Material Safety Data Sheet
Spot stain remover for guarry and terra cotta tiles,
brick, concrete etc.
Section 1. Chemical product and company identification
: 1660564
HG International b.v.
Manufacturer : Code
: 2.01
Damsluisweg 70 1332 EJ Almere MSDS#
Address :
: 15-10-2007.
Netherlands Validation date
Country :
: 15-10-2007.
+31 (0)36 54 94 700 Print date
Telephone No.: :
: P. Stienstra
+31 (0)36 54 94 744 Responsible name
Fax :
www..hginternational.com : +1.705.726.5445
Internet: : Telephone No.:
Solstrand Trading : +1.705.734.0857
Supplier : Fax
60 Lockhart road Barrie, Ontario L4N 9G8 : Canada
Address : Country
: Cleans oil, grease , fat and other stubborn stains from a variety of surfaces such as quarry and terra
Material uses
cotta tiles, brick, natural stone, etc.
In Case of Emergency : Chem. Tel Inc. (813) 248 0585 or Toll free (800) 255 3924
Section 2. Composition, Information on Ingredients
CAS # % by weight Exposure limits
Name
1,2,4-Trimethylbenzene 95-63-6 5 - 15 Not available.
propan-2-ol 67-63-0 1-5 Not available.
Mesitylene 108-67-8 1-5 Not available.
diphosphoric acid, tetrapotassium 7320-34-5 1-5 Not available.
salt
alcohols, c12-18, ethoxylated 68213-23-0 1-5 Not available.
cumene 98-82-8 1-5 Not available.
benzenesulfonic acid, c10-16-alkyl 85536-14-7 1-5 Not available.
derivs.
poly(oxy-1,2-ethanediyl), .alpha.- 68891-38-3 1-5 Not available.
sulfo-.omega.-hydroxy-, c12-14-alkyl
ethers, sodium salts
Xylene 1330-20-7 0-1 Not available.
phosphoric acid 7664-38-2 0-1 Not available.
Section 3. Hazards identification
: Liquid. (Opalescente)
Physical State and
Appearance
: CAUTION
Emergency overview
POISON
HARMFUL IF SWALLOWED.
IRRITANT.
COMBUSTIBLE.
May cause eye irritation.
Do not swallow.
Do not get in eyes, on skin or on clothing.
Do not breathe fumes.
Keep away from heat, sparks and flame.
: Dermal contact. Eye contact. Ingestion.
Routes of entry
Potential acute health effects
Eyes : This product may irritate eyes and skin upon contact. Inflammation of the eye is characterized by redness,
watering and itching.
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Spot stain remover for guarry and terra
cotta tiles, brick, concrete etc.
Skin : Can cause irritation. Skin inflammation is characterized by itching, scaling, reddening or, occasionally,
blistering.
Inhalation : Hazardous in case of inhalation (lung irritant, lung sensitizer). Over-exposure by inhalation may cause
respiration irritation.
Ingestion : Aspiration hazard if swallowed. Can enter lungs and cause damage.
: CARCINOGENIC EFFECTS: Classified A4 (Not classifiable for humans or animals.) by ACGIH, 3 (Not
Potential chronic health
classifiable for humans.) by IARC [propan-2-ol]. Classified A4 (Not classifiable for humans or animals.) by
effects
ACGIH, 3 (Not classifiable for humans.) by IARC [Xylene].
MUTAGENIC EFFECTS: Not available.
TERATOGENIC EFFECTS: Not available.
: Repeated or prolonged exposure is not known to aggravate any medical condition.
Medical conditions
aggravated by
overexposure:
: Not available.
Over-exposure
signs/symptoms
See toxicological Information (section 11)
Section 4. First aid measures
: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical
Eye Contact
attention if irritation occurs.
: In case of contact, immediately flush skin with plenty of water. Remove contaminated clothing and shoes.
Skin Contact
Wash clothing before reuse. Clean shoes thoroughly before reuse. Get medical attention.
: If inhaled, remove to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial
Inhalation
respiration. Get medical attention.
: Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an
Ingestion
unconscious person. If potentially dangerous quantities of this material have been swallowed, call a
physician immediately.
: Not available.
Notes to Physician
Section 5. Fire fighting measures
Flammable.
Flammability of the product :
Lowest known value: 280癈 (536癋) (benzenesulfonic acid, c10-16-alkyl derivs.).
Auto-ignition Temperature :
Closed cup: 48癈 (118.4癋). (Pensky-Martens.)
Flash Points :
Greatest known range: Lower: 2% Upper: 13% (propan-2-ol)
Flammable limits :
Decomposition products may include the following materials: carbon oxides (CO, CO2)
Products of combustion :
Not available.
