EC safety data sheet SIGMA-ALDRICH
Status: 1/23/2003
Trade name: HYDRANAL-Water Standard 1.00
Version : 1 / EU
Product no.: SEC34828 Date of printing :
1.) Identification of the substance/preparation and company
Product details
Trade name
HYDRANAL-Water Standard 1.00
Identification of the manufacturer / supplier
Address
Sigma-Aldrich Laborchemikalien GmbH
Wunstorfer Str. 40
D-30926 Seelze
Telephone no. +49 (0) 5137-999-0
Information provided by / telephone
Health, Safety & Environment - Product Defintion
Emergency telephone number
+49 (0) 5137-999-0
2.) Composition / information on ingredients
Chemical characterization
HYDRANAL-Water Standard 1.00
Standard for coulometric Karl Fischer titration
1 g (1 ml) contains 1.00 mg = 0.1 % H2O 20 0C
Hazardous ingredients
Anisol
CAS no. 100-66-3
Concentration > 60 %-b.w.
3.) Hazards possibilities
R phrases
10 Flammable.
4.) First aid measures
After inhalation
Remove the casualty into fresh air and keep him calm.
After skin contact
In case of contact with skin wash off immediately with plenty of water.
After eye contact
In case of contact with eyes rinse thoroughly with plenty of water and seek medical advice.
After ingestion
When swallowed, allow water to be drunk. Do not induce vomiting. Summon a doctor immediately.
5.) Fire-fighting measures
Suitable extinguishing media
Water mist; Foam; Carbon dioxide; Dry powder
Special protective equipment for firefighting
Use self-contained breathing apparatus.
6.) Accidental release measures
Personal precautions
Ensure adequate ventilation. Keep away sources of ignition.
Environmental precautions
Do not allow to enter drains or waterways.
Methods for cleaning up/taking up
Take up with absorbent material (eg sand, kieselguhr, universal binder). Pick for disposal in tightly closed
page: 1(2)
EC safety data sheet SIGMA-ALDRICH
Status: 1/23/2003
Trade name: HYDRANAL-Water Standard 1.00
Version : 1 / EU
Product no.: SEC34828 Date of printing :
containers
7.) Handling and storage
Handling
Advice on safe handling
Provide good ventilation of working area (local exhaust ventilation if necessary).
Advice on protection against fire and explosion
Keep away from sources of ignition - refrain from smoking.
Storage
Further information on storage conditions
Keep container tightly closed and dry in a cool, well-ventilated place.
VCI storage category
3A Flammable liquid substances
8.) Exposure controls / personal protection
Ingredients with occupational exposure limits to be monitored
None
Personal protective equipment
Hand protection
Rubber gloves
Eye protection
Safety glasses
Skin protection
light protective clothing, anti-static
General protective and hygiene measures
Do not inhale vapours; Remove soiled or soaked clothing immediately. Do not eat, drink or smoke during work time.
Wash hands before breaks and after work.
9.) Physical and chemical properties
Appearance
Form liquid
Colour colourless
Odour aromatic
Safety data
Changes in physical state
Value 155
type Boiling point
Value 癈
Pressure 1013 hPa
Flash point
Value 44 癈
Method closed cup
Density
Value 1.000 g/cm?br>
Reference temperature 20 癈
Soluble in
soluble in most organic solvents
Solubility in water
Remarks insoluble
10.) Stability and reactivity
Thermal decomposition
Remarks No decomposition if used as prescribed.
page: 2(2)
EC safety data sheet SIGMA-ALDRICH
Status: 1/23/2003
Trade name: HYDRANAL-Water Standard 1.00
Version : 1 / EU
Product no.: SEC34828 Date of printing :
11.) Toxicological information
Acute toxicity
Acute oral toxicity
LD50 2800 mg/kg
Species mouse
Source RTECS
LD50 3700 mg/kg
Species rat
Source RTECS
Irritant/corrosive effects
Irritant effect on skin
Species rabbit
Duration of exposure 24 h
evaluation Moderately irritating
Source RTECS
Other information (chapter 11.)
The toxicological information is based on the main components.
12.) Ecological information
General information / ecology
Biologically degradable, when diluted may be degraded in biological purification plants
13.) Disposal considerations
Product
May be released into drains. Observe local authority regulations
14.) Transport information
Land transport ADR/RID
Class 3
Packaging group III
Hazard no. 30
UN number 2222
Technical name ANISOL, LOESUNG,
Marine transport IMDG/GGVSee
Class 3
Packaging group III
UN number 2222
Propper shipping name ANISOLE, SOLUTION,
EmS 3-07
MARPOL MARINE POLLUTANT
Air transport ICAO/IATA
Class 3
Packaging group III
UN number 2222
Propper shipping name ANISOLE,
15.) Regulatory information
Hazardous component(s) to be indicated on label
Anisol
R phrases
10 Flammable.
page: 3(2)
EC safety data sheet SIGMA-ALDRICH
Status: 1/23/2003
Trade name: HYDRANAL-Water Standard 1.00
Version : 1 / EU
Product no.: SEC34828 Date of printing :
National regulations
VbF (Germany)
VbF-Class A II
Other regulations, restrictions and prohibition regulations (for Germany only)
Regulations D; additional ZH 1/319 "Data Sheet: Solvents (M 017)"
references
16.) Other information
Other information
Anisol
10 Flammable.
Department issuing safety data sheet
This information is based on our present state of knowledge. However, it should not constitute a guarantee for any
specific product properties and shall not establish a legally valid relationship.
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