Material Safety Data Sheet
Revision Date: 09/28/2006 Issue date: 09/28/2006
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product name: FREKOTE HMT DR Item No. : 83538
Product type: Mold Release Region: United States
Company address: Contact Information:
Henkel Corporation Telephone: 860.571.5100
1001 Trout Brook Crossing Emergency telephone: 860.571.5100
Rocky Hill, Connecticut 06067 Internet: www.loctite.com
Contains one or more components for which a Toxic Substances Control Act (TSCA) Low Volume Exemption (LVE) applies. See Section
15.
2. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous components % ACGIH TLV OSHA PEL OTHER
Hydrotreated heavy naphtha 30-60 None None 225 ppm TWA
64742-48-9
Dibutyl Ether 30-60 None None None
142-96-1
1,2,4-Trimethylbenzene 5-10 25 ppm TWA None None
95-63-6
Light aromatic solvent naphtha 5-10 None None 50 ppm
64742-95-6
1,3,5-Trimethylbenzene 1-5 25 ppm TWA None None
108-67-8
Proprietary Resin 1-5 None None None
Proprietary
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
HMIS:
Physical state: Liquid HEALTH: 1
Color: Colorless FLAMMABILITY: 2
Odor: Mild PHYSICAL HAZARD: 0
Personal Protection: See Section 8
WARNING: FLAMMABLE LIQUID AND VAPOR.
MAY AFFECT THE CENTRAL NERVOUS SYSTEM.
MAY BE HARMFUL IF SWALLOWED OR INHALED.
CAUSES EYE, SKIN AND RESPIRATORY TRACT IRRITATION
Relevant routes of exposure: Skin, Inhalation, Eyes, Ingestion
Potential Health Effects
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Inhalation: Vapors and mists will irritate nose and throat and possibly eyes. Breathing small amounts during
normal handling is not likely to cause harmful effects; breathing large amounts may be harmful. May
cause central nervous system effects, such as headache, nausea, vomiting, abdominal pain, dizziness,
confusion, breathing difficulties.
Skin contact: Solvent action can dry and defat the skin, causing the skin to crack, leading to dermatitis.
Eye contact: Moderate eye irritation.
Ingestion: May be harmful if swallowed. Central nervous system depression, including dizziness, drowsiness,
fatigue, nausea, headache, unconsciousness. Aspiration may occur during swallowing or vomiting,
resulting in lung damage.
Existing conditions aggravated by Dermatitis. Eczema. Other pre-existing skin conditions. Asthma. Other respiratory disorders (bronchitis,
exposure: emphysema, bronchial hyperreactivity).
See Section 11 for additional toxicological information.
4. FIRST AID MEASURES
Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get
medical attention.
Skin contact: Immediately flush skin with plenty of water (using soap, if available). Remove contaminated clothing
and shoes. Wash clothing before reuse. If skin irritation persists, call a physician.
Eye contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get immediate
medical attention.
Ingestion: Keep individual calm. Do not induce vomiting: contains petroleum distillates and/or aromatic solvents.
Never give anything by mouth to an unconscious person. Get medical attention immediately. If vomiting
occurs, prevent aspiration by keeping the patients head below the knees.
5. FIRE-FIGHTING MEASURES
Flash point: 32癈 (89.6癋) Tagliabue closed cup
Autoignition temperature: Not available
Flammable/Explosive limits-lower %: Not available
Flammable/Explosive limits-upper %: Not available
Extinguishing media: Carbon dioxide (CO2). Dry powder. Alcohol-resistant foam. Water spray. Do not use high volume water
jet.
Special fire fighting procedures: Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear. Water may
be unsuitable as an extinguishing media, but may be helpful in keeping adjacent containers cool. Keep
personnel upwind of fire.
Unusual fire or explosion hazards: Vapors may form explosive mixtures with air. Do not store or use near heat, spark, open flame or other
sources of ignition. Hydrocarbon solvents are basically non-conductors of electricity and can become
electrostatically charged during mixing, filtering or pumping at high flow rates. If this charge reaches a
significanltly high level, sparks can form that may ignite vapors of flammable liquids.
Hazardous combustion products: Oxides of carbon and nitrogen, aldehydes, acids and undetermined organics. Amines. Hydrochloric
acid. Collect contaminated fire extinguishing water separately. This must not be discharged into drains.
6. ACCIDENTAL RELEASE MEASURES
Environmental precautions: Prevent product from entering drains or open waters. Advise authorities if product has entered or may
enter seweres, water sources or extensive land areas. Prevent further leakage or spillage if safe to do
so. This product is insoluble in water and will float on surface.
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Clean-up methods: Remove all ignition sources. Ventilate area. Soak up with inert absorbent material (e.g. sand, silica gel,
acid binder, universal binder, sawdust). Store in a closed metal container until ready for disposal. Keep
people away from and upwind of spill/leak. Wear suitable protective clothing, gloves and eye/face
protection.
7. HANDLING AND STORAGE
Handling: During use and until all vapors are gone: Keep area ventilated - do not smoke; extinguish all flames,
pilot lights, and heaters; turn off stoves, electrical tools and appliances, and any other sources of
ignition. Make sure containers are properly grounded before use or transfer of material. Prevent contact
with eyes, skin and clothing. Do not breathe vapor and mist. Wash thoroughly after handling. For
operations where eye or face contact could occur, provide safety shower and eyewash fountain.
Storage: Store away from heat, sparks, flames, or other sources of ignition. Keep container closed. Store at or
below 48.8癈 (120癋).
Incompatible products: Refer to Section 10.
For information on product shelf life contact Henkel Customer Service at (800) 243-4874.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering controls: Use explosion-proof mechanical ventilation and local exhaust to control contaminants to within their
occupational exposure limits during the use of this product.
