X-DUTY CLEANER
Chemwatch Material Safety Data Sheet
Mar-23-2007 CHEMWATCH 4635-05
NB293EC Version No:5
CD 2007/1 Page 1 of 14
Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME
X-DUTY CLEANER
STATEMENT OF HAZARDOUS NATURE
CONSIDERED A HAZARDOUS SUBSTANCE ACCORDING TO OSHA 29 CFR 1910.1200.
NFPA
2
FLAMMABILITY
2 0
INSTABILITY
HEALTH HAZARD
SUPPLIER
Company: Dry- Treat Inc.
Address:
1201 Orange Street Suite 600
One Commerce Center
Willmington DE 19801
USA
Telephone: 1 866 667 5119
Telephone: +61 2 9954 3211
Emergency Tel: CHEM- TEL (800) 255- 3924 Outside
USA (813) 248- 0585
Emergency Tel: +61 2 9954 3211
Fax: +61 2 9954 3162
PRODUCT USE
Cleaner for tile, stone, paving and grout.
SYNONYMS
Section 2 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
RISK
May cause SENSITIZATION by skin contact.
HARMFUL - May cause lung damage if swallowed.
Irritating to eyes and skin.
Vapors may cause dizziness or suffocation.
Very toxic to aquatic organisms, may cause long- term adverse effects in the
aquatic environment.
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X-DUTY CLEANER
Chemwatch Material Safety Data Sheet
Mar-23-2007 CHEMWATCH 4635-05
NB293EC Version No:5
CD 2007/1 Page 2 of 14
Section 2 - HAZARDS IDENTIFICATION
POTENTIAL HEALTH EFFECTS
ACUTE HEALTH EFFECTS
SWALLOWED
Accidental ingestion of the material may be damaging to the health of the individual.
Ingestion may result in nausea, pain, vomiting. Vomit entering the lungs by aspiration
may cause potentially lethal chemical pneumonitis.
EYE
This material can cause eye irritation and damage in some persons.
The material may produce moderate eye irritation leading to inflammation. Repeated or
prolonged exposure to irritants may produce conjunctivitis.
SKIN
This material can cause inflammation of the skin on
contact in some persons.
Skin contact with the material may damage the health of the individual; systemic effects
may result following absorption.
The material may cause severe skin irritation after prolonged or repeated exposure and
may produce on contact skin redness, swelling, the production of vesicles, scaling and
thickening of the skin. Repeated exposures may produce severe ulceration.
Entry into the blood-stream, through, for example, cuts, abrasions or lesions, may
produce systemic injury with harmful effects. Examine the skin prior to the use of the
material and ensure that any external damage is suitably protected.
Absorption by skin may readily exceed vapor inhalation exposure. Symptoms for skin
absorption are the same as for inhalation.
INHALED
The vapor is discomforting.
Inhalation of vapor is more likely at higher than normal temperatures.
Inhalation of high concentrations of gas/vapor causes lung irritation with coughing and
nausea, central nervous depression with headache and dizziness, slowing of reflexes,
fatigue and inco-ordination.
Not considered an irritant through normal use.
CHRONIC HEALTH EFFECTS
Limited evidence suggests that repeated or long-term occupational exposure may produce
cumulative health effects involving organs or biochemical systems.
Skin contact with the material is more likely to cause a sensitization reaction in some
persons compared to the general population.
Chronic solvent inhalation exposures may result in nervous system impairment and liver
and blood changes. [PATTYS].
Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS
NAME CAS RN %
N- methyl- 2- pyrrolidone 872-50-4 30-60
d- limonene 5989-27-5 10-30
surfactants 10-30
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Chemwatch Material Safety Data Sheet
Mar-23-2007 CHEMWATCH 4635-05
NB293EC Version No:5
CD 2007/1 Page 3 of 14
Section 4 - FIRST AID MEASURES
SWALLOWED
- If swallowed do NOT induce vomiting.
- If vomiting occurs, lean patient forward or place on left side (head-down position, if
possible) to maintain open airway and prevent aspiration.
- Observe the patient carefully.
- Never give liquid to a person showing signs of being sleepy or with reduced awareness;
i.e. becoming unconscious.
- Give water to rinse out mouth, then provide liquid slowly and as much as casualty can
comfortably drink.
