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MATERIAL SAFETY DATA SHEET
Section 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRIMEX PLASTICS CORPORATION PRIME ABS SHEET
Trade Name:
Supplier: PRIMEX PLASTICS CORPORATION Emergency Response Number
1235 NORTH "F" STREET (800) 222-5116
RICHMOND, INDIANA 47374
Section 2. Composition and Information on Ingredients
CAS Number Chemical Name
9003-56-9 Acrylonitrile/Butadiene/Styrene
9003-54-7 Styrene/Acrylonitrile Copolymer
100-42-5 Acrylonitrile/Butadiene/Styrene Terpolymer
107-13-1 Residual Arrylonitrile Monomer
Section 3 Hazard Identification
Emergency Overview
The ABS sheet is not expected to be an inhalation hazard under normal processing conditions.
If material is processed under prolonged exposure to flame or high temperature, thermal burns to
The skin may occur, and gases may be produced that are irritatingto the respiratory system.
Primary Routes of Exposure
Routes of entry could include eye, skin, and inhalation, due to exposure to flame (molten plastic).
Acute Effects of Exposure due to High Temperature and Thermal Decomposition.
At Thermal Decomposition small amounts of Styrene, Ethybenzene and Acrylonitrile may be
emitted. Exposure of high concentrations of these vapors and fumes could cause nausea,
drowsiness, and headache.
Chronic Effects of Exposure to High Temperature and Thermal Decomposition
In October 1988, the National Institute for Occupational Safety and Health (NIOSH) found
insufficient evidence to classify Styrene as a Carcinogen.
Section 4 First-Aid Measures
Inhalation
Remove affected individual to fresh air, seek medical attention if difficulties in breathing occur.
Skin
If skin has contact with molten material, place affected area under cold running water. Seek
medical attention for removal of material from the affected area.
Eyes
If there is contact to the eyes with molten material, rinse with plenty of water and seek immediate
medical attention. If fines enter the eye, rinse with water for 15 minutes and seek immediate
medical attention if irritation develops.
Section 5 Fire-Fighting Measures
Suitable Extinguishering Media
Dry extinguisher, water, carbon dioxide, foam
Protective Equipment for Fire-Fighting
Firefighters should be equipped with self-contained breathing apparatus.
Hazardous Combustion Products
During a fire, irritating and toxic gasses and aerosols may be generated by thermal decomposition
and combustion.
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Section 6 Accidental Release Measures
The ABS material in sheet form is not applicable for this section.
Section 7 Handling and Storage
Handling
Protect against flame and intense heat.
Storage
Store in well ventilated area, avoid extreme heat and any sources of ignition, or open flames.
Secondary Use / Reprocessing
When reprocessing material for secondary use, ground all handling equipment. Keep material
and dust produced away from high heat and flame. Use good housekeeping practices when
reprocessing material.
Section 8 Exposure Controls and Personal Protection
Personal Protective Equipment
Respiratory Protection
During processing, respiratory protection may not be necessary if ventilation is adequately
provided. At excessive processing temperatures, breathing protection may be required.
Hand Protection
Gloves may be required when processing the sheet due to sharp edges and when plastic is in the
molten state.
Eye Protection
Safety glasses with side-shields are recommended.
General
Avoid contact with molten material on the skin, eyes and clothing. Handle product in accordance
with good industrial hygiene and safety practices.
Section 9 Physical and Chemical Properties
Physical State and Appearance
Solid ABS Sheet.
Flashpoint
730 deg. F - 752 deg. F (388 deg. C - 400 deg. C)
Autoignition Temperature
923 deg. F - 950 deg. F (495 deg. C - 510 deg. C)
Melting Point
180 deg. F - 225 deg. F (82 deg. C - 107 deg. C)
Section 10 Stability and Reactivity
Stability and Reactivity
This product in the finished state (sheet) is stable.
Incompatibility with Various Substances
Reactive with strong oxidizing agents.
Decomposition Temperature
Begins at approximately 500 deg. F (260 deg. C).
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Sectio 10 Stability and Reactivity Continued:
Hazardous Decomposition Products
Carbon Dioxide, Water, Carbon Monoxide, Hydrocarbons, Hydrogen cyanide and possibly some
original monomers (styrene and acrylonitrile) are released as fumes and vapors when processing
the sheet at high temperature and exposure to flame.
Section 11 Toxicological Information
Chronic Effects on Humans
No specific information is available, but no ecological hazard is suspected.
Other Toxic Effects on Humans
In plastic sheet form, not considered dangerous to humans.
Section 12 Ecological Information
No information is available but no ecological hazard is suspected
Section 13 Disposal Considerations
Waste Information
Transfer to an approved disposal area in accordance with federal, state and local regulations.
Section 14 Transport Information
DOT Classification
Not a DOT controlled or regulated material (U.S.A)
Section 15 Regulatory Information
OSHA Classification
This product is hazardous under the criteria of the Federal OSHA Hazard Communication
Standard 29 CFR 1910.1200.
TSCA
Components of this product are listed on the TSCA Inventory.
CERLA
This material is not subject to special reporting under the requirements of the Comprehensive
Environment Response, Compensation and Liability Act.
SARA Title III
Section 302 Extremely Hazardous Substances.
None reported.
Section 311/312 Hazard Categories
Immediate Health Hazard; Delayed Health Hazard
RCRA Status
It is the responsibility of the product user to determine at the time of disposal of the material,
if it should be classified as a hazardous waste. (40 CFR 261.20.24)
State Regulations
No Proposition 65 chemicals present at levels that would require a warning under the California
Safe Drinking Water and Toxic Enforcement Act.
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Section 16 Other Information
Hazardous Material Information System (U.S.A)
Health 1
Fire Hazard 0
Reactivity 0
Personal Protection 0
ABS - Acrylonitrile/Butadiene/Styrene Terpolymer Date Prepared: February 18, 2005
The information listed within this MSDS is solely designated for the finished processed sheet. The information
listed is to the best of our knowledge, accurate and reliable. However, there is no warrenty or guarantee that
can be made to its accuracy, reliability or completeness. Primex will not accept liability for any loss or
damage that may occur from the use of this information.
Prepared and Approved By: David Wolf
Approval date: February 18, 2005
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