Fire hazards in presence of :
various substances
: Risk of explosion of the product in the presence of mechanical impact: Not available.
Explosion hazards in
Risk of explosion of the product in the presence of static discharge: Not available.
presence of various
substances
: In case of fire, use water spray (fog), foam, dry chemical or CO2.
Fire fighting media and
instructions Flammable liquid and vapor. Vapor may cause flash fire. Vapors may accumulate in low or confined areas
or travel a considerable distance to a source of ignition and flash back. Runoff to sewer may create fire or
explosion hazard.
: Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA)
Special protective equipment
with a full face-piece operated in positive pressure mode.
for fire-fighters
: Not available.
Special remarks on fire
hazards
Special remarks on explosion : Not available.
hazards
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Spot stain remover for guarry and terra
cotta tiles, brick, concrete etc.
Section 6. Accidental release measures
: Immediately contact emergency personnel. Eliminate all ignition sources. Keep unnecessary personnel
Personal precautions
away. Use suitable protective equipment (section 8). Do not touch or walk through spilled material.
: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.
Environmental precautions
: If emergency personnel are unavailable, contain spilled material. For small spills, add absorbent (soil
Methods for cleaning up
may be used in the absence of other suitable materials) and use a non-sparking or explosion-proof
means to transfer material to a sealable, appropriate container for disposal. For large spills, dike spilled
material or otherwise contain it to ensure runoff does not reach a waterway. Place spilled material in an
appropriate container for disposal.
Section 7. Handling and storage
: Do not ingest. Keep container closed. Use only with adequate ventilation. Keep away from heat, sparks
Handling
and flame. To avoid fire or explosion, dissipate static electricity during transfer by grounding and bonding
containers and equipment before transferring material. Use explosion-proof electrical (ventilating, lighting
and material handling) equipment. Wash thoroughly after handling.
: Store in a segregated and approved area. Keep container in a cool, well-ventilated area. Keep container
Storage
tightly closed and sealed until ready for use. Avoid all possible sources of ignition (spark or flame).
Section 8. Exposure Controls, Personal Protection
: Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors
Engineering controls
below their respective occupational exposure limits. Ensure that eyewash stations and safety showers
are close to the workstation location.
Personal protection
Eyes : Safety eyewear complying with an approved standard should be used when a risk assessment indicates
this is necessary to avoid exposure to liquid splashes, mists or dusts.
Skin : Personal protective equipment for the body should be selected based on the task being performed and the
risks involved and should be approved by a specialist before handling this product.
Respiratory : Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk
assessment indicates this is necessary.Respirator selection must be based on known or anticipated
exposure levels, the hazards of the product and the safe working limits of the selected respirator.
Hands : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times
when handling chemical products if a risk assessment indicates this is necessary.
Other protection : Not available.
:
Personal protective
equipment (Pictograms)
Personal protection in case : Splash goggles. Full suit. Boots. Gloves. Suggested protective clothing might not be adequate.
Consult a specialist before handling this product.
of a large spill
Consult local authorities for acceptable exposure limits.
Section 9. Physical and chemical properties
: Liquid. (Opalescente)
Physical State and
Appearance
White. Yellow. (Light.)
Color :
Solvent.
Odor :
8.6 [Basic.]
pH :
0.946
:
Relative density
Not available.
Viscosity :
Easily soluble in the following materials: hot water, diethyl ether, acetone.
Solubility :
Soluble in the following materials: cold water.
: Closed cup: 48癈 (118.4癋). (Pensky-Martens.)
Flash point
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Spot stain remover for guarry and terra
cotta tiles, brick, concrete etc.
: Risk of explosion of the product in the presence of mechanical impact: Not available.
Explosive properties
Risk of explosion of the product in the presence of static discharge: Not available.
: Greatest known range: Lower: 2% Upper: 13% (propan-2-ol)
Explosion Limits
: Not applicable
Oxidizing properties
Physical chemical comments : Solubility in other solvents: not soluble
Section 10. Stability and reactivity
: Stable under recommended storage and handling conditions (see section 7).
Stability and Reactivity
: No additional remark.
Conditions of instability
: Reactive with alkalis.
Incompatibility with various
substances
: carbon oxides (CO, CO2)
Hazardous Decomposition
Products
: Will not occur.