- Seek medical advice.
EYE
If this product comes in contact with the eyes:
- Immediately hold eyelids apart and flush the eye continuously with running water.
- Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and
moving the eyelids by occasionally lifting the upper and lower lids.
- Continue flushing until advised to stop by the Poisons Information Center or a doctor,
or for at least 15 minutes.
- Transport to hospital or doctor without delay.
- Removal of contact lenses after an eye injury should only be undertaken by skilled
personnel.
SKIN
If skin contact occurs:
- Immediately remove all contaminated clothing, including footwear
- Flush skin and hair with running water (and soap if available).
- Seek medical attention in event of irritation.
INHALED
- If fumes or combustion products are inhaled remove from contaminated area.
- Lay patient down. Keep warm and rested.
- Prostheses such as false teeth, which may block airway, should be removed, where
possible, prior to initiating first aid procedures.
- Apply artificial respiration if not breathing, preferably with a demand valve
resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if necessary.
- Transport to hospital, or doctor.
NOTES TO PHYSICIAN
Treat symptomatically.
Section 5 - FIRE FIGHTING MEASURES
Flash Point (?>141.8
F):
Lower Explosive Limit (%): Not available
Upper Explosive Limit (%): Not available
Autoignition Temp (?Not available
F):
EXTINGUISHING MEDIA
- Water spray or fog.
- Foam.
- Dry chemical powder.
- BCF (where regulations permit).
- Carbon dioxide.
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Chemwatch Material Safety Data Sheet
Mar-23-2007 CHEMWATCH 4635-05
NB293EC Version No:5
CD 2007/1 Page 4 of 14
Section 5 - FIRE FIGHTING MEASURES
FIRE FIGHTING
- Alert Emergency Responders and tell them location and nature of hazard.
- Wear breathing apparatus plus protective gloves.
- Prevent, by any means available, spillage from entering drains or water course.
- Use water delivered as a fine spray to control fire and cool adjacent area.
- Avoid spraying water onto liquid pools.
- Do not approach containers suspected to be hot.
- Cool fire exposed containers with water spray from a protected location.
- If safe to do so, remove containers from path of fire.
GENERAL FIRE HAZARDS/HAZARDOUS COMBUSTIBLE PRODUCTS
- Combustible.
- Slight fire hazard when exposed to heat or flame.
- Heating may cause expansion or decomposition leading to violent rupture of containers.
- On combustion, may emit toxic fumes of carbon monoxide (CO).
- May emit acrid smoke.
- Mists containing combustible materials may be explosive.
Other combustion products include:
carbon dioxide (CO2).
nitrogen oxides (NOx).
FIRE INCOMPATIBILITY
Avoid contamination with oxidizing agents i.e. nitrates, oxidizing acids,
chlorine bleaches, pool chlorine etc. as ignition may result.
PERSONAL PROTECTION
Glasses:
Safety Glasses.
Chemical goggles.
Gloves:
Respirator:
Type AK Filter of sufficient capacity
Section 6 - ACCIDENTAL RELEASE MEASURES
MINOR SPILLS
- Remove all ignition sources.
- Clean up all spills immediately.
- Avoid breathing vapors and contact with skin and eyes.
- Control personal contact by using protective equipment.
- Contain and absorb spill with sand, earth, inert material or vermiculite.
- Wipe up.
- Place in a suitable labeled container for waste disposal.
MAJOR SPILLS
Moderate hazard.
- Clear area of personnel and move upwind.
- Alert Emergency Responders and tell them location and nature of hazard.
- Wear breathing apparatus plus protective gloves.
- Prevent, by any means available, spillage from entering drains or water course.
- No smoking, naked lights or ignition sources. Increase ventilation.
- Stop leak if safe to do so.
- Contain spill with sand, earth or vermiculite.
- Collect recoverable product into labeled containers for recycling.
- Absorb remaining product with sand, earth or vermiculite.
- Collect solid residues and seal in labeled drums for disposal.
- Wash area and prevent runoff into drains.
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Chemwatch Material Safety Data Sheet
Mar-23-2007 CHEMWATCH 4635-05
NB293EC Version No:5
CD 2007/1 Page 5 of 14
Section 6 - ACCIDENTAL RELEASE MEASURES
- If contamination of drains or waterways occurs, advise emergency services.
