02-0, Nickel. 123-91 -1, 1,4-Dioxane.
Canadian Regulatory Information
WHMIS HAZARD CLASS
D2B TOXIC MATERIALS
Other
SCHDLE B/HTSUS: 3214.10.00.10 Mastic based on rubber
16. OTHER INFORMATION
OTHER
These data are offered in good faith as typical values and not as product specifications. No warranty,
either expressed or implied, is made. The recommended industrial hygiene and safe handling
procedures are believed to be generally applicable. However, each user should review these
recommendations in the specific context of the intended use and determine whether they are
appropriate., C = ceiling limit NEGL = negligible EST = estimated NF = none found
NA = not applicable UNKN = unknown NE = none established REC = recommended ND =
none determined V = recommended by vendor SKN = skin TS = trade secret R =
recommended MST = mist NT = not tested STEL = short term exposure limit ppm =
parts per million ppb = parts per billion By-product= reaction by-product, TSCA inventory status
not required under 40 CFR part 720.30(h-2).
Page 7/7
Material Safety Data Sheet
Nexicor
8485 Broadwell Road
Version: 1.3
Cincinnati, Ohio 45244 07/24/2008
N185W Kitchen & Bath 5TG-
TUBE(0.439LBS-0.199KG) Acrylic Caulk
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Manufactured By: Daytona Plant
703 South Street
New Smyrna Beach FL 32168
07/24/2008
Revised:
Preparer: PRODUCT STEWARDSHIP COMPLIANCE AND STANDARDS
CHEMTREC 1-800-424-9300
Chemical Family/Use: Acrylic Latex Caulk
Formula: Mixture
HMIS
Flammability: 0 Reactivity: 0 Health: 1
NFPA
Flammability: 0 Reactivity: 0 Health: 1
2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
CAUTION! Irritating to eyes, respiratory system and skin. May cause adverse nerve and muscular effects.
Refer to other MSDS sections for detailed information.
Form: Solid Color: White Odor: Ammonia
POTENTIAL HEALTH EFFECTS
INGESTION
May cause gastrointestinal irritation, nausea, vomiting, and diarrhea.
SKIN
Can cause irritation and reddening of the skin.
INHALATION
Avoid inhalation of vapour or mist. Can irritate mucous membranes and respiratory tract with coughing
and shortness of breath. Symptoms of overexposure may be headache, dizziness, tiredness, nausea
and vomiting.
EYES
Causes eye irritation.
MEDICAL CONDITIONS AGGRAVATED
None known.
SUBCHRONIC (TARGET ORGAN )
None known.
Page 1/7
Material Safety Data Sheet
Nexicor
8485 Broadwell Road
Version: 1.3
Cincinnati, Ohio 45244 07/24/2008
N185W Kitchen & Bath 5TG-
TUBE(0.439LBS-0.199KG) Acrylic Caulk
CHRONIC EFFECTS / CARCINOGENICITY
This product or one of its ingredients present at 0.1% or more is NOT listed as a carcinogen or
suspected carcinogen by NTP, IARC, or OSHA.
ROUTES OF EXPOSURE
Inhalation; Dermal; Eyes
3. COMPOSITION / INFORMATION ON INGREDIENTS
PRODUCT COMPOSITION CAS REG NO. WGT. %
A. HA ZARDOUS
2-(2-Methoxyethoxy)ethanol, 111-77-3 1-5%
B. NON-HAZARDOUS
Water 7732-18-5 30 - 60 %
Vendor Trade secret-Acrylic - 10 - 30 %
Polymer
Limestone 471-34-1 10 - 30 %
Styrene, Butyl Acrylate, 2-Ethyl- 82539-93-3 10 - 30 %
Hexyl Acrylate, Methyl
Methacrylate
4. FIRST AID MEASURES
INGESTION
Do not induce vomiting. If victim is conscious, give 1-3 glasses of water to drink. Never give
anything by mouth to an unconscious person. Get medical attention if irritation persists.
SKIN
Wash off with soap and water. Get medical attention if irritation or symptoms from Section 3
develop.
INHALATION
If inhaled, remove to fresh air. If not breathing give artificial respiration using a barrier device. If
breathing is difficult give oxygen. Get medical attention.
EYES
In case of contact, immediately flush eyes with plenty of water for at least 15 minutes and get
medical attention if irritation persists.
