Material Safety Data Sheet
Revised 1/01
Manufacturer's Name Emergency Response #
Coatings For Industry, Inc. 1-800-535-5053
319 Township Line Road
Souderton, PA 18964 Non-Emergency #
215-723-0919
Formula
Proprietary Trade Name
Sunlube 320
Section II - Hazardous Ingredients
Material CAS No. %
N-Methyl-Pyrrolidone* 872-50-4 2.5
1,2-Propanediol 57-55-6 2
*ACGIH/TLV, OSHA/PEL - Not Established. (100 ppm recommended by mfg.)
Section III - Physical Data
Specific Gravity ~~~~~~~~~~~~~~~~~~~~~~~~~~~.98-1.02
% Volatile by Weight~~~~~~~~~~~~~~~~~~~~~~~~75
Vapor Density~~~~~~~~~~~~~~~~~~~~~~~~~~~~~Heavier than air
Solubility in water~~~~~~~~~~~~~~~~~~~~~~~~~~Soluble - Water Base
Appearance and Odor~~~~~~~~~~~~~~~~~~~~~~~milky, clear
Section IV - Fire and Explosion Hazard Data
Flash Point ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ Greater than 200?F. (Not regulated)
Extinguishing Media - Protein type air foams, water spray, ABC dry chemical
Unusual Fire and Explosion Hazards - Material will not sustain combustion but closed
containers may explode due to build up of steam pressure when exposed to heat.
Section V - Health Hazard Data
Threshold Limit Values - See Section II
Sunlube 320 MSDS Page 2 of 6
Acute Health Effects
May cause eye and skin irritation.
Ingestion may cause nausea, vomiting and diarrhea.
Inhalation may cause irritation of the respiratory tract and mucous membranes.
Chronic Health Effects
N-METHYL PYRROLIDONE (NMP) has been shown to produce reproductive and
developmental effects at very high, maternally toxic doses, in experimental animals.
These observations are not thought to be relevant to occupational usage of NMP.
Signs/Symptoms of Exposure
Irritation.
Routes of Exposure/Entry
Eyes, skin contact, inhalation, ingestion.
Target Organs
Eyes, respiratory tract, reproductive system, skin.
Medical Conditions Aggravated by Exposure
Pre-existing skin problems may be aggravated by prolonged or repeated contact.
Persons with sensitive airways (e.g., asthmatics) may react to vapors.
Carcinogenic Status
The components of this mixture are not known to be listed or regulated by IARC, NTP,
OSHA or ACGIH.
Section VI ?First Aid Measures
If irritation or other symptoms (as noted above) occur or persist from any route of
exposure, remove the affected individual from the area: see a physician/get medical
attention.
Eye Contact
Immediately flush eyes with plenty of clean water for an extended time, not less than five
(5) minutes. Flush longer if there is any indication of residual chemical in the eye.
Ensure adequate flushing of the eyes by separating the eyelids with fingers and roll eyes
in a circular motion.
Skin Contact
Wash the affected area thoroughly with plenty of water and soap.
inhalation
If affected, remove to fresh air.
If not breathing, give artificial respiration.
Ingestion
Get medical attention immediately.
Section VII - Reactivity Data
Stability: This product is stable.
Hazardous Polymerization: Hazardous polymerization will not occur.
Sunlube 320 MSDS Page 3 of 6
Conditions to Avoid
Do not freeze.
Incompatibility with other materials
Acidic conditions will cause the urethane resin to precipitate out of solution.
Hazardous Decomposition Products
Carbon monoxide, carbon dioxide, and oxides of nitrogen.
Section VIII - Spill or Leak Procedures
Containment Techniques
Contain spill.
If spilled in an enclosed area, ventilate.
Clean-Up Techniques
Wear proper personal protective clothing and equipment. Do not flush liquid into public
sewer, water systems or surface waters. Soak up large spill residue and small spills with
an inert absorbent. Place into labeled, closed container; store in safe location to await
disposal. Wash the spill area with soap and water.
Change contaminated clothing and launder before reuse.
Section IX ?Exposure Controls / Personal Protection
Engineering Controls
Always provide effective general and, when necessary, local exhaust ventilation to draw
spray, aerosol, fume, mist and vapor away from workers to prevent routine inhalation.
Ventilation must be adequate to maintain the ambient workplace atmosphere below the
exposure limit(s)outlined in the MSDS. Ventilation guidelines/techniques may be found
in publications such as Industrial Ventilation: American Conference of Governmental
Industrial Hygienists, 1330 Kemper Meadow Drive, Cincinnati, OH, 45240-1634, USA.
Eye/Face Protection
Wear eye protection.
Skin Protection
Wear chemical resistant (impervious) gloves.
Respiratory Protection
Wear a respirator approved by NIOSH/MSHA (e.g., an organic vapor respirator, a full
face air purifying respirator for organic vapors, or a self-contained breathing apparatus)
whenever exposure to aerosol, mist, spray, fume or vapor exceed the exposure limit(s) of
any chemical substance listed in this MSDS.
Use respirator in accordance with manufacturer's use limitations and
OSHA standard 1910.134 (29CFR).