EMERGENCY RESPONSE PLANNING GUIDELINES (ERPG)
The maximum airborne concentration below which it is believed that nearly all individuals could be exposed
for up to one hour WITHOUT experiencing or developing
life-threatening health effects is:
N-methyl-2-pyrrolidone 400 ppm
d-limonene 350 ppm
irreversible or other serious effects or symptoms which could impair an individual's ability to take
protective action is:
N-methyl-2-pyrrolidone 50 ppm
d-limonene 150 ppm
other than mild, transient adverse effects without perceiving a clearly defined odour is:
N-methyl-2-pyrrolidone 15 ppm
d-limonene 90 ppm
The threshold concentration below which most people will experience no appreciable risk of health effects:
N-methyl-2-pyrrolidone 10 ppm
d-limonene 30 ppm
American Industrial Hygiene Association (AIHA)
Ingredients considered according to the following cutoffs
Very Toxic (T+) >= 0.1% Toxic (T) >= 3.0%
R50 >= 0.25% Corrosive (C) >= 5.0%
R51 >= 2.5%
else >= 10%
where percentage is percentage of ingredient found in the mixture
Section 7 - HANDLING AND STORAGE
PROCEDURE FOR HANDLING
Avoid generating and breathing mist.
- Avoid all personal contact, including inhalation.
- Wear protective clothing when risk of exposure occurs.
- Use in a well-ventilated area.
- Prevent concentration in hollows and sumps.
- DO NOT enter confined spaces until atmosphere has been checked.
- Avoid smoking, naked lights or ignition sources.
- Avoid contact with incompatible materials.
- When handling, DO NOT eat, drink or smoke.
- Keep containers securely sealed when not in use.
- Avoid physical damage to containers.
- Always wash hands with soap and water after handling.
- Work clothes should be laundered separately.
- Use good occupational work practice.
- Observe manufacturer's storing and handling recommendations.
- Atmosphere should be regularly checked against established exposure standards to ensure
safe working conditions.
RECOMMENDED STORAGE METHODS
- Metal can or drum
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Chemwatch Material Safety Data Sheet
Mar-23-2007 CHEMWATCH 4635-05
NB293EC Version No:5
CD 2007/1 Page 6 of 14
Section 7 - HANDLING AND STORAGE
- Packing as recommended by manufacturer.
- Check all containers are clearly labeled and free from leaks.
STORAGE REQUIREMENTS
- Store in original containers.
- Keep containers securely sealed.
- No smoking, naked lights or ignition sources.
- Store in a cool, dry, well-ventilated area.
- Store away from incompatible materials and foodstuff containers.
- Protect containers against physical damage and check regularly for leaks.
- Observe manufacturer's storing and handling recommendations.
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE CONTROLS
Source Material TWA ppm TWA mg/m?STEL ppm STEL mg/m砅eak ppm Peak mg/m?TWA F/CC
_________ _________ _____ _____ _____ _____ _____ _____ _____
US AIHA N- methyl- 10
Workplace 2-
Environmen pyrrolidone
tal (n-
Exposure Methyl- 2-
Levels Pyrrolidone)
(WEELs)
Canada - N- methyl- 400
Ontario 2-
Occupatio pyrrolidone
nal (N-
Exposure Methyl- 2-
Limits pyrrolidone)
Canada - N- methyl- 100 400 125 500
Yukon 2-
Permissible pyrrolidone
(N-
Concentrat Methyl- 2-
ions for pyrrolidone)
Airborne
Contaminant
Substances
US AIHA d- 30
Workplace limonene
Environmen (d-
tal Limonene)
Exposure
Levels
(WEELs)
MATERIAL DATA
Not available. Refer to individual constituents.
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Chemwatch Material Safety Data Sheet
Mar-23-2007 CHEMWATCH 4635-05
NB293EC Version No:5
CD 2007/1 Page 7 of 14
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
INGREDIENT DATA
N-METHYL-2-PYRROLIDONE:
Reports of skin and eye irritation and chronic headaches have been
reported in workers exposed to 1-methyl-2-pyrrolidone. The Australian ES
is based on a 10-fold uncertainty factor of the no-observable-adverse-
effect level (NOAEL) of 24 ppm where adverse respiratory effects were
observed in a 4-week inhalation study in rats.
