January 28, 2009
Chemtane Energy LLC CHEMTANE 2 BLENDED in PROPANE
MSDS (MATERIAL SAFETY DATA SHEET)
1905 N Battlebell
Highlands, TX 77562
Phone numbers: Voice (281) 424-8787 Spill Chemtrec (800) 424-9300
Fax (281) 424-9349 (202) 483-7616 24 hr.
1. Identification of the substance/preparation and of the company/undertaking
Chemtane 2 in Propane / Formulated by Chemtane Energy LLC (See contact info above)
Person responsible for placing product on market: Raymond Davis 800-776-1485; Cell 281 382-1062
P.O. Box 2210
Baytown, Texas 77522
USA
Contact in EU: inmasegarra@gdaparatos.com
MSDS preparation: James Boucher jboucher@chemtane2.com
Health Emergency Toll Free 800-776-1485 (During office hours.) See numbers above for Spill.
Emergency phone:National Institute of Toxicology: 0034915628469
2. Hazards Identification
Extremely Flammable Liquid and Vapor
LIQUID CAN CAUSE SKIN AND EYE INJURY
MAY EXCLUDE OXYGEN AVAILABLE FOR BREATHING
MAY NOT GIVE LEAK DETECTION BY SENSE OF SMELL
CONTENTS UNDER PRESSURE
Hazardous in case of ingestion; Aspiration hazard if swallowed
Eye: Liquid or vapors may be mildly irritating.
Skin: prolonged or repeated contact with the liquid may cause defatting of the skin resulting in drying, redness,
and possibly blistering.
Inhalation: Vapors may be irritating to lungs and mucous membranes of the nose and throat.
Overexposure may cause dizziness, headache, excitation, drowsiness, loss of coordination, anesthesia,
unconsciousness, and reparatory arrest. Exposure to Chemtane V in concentrations of 500 ppm for ten minutes
was found not to be irritating to the mucous membranes or to produce local or systematic effects in humans.
Ingestion: May cause effects similar to those of inhalation and gastrointestinal irritation. If swallowed, may be
aspirated resulting in inflammation and possible fluid accumulation in the lungs.
Chronic: Prolonged or repeated skin contact may cause dermatitis.
Target Organs: Central nervous system, liver, lungs.
Revision Number 1 ?1/28/2009 Page 1 of 6 NE - Not Established
3. Composition/Information on Ingredients
Ingredients EINECS CAS OSHA
Name Number Number PEL Index No.
Propane (>96%) 200-827-9 74-98-6 1000 ppm 601-003-00-5
Soltrol 10 70024-92-9 70024-92-9 NE
Cyclopentane 206-016-6 287-92-3 600 ppm
n-Pentane 203-692-4 109-66-0 600 ppm
2-Methylpentane 203-523-4 107-83-5 500 ppm
Isopentane 201-142-8 78-78-4 NE
2,3-Dimethylbutane 201-193-6 79-29-8 500 ppm
Isohexanes 232-443-2 8030-30-6 NE
2-Propanol 200-661-7 67-63-0 500 ppm
4. First-Aid Measures
FIRST AID AND EMERGENCY PROCEDURES:
Eye: Flush eyes with running water for at least fifteen minutes. If irritation or adverse symptoms develop, seek
medical attention.
Skin: Wash skin with soap and water. If irritation or adverse symptoms develop, seek medical attention.
Inhalation: Remove from exposure. If breathing is difficult, give oxygen. If breathing ceases, administer artificial
respiration followed by oxygen. Seek immediate medical attention.
Ingestion: Do not induce vomiting. Seek immediate medical attention.
NOTE TO PHYSICIAN: Gastric lavage using a cuffed endotracheal tube may be performed at your discretion.
5. Fire-Fighting Measures
Flash Point -150 F (-101 C) LEL 2.3% UEL 9.4%
EXPLOSIVE LIMITS: (% by volume in Air) : LEL 2.3% UEL 9.4%
FIRE EXTINGUISHING MEDIA: Dry chemical, foam or carbon dioxide (CO2)
SPECIAL FIRE FIGHTING PROCEDURES: Evacuate area of all unnecessary personnel. Use NIOSH/MSHA
approved self-contained breathing apparatus and other protective equipment and/or garments described in
Section C if exposure conditions warrant. Shut off source. Water fog or spray to cool exposed containers and
equipment. Do not spray water directly on fire. Product will float and could be reignited on surface of water.
