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3M UK PLC 3M IRELAND
3M CENTRE, CAIN RD, 3M HOUSE, ADELPHI CENTRE,
BRACKNELL, BERKSHIRE, RG12 8HT DUN LAOGHAIRE, CO. DUBLIN
Tel: 01344 858000 Tel: 01 2803555
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MATERIAL SAFETY DATA SHEET
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Document id : 17-8530-2 Issue date : 20/01/2005
Version : 9.00 Supersedes date : 17/01/2005
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1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION
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Tradename:
3M(TM) SPRAYMOUNT(TM) ADHESIVE (UK-7874)
3M Product ID:
GS-2000-3478-2 GS-2000-3301-6 GS-2000-3391-7
GT-5000-4032-1 GS-2000-3482-4 GS-2000-3498-0 GS-2000-3341-2
GS-2000-3343-8 GS-2000-3357-8 GS-2000-3358-6
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2 COMPOSITION/INFORMATION ON INGREDIENTS
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Ingredient name and classification CAS number Percentage
------------------------------------- ------------------ -------------
ACETONE 67-64-1 25 - 40
EU Hazard Symbols and Risk Phrases: EU - Adaptation 25 (F,Xi;
R:11-36-66-67)
BUTANE 106-97-8 10 - 20
EU Hazard Symbols and Risk Phrases: EU - Adaptation 21 (F+;
R:12)
PROPANE 74-98-6 10 - 20
EU Hazard Symbols and Risk Phrases: EU - Adaptation 21 (F+;
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R:12)
NONVOLATILE COMPONENTS --- 5 - 15
HEPTANES 92045-53-9 7 - 13
EU Hazard Symbols and Risk Phrases: EU - Adaptation 22 (T;
R:Carc.Cat.2;45-65) EU - Additional Vendor Classification(N;
R:51/53)
ISOBUTANE 75-28-5 5 - 10
EU Hazard Symbols and Risk Phrases: EU - Adaptation 21 (F+;
R:12)
HEXANES 64742-49-0 5 - 10
EU Hazard Symbols and Risk Phrases: EU - Adaptation 22 (T;
R:Carc.Cat.2;45-65) EU - Additional Vendor
Classification(F,Xi,N; R:11-38-51/53-67)
PENTANE 109-66-0 1-5
EU Hazard Symbols and Risk Phrases: EU - Adaptation 25
(F+,N,Xn; R:12-51-53-65-66-67)
ISOPENTANE 78-78-4 0.5 - 1.5
EU Hazard Symbols and Risk Phrases: EU - Adaptation 25
(F+,N,Xn; R:12-51-53-65-66-67)
HEXANE 110-54-3 0 - 0.4
EU Hazard Symbols and Risk Phrases: EU - Adaptation 29
(F,Xi,Xn,N; R:11-38-48/20-51/53-Repr.Cat.3;62-65-67)
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3 HAZARDS IDENTIFICATION
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Critical hazards:
Irritant. Extremely flammable. Irritating to eyes. Repeated
exposure may cause skin dryness or cracking. Vapours may
cause drowsiness and dizziness. Harmful to aquatic organisms.
May cause long-term adverse effects in the aquatic
environment.
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4 FIRST-AID MEASURES
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Eye Contact:
Flush eyes with large amounts of water. If signs/symptoms
persist, get medical attention.
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Skin Contact:
Wash affected area with soap and water. If signs/symptoms
develop, get medical attention.
Inhalation:
Remove person to fresh air. If signs/symptoms persist, get
medical attention.
Ingestion:
Do not induce vomiting. Give victim two glasses of water.
Never give anything by mouth to an unconscious person. Get
medical attention.
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5 FIRE-FIGHTING MEASURES
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Suitable Extinguishing Media:
Use fire extinguishers with class B extinguishing agents
(e.g., dry chemical, carbon dioxide).
Exposure Hazards:
Closed containers exposed to heat from fire may build pressure
and explode.
Hazardous Decomposition:
Carbon monoxide - During Combustion. Carbon dioxide - during
combustion. Under recommended usage conditions, hazardous
decomposition products are not expected. Hazardous
decomposition products may occur as a result of oxidation,
heating, or reaction with another material.
Fire-Fighting Procedures:
Wear full protective equipment and a self-contained breathing
apparatus.
Special Instructions:
Aerosol container contains flammable material under pressure.
