Material Safety Data Sheet
NFPA / WHMIS Personal Protection DOT/TDG Road/Rail
4
1 0
3
Section I. Product Identification and Uses
Common/Trade
Alkylate (Lima)
name
Synonyms Full Range Alkylation Naphtha CAS # 64741-64-6
DSL This product is on the
Chemical family Hydrocarbon
Domestic Substances List
(DSL). TSCA (Toxic
Substance Control Act): This
product is listed on the
TSCA Inventory.
Missing
pictogram
Supplier Husky Lima Refinery, Manufacturer Husky Lima Refinery
1150 South Metcalf Street, 1150 South Metcalf Street
Lima OH, 45804 Lima, OH
403-298-6111 (General Information) 45804
Material uses Motorfuels, Petrochemicals
Section 2. First Aid Measures
Eye contact Flush eyes for at least 15 minutes with clean water. Patch lightly, allowing drainage. Seek medical
attention.
Skin contact Remove contaminated clothing. Wash skin thoroughly with soap and water. Seek medical attention if
irritation develops.
Inhalation Protect rescuer. Move exposed person to fresh air. If breathing has stopped apply artificial respiration.
Seek medical attention.
Ingestion If swallowed, do not induce vomiting or give liquids. Seek immediate medical attention.
Section 3. Hazardous Ingredients
ACGIH TLVs (OSHA PELs in Section 7)
TWA TWA STEL STEL CEIL CEIL
Name CAS # % by
(ppm) (Mg/M3) (ppm) (Mg/M3) (ppm) (Mg/M3)
Weight
Full Range Alkylation Naphtha 64741-64-6 300 n/av n/av n/av n/av n/av 100
Octane (and isomers) 111-65-3 300 n/av n/av n/av n/av n/av 0-85
Hexane (and isomers) 110-54-3 50 n/av n/av n/av n/av n/av 0-11
Heptane (and isomers) 143-82-5 400 n/av n/av n/av n/av n/av 0-10
Butane 106-97-8 1000 n/av n/av n/av n/av n/av 0-10
Pentane - iso 78-78-4 600 n/av n/av n/av n/av n/av 0-5
Pentane 100-41-4 600 n/av n/av n/av n/av n/av 0-5
Toluene 108-88-3 20 n/av n/av n/av n/av n/av 0-2
Nonane 111-84-2 200 n/av n/av n/av n/av n/av 0-2
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Alkylate (Lima) Page Number: 2
Toxicity values of the Octane LC50 Rat inhalation 118 g/cu m/4 hr
Hexane LD50 Rat oral 28,710 mg/kg
hazardous ingredients
Hexane LC50 Rat inhalation 48000 ppm/< 4 hr
Heptane LD50 Mouse iv 222 mg/kg
Heptane LC50 Rat inhalation 103 g/cu m/4 hr
Butane LC50: 278,000 ppm (Rat 4 hr)
Pentane - iso LC50 Mouse inhalation 1000 mg/L/1 hr (estimated)
Pentane LC50 Rat inhalation 364 g/cu m/4H
Toluene LD50: 5000 mg/kg (Rat, oral)
Toluene LC50: 8000 ppm (Rat, inhalation)
Toluene LD50: 14000 mg/kg (Rabbit, dermal)
Nonane LD50 Mouse iv 218 mg/kg
Nonane LC50 Rat inhalation 3200 ppm/4 hr
Section 4. Physical Data
Physical state and Colorless to light yellow liquid.
appearance
Odor Gasoline - Petroleum Odor Pleasant.
pH (1% soln/water) Not applicable.
Odor threshold Not available
Evaporation rate Not available
Freezing point -51.15 C (-60.1F)
Boiling point 27.8癈 (82癋) (initial boiling point)
Specific gravity 0.7 (Water = 1) at 60F
Volatility 100 (%vol)
Vapor density 3.6 (weighted average) (air =1)
Vapor pressure Not available
Water/oil dist. coeff. Not available.
Solubility Not available.
Molecular Weight Not applicable.
Melting Point Not available.
Density Not available.