D-LIMONENE:
Sensory irritants are chemicals that produce temporary and undesirable side-effects on
the eyes, nose or throat. Historically occupational exposure standards for these
irritants have been based on observation of workers' responses to various airborne
concentrations. Present day expectations require that nearly every individual should be
protected against even minor sensory irritation and exposure standards are established
using uncertainty factors or safety factors of 5 to 10 or more. On occasion animal no
-observable-effect-levels (NOEL) are used to determine these limits where human results
are unavailable. An additional approach, typically used by the TLV committee (USA) in
determining respiratory standards for this group of chemicals, has been to assign ceiling
values (TLV C) to rapidly acting irritants and to assign short-term exposure limits (TLV
STELs) when the weight of evidence from irritation, bioaccumulation and other endpoints
combine to warrant such a limit. In contrast the MAK Commission (Germany) uses a five
-category system based on intensive odour, local irritation, and elimination half-life.
However this system is being replaced to be consistent with the European Union (EU)
Scientific Committee for Occupational Exposure Limits (SCOEL); this is more closely
allied to that of the USA.
OSHA (USA) concluded that exposure to sensory irritants can:
- cause inflammation
- cause increased susceptibility to other irritants and infectious agents
- lead to permanent injury or dysfunction
- permit greater absorption of hazardous substances and
- acclimate the worker to the irritant warning properties of these substances thus
increasing the risk of overexposure.
CEL TWA: 30 ppm, 165.6 mg/m3 (compare WEEL-TWA*)
A Workplace Environmental Exposure Level* has been established by AIHA
(American Industrial Hygiene Association) who have produced the following
rationale:
D-limonene is not acutely toxic. In its pure form it is not a sensitiser
but is irritating to the skin. Although there is clear evidence of
carcinogenicity in male rats, the effect has been attributed to an
alpha-2u-globin (a2u-G) renal toxicity which is both species and gender
specific. Humans do not synthesise a2u-G, and metabolism studies indicate
that 75% to 95% of d-limonene is excreted in 2-3 days with different
metabolites identified between humans and rats. In a 2-year study, liver
effects were noted in male mice at 500 mg/kg and reduced survival was noted
in female rats at 600 mg/kg. The no observable effect levels (NOELs) were
250 and 300 mg/kg, respectively. A WEEL of 30 ppm is recommended to
protect against these effects.
PERSONAL PROTECTION
EYE
- Safety glasses with side shields; or as required,
- Chemical goggles.
- Contact lenses pose a special hazard; soft lenses may absorb irritants and all lenses
concentrate them.
HANDS/FEET
DO NOT use this product to clean the skin.
Do NOT use rubber or PVC gloves. Use butyl, teflon, nylon, neoprene.
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Chemwatch Material Safety Data Sheet
Mar-23-2007 CHEMWATCH 4635-05
NB293EC Version No:5
CD 2007/1 Page 8 of 14
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
OTHER
- Overalls.
- Barrier cream.
- Eyewash unit.
RESPIRATOR
Respiratory protection may be required when ANY "Worst Case" vapor-phase concentration is
exceeded (see Computer Prediction in "Exposure Standards").
Protection Factor Half- Face Respirator Full- face Respirator Spray/Mist Spatter
(Min)
10 x PEL AK- 1 - AK-
AK- PAPR- 1 - AK- PAPR-
20 x PEL - AK- 1 AK-
- AK- PAPR- 1 AK- PAPR-
100 x PEL - AK- 2 AK-
- AK- PAPR- 2 AK- PAPR-
^ - Full-face
Explanation of Respirator Codes:
Class 1 low to medium absorption capacity filters.
Class 2 medium absorption capacity filters.
Class 3 high absorption capacity filters.
PAPR Powered Air Purifying Respirator (positive pressure) cartridge.
Type A for use against certain organic gases and vapors.
Type AX for use against low boiling point organic compounds (less than 65ºC).
Type B for use against certain inorganic gases and other acid gases and vapors.
Type E for use against sulfur dioxide and other acid gases and vapors.
Type K for use against ammonia and organic ammonia derivatives
Class P1 intended for use against mechanically generated particulates of sizes most
commonly encountered in industry, e.g. asbestos, silica.