Sunlube 320 MSDS Page 4 of 6
Section X ?Toxicological Information
Route Species Exposure and Dose
n-Methyl pyrrolidone
Oral Rat, adult LD50 4200. mg/kg
Skin Rabbit, adult LD50 8000. mg/kg
1,2 Propanediol
Oral Rat, adult LD50 20 gm/kg
Skin Rabbit, adult LD 50 20800mg/kg
N-METHYL PYRROLIDONE: Human experience has demonstrated redness, cracking
and blistering through repeated or prolonged contact. NMP was reported to be fetotoxic
and to increase skeletal abnormalities when administered dermally to rats during
gestation at very high, maternally toxic doses. NMP was not fetotoxic or teratogenic in
rats exposed to NMP vapors up to 0.36 mg/L during gestation (Fund. and Appl. Tox.
9:222-235, 1987). NMP has been reported to cause aneuploidy in saccharomyces, but is
not mutagenic in the Ames test (Env. and Molec. Mut 11(1)31-40, 1988).
Section XI ?Handling and Storage
Handling
Avoid eye contact.
Avoid repeated or prolonged skin contact.
Avoid inhalation of aerosol, mist, spray, fume or vapor.
Avoid drinking, tasting, swallowing or ingesting this product.
Wash thoroughly after handling this product. Always wash up before eating, smoking or
using the facilities.
Provide eyewash fountains and safety showers in the work area.
Use under well-ventilated conditions.
Under normal conditions of use, curing (heating) of this polymer may generate a small
amount of dimethyl ethanol amine. Substrates coated or impregnated with this polymer
can emit dimethyl ethanol amine until the polymer is fully reacted.
Storage
Do not store in open, unlabeled or mislabeled containers.
Do not allow product to freeze.
Do not puncture or stack drums.
Keep container closed when not in use.
Do not reuse empty container without commercial cleaning or reconditioning.
Sunlube 320 MSDS Page 5 of 6
Section XII - Additional Regulatory Information
--SARA Title III section 313--
This product contains the following toxic chemicals subject to the reporting requirements
of section 313 of the Emergency Planning and Community Right to Know Act of 1986
and of 40 CFR 372:
CAS# 872-50-4 N-Methyl-Pyrrolidone 2.5 % by weight
--SARA Title III Section 312 Hazard Category (40 CFR 311/312)--
Acute Health: No Release of Pressure: No
Chronic Health: Yes Reactive: No
Fire: No
--The following ingredients are registered for TSCA 12B--
n-Methyl pyrrolidone
-California Proposition 65 -----"Substances known to the state of California to cause
cancer, birth defects or other reproductive harm": None known*to be present or none in
reportable amounts for occupational exposure as per OSHA's approval of the California
Hazard Communication Standard, Federal Register, page 31159 ff, 6 June 1997.
US (Federal) Regulations
TSCA: All components of this product are either listed on the U.S. Toxic Substances
Control Act (TSCA) inventory of chemicals or are otherwise compliant with TSCA
regulations.
International Regulations
Canadian DSL: One or more components in this product are Transitional.
Canadian Ingredient Disclosure List (WHMIS) :. Not applicable.
Canadian WHMIS: This product is controlled under the Canadian Hazardous Materials
Information System (WHMIS) and is classified as: D2B
Section XIII ?Other Information
HMIS Rating (H-F-R-PPI) 1-0-0-B
NFPA Rating (H-F-R) 0-0-0
KEY: O=Insignificant; 1=Slight; 2=Moderate; 3=High; 4=Extreme.
Hazardous Materials Identification System (HMIS), National Paint and Coatings Assn.
rating applies to product "as packaged" (i.e., ambient temperature).
National Fire Protection Association (NFPA) rating identifies the severity of hazards of
material during a fire emergency (i.e., "on fire").
Legend:
Sunlube 320 MSDS Page 6 of 6
ACGIH: American Conference of Governmental Industrial Hygienists
CAS NO: Chemical Abstract Service Registry Number
IARC: International Agency for Research on Cancer
MSHA: Mine Safety and Health Administration
NIOSH: National Institute for Occupational Safety and Health
NTP: National Toxicology Program
N/A: Not Applicable
N/E: None Established
OSHA: Occupational Safety and Health Administration
PEL: Permissible Exposure Limit
PNOC: Particulates Not Otherwise Classified
RTK: Right To Know
STEL: Short Term Exposure Limit (15 minute Time Weighted Average)
TLV: Threshold Limit Value
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NOTICE : This information is presented in good faith and believed to be accurate as of
the effective date below. However, no warranty is express or implied regarding the
accuracy of this data or the results to be obtained from the use thereof. Coatings For
Industry, Inc. assumes no responsibility for personal injury or property damage to
vendees, users, or third parties caused by the material, such vendees or users assume all
risks associated with the use of the material. Regulatory requirements are subject to
change and may differ from one location to another; it is the buyer's responsibility to
ensure that its activities comply with federal, state or provincial, and local laws. The
preceding specific information is made for the purpose of complying with numerous
federal, state or provincial, and local laws and regulations.
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