Page 2/7
Material Safety Data Sheet
Nexicor
8485 Broadwell Road
Version: 1.3
Cincinnati, Ohio 45244 07/24/2008
N185W Kitchen & Bath 5TG-
TUBE(0.439LBS-0.199KG) Acrylic Caulk
NOTE TO PHYSICIAN
Treatment is symptomatic and supportive.
5. FIRE-FIGHTING MEASURES
FLASH POINT: > 93.3 癈; 200 癋
METHOD: estimated
IGNITION TEMPERATURE: Unknown
FLAMMABLE LIMITS IN AIR - LOWER (%): Unknown
FLAMMABLE LIMITS IN AIR - UPPER (%): Unknown
SENSITIVITY TO MECHANICAL IMPACT: No
SENSITIVITY TO STATIC DISCHARGE
Sensitivity to static discharge is not expected.
EXTINGUISHING MEDIA
All standard extinguishing agents are suitable.
SPECIAL FIRE FIGHTING PROCEDURES
Firefighters must wear NIOSH/MSHA approved positive pressure self-contained breathing
apparatus with full face mask and full protective clothing.
6. ACCIDENTAL RELEASE MEASURES
ACTION TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED
Wipe, scrape or soak up in an inert material and put in a container for disposal. Wash walking
surfaces with detergent and water to reduce slipping hazard. Wear proper protective equipment as
specified in the protective equipment section. Keep out of water supplies and sewers.
7. HANDLING AND STORAGE
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE
Do not inhale vapors. Avoid contact with skin and eyes. Avoid accidental ingestion of this material.
Wash hands and face before eating, drinking, smoking, using toilet facilities, or applying cosmetics.
Keep container tightly closed. Keep away from children.
Page 3/7
Material Safety Data Sheet
Nexicor
8485 Broadwell Road
Version: 1.3
Cincinnati, Ohio 45244 07/24/2008
N185W Kitchen & Bath 5TG-
TUBE(0.439LBS-0.199KG) Acrylic Caulk
8.EXPOSURE CONTROLS / PERSONAL PROTECTION
ENGINEERING CONTROLS
Eyewash stations; Showers
RESPIRATORY PROTECTION
If exposure limits are exceeded or respiratory irritation is experienced, NIOSH/MSHA approved
respiratory protection should be worn. Supplied air respirators may be required for non-routine or
emergency situations. Respiratory protection must be provided in accordance with OSHA regulations
(see 29CFR 1910.134).
PROTECTIVE GLOVES
Neoprene
EYE AND FACE PROTECTION
Safety glasses with side-shields; Monogoggles.
OTHER PROTECTIVE EQUIPMENT
Wear suitable protective clothing and eye/face protection.
Exposure Guidelines
Component CAS RN Source Value
Absence of values indicates none found
PEL - OSHA Permissible Exposure Limit; TLV - ACGIH Threshold Limit Value; TWA - Time Weighted Average; INTL REL - Internal
Recommended Exposure Limit
OSHA revoked the Final Rule Limits of January 19, 1989 in response to the 11th Circuit Court of Appeals decision (AFL-CIO v. OSHA)
effective June 30, 1993. See 29 CFR 1910.1000 (58 FR 35338).
9.PHYSICAL AND CHEMICAL PROPERTIES
BOILING POINT - C & F: 100.00 癈; 212 癋
VAPOR PRESSURE (20 C) (MM HG): Unknown
FREEZING POINT: Unknown
MELTING POINT: Unknown
PHYSICAL STATE: Solid
ODOR: Ammonia
COLOR: White
SPECIFIC GRAVITY (WATER=1): ca. 1.22
DENSITY: ca. 1.227 g/cm3
ACID / ALKALINITY (MEQ/G): Unknown
pH: 7.7 - 8.1
VOLATILE ORGANIC CONTENT (VOL): Unknown
SOLUBILITY IN WATER (20 C): Unknown
SOLUBILITY IN ORGANIC SOLVENT (STATE Unknown
SOLVENT):
Page 4/7
Material Safety Data Sheet
Nexicor
8485 Broadwell Road
Version: 1.3
Cincinnati, Ohio 45244 07/24/2008
N185W Kitchen & Bath 5TG-
TUBE(0.439LBS-0.199KG) Acrylic Caulk
VOC EXCL. H2O & EXEMPTS (G/L): 32.95
10. STABILITY AND REACTIVITY
STABILITY
Stable
HAZARDOUS POLYMERIZATION
Will not occur
HAZARDOUS THERMAL DECOMPOSITION / COMBUSTION PRODUCTS
Carbon dioxide (CO2); Carbon monoxide; Oxides of nitrogen.; Toxic monomer fumes.; This product
contains methylpolysiloxanes which can generate formaldehyde at approximately 300 degrees
Fahrenheit (150'C) and above, in atmospheres which contain oxygen. Formaldehyde is a skin and
respiratory sensitizer, eye and throat irritant, acute toxicant, and potential cancer hazard. A MSDS for
formaldehyde is available from Momentive.
