Safety Data Sheet 1907/2006/EC - GB
Spray adhesive
Article number: 13 90 05
Buehler GmbH
Date printed: 23.04.2009, Revision: 23.04.2009 Page 1 / 6
1 Identification of the substance / preparation and of the company
Product: Spray adhesive
Article number: 13 90 05
Registration number: not applicable
Use: see product designation
Identified use: none
Method of operation: See product information.
Company: Buehler GmbH
In der Steele 2
D-40599 D黶seldorf / GERMANY
Phone: 0800 707 6273
Fax: 0800 707 6274
Homepage: www.buehler-met.de/en/
E-mail: sales@buehler.co.uk
Emergency phone: 0800 707 6273 (Only valid if dialled within the UK) +49 (0) 211 974100
Responsible: Simonavicius@chemiebuero.de
2 Hazards identification
Physico-chemical hazards: See chapter 10 and R-phrases.
Human health dangers: See R-phrases.
Environmental hazards: See R-phrases.
Other hazards: none
Hazard symbols:
Extremely flammable Irritant
R-phrases: R 12: Extremely flammable.
R 36: Irritating to eyes.
R 52/53: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
R 66: Repeated exposure may cause skin dryness or cracking.
R 67: Vapours may cause drowsiness and dizziness.
3 Composition / Information on ingredients
10 - 20% Propane
F+, R12 CAS: 74-98-6, EINECS/ELINCS: 200-827-9, EU-INDEX: 601-003-00-5, ECBnr:
10 - 20% Butane
F+, R12 CAS: 106-97-8, EINECS/ELINCS: 203-448-7, EU-INDEX: 601-004-00-0, ECBnr:
5 - 10% iso-Butane
F+, R12 CAS: 75-28-5, EINECS/ELINCS: 200-857-2, EU-INDEX: 601-004-00-0, ECBnr:
0,5 - < 1,5% Isopentane
Xn-F+-N, R12-65-66-67-51/53 CAS: 78-78-4, EINECS/ELINCS: 201-142-8, EU-INDEX: 601-006-00-1, ECBnr:
7 - < 12% Naphtha (petroleum), hydrodesulfurized light, dearomatized
F-Xn-N, R11-38-51/53-65-67 CAS: 92045-53-9, EINECS/ELINCS: 295-434-2, EU-INDEX: 649-383-00-1, ECBnr:
5 - < 7,5% Naphtha (petroleum), hydrotreated light [contains less than 0,1 % w/w benzene (EINECS No 200-753-7)]
F-Xn-N, R11-38-51/53-65-67 CAS: 64742-49-0, EINECS/ELINCS: 265-151-9, EU-INDEX: 649-328-00-1, ECBnr:
0,1 - < 0,5% n-Hexane
F-Xn-N, R11-38-48/20-51/53-62-65-67 CAS: 110-54-3, EINECS/ELINCS: 203-777-6, EU-INDEX: 601-037-00-0, ECBnr:
1 - < 3,5% Pentane
F+-Xn-N, R12-65-66-67-51/53 CAS: 109-66-0, EINECS/ELINCS: 203-692-4, EU-INDEX: 601-006-00-1, ECBnr:
25 - 35% Acetone
F-Xi, R11-36-66-67 CAS: 67-64-1, EINECS/ELINCS: 200-662-2, EU-INDEX: 606-001-00-8, ECBnr:
Comment on component parts: For the wording of the listed risk phrases refer to section 16.
http://www.chemiebuero.de Tel.+49(0)941-566-398(-792)Fax.+49(0)941-566-994 eMail:info@chemiebuero.de wbl00052 gb
Safety Data Sheet 1907/2006/EC - GB
Spray adhesive
Article number: 13 90 05
Buehler GmbH
Date printed: 23.04.2009, Revision: 23.04.2009 Page 2 / 6
4 First aid measures
General information: Change soaked clothing.
Inhalation: Ensure supply of fresh air.
In the event of symptoms seek for medical treatment.
Skin contact: In case of contact with skin wash off immediately with soap and water.
Consult a doctor if skin irritation persists.
Eye contact: In case of contact with eyes rinse thoroughly with plenty of water and seek medical advice.
Ingestion: not applicable
Advice to doctor: Treat symptomatically.
5 Fire-fighting measures
Suitable extinguishing media: Dry powder.
Carbon dioxide.
Foam.
Water spray jet.
Extinguishing media that must not be used:
Full water jet.
Special exposure hazards arising from the substance or preparation itself or combustion products:
Unknown risk of formation of toxic pyrolysis products.
Bursting aerosols can be forcibly projected from a fire.