Respiratory protection: Use a NIOSH approved air purifying respirator with an organic vapor cartridge if the potential to exceed
established exposure limits exists.
Skin protection: Use chemical resistant, impermeable clothing including gloves and either an apron or body suit to
prevent skin contact.
Eye/face protection: Chemical splash goggles or safety glasses with side shields. In a splash hazard environment, chemical
goggles should be used in combination with a full face shield. An eyewash and safety shower should
be nearby and ready for use.
See Section 2 for exposure limits.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical state: Liquid
Color: Colorless
Odor: Mild
Vapor pressure: 2.39 mmHg
pH: Not applicable
Boiling point/range: 142.78癈 (289癋)
Melting point/range: Not determined
Specific gravity: .782
Vapor density: Approximately 4.8
Evaporation rate: <0.2 (Ether = 1)
Solubility in water: Insoluble
Partition coefficient (n-octanol/water): Not determined
VOC content: >95% (estimated)
10. STABILITY AND REACTIVITY
Stability: Risk of ignition. Stable under normal conditions of storage and use.
Hazardous polymerization: Will not occur.
Hazardous decomposition products: Hydrocarbons. Carbon monoxide. Traces of Ammonia.
Incompatability: Strong oxidizing agents. Humid air. Water.
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Conditions to avoid: Avoid static discharge. Vapours may form explosive mixture with air. Spray mist may be flammable at
temperatures below the flash point. Keep away from open flames, hot surfaces and sources of ignition.
Exposure to air or moisture over prolonged periods. Fire or intense heat may cause violent rupture of
packages.
11. TOXICOLOGICAL INFORMATION
Carcinogen Status
Hazardous components NTP Carcinogen IARC Carcinogen OSHA Carcinogen
Hydrotreated heavy naphtha No No No
64742-48-9
Dibutyl Ether No No No
142-96-1
1,2,4-Trimethylbenzene No No No
95-63-6
Light aromatic solvent naphtha No No No
64742-95-6
1,3,5-Trimethylbenzene No No No
108-67-8
Proprietary Resin No No No
Proprietary
Literature Referenced Target Organ & Other Health Effects
Hazardous components Health Effects/Target Organs
Hydrotreated heavy naphtha Irritant
64742-48-9
Dibutyl Ether Irritant
142-96-1
1,2,4-Trimethylbenzene Central nervous system, Irritant, Respiratory
95-63-6
Light aromatic solvent naphtha Irritant
64742-95-6
1,3,5-Trimethylbenzene Central nervous system, Irritant, Respiratory
108-67-8
Proprietary Resin No data
Proprietary
12. ECOLOGICAL INFORMATION
Ecological information: Not available
13. DISPOSAL CONSIDERATIONS
Information provided is for unused product only.
Recommended method of disposal: Recommended method of disposal: Dispose of according to Federal, State and local governmental
regulations.
EPA hazardous waste number: D001: Ignitable. This product may contain traces of Benzene and may be classified as a hazardous
waste (waste number(s) D018) under EPA RCRA (40 CFR 261.24). However this product is only
classifiable as hazardous waste if it exhibits the characteristics of toxicity as shown by the toxicity
characteristic leaching procedure (TCLP). Under RCRA, it is the responsibility of the end user of this
product to determine whether it meets this criteria at the time of disposal.
14. TRANSPORT INFORMATION
U.S. Department of Transportation Ground (49 CFR):
Proper shipping name: RESIN SOLUTION
Hazard class or division: 3
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Identification number: UN 1866
Packing group: III
International Air Transportation (ICAO/IATA):
Proper shipping name: RESIN SOLUTION
Hazard class or division: 3
Identification number: UN 1866
Packing group: III
WaterTransportation (IMO/IMDG):
Proper shipping name: RESIN SOLUTION
Hazard class or division: 3
Identification number: UN 1866
Packing group: III
15. REGULATORY INFORMATION
United States Regulatory Information
TSCA 8 (b) Inventory Status: All components of this product are listed on the U.S. Toxic Substances Control Act (TSCA) or are
exempted from listing because a Low Volume Exemption (LVE) has been granted in accordance with
40 CFR 723.50.
TSCA 12 (b) Export Notification: None.
CERCLA/SARA Section 302 EHS: None.
CERCLA/SARA Section 311/312: Fire, Immediate Health Hazard, Delayed Health Hazard
CERCLA/SARA 313: This product contains the following toxic chemicals subject to the reporting requirements of section 313
of the Emergency Planning and Community Right-To-Know Act of 1986 (40 CFR 372). 1,2,4-
Trimethylbenzene (CAS# 95-63-6).
California Proposition 65: This product contains a chemical known to the State of California to cause cancer and birth defects or
other reproductive harm.
Canada Regulatory Information
CEPA DSL/NDSL Status: One or more components are not listed on, and are not exempt from listing on either the Domestic
Substances List or the Non-Domestic Substances List. Please contact Product Safety and Regulatory
Affairs for more information.
WHMIS hazard class: B.2, D.2.B
16. OTHER INFORMATION
This material safety data sheet contains changes from the previous version in sections: 2,8
Prepared by: Dan Shaw, Product Safety and Regulatory Affairs Specialist
DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation
does not assume responsibility for any results obtained by persons over whose methods Henkel Corporation has no control. It is the
user's responsibility to determine the suitability of Henkel's products or any production methods mentioned herein for a particular
purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be
involved in the handling and use of any of Henkel Corporation's products. In light of the foregoing, Henkel Corporation specifically
disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale
or use of Henkel Corporation's products. Henkel Corporation further disclaims any liability for consequential or incidental damages of
any kind, including lost profits.
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