INCOMPATIBILITY (MATERIALS TO AVOID)
None known.
CONDITIONS TO AVOID
Unknown
11. TOXICOLOGICAL INFORMATION
ACUTE ORAL
Remarks: NONE FOUND
ACUTE DERMAL
Remarks: NONE FOUND
ACUTE INHALATION
Remarks: NONE FOUND
OTHER
None.
MUTAGENICITY
Unknown
OTHER EFFECTS OF OVEREXPOSURE
None known.
Page 5/7
Material Safety Data Sheet
Nexicor
8485 Broadwell Road
Version: 1.3
Cincinnati, Ohio 45244 07/24/2008
N185W Kitchen & Bath 5TG-
TUBE(0.439LBS-0.199KG) Acrylic Caulk
12. ECOLOGICAL INFORMATION
ECOTOXICITY
No data available
CHEMICAL FATE
No data available
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD
Disposal should be made in accordance with federal, state and local regulations.
14. TRANSPORT INFORMATION
Further Information: This product is not regarded as dangerous goods according to the
national and international regulations on the transport of dangerous
goods.
15. REGULATORY INFORMATION
Inventories
TSCA list y (Positive listing)
Philippines Inventory of y (Positive listing)
Chemicals and Chemical
Substances (PICCS)
Canada DSL Inventory y (Positive listing)
China Inventory of Existing n (Negative listing)
Chemical Substances
Canada NDSL Inventory n (Negative listing)
n (Negative listing)
Japan Inventory of Existing &
New Chemical Substances
(ENCS)
n (Negative listing)
Korea Existing Chemicals
Inventory (KECI)
n (Negative listing)
Australia Inventory of Chemical
Substances (AICS)
For inventories that are marked as quantity restricted or special cases, please contact Momentive .
Page 6/7
Material Safety Data Sheet
Version: 1.3
07/24/2008
N185W Kitchen & Bath 5TG-
TUBE(0.439LBS-0.199KG) Acrylic Caulk
US Regulatory Information
CERCLA
Reportable quantity: 1233 lbs
PRODUCT COMPOSITION Chemical CERCLA Reportable Quantity
10605-21-7 Reportable quantity: 1 LBS
SARA (311,312) HAZARD CLASS
Acute Health Hazard; Chronic Health Hazard
SARA (313) CHEMICALS
CALIFORNIA PROPOSITION 65
Warning! This product contains a chemical known to the State of California to cause cancer, birth
defects or other reproductive harm.
79-06-1, 2-Propenamide. 7439-92-1, Lead. 140-88-5, Ethyl Acrylate. 872-50-4, N-METHYL
PYRROLI DIN ONE. 108-88-3, Toluene. 75-21-8, Ethylene Oxide. 50-00-0, Formaldehyde. 71-43-2,
Benzene. 7440-02-0, Nickel. 123-91 -1, 1,4-Dioxane.
Canadian Regulatory Information
WHMIS HAZARD CLASS
D2B TOXIC MATERIALS
Other
SCHDLE B/HTSUS: 3214.10.00.10 Mastic based on rubber
16. OTHER INFORMATION
OTHER
These data are offered in good faith as typical values and not as product specifications. No warranty,
either expressed or implied, is made. The recommended industrial hygiene and safe handling
procedures are believed to be generally applicable. However, each user should review these
recommendations in the specific context of the intended use and determine whether they are
appropriate., C = ceiling limit NEGL = negligible EST = estimated NF = none found
NA = not applicable UNKN = unknown NE = none established REC = recommended ND =
none determined V = recommended by vendor SKN = skin TS = trade secret R =
recommended MST = mist NT = not tested STEL = short term exposure limit ppm =
parts per million ppb = parts per billion By-product= reaction by-product, TSCA inventory status
not required under 40 CFR part 720.30(h-2).