Section 5. Fire and Explosion Data
Auto-ignition 287癈 (548.6癋)
temperature
Flash points CLOSED CUP: -57.15癈 (-70.9癋)
Flammable limits LFL = 1% UFL = 6%
Extinguishing Media Use DRY chemicals, CO2, or foam to extinguish fire. Water may not be an effective medium to
extinguish fire. Cool containing vessels with water jet in order to prevent pressure build-up,
autoignition or explosion.
Special fire fighting Use supplied air or self contained breathing apparatus (SCBA) for large fires or for fires in enclosed
areas. Qualified persons wearing full fire-fighting suits and approved/certified self-contained breathing
procedures
apparatus.
Flammability Highly flammable liquid. Released vapors may form flammable/explosive mixtures at or above the
flash point. Vapors may travel considerable distances to ignition sources and cause a flash fire. All
storage containers and pumping equipment must be grounded.
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Alkylate (Lima) Page Number: 3
Remark
No additional remark.
Risks of explosion This material is sensitive to static discharge. This product is not sensitive to mechanical impact.
Remark
No additional remark.
Section 6. Reactivity Data
Stability The product is stable.
Hazardous decomp. Carbon monoxide, carbon dioxide and irritant fumes and gases including sulfur oxides, nitrogen oxides
and aldehydes.
products
Reactivity Incompatible material: Strong acids, strong oxidizers, chlorine. Hazardous polymerization: Will not
occur.
Remark
No additional remark.
Section 7. Toxicological Properties
Routes of entry Ingestion. Inhalation. Eye contact. Skin contact.
OSHA PEL Octane OSHA PEL 500 ppm (8 Hour TWA)
Hexane OSHA PEL 500 ppm (8 Hour TWA)
Heptane OSHA PEL 500 ppm (8 Hour TWA)
Pentane OSHA PEL 1000 ppm (8 Hour TWA)
Toluene OSHA PEL 200 ppm (8 Hour TWA) 300 ppm (Acceptable Ceiling Concentration) 500 ppm
(Acceptable maximum peak above the acceptable ceiling concentration for an 8-hr shift)
Toxicity to animals Octane LC50 Rat inhalation 118 g/cu m/4 hr
Octane LC50 Rat
inhalation 118 g/cu m/4
hr
Hexane LD50 Rat oral
28,710 mg/kg
Hexane LC50 Rat inhalation
48000 ppm/< 4 hr
Heptane LD50 Mouse iv
222 mg/kg
Hexane LD50 Rat oral 28,710 mg/kg
Heptane LC50 Rat
inhalation 103 g/cu m/4
hr
Hexane LC50 Rat inhalation 48000 ppm/< 4 hr
Heptane LD50 Mouse iv 222 mg/kg
Heptane LC50 Rat inhalation 103 g/cu m/4 hr
Butane LC50: 278,000 ppm (Rat 4 hr)
Pentane - iso LC50 Mouse inhalation 1000 mg/L/1 hr (estimated)
Pentane LC50 Rat inhalation 364 g/cu m/4H
Toluene LD50: 5000 mg/kg (Rat, oral)
Toluene LC50: 8000 ppm (Rat, inhalation)
Toluene LD50: 14000 mg/kg (Rabbit, dermal)
Nonane LD50 Mouse iv 218 mg/kg
Nonane LC50 Rat inhalation 3200 ppm/4 hr
Remark
No additional remark.
Chronic effects Octane is known to cause skin irritation, drowsiness, dermatitis, chemical pneumonitis (aspiration liquid)
and narcosis.
Hexane is known to cause nausea, headach, peripheral neuropathy, numb extremities, muscle
weakness, dermatits, dizziness and chemical pneumonitis (aspiration liquid). Hexane is readily absorbed
through the skin.
Heptane is known to cause skin irritation, dizziness, stupor, incoordination, loss of appetite, nausea,
dermatitis and chemical pneumonitis (aspiration liquid).
Butane is known to cause cardiac sensitization, CNS depression, drowsiness, narcosis and liquid
frostbite .
Pentanes are known to cause dermatitis, chemical pneumonitis (aspiration liquid), drowsiness and
narcosis.
Nonane is known to cause skin irritation, headache, drowsiness, dizziness, confusion, nausea, tremor,
incoordination, chemical pneumonitis (aspiration liquid).