Special protective equipment for firefighters:
Use self-contained breathing apparatus.
Additional information: Fire residues and contaminated firefighting water must be disposed of in accordance within the local
regulations.
6 Accidental release measures
Personal precautions: Keep away from all sources of ignition.
Ensure adequate ventillation.
Environmental precautions: not applicable
Methods for cleaning up: Take up mechanically.
Take up residues with absorbent material (e.g. sand).
Dispose of absorbed material in accordance within the regulations.
7 Handling and storage
Advice on safe handling: Use solvent-resistant equipment.
Use only in well-ventilated areas.
Advice on protection against fire and explosion:
Keep away from all sources of ignition - Refrain from smoking.
Vapours can form an explosive mixture with air.
Requirements for storage rooms and vessels:
Provide solvent-resistant and impermeable floor.
Advice on storage compatibility: Do not store together with oxidizing agents.
Further information on storage conditions:
Keep container in a well-ventilated place.
Protect from heat/overheating.
http://www.chemiebuero.de Tel.+49(0)941-566-398(-792)Fax.+49(0)941-566-994 eMail:info@chemiebuero.de wbl00052 gb
Safety Data Sheet 1907/2006/EC - GB
Spray adhesive
Article number: 13 90 05
Buehler GmbH
Date printed: 23.04.2009, Revision: 23.04.2009 Page 3 / 6
8 Exposure controls / personal protection
Additional advice on system design:
Ensure adequate ventilation on workstation.
Ingredients with occupational exposure limits to be monitored:
1 - < 3,5% Pentane, 600ppm*, 1800mg/m?,
5 - < 7,5% Naphtha (petroleum), hydrotreated light [contains less than 0,1 % w/w benzene (EINECS No 200-753-7)], 1200mg/m?,
7 - < 12% Naphtha (petroleum), hydrodesulfurized light, dearomatized, 1200mg/m?,
0,5 - < 1,5% Isopentane, 600ppm*, 1800mg/m?,
5 - 10% iso-Butane, 600ppm*, 1450mg/m?, General remarks: n-Butane
0,1 - < 0,5% n-Hexane, 20ppm*, 72mg/m?, General remarks: EU
25 - 35% Acetone, 500ppm*, 1210mg/m?,
10 - 20% Butane, 600ppm*, 1450mg/m?,
* WEL: Workplace exposure limit
Respiratory protection: Breathing apparatus in the event of high concentrations.
Short term: filter apparatus, combination filter A-P2.
Hand protection: Butyl rubber, >120 min (EN 374).
Eye protection: Safety glasses.
Skin protection: not applicable
General protective measures: Avoid contact with eyes and skin.
Do not inhale gases/vapours/aerosols.
Hygiene measures: Do not eat, drink, smoke or take drugs at work.
Wash hands before breaks and after work.
Use barrier skin cream.
Delimitation and monitoring of the environmental exposition:
not determinated
9 Physical and chemical properties
Form: aerosol
Color: white
Odor: characteristic
pH-value: not applicable
pH-value [1%]: not applicable
Boiling point [癈]: not applicable
Flash point [癈]: not applicable
Flammability [癈]: not applicable
Lower explosion limit: 1,0 Vol.%
Upper explosion limit: 13,0 Vol.%
Oxidizing properties: no
Vapour pressure [kPa]: not determinated
Density [g/ml]: 0,71
Density at [癈]: 20
Bulk density [kg/m砞: not applicable
Solubility in water: insoluble
Partition coefficient [n-octanol/water]:
not determinated
Viscosity: not applicable
Relative vapour density determined in air:
not applicable
Evaporation speed: not applicable
Melting point [癈]: not applicable
Autoignition temperature [癈]: not applicable
Decomposition temperature: not applicable
http://www.chemiebuero.de Tel.+49(0)941-566-398(-792)Fax.+49(0)941-566-994 eMail:info@chemiebuero.de wbl00052 gb
Safety Data Sheet 1907/2006/EC - GB
Spray adhesive
Article number: 13 90 05
Buehler GmbH
Date printed: 23.04.2009, Revision: 23.04.2009 Page 4 / 6
10 Stability and reactivity
Hazardous reactions: Risk of bursting.
Evolution of flammable mixtures possible in air when heated above flash point and/or during spraying
or misting.
Hazardous decomposition products:
Flammable gases/vapours.
11 Toxicological information
Acute oral toxicity: not determinated
Acute dermal toxicity: not determinated
Acute inhalational toxicity: not determinated
Irritant effect on eye: not determinated
Irritant effect on skin: not determinated
Sensitization: not determinated
Subacute toxicity: not determinated
Chronic toxicity: not determinated
Mutagenicity: not determinated
Reproduction toxicity: not determinated
Carcinogenicity: not determinated
Experiences made in practice: none
General remarks: Toxicological data are not available.