Class P2 intended for use against both mechanically and thermally generated particulates,
e.g. metal fume.
Class P3 intended for use against all particulates containing highly toxic materials,
e.g. beryllium.
The local concentration of material, quantity and conditions of use determine the type of
personal protective equipment required.
Use appropriate NIOSH-certified respirator based on informed professional
judgement. In conditions where no reasonable estimate of exposure can be
made, assume the exposure is in a concentration IDLH and use NIOSH-certified
full face pressure demand SCBA with a minimum service life of 30 minutes, or
a combination full facepiece pressure demand SAR with auxiliary self-contained
air supply. Respirators provided only for escape from IDLH atmospheres shall be
NIOSH-certified for escape from the atmosphere in which they will be used.
ENGINEERING CONTROLS
Use in a well-ventilated area.
General exhaust is adequate under normal operating conditions. Local exhaust ventilation
may be required in specific circumstances. If risk of overexposure exists, wear an
approved respirator. Correct fit is essential to obtain adequate protection. Provide
adequate ventilation in warehouse or closed storage areas.
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Mar-23-2007 CHEMWATCH 4635-05
NB293EC Version No:5
CD 2007/1 Page 9 of 14
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL PROPERTIES
Liquid.
Mixes with water.
Molecular Weight: Not applicable Boiling Range (?Not av ailable
F):
Melting Range (?Not available.
F): Specific Gravity (water =1): 1.015
Solubility in water (g/L): Miscible pH (as supplied): Not applicable
pH (1% solution): Not applicable. Vapor Pressure (mmHg): Not available
Volatile Component (%vol): Not available Evaporation Rate: Not available
Relative Vapor Density (air=1): >1 Flash Point (?>141.8
F):
Lower Explosive Limit (%): Not available Upper Explosive Limit (%): Not available
Autoignition Temp (?Not available
F): Decomposition Temp ( ?Not available.
F):
State: Liquid Viscosity: Not Available
APPEARANCE
Very light yellow, clear liquid with solvent odour; dispersible in water.
USA VOC content: < 20 g/litre
Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION
CONDITIONS CONTRIBUTING TO INSTABILITY
- Presence of incompatible materials.
- Product is considered stable.
- Hazardous polymerization will not occur.
STORAGE INCOMPATIBILITY
Avoid reaction with oxidizing agents.
Section 11 - TOXICOLOGICAL INFORMATION
X-Duty Cleaner
TOXICITY AND IRRITATION
Not available. Refer to individual constituents.
N-METHYL-2-PYRROLIDONE:
Oral (rat) LD50: 4200 mg/kg* Eye (rabbit):
Oral (rat) LD50: 3914 mg/kg *[Manufacturer]
Dermal (rabbit) LD50: 8000 mg/kg
The material may produce moderate eye irritation leading to inflammation. Repeated or
prolonged exposure to irritants may produce conjunctivitis.
100 mg - moderate
D-LIMONENE:
TOXICITY IRRITATION
Oral (rat) LD50: 4400 mg/kg Nil Reported
Inhalation (rat) LC50: 90860 mg/m? Skin (rabbit): 500mg/24h Moderate
Contact allergies quickly manifest themselves as contact eczema, more rarely as urticaria
or Quincke's edema. The pathogenesis of contact eczema involves a cell-mediated (T
lymphocytes) immune reaction of the delayed type. Other allergic skin reactions, e.g.
contact urticaria, involve antibody-mediated immune reactions. The significance of the
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Mar-23-2007 CHEMWATCH 4635-05
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Section 11 - TOXICOLOGICAL INFORMATION
contact allergen is not simply determined by its sensitization potential: the
distribution of the substance and the opportunities for contact with it are equally
important. A weakly sensitizing substance which is widely distributed can be a more
important allergen than one with stronger sensitizing potential with which few
individuals come into contact. From a clinical point of view, substances are noteworthy
if they produce an allergic test reaction in more than 1% of the persons tested.
The substance is classified by IARC as Group 3:
NOT classifiable as to its carcinogenicity to humans.
Evidence of carcinogenicity may be inadequate or limited in animal testing.