Page 7/7
Material Safety Data Sheet
Nexicor
8485 Broadwell Road
Version: 1.3
Cincinnati, Ohio 45244 08/03/2008
N585W 1 2C-CRTRG(0.807LBS-0.366KG)
Acrylic Caulk
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Manufactured By: Euless Plant
10950 S. Pipeline Rd
Euless TX 76040
08/03/2008
Revised:
Preparer: PRODUCT STEWARDSHIP COMPLIANCE AND STANDARDS
CHEMTREC 1-800-424-9300
Chemical Family/Use: Sealant
Formula: Mixture
HMIS
Flammability: 0 Reactivity: 0 Health: 1
NFPA
Flammability: 0 Reactivity: 0 Health: 1
2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
WARNING! Stable Harmful by inhalation, in contact with skin and if swallowed. Refer to other MSDS
sections for detailed information.
Form: Solid Color: white Odor: acrylic
POTENTIAL HEALTH EFFECTS
INGESTION
May be harmful if swallowed. Irritation of the mouth, throat, and stomach. May cause kidney damage.
May cause headache, dizziness, nausea, vomiting, gastrointestinal irritation and central nervous
system depression.
SKIN
May be absorbed through skin and produce effects as listed under "Ingestion". Can cause irritation
and reddening of the skin.
INHALATION
Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting. Can irritate
mucous membranes and respiratory tract with coughing and shortness of breath. Avoid inhalation of
vapour or mist.
EYES
Contact can cause severe irritation and conjunctivitis (redness and swelling).
MEDICAL CONDITIONS AGGRAVATED
Central nervous system disorders. Pre-existing skin or respiratory diseases. Kidney disorders
Page 1/3
Material Safety Data Sheet
Nexicor
8485 Broadwell Road
Version: 1.3
Cincinnati, Ohio 08/03/2008
N585W 1 2C-CRTRG(0.807LBS-0.366KG)
Acrylic Caulk
SUBCHRONIC (TARGET ORGAN )
Respiratory system; Kidney; Central nervous system; Target organs include:
CHRONIC EFFECTS / CARCINOGENICITY
This product or one of its ingredients present at 0.1% or more is NOT listed as a carcinogen or
suspected carcinogen by NTP, IARC, or OSHA.
ROUTES OF EXPOSURE
Ingestion; Inhalation; Absorption through skin.
3. COMPOSITION / INFORMATION ON INGREDIENTS
PRODUCT COMPOSITION CAS REG NO. WGT. %
A. HA ZARDOUS
ETHANEDIOLE 107-21-1 1-5%
B. NON-HAZARDOUS
Titanium Dioxide 13463-67-7 1-5%
Limestone 471-34-1 10 - 30 %
Water 7732-18-5 30 - 60 %
Acrylic Polymer - 30 - 60 %
4. FIRST AID MEASURES
INGESTION
Immediate medical attention is required. Do NOT induce vomiting. If victim is conscious, give 2-4
glasses of water.
SKIN
Wash off with soap and water. Remove and wash contaminated clothing before re-use. Get
medical attention if irritation or symptoms from Section 3 develop. Flush skin with large amounts
of water for at least 15 minutes until no evidence of chemical remains.
INHALATION
Get medical attention if irritation or symptoms from Section 3 develop. If not breathing, begin
artificial respiration using a barrier device. Because of chemical properties, do not use mouth-to-
mouth contact. Remove to fresh air.
EYES
In case of contact, immediately flush eyes with plenty of water for at least 15 minutes and get
Page 2/3
Material Safety Data Sheet
Nexicor
8485 Broadwell Road
Version: 1.3
Cincinnati, Ohio 08/03/2008
N585W 1 2C-CRTRG(0.807LBS-0.366KG)
Acrylic Caulk
medical attention if irritation persists.
NOTE TO PHYSICIAN
Treatment is symptomatic and supportive.
5. FIRE-FIGHTING MEASURES
METHOD: Not applicable
IGNITION TEMPERATURE: Unknown
FLAMMABLE LIMITS IN AIR - LOWER (%): Unknown
FLAMMABLE LIMITS IN AIR - UPPER (%): Unknown
SENSITIVITY TO MECHANICAL IMPACT: No
SENSITIVITY TO STATIC DISCHARGE
Sensitivity to static discharge is not expected.
EXTINGUISHING MEDIA
Water, Foam, Carbon dioxide (CO2), Dry chemical
SPECIAL FIRE FIGHTING PROCEDURES
Fire may produce poisonous or irritating gas, fumes, or vapors. See Section 10 for hazardous
decomposition products., Firefighters must wear NIOSH/MSHA approved positive pressure self-
contained breathing apparatus with full face mask and full protective clothing.
