BASF Corporation
HELPING MAKE PRODUCTS BETTERTM
Safety data sheet
PLURACOL?1365 POLYOL
Revision date : 2004/06/01 Page: 1/5
Version: 1.0 (30088418/MDS_GEN_US/EN)
1. Substance/preparation and company identification
Company 24 Hour Emergency Response Information
BASF Corporation CHEMTREC: (800) 424-9300
3000 Continental Drive - North BASF HOTLINE: (800) 832-HELP
Mount Olive, NJ 07828-1234
2. Composition/information on ingredients
CAS Number Content (W/W) Chemical name
100.0 % Graft Polyether Polyol
100-42-5 < 500.0 PPM STYRENE
107-13-1 < 100.0 PPM acrylonitrile
3. Hazard identification
Emergency overview
CAUTION: MAY CAUSE EYE, SKIN AND RESPIRATORY TRACT IRRITATION.
Potential health effects
Primary routes of exposure
Routes of entry for solids and liquids include eye and skin contact, ingestion and inhalation. Routes of entry
for gases include inhalation and eye contact. Skin contact may be a route of entry for liquified gases.
Acute toxicity:
Ingestion may cause gastrointestinal disturbances.
Information on: Acrylonitrile
Although at excessive exposure levels AN presents a cancer hazard, this polyol had low residual
AN levels and meets performance exemption (a)(2)(i.i.) of the OSHA AN standard. No special
handling, labeling or surveillance are required.
Irritation:
Irritating to respiratory system. Irritating to eyes and skin.
Repeated dose toxicity:
No known chronic effects.
Medical conditions aggravated by overexposure:
Data available do not indicate that there are medical conditions that are generally recognized as being
aggravated by exposure to this substance/product.
4. First-aid measures
General advice:
Remove contaminated clothing.
BASF Corporation
HELPING MAKE PRODUCTS BETTERTM
Safety data sheet
PLURACOL?1365 POLYOL
Revision date : 2004/06/01 Page: 2/5
Version: 1.0 (30088418/MDS_GEN_US/EN)
If inhaled:
Remove the affected individual into fresh air and keep the person calm. Assist in breathing if necessary.
Immediate medical attention required.
If on skin:
Wash affected areas thoroughly with soap and water. Immediate medical attention required.
If in eyes:
In case of contact with the eyes, rinse immediately for at least 15 minutes with plenty of water. Immediate
medical attention required.
If swallowed:
Rinse mouth and then drink plenty of water. Induce vomiting. Never induce vomiting or give anything by
mouth if the victim is unconscious or having convulsions. Immediate medical attention required.
5. Fire-fighting measures
Flash point: > 160 癈 (DIN 51758)
Autoignition: No data available.
Suitable extinguishing media:
water, dry extinguishing media, carbon dioxide, foam
Hazards during fire-fighting:
carbon dioxide, carbon monoxide, hydrogen cyanide, nitrogen oxides
The substances/groups of substances mentioned can be released in case of fire.
Protective equipment for fire-fighting:
Firefighters should be equipped with self-contained breathing apparatus and turn-out gear.
Further information:
Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.
6. Accidental release measures
Cleanup:
For large amounts: Pump off product.
For residues: Pick up with suitable absorbent material (e.g. sand, sawdust, general-purpose binder,
kieselguhr). Dispose of contaminated material as prescribed.
Spills should be contained, solidified, and placed in suitable containers for disposal.
7. Handling and storage
Handling
Protection against fire and explosion:
No special precautions necessary.
BASF Corporation
HELPING MAKE PRODUCTS BETTERTM
Safety data sheet
PLURACOL?1365 POLYOL
Revision date : 2004/06/01 Page: 3/5
Version: 1.0 (30088418/MDS_GEN_US/EN)
Storage
General advice:
No special precautions necessary.
Storage stability:
Storage temperature: 70 - 80 癋
Protect against moisture.
8. Exposure controls and personal protection
Advice on system design:
Provide local exhaust ventilation to control vapours/mists.
Personal protective equipment
Respiratory protection:
Wear a NIOSH-certified (or equivalent) organic vapour/particulate respirator as needed.
Hand protection:
Chemical resistant protective gloves
Eye protection:
Wear face shield or tightly fitting safety goggles (chemical goggles) if splashing hazard exists.
General safety and hygiene measures:
Avoid contact with skin. Handle in accordance with good industrial hygiene and safety practice. Wear
protective clothing as necessary to prevent contact. Avoid inhalation of vapours/mists.