Remark
No additional remark.
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Alkylate (Lima) Page Number: 4
Acute effects Irritancy: Skin, eye and upper respiratory tract irritant.
Ingestion Pulmonary aspiration hazard if swallowed and vomiting occurs.
Skin Prolonged skin contact can cause defatting of the skin resulting in dry cracked skin and dermatitis.
Eyes Eye contact with product or product vapors may result in eye irritation.
May cause headache, dizziness, loss of appetite and loss of consiousness. Product vapors are irritating
Inhalation
to the respiratory tract.
Remark
Synergistic materials Not available.
Section 8. Preventive Measures
Waste disposal Dispose of in accordance with all federal, state/provincial and local regulations.
Storage Keep away from all ignition sources. Maintain temperature below the flash point. Avoid all possible
sources of ignition (spark or flame).
Ventilation Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors
below their respective threshold limit value. Use explosion-proof ventilation equipment.
Spill and leak Evacuate unecessary personnel. Eliminate all ignition sources. Be alert to the potential for the presence
of hydrogen sulphide gas and don appropriate protective equipment. Stop leak if safe to do so. Contain
spill and absorb with inert absorbent. Large spills should be removed with explosion proof vacuum
equipment. Large pools may be covered with foam to prevent vapor evolution. Comply with federal,
state/provincial, and local requirements for spill notification.
Section 9. Classification/Regulatory Information
DOT/TDG TDG CLASS 3: Flammable liquid with a flash point less than or equal to 60.5 C (140.9 F). Closed cup test
method.
Road/Rail
3
GASOLINE, 3, UN1203, PGII
Remark
No additional remark.
WHMIS WHMIS CLASS B-2: Flammable liquid with a flash point lower than 37.8癈 (100癋).
WHMIS CLASS D-2A: Material causing other toxic effects (VERY TOXIC).
WHMIS CLASS D-2B: Material causing other toxic effects (TOXIC).
Remark
No additional remark.
Other This product is on the Domestic Substances List (DSL). TSCA (Toxic Substance Control Act): This product is
listed on the TSCA Inventory.
Refer to federal, state/provincial, and local legislation for further requirements.
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Alkylate (Lima) Page Number: 5
National Fire
4 Flammability
Protection
Association 1 0
Health Instability
(U.S.A.)
Special
Section 10. Protective Clothing
Eye Non-vented chemical goggles to prevent eye irritation from the solvent vapors.
Impervious gloves and clothing should be worn as appropriate to protect against skin contact. Neoprene or
Skin
nitrile material is suggested.
Respiratory protection may be required in poorly ventilated areas. Properly fitted air purifying masks equipped
Respiratory
with organic vapor filters will provide protection at low concentrations. Wear NIOSH approved respiratory
protection adequate for the expected concentration of the substance in the air.
As required by the situation according to your companies policies and procedures. Contact your supervisor for
Other
direction.
Section 11. Preparation Information
References -Provisional Domestic Substances List, Canadian Ennvironmental Protection Act, Volume 1-Registry Number
Index, April 1990; Environment Canada. -SAX, N.I. Dangerous Properties of Industrial Materials. Toronto, Van
Nostrand Reinold, 6e ed. 1984. CCOHS (Chem advi)
CCOHS(Cheminfo) Doccumentation of the Threshold Limit Values and Biological Exposure Indices (ACGIH)
Pocket Guide to Chemical Hazards (NIOSH)
Transportation of Dangerous Goods Shedule II List II
MSDS Status
Acronyms: TLV = Threshold Limit Value N/AP = Not applicable N/AV = Not Available COC = Cleveland Open Cup PMCC =
Pensky Martens Closed Cup
Validated by Husky Corporate Hygiene on 3/19/2009. Verified by Husky Corporate
Hygiene.
Supersedes: 11/28/2005 Printed 3/16/2009.
Emergency Phone # Canada: 403-262-2111
Emergency Phone # USA: Chemtrec 1-800-424-9300
While the company believes the data set forth herein are accurate as of the date hereof, the company makes no
warranty with respect thereto and expressly disclaims all liability for reliance thereon. Such data are offered solely
for your consideration, investigation and verification.
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