M102-0413 Pre-Catalyzed Sealer
MATERIAL SAFETY DATA SHEET
RPM Wood Finishes Group
3194 Hickory Boulevard
Hudson, North Carolina 28638
828-728-8266
EMERGENCY PHONE (CHEM TREC): . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1-800-424-9300
FOR ALL INTERNATIONAL TRANSPORTATION ACCIDENTS. . . . . . . . . . . . . . . . .1-703-527-3887 (collect)
Health: 2 Flammability: 4 Reactivity 0
PRODUCT NAME: M102-0413 Pre-Catalyzed Sealer
I. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
REVISION DATE: 18/04/01
SUPERCEDES: None
MSDS NO. S82-1690
II. COMPOSITION/INFORMATION ON INGREDIENTS
CHEMICAL NAME % CAS # PEL
acetone 21-30 67-64-1 1000 ppm TWA; 2400 mg/m3 TWA
Isobutyl Alcohol 1-10 78-83-1 100 ppm TWA; 300 mg/m3 TWA
PROPANE 11-20 74-98-6 1000 ppm TWA; 1800 mg/m3 TWA
n-Butyl acetate 1-10 123-86-4 150 ppm TWA; 710 mg/m3 TWA
ISOBUTANE 1-10 75-28-5 No PEL established
isopropanol 11-20 67-63-0 400 ppm TWA; 980 mg/m3 TWA
Nitrocellulose 1-10 9004-70-0 No PEL established
Collodion
Toluene 1-10 108-88-3 200 ppm TWA; C 300 ppm
Xylene 1-10 1330-20-7 100 ppm TWA; 435 mg/m3 TWA
n-Butyl alcohol 1-10 71-36-3 100 ppm TWA; 300 mg/m3 TWA
Ethylbenzene <1 100-41-4 100 ppm TWA; 435 mg/m3 TWA
Formaldehyde <1 50-00-0 No PEL established
III. HAZARDS IDENTIFICATION
Absorption., Inhalation, ingestion, skin, eyes.
Routes of Entry:
Skin disease including eczema and sensitization. Respiratory disease including
Medical Conditions Aggravated:
asthma and bronchitis. Eye disease. Digestive tract disease. Kidney disease. Liver
disease.
Immediate (Acute) Health Effects
Inhalation
Can cause severe respiratory irritation, dizziness, weakness, fatigue, nausea, headache
Extreme Warning:
and possible unconsciousness.
Irritation may be delayed for several hours.
General Warning:
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Highly toxic! Can cause systemic damage (see "Target Organs" ). Respiratory failure
Extreme Toxic Warning:
is possible at high doses.
Methanol can cause central nervous system depression and overexposure can cause
General Toxic Warning:
damage to the optic nerve resulting in visual impairment or blindness. Inhalation of
high concentrations may result in central nervous system (CNS) effects such as
dizziness, weakness, fatigue, nausea, headache, and lack of coordination. Inhalation
may cause severe central nervous system depression (including unconsciousness).
Skin Contact
Can cause moderate skin irritation, defatting, and dermatitis. Not likely to cause
Extreme Warning:
permanent damage.
Substance causes moderate skin irritation. Continued or prolonged contact may
General Warning:
irritate the skin and cause a skin rash (dermatitis). Moderately irritating to the skin.
Eye Contact
Can cause severe irritation. Eye contact may result in corneal injury. Symptoms may
Extreme Warning:
include discomfort or pain, excess blinking and tear production, with marked redness
and swelling of the conjunctiva. Temporary vision impairment (cloudy or blurred
vision) is possible.
Irritating but will not permanently injure eye tissue.
General Warning:
Skin Absorption
Toxic if absorbed through the skin. Likely to cause significant systemic damage.
Extreme Warning:
Contains methanol. Upon prolonged or repeated exposure, may cause deterioration of
General Warning:
the optic nerve if large quantities are absorbed through the skin. Repeated absorption
of large quantities may lead to blindness. Can be absorbed through the skin but
exposure must be extensive before adverse health effects occur. Toxic and may be
harmful if absorbed through the skin; may produce target organ damage.
Component(s) may be absorbed through intact skin, but it is unlikely that harmful
affects will occur unless contact is prolonged, repeated, and extensive.
Ingestion
Irritating to mouth, throat, and stomach. Can cause abdominal discomfort, nausea,
Extreme Warning:
vomiting and diarrhea.
May cause nausea. Aspiration of material into the lungs can cause chemical
General Warning:
pneumonitis which can be fatal.