Dermal (rabbit): >5000 mg/kg
Tumorigenic by RTECS criteria
data for similar material l-limonene
MATERIAL CARCINOGEN SENSITIZER SKIN MUTAGEN REPROTOXIN
______________________________ ____________ __________ __________ __________ __________
N- methyl- 2- pyrrolidone CP65:Yes
REPROTOXIN
Californian Proposition 65 - Reproductive Toxicity:
TYPE: N-methyl-2-pyrrolidone: developmental DATE LISTED: June 15, 2001
Section 12 - ECOLOGICAL INFORMATION
DO NOT discharge into sewer or waterways.
Refer to data for ingredients, which follows:
N-METHYL-2-PYRROLIDONE:
DO NOT discharge into sewer or waterways.
log Kow: -0.44-0.1
D-LIMONENE:
Substances containing unsaturated carbons are ubiquitous in indoor environments. They
result from many sources (see below). Most are reactive with environmental ozone and many
produce stable products which are thought to adversely affect human health.The potential
for surfaces in an enclosed space to facilitate reactions should be considered.
Source of unsaturated Unsaturated substances Major Stable Products produced
substances (Reactive Emissions) following reaction with ozone.
Occupants (exhaled breath, ski Isoprene, nitric oxide, Methacrolein, methyl vinyl
oils, personal care products) squalene, unsaturated sterols, ketone, nitrogen dioxide,
oleic acid and other acetone, 6MHQ, geranyl acetone,
unsaturated fatty acids, 4OPA, formaldehyde, nonanol,
unsaturated oxidation products decanal, 9- oxo- nonanoic acid,
azelaic acid, nonanoic acid.
Soft woods, wood flooring, Isoprene, limonene, alpha- Formaldehyde, 4- AMC,
including cypress, cedar and pinene, other terpenes and pinoaldehyde, pinic acid,
silver fir boards, houseplants sesquiterpenes pinonic acid, formic acid,
methacrolein, methyl vinyl
ketone, SOAs including
ultrafine particles
Carpets and carpet backing 4- Phenylcyclohexene, 4- Formaldehyde, acetaldehyde,
vinylcyclohexene, styrene, 2- benzaldehyde, hexanal, nonanal,
ethylhexyl acrylate, 2 - nonenal
unsaturated fatty acids and
esters
Linoleum and paints/polishes Linoleic acid, linolenic acid Propanal, hexanal, nonanal, 2-
containing linseed oil heptenal, 2- nonenal, 2-
decenal, 1- pentene- 3 - one,
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Section 12 - ECOLOGICAL INFORMATION
propionic acid, n- butyric acid
Latex paint Residual monomers Formaldehyde
Certain cleaning products, Limonene, alpha- pinene, Formaldehyde, acetaldehyde,
polishes, waxes, air fresheners terpinolene, alpha- terpineol, glycoaldehyde, formic acid,
linalool, linalyl acetate and acetic acid, hydrogen and
other terpinoids, longifolene organic peroxides, acetone,
and other sesquiterpenes benzaldehyde, 4- hydroxy- 4-
methyl- 5- hexen- 1- al, 5 -
ethenyl- dihydro- 5- methyl-
2(3H)- furanone, 4- AMC, SOAs
including ultrafine particles
Natural rubber adhesive Isoprene, terpenes Formaldehyde, methacrolein,
methyl vinyl ketone
Photocopier toner, printed Styrene Formaldehyde, benzaldehyde
paper, styrene polymers
Environmental tobacco smoke Styrene, acrolein, nicotine Formaldehyde, benzaldehyde,
hexanal, glyoxal, N-
methylformamide,
nicotinaldehyde, cotinine
Soiled clothing, fabrics, Squalene, unsaturated sterols, Acetone, geranyl acetone, 6MHO,
bedding oleic acid and other saturated 40PA, formaldehyde, nonanal,
fatty acids decanal, 9 - oxo- nonanoic
acid, azelaic acid, nonanoic
acid
Soiled particle filters Unsaturated fatty acids from Formaldehyde, nonanal, and
plant waxes, leaf litter, and other aldehydes; azelaic acid;
other vegetative debris; soot; nonanoic acid; 9- oxo- nonanoic
diesel particles acid and other oxo- acids;
compounds with mixed functional
groups (=O, - OH, and - COOH)
Ventilation ducts and duct Unsaturated fatty acids and C5 to C10 aldehydes
liners esters, unsaturated oils,
neoprene
" Urban grime" Polycyclic aromatic Oxidized polycyclic aromatic
hydrocarbons hydrocarbons
Perfumes, colognes, essential Limonene, alpha- pinene, Formaldehyde, 4- AMC, acetone,
oils (e.g. lavender, linalool, linalyl acetate, 4- hydroxy- 4- methyl- 5-
eucalyptus, tea tree) terpinene- 4- ol, gamma - hexen- 1- al, 5- ethenyl -
terpinene dihydro- 5- methyl- 2(3H)
furanone, SOAs including
ultrafine particles
Overall home emissions Limonene, alpha- pinene, Formaldehyde, 4- AMC,
styrene pinonaldehyde, acetone, pinic
acid, pinonic acid, formic
acid, benzaldehyde, SOAs
including ultrafine particles
Abbreviations: 4-AMC, 4-acetyl-1-methylcyclohexene; 6MHQ, 6-methyl-5-heptene-2-one, 4OPA,
4-oxopentanal, SOA, Secondary Organic Aerosols
Reference: Charles J Weschler; Environmental Helath Perspectives, Vol 114, October 2006.