FIRE AND EXPLOSION HAZARDS: Carbon oxides formed when burned. Highly flammable vapors which are
heavier than air may accumulate in low areas and/or spread along ground away from handling site. Flash back
along vapor trail is possible.
Unusual Fire and Explosion Hazards pressurized containers can present explosion hazard in fire.
High volatility, heavier than air.
6. Accidental Release Measures
Precautions Required if Material is Released or Spilled:
Evacuate area of all unnecessary personnel. Wear Protective equipment and/or garments described in
Section C if exposure conditions warrant. Shut off source if possible and contain spill. Protect from ignition.
Keep out of water sources and sewers.
Uncontrolled releases should be responded to by trained personnel using pre-planned procedures. Proper
protective equipment should be used. In case of a release, clear the affected area and protect people.
Revision Number 1 ?1/28/2009 Page 2 of 6
Adequate fire protection must be provided. Minimum Personal Protective Equipment should be Level B: fire-
retardant protective clothing, mechanically-resistant gloves and Self-Contained Breathing Apparatus. Use
only non-sparking tools and equipment. Locate and seal the source of the leaking gas. Protect personnel
attempting the shut-off with water-spray. Allow the gas to dissipate. Monitor the surrounding area for
combustible gas levels, and oxygen. Combustible gas concentration must be below 10% of the LEL of
Propane (see Section 5, Fire-Fighting Measures) prior to entry of response personnel. The atmosphere must
contain components below levels listed in Section 2 (Composition and Information on Ingredients) and have
at least 19.5 percent oxygen before personnel can be allowed in the area without Self-Contained Breathing
Apparatus. Attempt to close the main source valve prior to entering the area. If this does not stop the release
(or if it is not possible to reach the valve), allow the gas to release in-place or remove it to a safe area and
allow the gas to be released there.
7. Handling and Storage
WORK PRACTICES AND HYGIENE PRACTICES: As with all chemicals, avoid getting this gas mixture IN YOU.
Do not eat or drink while handling chemicals. Be aware of any signs of overexposure [See Section 3 (Hazard
Identification)], because overexposure to fatal concentrations of this product could occur without any significant
warning symptoms.
STORAGE AND HANDLING PRACTICES: Cylinders should be stored in dry, well-ventilated areas away from
sources of heat. Compressed gases can present significant safety hazards. Store containers away from heavily
trafficked areas and emergency exits. Post "No Smoking or Open Flames" signs in storage or use areas.
SPECIAL PRECAUTIONS FOR HANDLING GAS CYLINDERS: Protect cylinders against physical damage. Store
in cool, dry, well-ventilated, fireproof area, away from flammable materials and corrosive atmospheres. Store away
from heat and ignition sources and out of direct sunlight. Do not store near elevators, corridors or loading docks.
Avoid storing products by incompatible chemicals. Do not store containers where they can come into contact with
moisture. Cylinders should be stored upright and be firmly secured to prevent falling or being knocked over.
Cylinders can be stored in the open, but in such cases, should be protected against extremes of weather and from
the dampness of the ground to prevent rusting. Never tamper with pressure relief devices in valves and cylinders.
Cylinders should be separated from oxygen cylinders, or other oxidizers, by a minimum distance of 20 ft., or by a
barrier of non-combustible material at least 5 ft. high, having a fire-resistance rating of at least 0.5 hours. Isolate
from other incompatible chemicals (refer to Section 10, Stability and Reactivity). Storage areas must meet
national electrical codes for Class 1 Hazardous Areas. Post "No Smoking or Open Flames" signs in storage or
use areas. Consider installation of leak detection and alarm for storage and use areas. Have appropriate
extinguishing equipment in the storage area (i.e. sprinkler system, portable fire extinguishers).
The following rules are applicable to situations in which cylinders are being used:
Before Use: Move cylinders with a suitable hand-truck. Do not drag, slide or roll cylinders. Do not drop cylinders or
permit them to strike each other. Secure cylinders firmly. Leave the valve protection cap in-place until cylinder is
ready for use.