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6 ACCIDENTAL RELEASE MEASURES
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Personal Precautions:
Refer to other sections of this Material Safety Data Sheet for
information regarding physical and health hazards, respiratory
protection, ventilation, and personal protective equipment.
Methods for Cleaning up:
Working from around the edges of the spill inward, cover with
bentonite, vermiculite, or commercially available inorganic
absorbent material. Mix in sufficient absorbent until it
appears dry. Seal the container. Evacuate unprotected and
untrained personnel from hazard area. The spill should be
cleaned up by qualified personnel. Remove all ignition sources
such as flames, smoking materials, and electrical spark
sources. Use only non-sparking tools. Ventilate the area with
fresh air. Contain spill. Cover spill area with a
fire-extinguishing foam. An aqueous film forming foam (AFFF)
is recommended. Remember, adding an absorbent material does
not remove a toxic, corrosivity or flammability hazard.
Collect as much of the spilled material as possible using
non-sparking tools. Clean up residue with an appropriate
solvent selected by a qualified and authorised person.
Ventilate the area with fresh air. Read and follow safety
precautions on the solvent label and MSDS. Collect the
resulting residue containing solution. Place in a suitable
metal container. Dispose of collected material as soon as
possible.
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7 HANDLING AND STORAGE
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Precautions for Safe Storage:
Store away from heat.
Fire Prevention:
No smoking while handling this material. Flammable liquefied
gas. Do not spray near flames or sources of ignition. Aerosol
container contains flammable gas under pressure.
Precautions for Safe Handling:
Do not pierce or burn container, even after use.
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8 EXPOSURE CONTROLS/PERSONAL PROTECTION
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Eye Protection:
Avoid eye contact with vapours, mists, or spray.
Skin Protection:
Gloves not normally required. Avoid prolonged or repeated skin
contact.
Respiratory Protection:
Avoid inhalation of vapours, mists or spray.
Ingestion:
Do not eat, drink or smoke when using this product. Wash
exposed areas thoroughly with soap and water. Keep out of the
reach of children.
Recommended Ventilation:
Use with appropriate local exhaust ventilation. Do not use in
a confined area or areas with little or no air movement. Use
general dilution ventilation and/or local exhaust ventilation
to control airborne exposures to below Occupational Exposure
Limits and/or control dust, fume, or airborne particles. If
ventilation is not adequate, use respiratory protection
equipment.
Exposure Limits:
ACETONE (67-64-1)
UK HSE TWA: 500 ppm; 1210 mg/m3 OES
UK HSE STEL: 1500 ppm; 3620 mg/m3 OES
BUTANE (106-97-8)
UK HSE TWA: 600 ppm; 1450 mg/m3 OES
UK HSE STEL: 750 ppm; 1810 mg/m3 OES
PROPANE (74-98-6)
UK HSE TWA: Asphyxiant OES
PENTANE (109-66-0)
UK HSE TWA: 600 ppm; 1800 mg/m3 OES
UK HSE STEL: 750 ppm; 2250 mg/m3 OES
ISOPENTANE (78-78-4)
UK HSE TWA: 600 ppm; 1800 mg/m3 OES
UK HSE STEL: 750 ppm; 2250 mg/m3 OES
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HEXANE (110-54-3)
UK HSE TWA: 20 ppm; 72 mg/m3 OES
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9 PHYSICAL AND CHEMICAL PROPERTIES
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Appearance and Odour: Gas, transparent Aerosol -
white liquid in aerosol with a
strong ketone odour.
pH: Not applicable
Boiling point/boiling range: Not applicable
Melting point/melting range: Not applicable
Flash point: -46 C
Autoflammability: Not determined
Vapour pressure: Not determined
Water Solubility: Nil
Specific gravity: 0.65
Vapour density: Greater than1
Percent Volatile: 88.5 % by wt
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10 STABILITY AND REACTIVITY
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Conditions to Avoid:
Sparks and/or Flames.
Materials to Avoid:
None known.
Hazardous Decomposition:
NONE. Hazardous polymerisation will not occur. Stable.
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11 TOXICOLOGICAL INFORMATION
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Effects from Eye Contact:
Sprayed material may cause eye irritation. Signs/symptoms may
include redness, swelling, pain, tearing, and blurred or hazy
vision.
Effects from Skin Contact:
Mild Skin Irritation: signs/symptoms may include localised
redness, swelling, and itching.