6. ACCIDENTAL RELEASE MEASURES
ACTION TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED
Wear proper protective equipment as specified in the protective equipment section. Collect spilled
material and place in closed container for recovery or disposal.
7. HANDLING AND STORAGE
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE
Avoid contact with skin and eyes. Remove and wash contaminated clothing before re-use. Keep away
from children. Keep container dry. Store away from heat, sources of ignition, and incompatibles. Avoid
accidental ingestion of this material. Wash hands and face before eating, drinking, smoking, using
toilet facilities, or applying cosmetics. Avoid inhalation of vapour or mist.
Page 3/3
Material Safety Data Sheet
Nexicor
8485 Broadwell Road
Version: 1.3
Cincinnati, Ohio 08/03/2008
N585W 1 2C-CRTRG(0.807LBS-0.366KG)
Acrylic Caulk
8.EXPOSURE CONTROLS / PERSONAL PROTECTION
ENGINEERING CONTROLS
Eyewash stations; Showers
RESPIRATORY PROTECTION
If exposure limits are exceeded or respiratory irritation is experienced, NIOSH/MSHA approved
respiratory protection should be worn. Supplied air respirators may be required for non-routine or
emergency situations. Respiratory protection must be provided in accordance with OSHA regulations
(see 29 CFR 191 0.134).
PROTECTIVE GLOVES
Impervious gloves
EYE AND FACE PROTECTION
Safety glasses with side-shields
OTHER PROTECTIVE EQUIPMENT
Wear suitable protective clothing and eye/face protection.
Exposure Guidelines
Component CAS RN Source Value
ETHANEDIOLE 107-21-1 ACGIH, Ceiling Aerosol. 100 mg/m3
ETHANEDIOLE 107-21-1 ACGIH, Ceiling Aerosol. 100 mg/m3
Absence of values indicates none found
PEL - OSHA Permissible Exposure Limit; TLV - ACGIH Threshold Limit Value; TWA - Time Weighted Average
OSHA revoked the Final Rule Limits of January 19, 1989 in response to the 11th Circuit Court of Appeals decision (AFL-CIO v. OSHA)
effective June 30, 1993. See 29 CFR 1910.1000 (58 FR 35338).
9.PHYSICAL AND CHEMICAL PROPERTIES
BOILING POINT - C & F: Unknown
VAPOR PRESSURE (20 C) (MM HG): Unknown
FREEZING POINT: Unknown
MELTING POINT: Unknown
PHYSICAL STATE: Solid
ODOR: acrylic
COLOR: white
SPECIFIC GRAVITY (WATER=1): ca. 1.27
DENSITY: ca. 1.227 g/cm3
ACID / ALKALINITY (MEQ/G): Unknown
pH: Unknown
SOLUBILITY IN WATER (20 C): Soluble
SOLUBILITY IN ORGANIC SOLVENT (STATE Unknown
SOLVENT):
Page 4/4
Material Safety Data Sheet
Nexicor
8485 Broadwell Road
Version: 1.3
Cincinnati, Ohio 08/03/2008
N585W 1 2C-CRTRG(0.807LBS-0.366KG)
Acrylic Caulk
VOC EXCL. H2O & EXEMPTS (G/L): 30
10. STABILITY AND REACTIVITY
STABILITY
Stable
HAZARDOUS POLYMERIZATION
Will not occur
HAZARDOUS THERMAL DECOMPOSITION / COMBUSTION PRODUCTS
Carbon dioxide (CO2); Carbon monoxide
INCOMPATIBILITY (MATERIALS TO AVOID)
None known.
CONDITIONS TO AVOID
None known.
11. TOXICOLOGICAL INFORMATION
ACUTE ORAL
Remarks: Unknown
ACUTE DERMAL
Remarks: Unknown
ACUTE INHALATION
Remarks: Unknown
OTHER
None.
MUTAGENICITY
Unknown
Other effects of overexposure
None known.
12. ECOLOGICAL INFORMATION
Page 5/5
Material Safety Data Sheet
Nexicor
8485 Broadwell Road
Version: 1.3
Cincinnati, Ohio 08/03/2008
N585W 1 2C-CRTRG(0.807LBS-0.366KG)
Acrylic Caulk
Additional ecological information
No data available
CHEMICAL FATE
No data available
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD
Disposal should be made in accordance with federal, state and local regulations.
14. TRANSPORT INFORMATION
Further Information: This product is not regarded as dangerous goods according to the
national and international regulations on the transport of dangerous
goods.