9. Physical and chemical properties
Form: viscous
Odour: almost odourless
Colour: slightly milky, cloudy
Vapour pressure: > 1 mbar ( 25 癈)
Density: 1.05 g/cm3 ( 25 癈) (DIN 51757)
( 25 癈) (DIN 51550)
Viscosity, dynamic: 4,000 - 10,000
mPa.s
Solubility in water: sparingly soluble
Miscibility with water: partly miscible
10. Stability and reactivity
Conditions to avoid:
> 80 degrees Fahrenheit
Avoid moisture.
Decomposition products:
Hazardous decomposition products: carbon monoxide, carbon dioxide
Thermal decomposition:
No decomposition if stored and handled as prescribed/indicated.
No data available.
Corrosion to metals:
BASF Corporation
HELPING MAKE PRODUCTS BETTERTM
Safety data sheet
PLURACOL?1365 POLYOL
Revision date : 2004/06/01 Page: 4/5
Version: 1.0 (30088418/MDS_GEN_US/EN)
No corrosive effect on metal.
11. Toxicological information
12. Ecological information
Environmental toxicity
Other ecotoxicological advice:
Do not allow to enter soil, waterways or waste water channels. Inhibition of degradation activity in activated
sludge is not to be anticipated during correct introduction of low concentrations. The product has not been
tested. The statement has been derived from products of a similar structure and composition.
13. Disposal considerations
Waste disposal of substance:
Incinerate in a licensed facility.
Do not discharge substance/product into sewer system.
Dispose of in a licensed facility.
Contaminated packaging:
Steel drums must be emptied and can be sent to a licensed drum reconditioner for reuse, a scrap metal
dealer or an approved landfill. Refer to 40 CFR ?261.7 (residues of hazardous waste in empty containers).
Decontaminate containers prior to disposal. Recommend crushing, puncturing or other means to prevent
unauthorized use of used containers.
14. Transport information
Reference Bill of Lading
15. Regulatory information
Federal Regulations
Registration status:
TSCA, US released / listed
16. Other information
Recommended use: polyurethane component, industrial chemicals
Suitable for use in industrial sector: Polymers industry, chemical industry
HMIS III rating
Health: 1 Flammability: 0 Physical hazard: 0
BASF Corporation
HELPING MAKE PRODUCTS BETTERTM
Safety data sheet
PLURACOL?1365 POLYOL
Revision date : 2004/06/01 Page: 5/5
Version: 1.0 (30088418/MDS_GEN_US/EN)
HMIS uses a numbering scale ranging from 0 to 4 to indicate the degree of hazard. A value of zero means that the
substance possesses essentially no hazard; a rating of four indicates high hazard.
Local contact information
William Robert
1-734-324-5244
PLURACOL is a registered trademark of BASF Corporation or BASF AG
IMPORTANT: WHILE THE DESCRIPTIONS, DESIGNS, DATA AND INFORMATION CONTAINED HEREIN
ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE, IT IS PROVIDED FOR YOUR
GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT PROCESSING OR APPLICATION/USE,
WE RECOMMEND THAT YOU MAKE TESTS TO DETERMINE THE SUITABILITY OF A PRODUCT FOR
YOUR PARTICULAR PURPOSE PRIOR TO USE. NO WARRANTIES OF ANY KIND, EITHER
EXPRESSED OR IMPLIED, INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A
PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED OR DESIGNS, DATA OR
INFORMATION SET FORTH, OR THAT THE PRODUCTS, DESIGNS, DATA OR INFORMATION MAY BE
USED WITHOUT INFRINGING THE INTELLECTUAL PROPERTY RIGHTS OF OTHERS. IN NO CASE
SHALL THE DESCRIPTIONS, INFORMATION, DATA OR DESIGNS PROVIDED BE CONSIDERED A
PART OF OUR TERMS AND CONDITIONS OF SALE. FURTHER, YOU EXPRESSLY UNDERSTAND AND
AGREE THAT THE DESCRIPTIONS, DESIGNS, DATA, AND INFORMATION FURNISHED BY BASF
HEREUNDER ARE GIVEN GRATIS AND BASF ASSUMES NO OBLIGATION OR LIABILITY FOR THE
DESCRIPTION, DESIGNS, DATA AND INFORMATION GIVEN OR RESULTS OBTAINED, ALL SUCH
BEING GIVEN AND ACCEPTED AT YOUR RISK.
END OF DATA SHEET
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