Hazardous polymerization
Section 11. Toxicological information
propan-2-ol LD50 5045 mg/kg Oral Rat
LD50 6410 mg/kg Oral Rabbit
LD50 3600 mg/kg Oral Mouse
LD50 12800 mg/kg Dermal Rabbit
LD50 12800 mg/kg Dermal Rabbit
LDLo 1537 mg/kg Oral Dog
LDLo 3570 mg/kg Oral human
LDLo 5272 mg/kg Oral man
diphosphoric acid, tetrapotassium LD50 >2000 mg/kg Oral Rat
salt LD50 >4640 mg/kg Dermal Rabbit
LDLo 4640 mg/kg Oral Rat
alcohols, c12-18, ethoxylated LD50 2500 to 5000 Oral Rat
mg/kg
LD50 >5000 mg/kg Dermal Rabbit
cumene LD50 1400 mg/kg Oral Rat
LD50 12750 mg/kg Oral Mouse
benzenesulfonic acid, c10-16-alkyl LD50 1150 mg/kg Oral Rat
derivs.
Xylene LD50 4300 mg/kg Oral Rat
LD50 2119 mg/kg Oral Mouse
LD50 4300 mg/kg Oral Mammal
LD50 >1700 mg/kg Dermal Rabbit
LD50 1700 mg/kg Dermal Rabbit
LDLo 50 mg/kg Oral human
phosphoric acid LD50 1530 mg/kg Oral Rat
LD50 2740 mg/kg Dermal Rabbit
:
IDLH
: CARCINOGENIC EFFECTS: Classified A4 (Not classifiable for humans or animals.) by ACGIH, 3 (Not
Chronic effects on humans
classifiable for humans.) by IARC [propan-2-ol]. Classified A4 (Not classifiable for humans or animals.)
by ACGIH, 3 (Not classifiable for humans.) by IARC [Xylene].
Contains material which causes damage to the following organs: blood, upper respiratory tract, skin,
central nervous system (CNS), eye, lens or cornea
: Hazardous by the following route of exposure: of eye contact (irritant), of inhalation (lung irritant).
Other toxic effects on
humans
: Not available.
Special remarks on toxicity
to animals
: Not available.
Special remarks on chronic
effects on humans
: Not available.
Special remarks on other
toxic effects on humans
Specific effects
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Spot stain remover for guarry and terra
cotta tiles, brick, concrete etc.
: Contains material which may cause cancer, based on animal data. Risk of cancer depends on duration
Carcinogenic effects
and level of exposure.
: No known significant effects or critical hazards.
Mutagenic effects
: No known significant effects or critical hazards.
Reproduction toxicity
Section 12. Ecological information
1,2,4-Trimethylbenzene Pimephales promelas (LC50) 96 hour(s) 7.72 mg/l
propan-2-ol FATHEAD MINNOWS (EC50) 96 hour(s) 6550 mg/l
Lepomis macrochirus (LC50) 96 hour(s) >1400 mg/l
Pimephales promelas (LC50) 96 hour(s) 6550 mg/l
Pimephales promelas (LC50) 96 hour(s) 9640 mg/l
Pimephales promelas (LC50) 96 hour(s) 10400 mg/l
Pimephales promelas (LC50) 96 hour(s) 11130 mg/l
Mesitylene Scenedesmus subspicatus 48 hour(s) 25 mg/l
(EC50)
Scenedesmus subspicatus 48 hour(s) 53 mg/l
(EC50)
diphosphoric acid, tetrapotassium salt Fish (LC50) 48 hour(s) >750 mg/l
alcohols, c12-18, ethoxylated Daphnia (EC50) 48 hour(s) 0.75 to 1.2 mg/l
Rainbowtrout (LC50) 96 hour(s) 1.8 mg/l
cumene Daphnia magna (EC50) 48 hour(s) 10.6 mg/l
Daphnia magna (EC50) 48 hour(s) 11.2 mg/l
Oncorhynchus mykiss (LC50) 96 hour(s) 2.7 mg/l
Poecilia reticulata (LC50) 96 hour(s) 5.1 mg/l
Pimephales promelas (LC50) 96 hour(s) 6.32 mg/l
benzenesulfonic acid, c10-16-alkyl derivs. Aquatic invertebrates. (EC50) 48 hour(s) 1 to 10 mg/l
Fauna (EC50) 72 hour(s) 10 to 100 mg/l
Brachydanio Rerio (LC50) 96 hour(s) 1 to 10 mg/l
Xylene Oncorhynchus mykiss (LC50) 96 hour(s) 3.3 mg/l
Oncorhynchus mykiss (LC50) 96 hour(s) 8.2 mg/l
Lepomis macrochirus (LC50) 96 hour(s) 8.6 mg/l
Lepomis macrochirus (LC50) 96 hour(s) 12 mg/l
Lepomis macrochirus (LC50) 96 hour(s) 13.3 mg/l
Pimephales promelas (LC50) 96 hour(s) 13.4 mg/l
Not available.
BOD and COD :
Partially biodegradable.
Biodegradable/OECD :
Not available.