Drinking Water Standards:
hydrocarbon total: 10 ug/l (UK max.).
Do NOT allow product to come in contact with surface waters or to intertidal areas below
the mean high water mark. Do not contaminate water when cleaning equipment or disposing
of equipment wash-waters.
Wastes resulting from use of the product must be disposed of on site or at approved waste
sites.
DO NOT discharge into sewer or waterways.
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Section 13 - DISPOSAL CONSIDERATIONS
Disposal Instructions
All waste must be handled in accordance with local, state and federal
regulations.
- Consult manufacturer for recycling options and recycle where possible .
- Consult Waste Management Authority for disposal.
- Incinerate residue at an approved site.
- Recycle containers where possible, or dispose of in an authorized landfill.
Section 14 - TRANSPORTATION INFORMATION
NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS:UN, IATA,
IMDG
Section 15 - REGULATORY INFORMATION
REGULATIONS
US EPCRA Section 313 Chemical List For Reporting Year 2004
Ingredient CAS % de minimus
concentration
N- methyl- 2- pyrrolidone 872- 50- 4 1.0
N-methyl-2-pyrrolidone (CAS: 872-50-4) is found on the following regulatory lists;
Canada - Ontario Occupational Exposure Limits
Canada - Yukon Permissible Concentrations for Airborne Contaminant Substances
Canada Domestic Substances List (DSL)
Canada National Pollutant Release Inventory (NPRI)
IMO MARPOL 73/78 (Annex II) - List of Noxious Liquid Substances Carried in Bulk
International Council of Chemical Associations (ICCA) - High Production Volume List
OECD Representative List of High Production Volume (HPV) Chemicals
US - California Proposition 65 - Maximum Allowable Dose Levels (MADLs) for Chemicals
Causing Reproductive Toxicity
US - California Proposition 65 - Reproductive Toxicity
US - Minnesota Hazardous Substance List
US ACGIH Biological Exposure Indices (BEI) - Notice of Intended Changes
US AIHA Workplace Environmental Exposure Levels (WEELs)
US DOE Temporary Emergency Exposure Limits (TEELs)
US DOT Coast Guard Bulk Hazardous Materials - List of Flammable and Combustible Bulk
Liquid Cargoes
US EPA High Production Volume Program Chemical List
US EPCRA Section 313 Chemical List For Reporting Year 2004
US Toxic Substances Control Act (TSCA) - Inventory
US TSCA Section 12(b) - List of Chemical Substances Subject to Export Notification
Requirements
US TSCA Section 4 - Chemicals Subject to Testing Consent Orders
US TSCA Section 4/12 (b) - Sunset Date/Status
N-methyl-2-pyrrolidone (CAS: 26138-58-9) is found on the following regulatory lists;
Canada National Pollutant Release Inventory (NPRI)
d-limonene (CAS: 5989-27-5) is found on the following regulatory lists;
Canada Domestic Substances List (DSL)
Canada Ingredient Disclosure List (SOR/88-64)
continued...