During Use: Use designated CGA fittings and other support equipment. Do not use adapters. Do not heat cylinder
by any means to increase the discharge rate of the product from the cylinder. Use check valve or trap in discharge
line to prevent hazardous backflow into the cylinder. Do not use oils or grease on gas-handling fittings or
equipment.
After Use: Close main cylinder valve. Replace valve protection cap. Mark empty cylinders "EMPTY".
NOTE: Use only DOT or ASME Code containers. Earth-ground and bond all lines and equipment associated with
this product. Close valve after each use and when empty. Cylinders must not be recharged except by or with the
consent of owner. For additional information refer to the Compressed Gas Association Pamphlet P-1, Safe Handling
of Compressed Gases in Containers. Additionally, refer to CGA Bulletin SB-2 "Oxygen Deficient Atmospheres".
PROTECTIVE PRACTICES DURING MAINTENANCE OF CONTAMINATED EQUIPMENT: Follow practices
indicated in Section 6 (Accidental Release Measures). Make certain application equipment is locked and tagged-out
safely. Always use product in areas where adequate ventilation is provided.
Revision Number 1 ?1/28/2009 Page 3 of 6
8. Exposure Controls / Personal Protection
Ventilation and engineering controls: Use with adequate ventilation to ensure compliance with exposure limits
described in Section 3 (Composition /Information on Ingredients). Local exhaust ventilation is preferred, because
it prevents dispersion of this gas mixture into the work place by eliminating it at its source. If appropriate, install
automatic monitoring equipment to detect the levels of flammable gas, and oxygen.
Respiratory protection: Maintain Oxygen levels above 19.5% in the workplace. If respiratory protection is
needed, use of a full-facepiece pressure/demand SCBA or a full facepiece, supplied air respirator with
auxiliary self-contained air supply is required
Eye protection: Splash goggles, face-shields or safety glasses.
Hand protection: Wear mechanically-resistant gloves when handling cylinders of this product. If use of this gas
mixture involves the use of other chemicals, wear gloves appropriate for those materials.
Body protection: Use body protection appropriate for task. Cotton clothing is recommended to prevent static
electric build up. If a hazard of injury to the feet exists due to falling objects, rolling objects, where objects
may pierce the soles of the feet or where employee's feet may be exposed to electrical hazards, use foot
protection.
9. Physical and Chemical Properties
Boiling Point -42 癈 (- 43.6 癋)
Specific Gravity (H2O = 1) at 25癈 (77癋) and 1 atm: 0.5077
Specific Gravity (Air = 1) at 21.1癈 (70癋) and 1 atm: 1.523
Vapor Density at 21.1癈 (70癋) and 1 atm: 0.2612 lb/ft3 (4.183 kg/m3)
Vapor Pressure 218 PSI @ 37.78 C ; 110 PSI @ 21.1 C
Evaporation Rate (Butyl Acetate = 1) 1.00
Solubility in Water Not Soluble
Appearance is Colorless Gas
Odor ?Faint unpleasant Odor
Gas at Standard Temperature and Pressure (STP)
Freezing Point at 1 atm: -187.69癈 (-305.84癋)
Flash Point (test method): -104癈 (-156癋) TCC
Flammable
Flammable Limits in Air, % by volume: LOWER: 2.1% UPPER: 9.5%
Solubility in Water @ 20癈 (68癋): 0.065
Autoignition Temperature: 450癈 (842癋)
Molecular Weight: 44.096
Molecular Formula: C3H8
10. Stability and Reactivity
Stability: Stable
Incompatibility (Materials to Avoid): oxygen and strong oxidizing agents
Hazardous Polymerization: Will Not Occur
Conditions to Avoid: Avoid exposing cylinders to extremely high temperatures, which could cause the cylinders to
rupture. Avoiding exposing this gas mixture to incompatible chemicals.
Hazardous Decomposition Products: Carbon oxides formed when burned.
Revision Number 1 ?1/28/2009 Page 4 of 6
11. Toxicological Information
Toxicity data: The following data are for Propane component of this mixture.
All other components are in less than 1% concentration.
PROPANE.
Skin Contact (Rabbit): Several formulations containing an isobutane-propane mixture were tested for skin
irritation effects. All formulations contained less than 13% propane. All of the formulations containing propane
caused only mild irritation.