Toxic if swallowed. May cause target organ failure and/or death.
Extreme Toxic Warning:
Upon ingestion of a large quantity of this material, visual disturbances may occur.
General Toxic Warning:
Onset of the response may be delayed. Substance is harmful if swallowed. Large
exposure may be fatal. Ingestion of this product may result in central nervous system
effects including headache, sleepiness, dizziness, slurred speech and blurred vision.
Target Organ Acute Toxicity:
Acetone respiratory system, skin, eyes, CNS
Isobutyl alcohol eyes, skin, respiratory system, CNS
Propane CNS
n-Butyl acetate eyes, skin, respiratory system, CNS
Isobutane CNS
Isopropyl alcohol eyes, skin, respiratory system
Toluene CNS, liver, kidneys, skin, eyes, respiratory system
Xylenes (o-, m-, p- isomers) CNS, eyes, blood, liver, kidneys, skin, GI tract, respiratory system
n-Butyl alcohol skin, eyes, respiratory system, CNS
Ethyl benzene eyes, respiratory system, skin, CNS
Formaldehyde (and formalin) eyes, skin, respiratory system, nasal cancer
Long-Term (Chronic) Health Effects:
Carcinogenicity
Contains a substance that is a probable cancer hazard based on human studies.
Extreme Warning:
General Warning:
M102-0413 Pre-Catalyzed Sealer Page 2 of 8
Reproductive and Developmental Toxicity
Extreme Warning:
Possible reproductive hazard. A component in this product has been shown to cause
General Warning:
birth defects and reproductive disorders in laboratory animals at doses that could be
encountered in the workplace.
No data available to indicate product or any components present at greater than 0.1%
Mutagenicity:
is mutagenic or genotoxic.
Inhalation
Upon prolonged and/or repeated exposure, can cause severe respiratory irritation,
Extreme Warning:
dizziness, weakness, fatigue, nausea, headache and possible unconsciousness.
No data.
General Warning:
Skin Contact
Upon prolonged or repeated contact, can cause moderate skin irritation, defatting, and
Extreme Warning:
dermatitis. Not likely to cause permanent damage.
Prolonged or repeated contact may cause irritation. May cause lingering affects but
General Warning:
not likely to result in permanent damage if the exposure is eliminated.
Eye Contact
Upon prolonged or repeated contact, can cause severe irritation. Eye contact may
Extreme Warning:
result in corneal injury. Symptoms may include discomfort or pain, excess blinking
and tear production, with marked redness and swelling of the conjunctiva. Temporary
vision impairment (cloudy or blurred vision) is possible.
No data.
General Warning:
Skin Absorption
Upon prolonged or repeated exposure, toxic if absorbed through the skin. Likely to
Extreme Warning:
cause systemic damage.
No data.
General Warning:
Respiratory Tract. Skin. Eyes. Nervous System. Digestive Tract. Kidneys. Liver.
Target Organ Chronic Toxicity
Blood.
No additional health information available.
Supplemental Health Hazard
Information:
IV. FIRST AID
Inhalation
Remove to fresh air. If breathing is difficult, have a trained individual administer
Extreme Warning:
oxygen. If not breathing, give artificial respiration and have a trained individual
administer oxygen. Get medical attention immediately.
Remove to fresh air. If not breathing, give artificial respiration. If breathing is
General Warning:
difficult, give oxygen. Get immediate medical attention.
Eyes
Immediately flush eyes with plenty of water for at least 20 minutes retracting eyelids
Extreme Warning:
often. Tilt the head to prevent chemical from transferring to the uncontaminated eye.
Get immediate medical attention and monitor the eye daily as advised by your
physician.
Flush eye with water for 20 minutes. Get medical attention. Flush immediately under
General Warning:
running water for 15 minutes. If redness or irritation occurs, seek medical attention.
Skin Contact
Wash with soap and water. Remove contaminated clothing, launder immediately, and
Extreme Warning:
discard contaminated leather goods. Get medical attention immediately.
Wash exposed areas thoroughly with soap and water until chemical is removed.
General Warning:
Removed contaminated clothing and launder before reuse. Wash with soap and water.
Get medical attention if irritation develops or persists.
Ingestion
Do not induce vomiting and seek medical attention immediately. Drink two glasses of
Extreme Warning:
water or milk to dilute. Provide medical care provider with this MSDS.