Effects from Inhalation:
Sprayed material may cause irritation of the respiratory
system. Signs/symptoms may include cough, sneezing, nasal
discharge, hoarseness, wheezing, breathing difficulty, nose
and throat pain, coughing up blood, and non respiratory
effects such as painful and watery eyes. Intentional
concentration and inhalation may be harmful or fatal.
Effects from Ingestion:
Gastrointestinal Effects: Signs/symptoms may include stomach
upset, nausea, vomiting and diarrhoea.
Other Effects and Information:
Central Nervous System (CNS) Depression: Signs/symptoms may
include headache, dizziness, drowsiness, incoordination,
nausea, slowed reaction time, slurred speech, giddiness, and
unconsciousness.
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12 ECOLOGICAL INFORMATION
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Ecotoxicity Data:
Not determined.
Ecofate Data:
Not determined.
Special statements for 2001/58/EC:
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One or more components of this product have significant known
or predicted environmental hazards, but a conservative
assessment indicates a low environmental risk. Intended use
and proper disposal are unlikely to cause the environmentally
hazardous component(s) to enter the environment in quantities
or by routes that could cause the adverse environmental
impacts.
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13 DISPOSAL CONSIDERATIONS
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Product as Sold:
Incinerate in a permitted hazardous waste incinerator. As a
disposal alternative, dispose of waste product in a permitted
hazardous waste facility. Incinerate at a facility equipped to
handle gaseous waste. Facility must be capable of handling
aerosol cans.
Special Instructions:
Since regulations vary, consult applicable regulations or
authorities before disposal.
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14 TRANSPORT INFORMATION
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UN NUMBER:
UN number: UN1950
UK ROAD/SEA FREIGHT (IMO) CLASSIFICATION:
Substance Identification Number: UN1950
Class: 2.0
Packing Group: Not applicable.
Proper Shipping Name: Aerosols
ADR/RID CLASSIFICATION:
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Class: 2.0
ADR classification: 5 (f)
ICAO/IATA CLASSIFICATION:
Class: 2.1
Sub-Risk: Not applicable.
Packing Group: Not applicable.
Proper Shipping Name: Aerosols, flammable.
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15 REGULATORY INFORMATION
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Disclosable Ingredients:
ACETONE, HEPTANES, HEXANES, PENTANE
Symbol(s):
(Xi) St. Andrew's Cross (Irritant). (F+) Flame (Extremely
Flammable).
Risk Phrases:
(R12) Extremely flammable. (R36) Irritating to eyes. (R66)
Repeated exposure may cause skin dryness or cracking. (R67)
Vapours may cause drowsiness and dizziness. (R52/53) Harmful
to aquatic organisms. May cause long-term adverse effects in
the aquatic environment.
Safety Phrases:
Keep away from heat. Keep away from sources of ignition
including pilot lights and sparks. No smoking. Do not breathe
vapour or spray. Use only in well ventilated areas. Avoid
contact with the skin and eyes. In case of contact with eyes,
rinse immediately with plenty of water and seek medical
advice. After contact with skin, wash immediately with plenty
of soap and water. WARNING! Pressurised container. Protect
from sunlight and do not expose to temperatures exceeding 50
degrees C. Do not pierce or burn, even after use. Do not
spray on a naked flame or incandescent material. Avoid release
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to the environment. Refer to special instructions/safety data
sheets. Keep out of the reach of children.
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16 OTHER INFORMATION
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Regulatory Information: The following UK Regulations
as amended may affect the
product as supplied: The
Chemicals (Hazard Information
and Packaging for supply)
Regulations, as amended. The
Carriage of Dangerous Goods
(Classification, Packaging and
Labelling) and use of
Transportable Pressure
Receptacles Regulations 1996,
as amended. Carriage of
Dangerous Goods by Road
regulations, 1996, as amended.
The Control of Substances
Hazardous to Health
Regulations 1999 as amended.
The Special Waste Regulations
1996, as amended. The
Environmental Protection Act,
1990 The Health and Safety at
Work Act, 1974.
Reissue date/Reason for reissue.
Added and removed 3M ID stock number and updated sections 2,
5, 6, 12, 13.
Intended Use of Product:
Spray adhesive that allows for repositioning.
The information on this Data Sheet is based on our experience and is
correct to the best of our knowledge at the date of publication, but
we do not accept any liability for any loss, damage or injury
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resulting from its use (except as required by law). The information
may not be valid for any use not referred to in this Data Sheet or
use of the product in combination with other materials. For these
reasons, it is important that customers carry out their own test to
satisfy themselves as to the suitability of the product for their own
intended applications.
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