15. REGULATORY INFORMATION
Inventories
Canada DSL Inventory y (Positive listing)
China Inventory of Existing y (Positive listing)
Chemical Substances
Canada NDSL Inventory n (Negative listing)
Japan Inventory of Existing & n (Negative listing)
New Chemical Substances
(ENCS)
n (Negative listing)
Korea Existing Chemicals
Inventory (KECI)
n (Negative listing)
Australia Inventory of Chemical
Substances (AICS)
n (Negative listing)
Philippines Inventory of
Chemicals and Chemical
Substances (PICCS)
TSCA list y (Positive listing)
For inventories that are marked as quantity restricted or special cases, please contact Momentive.
Page 6/6
8
Material Safety Data Sheet
Version: 1.3
08/03/2008
N585W 1 2C-CRTRG(0.807LBS-0.366KG)
Acrylic Caulk
US Regulatory Information
SARA (313) CHEMICALS
107-21-1, 1 ,2-Ethanediol75-2 1-8, Ethylene Oxide50-00-0, Formaldehyde7664-41 -7,
Canadian Regulatory Information
WHMIS HAZARD CLASS
D2B TOXIC MATERIALS
Other
SCHDLE B/HTSUS: 3214.10.00.10 Mastic based on rubber
CALIFORNIA PROPOSITION 65
WARNING! This product contains a chemical known in the State of California to cause cancer.
140-88-5, Ethyl Acrylate. 7439-92-1, Lead. 123-91-1, 1 ,4-Dioxane. 7440-02-0, Nickel. 50-00-0,
Formaldehyde. 14808-60-7, Quartz. 75-21-8, Ethylene Oxide.
16. OTHER INFORMATION
OTHER
These data are offered in good faith as typical values and not as product specifications. No warranty,
either expressed or implied, is made. The recommended industrial hygiene and safe handling
procedures are believed to be generally applicable. However, each user should review these
recommendations in the specific context of the intended use and determine whether they are
appropriate., C = ceiling limit NEGL = negligible EST = estimated NF = none found
NA = not applicable UNKN = unknown NE = none established REC = recommended ND =
none determined V = recommended by vendor SKN = skin TS = trade secret R =
recommended MST = mist NT = not tested STEL = short term exposure limit ppm =
parts per million ppb = parts per billion By-product= reaction by-product, TSCA inventory status
not required under 40 CFR part 720.30(h-2).
ONE-COMPONENT POLYURETHANE FOAM SEALANT/ADHESIVE (134a)
(Includes Strawfoam, Gunfoam, Window and Door, Sub-Floor, General Use and Roof Tile. Includes Cylinders)
MSDS # A16354
D12-S, D24-S, D24-GF, D24-GW, D24-SW,
D24-SF. D24-GFB
MATERIAL SAFETYDATA SHEET
1. IDENTIFICATION
Chemical Product
One-Component Polyurethane Foam
Sealant/Adhesive Supplier Information
Nexicor
8485 Broadwell Road
Cincinnati, Ohio 45244
Emergency Overview
24 HOUR Emergency Phone Number:
Transportation Emergency:
International Transportation Emergency:
Revised: March 2008-5
Product is a liquid urethane prepolymer mixture that is packaged under pressure (Non-Flammable Compressed Gas).
Containers should not be heated above 120癋 (49癈) to avoid excessive pressure build-up.
2. COMPOSITION
Chemical Name (common names) CAS Number Percentage LD50 LC50
1,1,1,2- Tetrafluoroethane 811-97-2 10 to 30 percent NA NA
(Non-Flammable Compressed Gas,
HFC, Fluorocarbon) 1 34a
4,4' - Diphenylmethane 101-68-8 5 to 10 percent NA NA
Diisocyanate (MDI)
Higher Oligomers of MDI 9016-87-9 5 to 10 percent NA NA
(Polymeric MDI)
Urethane Pre-polymer Blend Not Available 60 to 100 percent NA NA
(Non-Hazardous Proprietary Blend) This Section
(NOTE: See Section 8 of this MSDS for Exposure Guidelines)
3. HAZARDS IDENTIFICATION
Physical Hazards
Since the containers are pressurized, storage temperature should not exceed 120癋 (49癈) in order to avoid excessive
pressure build-up and possible container rupture. Also, the product has strong adhesive-like characteristics and will
adhere aggressively to skin and other surfaces. If accidental contact occurs, follow the appropriate first-aid
procedure described in Section 4 of this MSDS.