M102-0413 Pre-Catalyzed Sealer Page 3 of 8
Drink 3-4 glasses of water and DO NOT induce vomiting. Do not give anything by
General Warning:
mouth to an unconscious or convulsing person. Get medical attention. Induce
vomiting as a last measure. Induced vomiting may lead to aspiration of the material
into the lungs potentially causing chemical pneumonitis that may be fatal. First aid is
normally not required.
Treat according to symptoms present.
Notes to MD:
V. FIRE FIGHTING MEASURES
Flammability Summary:
-144C;-97F
Flash Point:
12.8 @ 77?F
Upper Flammable/Explosive
Limit, % in air:
1.3 @ 77?F
Lower Flammable/Explosive
Limit, % in air:
Fire Hazards
Vapors may be ignited by heat, sparks, flames or other sources of ignition at or above
Extreme Warning:
the low flash point giving rise to a Class B fire. Vapors are heavier than air and may
travel to a source of ignition and flash back.
Flammable Liquid. Can release vapors that form explosive mixtures at temperatures at
General Warning:
or above the flash point.
Keep unnecessary people away. Isolate hazard area and deny entry. Stay upwind, out
of low areas, and ventialte closed spaces before entering.
Extinguishing Media
Use alcohol resistant foam, carbon dioxide, or dry chemical extinguishing agents.
Extreme Warning:
Water spray or fog may also be effective for extinguishing if swept across the base of
the fire. Water can also be used to absorb heat and keep exposed material from being
damaged by fire.
Use alcohol resistant spray, Carbon Dioxide, water spray or dry chemical to
General Warning:
extinguish a fire involving this chemical. Flammable component(s) of this material
may be lighter than water and burn while floating on the surface. Water fog, foam,
CO2, or dry chemical.
Fire Fighting Instructions
Do not enter fire area without proper protection including self-contained toxic
Extreme Warning:
breathing apparatus and full protective equipment. Fight fire from a safe distance and
a protected location due to the potential of hazardous vapors and decomposition
products. Flammable component(s) of this material may be lighter than water and
burn while floating on the surface. Use water spray/fog for cooling.
Flammable Liquid. Can release vapors that form explosive mixtures at temperatures at
General Warning:
or above the flash point.
Keep unnecessary people away. Isolate hazard area and deny entry. Stay upwind, out
of low areas, and ventialte closed spaces before entering.
Hazardous Combustion Products: Carbon dioxide, Carbon monoxide Hydrogen cyanide Nitrogen containing gases
Toxic gases
VI. ACCIDENTAL RELEASE MEASURES
Health Consideration for Spill Response
Exposure to the spilled material may be irritating or harmful. Follow personal
Extreme Warning:
protective equipment recommendations found in Section VIII of this MSDS.
Additional precautions may be necessary based on special circumstances created by
the spill including; the material spilled, the quantity of the spill, the area in which the
spill occurred. Also consider the expertise of employees in the area responding to the
spill.
No data.
General Warning:
M102-0413 Pre-Catalyzed Sealer Page 4 of 8
Spill Mitigation Procedures
General Methods:
Prevent the spread of any spill to minimize harm to human health and the environment
Extreme Warning:
if safe to do so. Wear complete and proper personal protective equipment following
the recommendation of Section VIII at a minimum. Dike with suitable absorbent
material like granulated clay. Gather and store in a sealed container pending a waste
disposal evaluation.
Gather and store in a sealed container pending a waste disposal evaluation. Avoid
General Warning:
runoff into storm sewers and ditches that lead to waterways. Immediately remove all
sources of ignition.
VII. HANDLING AND STORAGE
Handling
Harmful or irritating material. Avoid contact and avoid breathing the material. Use
Extreme Warning:
only in a well ventilated area.
Use spark-proof tools and explosion-proof equipment. Use bonding and grounding
General Warning:
when transferring quantities of material. Wash thoroughly after handling. Avoid
contact with material. Ground and bond containers when transferring material. Keep
in air-tight containers- material is hygroscopic. Remove contaminated clothing and
wash before reuse. "Empty" containers retain product residue (liquid and/or vapor)
and can be dangerous.
Storage
Store in a cool dry ventilated location. Isolate from incompatible materials and
Extreme Warning:
conditions. Keep container(s) closed.
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Vent
General Warning:
container carefully, periodically, as needed to relieve pressure. Store in a cool place in
original container and protect from sunlight. Do not store in direct sunlight.