Effects on Short-Term Inhalation: Guinea-pigs breathing 5.5% propane by volume developed tremors after 5
minutes. Nausea, retching, and stupefaction were observed when animals were exposed for 30-120 minutes. All
the animals survived a two-hour exposure and had no significant tissue damage. A gas concentration of 89% did
not cause anesthesia, but depressed the blood pressure of cats. Inhalation of 10 percent propane by mice and
15% by dogs cause weak cardiac sensitization, Presumably, all of these effects are reversible when exposure
ceases. In primates, 10% propane caused some change in heart function. At 20% there was aggravation of these
symptoms and respiratory depression.
Effects of Long-Term Inhalation: No toxicity or abnormalities were observed when monkeys were exposed to
approximately 750 ppm for 90 days. Similar results were obtained when monkeys were exposed to an aerosol
spray containing 65% propane and isobutane.
Suspected cancer agent: The components of this gas mixture are not found on the following lists: U.S.
FEDERAL OSHA Z LIST, NTP, CAL/OSHA, IARC, and therefore are not considered to be, nor suspected to be
cancer-causing agents by these agencies.
Irritancy of product: Prolonged contact may result in mild irritation of the skin. Contact with rapidly expanding
gases can cause frostbite and damage to exposed skin and eyes.
Sensitization of product: The components of this gas mixture are not human skin or respiratory sensitizers. The
Propane component of this gas is considered to be a weak cardiac sensitizer, based on animal testing.
Reproductive toxicity information: Listed below is information concerning the effects of this product and its
components on the human reproductive system.
Mutagenicity: This product is not reported to cause mutagenic effects in humans.
Embryotoxicity: This product is not reported to cause embryotoxic effects in humans.
Teratogenicity: This product is not reported to cause teratogenic effects in humans.
Reproductive Toxicity: This product is not reported to cause adverse reproductive effects in humans.
12. Ecological Information
Environmental stability: This gas mixture will be dissipated rapidly in well-ventilated areas.
Effect of material on plants or animals: Due to the gaseous nature of this mixture, no adverse effect is
expected in animal and plant, except frost produced in the presence of rapidly expanding gases may adversely
affect plant life.
Effect of chemical on aquatic life: No evidence is currently available on the effects of this gas mixture on
aquatic life.
Floats on top of water. Specific Gravity (H2O = 1): 0.63 at 15.6/15.6 oC (60/60 oF)
Does and not readily contaminate groundwater.
13. Disposal Considerations
Disposal by incineration is acceptable.
Waste Disposal (Insure Conformity with all Applicable Disposal Regulations): Incinerate or otherwise manage
empty damaged cylinders at a permitted waste management facility.
Revision Number 1 ?1/28/2009 Page 5 of 6
14. Transport Information
DOT IDENTIFICATION NUMBER UN1978
DOT Hazard Class 2
Road and train classification
(TPC/ADR/TPF/RID): 23
Road and train transport hazard label
(TPC/ADR/TPF/RID): 2.1
FLAMMABLE GAS
15. Regulatory Information
Labelling of containers:
Pictogram: F+ Extremely flammable
Risk sentence: R12 Extremely flammable
Safety sentences: S2: Keep away from children
S9: Store and use with adequate ventilation
S16: Keep away from flames or sparks. Do not smoke
S33: Avoid electrostatic charges.
Follow Home regulations regarding:
Labour code
Classified installations
Habitable places
Public premises
Very high buildings
16. Other Information
MSDS has been prepared according to directive 91/155/CEE (J.O. N?L76 del 22.03.91,p.35) modified
This
by REACH directive
The information contained herein is based on data considered accurate. However, no warranty is
expressed or implied regarding the accuracy of these data or the results to be obtained from the use
thereof. GD Aparatos y Accesorios para Gas, S.L. assumes no responsibility for injury to the vendee
or third persons proximately caused by the material if reasonable safety procedures are not adhered
to as stipulated in the data sheet. Additionally, GD Aparatos, assumes no responsibility for injury to
the vendee or third persons proximately caused by abnormal use of the material even if reasonable
safety procedures are followed. Furthermore, vendee assumes the risk in his use of the material.
Revision Number 1 ?1/28/2009 Page 6 of 6
|