POLYURETHANE FOAM SEALANT/ADHESIVE ISSUE DATE: March 2005 LAST REV: March 2008-5 PAGE 2 OF 4
Potential Health Effects
The primary adverse health effects of this product are related to the Polymeric Isocyanate (MDI) component, and, to
a lesser degree, the Fluorocarbon (134a) component. Therefore, adequate ventilation should be provided to avoid
exceeding the exposure limits of these components (See Section 8). The likelihood of exceeding these limits are low
due to the low concentration of vapor produced during normal use. However, if used indoors, mechanical ventilation
or exhaust should be provided during use and until product is cured.
Entry Route: Effects of Overexposure
Inhalation: May irritate mucous membranes with tightness in chest, coughing, or allergic asthma-like sensitivity.
Extensive overexposure can lead to respiratory symptoms like bronchitis and pulmonary edema. These
effects are usually reversible.
Overexposure to 1,1,1,2 - Tetrafluoroethane may cause lightheadedness, headaches, or lethargy. Persons
with cardiac arrhythmia may be at increased risk in severe exposure.
Eyes: May be irritating to eyes. Foam contact can cause physical damage due to adhesive character.
Skin: May cause localized irritation, reddening or swelling. Prolonged or repeated exposure may lead to
sensitization and/or contact dermatitis.
Ingestion: May cause irritation of mucous membranes in the mouth and digestive tract.
4. FIRST AID
Inhalation: If breathing difficulty is experienced, move to area free of exposure. Provide fresh air. If necessary, provide
oxygen or artificial respiration by trained personnel and obtain medical attention.
Eye Contact: Flush with clean water for at least 15 minutes and obtain medical attention.
Skin Contact: Use a rag to remove excess foam from skin and remove contaminated clothing. Use of a solvent, such as
acetone (nail polish remover) or mineral spirits, may help in removing uncured foam residue from clothing or
other surfaces (avoid eye contact). Cured foam may be physically removed by persistent washing with soap
and water. If irritation develops, use mild skin cream. If irritation persists, obtain medical attention.
Ingestion: Drink 1 to 3 glasses of water and seek immediate medical attention. Never give anything orally to an
unconscious person.
5. FIRE FIGHTING MEASURES
High temperatures will raise the pressure in the containers, which may lead to rupturing. Extinguishing media include: dry
chemical, carbon dioxide, Halon 1211, chemical foam, or water spray if used in large quantities (water contamination will
produce carbon dioxide). Wear self-contained breathing apparatus to protect against toxic decomposition by-products,
including CO, CO2, NO, and traces of HCN. Cured foam is organic and, therefore, will burn in the presence of sufficient
heat, oxygen and an ignition source. Main hazards associated with burning foam are similar to burning of other organic
materials (wood, paper, cotton, etc.) and precautions against exposure should be taken accordingly. Avoid welding or other
"hot work" in the vicinity of exposed cured foam.
6. ACCIDENTAL RELEASE MEASURES/DISPOSAL CONSIDERATIONS
Read all product instructions before using. Personal protective equipment should include (impervious gloves, protective eye
wear and suitable work clothes). Uncured product is very sticky, so carefully remove the bulk of the foam by scraping it up
and then immediately remove residue with a rag and solvent such as polyurethane cleaner, mineral spirits, acetone (nail
polish remover), paint thinner, etc. Once the product has cured, it can only be removed physically by scraping, buffing, etc.
Dispose as plastic waste (foam plastic) in accordance with all applicable guidelines and regulations.
Before disposing of containers, relieve container of any remaining foam and pressure. Allow product to fully cure before
disposing. Never discard in a liquid state.
POLYURETHANE FOAM SEALANT/ADHESIVE ISSUE DATE: March 2005 LAST REV: March 2008-5 PAGE 3 OF 4
7. HANDLING AND STORAGE
Store in a cool, dry place. Ideal storage temperature is 60癋 to 80癋 (15.5癈 to 26.6癈). Storage above 90癋 (32.2癈) will
shorten the shelf life. Storage below 55癋 (12.7癈) may affect foam quality if chemicals are not warmed before using.
Protect containers from physical abuse. Protect unused product from freezing.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Read all product instructions before using. Personal protective equipment should include impervious gloves, protective eye
wear and suitable work clothes. Adequate ventilation should also be employed so that vapor levels do not exceed
recommended guidelines. If vapor levels are expected to exceed these guidelines, use NIOSH approved, positive pressure,
supplied air respirator or a negative pressure half mask with organic vapor cartridges and dust/mist pre-filters. Exercise good
personal hygiene, wash thoroughly after each use.