VIII. ENGINEERING CONTROLS AND PERSONAL PROTECTIVE EQUIPMENT
Engineering Controls
Local exhaust ventilation or other engineering controls are normally required when
Extreme Warning:
handling or using this product to avoid overexposure.
Ventilation should effectively remove and prevent buildup of any vapor/mist/fume
General Warning:
generated from the handling of this product. General room or local exhaust
ventilation is usually required to meet employee exposure standards and/or to ensure
employees are not overexposed to airborne material as described in Section III.
Explosion proof exhaust ventilation should be used. Local exhaust.
Protective Equipment
Respiratory Tract
Respirators should be selected by and used under the direction of a trained health and
safety professional following requirements found in OSHA's respirator standard (29
CFR 1910.134) and ANSI's standard for respiratory protection (Z88.2-1992). A
written respiratory protection program, including provisions for medical certification,
training, fit testing, exposure assessments, maintenance, inspection, cleaning, and
convenient, sanitary storage should be implemented.
Eyes
Wear chemically resistant safety glasses with side shields when handling this product.
Wear additional eye protection such as chemical splash goggles and/or face shield
when the possibility exists for eye contact with splashing or spraying liquid, or
airborne material. Do not wear contact lenses. Have an eye wash station available.
Skin
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Avoid skin contact by wearing chemically resistant gloves, an apron and other
protective equipment depending upon conditions of use. Inspect gloves for chemical
break-through and replace at regular intervals. Clean protective equipment regularly.
Wash hands and other exposed areas with mild soap and water before eating,
drinking, and when leaving work.
IX. PHYSICAL DATA
Physical State: Colored Liquid
Odor: Strong Solvent
Solids Vol % 7.4352
Solids Wt % 11.2975
Material VOC lbs/gal: 4.02
Material VOC gms/l: 482.35
Weight per gallon: 7.2580000
X. STABILITY AND REACTIVITY
Stability Information
Normally stable. Keep away from heat, sparks and flame.
Extreme Warning:
Stable.
General Warning:
Conditions to Avoid
Sparks, open flame, other ignition sources, and elevated temperatures.
Extreme Warning:
Avoid: heat, sparks, flame and oxidizing agents.
General Warning:
Strong oxidizing agents. Strong acids. Strong alkalies. Amines. Oxidizing materials.
Chemical Incompatibility:
Hazardous Polymerization will not occur.
Hazardous Polymerization:
XI. TOXICOLOGICAL INFORMATION
Chemical Name CAS Number LD50/LC50
Acetone 67-64-1 Inhalation LC50 Rat : 50100 mg/m3/8H; Inhalation LC50 Mouse : 44
gm/m3/4H; Oral LD50 Rat : 5800 mg/kg; Oral LD50 Mouse : 3 gm/kg
Isobutyl alcohol 78-83-1 Oral LD50 Rat : 2460 mg/kg; Dermal LD50 Rabbit : 3400 mg/kg
Acetic acid, butyl ester 123-86-4 Inhalation LC50 Rat : 2000 ppm/4H; Inhalation LC50 Mouse : 6 gm/m3/2H;
Oral LD50 Rat : 10768 mg/kg; Oral LD50 Mouse : 6 gm/kg; Dermal LD50
Rabbit : >17600 mg/kg
Propane, 2-methyl- 75-28-5 Inhalation LC50 Rat : 57 pph/15M
Isopropyl alcohol 67-63-0 Inhalation LC50 Rat : 16000 ppm/8H; Oral LD50 Rat : 5045 mg/kg; Oral
LD50 Mouse : 3600 mg/kg; Dermal LD50 Rabbit : 12800 mg/kg
Nitrocellulose 9004-70-0 Oral LD50 Rat : >5 gm/kg; Oral LD50 Mouse : >5 gm/kg
Toluene 108-88-3 Inhalation LC50 Rat : 49 gm/m3/4H; Inhalation LC50 Mouse : 400 ppm/24H;
Oral LD50 Rat : 636 mg/kg; Dermal LD50 Rabbit : 14100 uL/kg
Xylene 1330-20-7 Inhalation LC50 Rat : 5000 ppm/4H; Oral LD50 Rat : 4300 mg/kg; Dermal
LD50 Rabbit : >1700 mg/kg
Butyl alcohol 71-36-3 Inhalation LC50 Rat : 8000 ppm/4H; Oral LD50 Rat : 790 mg/kg; Oral LD50
Mouse : 2680 mg/kg; Dermal LD50 Rabbit : 3400 mg/kg
Benzene, ethyl- 100-41-4 Oral LD50 Rat : 3500 mg/kg; Dermal LD50 Rabbit : 17800 uL/kg
Formaldehyde 50-00-0 Inhalation LC50 Rat : 203 mg/m3; Inhalation LC50 Mouse : 454 gm/m3/4H;
Oral LD50 Rat : 100 mg/kg; Oral LD50 Mouse : 42 mg/kg; Dermal LD50
Rabbit : 270 uL/kg
XII. ECOLOGICAL INFORMATION
Keep out of waterways.