The product was classified on the basis of the calculation procedure of the preparation directive.
12 Ecological information
Fish toxicity: not determinated
Daphnia toxicity: not determinated
Behaviour in environment compartments:
not determinated
Behaviour in sewage plant: not determinated
Bacteria toxicity: not determinated
Biological degradability: not determinated
COD: not determinated
BOD 5: not determinated
AOX-advice: not determinated
2006/11/EC: yes
General information: The product was classified on the basis of the calculation procedure of the preparation directive.
13 Disposal considerations
Product: Dispose of as hazardous waste.
Contaminated packaging: Uncontaminated packaging may be taken for recycling.
Waste no. (recommended): 160504* gases in pressure containers (including halons) containing dangerous substances
http://www.chemiebuero.de Tel.+49(0)941-566-398(-792)Fax.+49(0)941-566-994 eMail:info@chemiebuero.de wbl00052 gb
Safety Data Sheet 1907/2006/EC - GB
Spray adhesive
Article number: 13 90 05
Buehler GmbH
Date printed: 23.04.2009, Revision: 23.04.2009 Page 5 / 6
14 Transport information
Classification according to ADR: UN 1950 AEROSOLS 2.1,
- Classification Code: 5F
- Label:
- ADR LQ LQ2: 1l
- ADR 1.1.3.6 (8.6): Transport category (tunnel restriction code): 2 (D)
Classification according to UN 1950 Aerosols 2.1 -
IMDG:
- EMS: F-D, S-U
- Label:
- IMDG Limited Quantities: LQ: 1 l
Classification according to IATA: UN 1950 Aerosols, flammable 2.1 (),
- Label:
15 Regulatory information
Exposure scenario: not applicable
Chemical safety report: not applicable
Labelling: The product is classified and labelled in accordance within EC-directives.
Hazard symbols:
Extremely flammable Irritant
R-phrases: R 12: Extremely flammable.
R 36: Irritating to eyes.
R 52/53: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
R 66: Repeated exposure may cause skin dryness or cracking.
R 67: Vapours may cause drowsiness and dizziness.
S-phrases: S 23.4: Do not breathe spray.
S 24/25: Avoid contact with skin and eyes.
S 51: Use only in well-ventilated areas.
Special labelling: Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50 癈.
Do not pierce or burn, even after use.
Do not spray on a naked flame or any incandescent material. Keep away from sources of ignition - No
smoking.
Keep out of reach of children.
Authorisation, TITEL VII: not applicable
Restrictions, TITEL VIII: not applicable
EEC-REGULATIONS: 1967/548 (2008/58, 30. ATP/ 31. ATP); 1991/689 (2001/118); 1999/13; 2004/42; 648/2004;
1907/2006.
TRANSPORT-REGULATIONS: DOT-Classification, ADR (2009); IMDG-Code (34. Amdt.); IATA-DGR (2009).
NATIONAL REGULATIONS EH40/2005 Workplace exposure limits with amendments October 2007.
http://www.chemiebuero.de Tel.+49(0)941-566-398(-792)Fax.+49(0)941-566-994 eMail:info@chemiebuero.de wbl00052 gb
Safety Data Sheet 1907/2006/EC - GB
Spray adhesive
Article number: 13 90 05
Buehler GmbH
Date printed: 23.04.2009, Revision: 23.04.2009 Page 6 / 6
16 Other informations
R-phrases (Chapter 03): R 12: Extremely flammable.
R 36: Irritating to eyes.
R 38: Irritating to skin.
R 11: Highly flammable.
R 67: Vapours may cause drowsiness and dizziness.
R 48/20: Harmful - danger of serious damage to health by prolonged exposure through inhalation.
R 66: Repeated exposure may cause skin dryness or cracking.
R 65: Harmful - may cause lung damage if swallowed.
R 51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R 62: Possible risk of impaired fertility.
Modified position: Chapter: 15; Minus R 43: May cause sensitisation by skin contact.
Chapter: 15; Minus S 37: Wear suitable gloves.
Observe employment restrictions for people:
yes
VOC (1999/13/CE): ~90%
Customs Tariff: not determinated
Disclaimer: This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product
features and shall not establish a legally valid contractual relationship.
http://www.chemiebuero.de Tel.+49(0)941-566-398(-792)Fax.+49(0)941-566-994 eMail:info@chemiebuero.de wbl00052 gb
|