Exposure Guidelines OSHA ACGIH
4,4' ?Diphenylmethane .020 ppm ceiling .005 ppm TWA
.200 mg/m3 ceiling .051 mg/m3 TWA
Diisocyanate (MDI)
Higher Oligomers of MDI None Established None Established
1,1,1,2 - Tetrafluoroethane (Non-Flammable None Established None Established
Compressed Gas, HFC Fluorocarbon 134a)
(None of the components in this product are listed by IARC, NTP, OSHA or ACGIH as a carcinogen).
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical Appearance : Viscous liquid which foams upon release from container as an off-white to yellowish
froth (Note: Appearance may differ with the introduction of a dye or colorant).
Odor : Slight fluorocarbon odor during curing stage
Specific Gravity : Approximately 1.2 (H2O = 1)
Boiling Point : 1,1,1,2 - Tetrafluoroethane (Non-Flammable Compressed Gas, HFC Fluorocarbon 134a)
boils at -15癋 (-26. 1癈).
Other components boil at temperatures greater than 200癋 (93.3癈).
Product flash point has been tested at approximately 800癋 (426.6癈).
Flash Point :
Vapor Pressure : Contents under pressure have vapor pressure greater than 50 psig / 345 kPa. After
release from container, vapor pressure is very low (not determined).
Solubility in Water : Insoluble, reacts slowly with water during cure; liberating traces of CO2.
Explosion Data : Contents are not known to be sensitive to mechanical impact or static discharge.
10. STABILITY AND REACTIVITY
This product is considered stable under normal and anticipated storage and handling conditions. Do not store above 120癋
(49癈). For longest shelf life, avoid storage above 90癋 (32.2癈). Avoid alcohols, strong bases or amines and metal
compounds (such as small particle metal catalysts).
POLYURETHANE FOAM SEALANT/ADHESIVE ISSUE DATE: March 2005 LAST REV: March 2008-5 PAGE 4 OF 4
11. TRANSPORTATION
Shipping Information
Containers Less Than 1000 cu. cm. (1 liter) Containers Greater Than 1000 cu. cm. (1 liter)
Ground Consumer Commodity ORM-D (On Shipper UN1956 Compressed Gas n.o.s. (Fluorocarbon)
Carton) 2.2 (Non-Flammable Gas Label)
Consumer Commodity Polyurethane Foam
Sealant/Adhesive (On Shipping Document)
UN1956 Compressed Gas n.o.s. (Fluorocarbon)
Air UN1950 Aerosols, Non-Flammable 2.2
2.2 (Non-flammable Gas Label)
(Non-flammable Gas Label)
Water UN1950 AEROSOLS "LTD QTY" 2 UN1956 Compressed Gas n.o.s. (Fluorocarbon)
2.2
Exceptions N/A
Note Emergency Response Guide Numbers - Consumer Commodity # 171. For Aerosols and Compressed Gas
# 126.
12. REGULATORY
Toxic Substances Control Act (TSCA)/Domestic Substances List (DSL):
All ingredients are listed on the TSCA inventory, as well as the Canadian Domestic Substances List.
SARA Title III:
Contains Diphenylmethane Diisocyanate (CAS #101-68-8) subject to the reporting requirements of SARA Title III.
Applicability must be determined by the end user.
Proposition 65:
Based on information currently available, this product is not known to contain detectable amounts of any chemicals currently
listed under California Proposition 65.
V.O.C. Content:
Based on the current EPA definition of volatile organic compound, this product does not have any V.O.C. content.
13. O T H E R
NFPA: Fire 1; Health 2; Reactivity 1
HMIS: Flammability 1; Health 2; Reactivity 1
The information and recommendations set forth herein are presented in good faith and believed to be correct as of the date
hereof. The manufacturer makes no representations as to the completeness or accuracy thereof. Information is supplied upon
the condition that the persons receiving it will make their own determination as to its suitability for their purposes prior to
use. In no event will the manufacturer be responsible for damages of any nature whatsoever resulting from the use of or
reliance upon information. No representations or warranties, either expressed or implied, of merchantability or fitness for a
particular use are made hereunder with respect to this information or the product to which information refers.
Information contained herein is deemed to be reliable, conservative and accurate. Nexicor reserves the right to change the design, specifications or any other
features at any time and without notice, while otherwise maintaining regulatory compliance.
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