X-DUTY CLEANER
Chemwatch Material Safety Data Sheet
Mar-23-2007 CHEMWATCH 4635-05
NB293EC Version No:5
CD 2007/1 Page 13 of 14
Section 15 - REGULATORY INFORMATION
Canada National Pollutant Release Inventory (NPRI)
International Agency for Research on Cancer (IARC) Carcinogens
OECD Representative List of High Production Volume (HPV) Chemicals
OSPAR List of Substances of Possible Concern
US DOE Temporary Emergency Exposure Limits (TEELs)
US EPA High Production Volume Program Chemical List
US Food Additive Database
US NFPA 30B Manufacture and Storage of Aerosol Products - Chemical Heat of Combustion
US Toxic Substances Control Act (TSCA) - Inventory
d-limonene (CAS: 138-86-3) is found on the following regulatory lists;
Canada Domestic Substances List (DSL)
Canada Ingredient Disclosure List (SOR/88-64)
Canada National Pollutant Release Inventory (NPRI)
IMO MARPOL 73/78 (Annex II) - List of Noxious Liquid Substances Carried in Bulk
OECD Representative List of High Production Volume (HPV) Chemicals
US - New Jersey Right to Know Hazardous Substances
US - New Jersey Right to Know Hazardous Substances (Spanish)
US AIHA Workplace Environmental Exposure Levels (WEELs)
US Department of Transportation (DOT) Marine Pollutants - Appendix B
US DOT Coast Guard Bulk Hazardous Materials - List of Flammable and Combustible Bulk
Liquid Cargoes
US EPA High Production Volume Chemicals Additional List
US Toxic Substances Control Act (TSCA) - Inventory
Section 16 - OTHER INFORMATION
INGREDIENTS WITH MULTIPLE CAS NUMBERS
Ingredient Name CAS
N- methyl- 2- pyrrolidone 872- 50- 4, 26138- 58- 9
d- limonene 5989- 27- 5, 138- 86- 3
REPRODUCTIVE HEALTH GUIDELINES
Ingredient ORG UF Endpoi CR Adeq
nt TLV
N- methyl- 2- pyrrolidone 0.91 mg/m3 1000 D NA -
These exposure guidelines have been derived from a screening level of risk assessment and
should not be construed as unequivocally safe limits. ORGS represent an 8-hour time
-weighted average unless specified otherwise.
CR = Cancer Risk/10000; UF = Uncertainty factor:
TLV believed to be adequate to protect reproductive health:
LOD: Limit of detection
Toxic endpoints have also been identified as:
D = Developmental; R = Reproductive; TC = Transplacental carcinogen
Jankovic J., Drake F.: A Screening Method for Occupational Reproductive Health Risk:
American Industrial Hygiene Association Journal 57: 641-649 (1996).
EXPOSURE STANDARD FOR MIXTURES
"Worst Case" computer-aided prediction of vapour components/concentrations:
Composite Exposure Standard for Mixture (TWA) (mg/m3): 165.6 mg/m?br>
If the breathing zone concentration of ANY of the components listed below is exceeded,
"Worst Case" considerations deem the individual to be overexposed.
Component Breathing Zone ppm Breathing Zone mg/m3 Mixture Conc: (%).
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X-DUTY CLEANER
Chemwatch Material Safety Data Sheet
Mar-23-2007 CHEMWATCH 4635-05
NB293EC Version No:5
CD 2007/1 Page 14 of 14
Section 16 - OTHER INFORMATION
Component Breathing zone Breathing Zone Mixture Conc
(ppm) (mg/m? (%)
d-limonene 30.00 165.6000 30.0
Operations which produce a spray/mist or fume/dust, introduce particulates to the
breathing zone.
If the breathing zone concentration of ANY of the components listed below is exceeded,
"Worst Case" considerations deem the individual to be overexposed.
At the "Composite Exposure Standard for Mixture" (TWA) (mg/m3): 30 mg/m?br>
Reasonable care has been taken in the preparation of this information, but the
author makes no warranty of merchantability or any other warranty, expressed or
implied, with respect to this information. The author makes no representations
and assumes no liability for any direct, incidental or consequential damages
resulting from its use. CHEMTREC: (800) 424- 9300
Issue Date: Mar-23-2007
Print Date: Mar-29-2007
This document is copyright. Apart from any fair dealing for the purposes of
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Act, no part may be reproduced by any process without written permission from
CHEMWATCH. TEL (+61 3) 9572 4700.
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