Mobility :
Decomposition products may include the following materials: carbon oxides (CO, CO2) and water,
Products of degradation :
nitrogen oxides (NO, NO2 etc.), sulfur oxides (SO2, SO3 etc.), phosphates. Some metallic oxides.
: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Toxicity of the products of
biodegradation
: No additional remark.
Special remarks on the
products of biodegradation
Section 13. Disposal considerations
: The generation of waste should be avoided or minimized wherever possible. Avoid dispersal of spilled
Waste information
material and runoff and contact with soil, waterways, drains and sewers. Disposal of this product, solutions
and any by-products should at all times comply with the requirements of environmental protection and
waste disposal legislation and any regional local authority requirements.
: Not available.
Waste stream
Consult your local or regional authorities.
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Spot stain remover for guarry and terra
cotta tiles, brick, concrete etc.
Section 14. Transport information
Regulatory UN Proper shipping name Class Packing group Label Additional information
Information number
Combustible III
3295 UN 3295, Marine pollutant
DOT
liquid.
HYDROCARBONS, Marine pollutant (P)
Classification FLAMMABLE LIQUID
LIQUID, N.O.S., 3
(Aromatic Hydrocarbons, Limited quantity
22%, mixture), Class 3, Yes.
PG III, (FP 129.2癋)
(1,2,4-Trimethylbenzene). Special provisions
Marine pollutant (cumene) Limited Quantities
Remarks
ORM-D / CONSUMER
COMMODITY
3295 UN 3295, 3 III Marine pollutant
TDG
HYDROCARBONS, Marine pollutant (P)
Classification
LIQUID, N.O.S., 3
(Aromatic Hydrocarbons, Special provisions
22%, mixture), Class 3, ORM-D / CONSUMER
PG III, (FP 129.2癋) COMMODITY
(1,2,4-Trimethylbenzene).
Marine pollutant Remarks
Limited Quantity
UN 3295, "dangerous 3 III
3295 Hazard identification
ADR/RID
goods in limited quantities
Class number
of class 3", III, ADR (1,2,4- 30
3
Trimethylbenzene)
Reportable quantity
45
Remarks
Limited quantity for upto
5 litre inner packing
Else; UN 3295,
HYDROCARBONS,
LIQUID, N.O.S.,
(Aromatic hydrocarbons,
mixture), class 3, III,
ADR
"dangerous goods in 3 III
3295 Emergency schedules
IMDG Class
limited quantities of class (EmS)
3" UN 3295, PG III (1,2,4- 3-07
3
Trimethylbenzene). Marine
pollutant (alcohols, c12- Marine pollutant
18, ethoxylated, poly(oxy- Marine pollutant (P)
1,2-ethanediyl),
.alpha.,.alpha.'-[(9-
Reportable quantity
octadecenylimino)di-2,1-
30
ethanediyl]bis[.omega.-
hydroxy-, (z)-)
Remarks
Limited quantity for upto
5 litre inner packing
Else;
HYDROCARBONS,
LIQUID, N.O.S.,
(Aromatic hydrocarbons,
43%, mixture), class 3,
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Spot stain remover for guarry and terra
cotta tiles, brick, concrete etc.
UN 3295, PG III, (+48癈
c.c.)
3295 "dangerous goods in 3 III RemarksElse;
IATA-DGR
limited quantities of class
Class HYDROCARBONS,
3" UN 3295, PG III (1,2,4- LIQUID, N.O.S.,
3
Trimethylbenzene) (Aromatic hydrocarbons,
43%, mixture), class 3,
UN 3295, PG III, (+48癈
c.c.)
Section 15. Regulatory information
: Class B-2: Flammable liquid with a flash point lower than 37.8癈 (100癋).
WHMIS (Canada)
No products were found.
International regulations
EINECS : Not available.
DSCL (EEC) : R10- Flammable.
R65- Harmful: may cause lung damage if swallowed.
R36/37- Irritating to eyes and respiratory system.
R66- Repeated exposure may cause skin dryness or cracking.
R67- Vapors may cause drowsiness and dizziness.
R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
International lists :
Section 16. Other information
: POISON
Label Requirements
HARMFUL IF SWALLOWED.
IRRITANT.
COMBUSTIBLE.
Hazardous Material 3 National Fire
Health Flammability
1
Information System Protection
1
Fire hazard
Health Instability
3 0
(U.S.A.) Association
0
Reactivity
(U.S.A.) Special
C
Personal protection
: Not available.
References
Other special considerations : Not available.
15-10-2007.
Date of printing :
15-10-2007.
:
Date of issue
No previous validation.
Date of previous issue :
2.01
Version :
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its
subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should
be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.
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