Overview (for ingredients):
Ecological Toxicity Values:
XIII. DISPOSAL CONSIDERATIONS
Waste Description for Spent Product:
Spent or discarded material is a hazardous waste.
Extreme Warning:
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The waste may be a listed and/or characteristic hazardous waste. The waste may be a
General Warning:
listed hazardous waste.
Disposal Methods:
Dispose of by incineration following Federal, State, Local, or Provincial regulations.
Extreme Warning:
If discarded, this product is considered a RCRA ignitable waste, D001.
Potential EPA Waste Codes:
Components Subject to USEPA Land Disposal Restrictions:
Acetone 67-64-1 20.66 %
Isobutyl alcohol 78-83-1 1.04 %
Toluene 108-88-3 3.64 %
Xylenes (o-, m-, p- isomers) 1330-20-7 1.63 %
n-Butyl alcohol 71-36-3 5.41 %
Ethyl benzene 100-41-4 0.26 %
XIV. TRANSPORTATION INFORMATION
Aerosols, flammable 2.1 UN1950
DOT
XV. REGULATORY INFORMATION
Toxic Substances Control Act (TSCA):
Chemical Name Regulation CASRN %
Isopropyl alcohol SARA 313 Reportable: 67-63-0 10.49
Toluene SARA 313 Reportable: 108-88-3 3.64
Xylene (mixed isomers) SARA 313 Reportable: 1330-20-7 1.63
n-Butyl alcohol SARA 313 Reportable: 71-36-3 5.41
Ethyl benzene SARA 313 Reportable: 100-41-4 0.26
Formaldehyde SARA 313 Reportable: 50-00-0 0.03
Phosphoric acid SARA 313 Reportable: 7664-38-2 0.00
Formaldehyde Extremely Haz. Substances: 50-00-0 0.03
TPQ = 500 pounds; RQ = 100 pounds SARA Threshold Planning Quantity: 50-00-0 0.03
(does not meet toxicity criteria but
because of high production volume and
recognized toxicity is considered a
chemical of concern)
50-00-0 0.03
Formaldehyde (gas) California Proposition 65 Cancer List:
108-88-3 3.64
Toluene California Proposition 65
Developmental Toxicity:
67-64-1 20.66
acetone New Jersey Right To Know:
74-98-6 14.73
Propane New Jersey Right To Know:
123-86-4 7.22
n-Butyl acetate New Jersey Right To Know:
75-28-5 6.67
Isobutane New Jersey Right To Know:
67-63-0 10.49
isopropanol New Jersey Right To Know:
XVI. ADDITIONAL INFORMATION
IMPORTANT: WHILE THE DESCRIPTIONS, DATA AND INFORMATION
Other Information:
CONTAINED HEREIN ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE
ACCURATE, IT IS PROVIDED FOR YOUR GUIDANCE ONLY. BECAUSE MANY
FACTORS MAY AFFECT PROCESSING OR APPLICATION/USE, WE RECOMMEND
THAT YOU PERFORM AN ASSESSMENT TO DETERMINE THE SUITABILITY OF A
PRODUCT FOR YOUR PARTICULAR PURPOSE PRIOR TO USE. NO WARRANTIES
OF ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDING FITNESS FOR A
PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED, DATA
OR INFORMATION SET FORTH. IN NO CASE SHALL THE DESCRIPTIONS,
INFORMATION,OR DATA PROVIDED BE CONSIDERED A PART OF OUR TERMS
AND CONDITIONS OF SALE. FURTHER, THE DESCRIPTIONS, DATA AND
INFORMATION FURNISHED HEREUNDER ARE GIVEN GRATIS. NO OBLIGATION
OR LIABILITY FOR THE DESCRIPTION, DATA AND INFORMATION GIVEN ARE
ASSUMED. ALL SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK.
M102-0413 Pre-Catalyzed Sealer Page 7 of 8
MSDS glossary.
M102-0413 Pre-Catalyzed Sealer Page 8 of 8
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