MSDS (Material Safety Data Sheet)
GreyhoundTM Insecticide Page 1 of 3
P.O. Box 34645 Omaha, NE 68134 Toll-Free: 800-698-4641 Phone: 402-339-4459 Fax: 402-339-5011 www.ArborSystems.com
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1. PRODUCT IDENTIFICATION
Product Name: GreyhoundTM Insecticide EPA Reg. No.: 69117-2 Chemical Description: A mixture of avermectins
containing primarily Avermectin B1a and Avermectin B1b
Active Ingredient (%): Abamectin (2.0%) EPA Est: 69117-NE-1
Chemical Class: Glycoside Insecticide
CAS Nos.: 65195-56-4 and 65195-55-3 EPA Signal Word: Warning
2. COMPOSITION/INFORMATION ON INGREDIENTS
OSHA ACGIH NTP/IARC/OSHA
Material PEL TLV Other Carcinogen
5 mg/m3 (mist) 5 mg/m3 (mist); 10 mg/m3 5 mg/m3 (mist); 10 mg/m3
Mineral Oil No
(STEL) (STEL) **
2 mg/m3 TWA (inhalable) 10 mg/m3 TWA **
Butylated Hydroxytoluene (BHT) Not established IARC Group 3
n-Methylpyrrolidone (<=30%) Not established Not established 10 ppm TWA **** No
3
Abamectin (2.0%) Not established Not established 0.02 mg/m TWA *** No
** Recommended by NIOSH
*** Occupational Exposure Limit (OEL)
**** Recommended by AIHA (American Industrial Hygiene Association)
Ingredients not precisely identified are proprietary or non-hazardous. Values are not product specifications.
Hazard Categroy: C, S
3. HAZARDS IDENTIFICATION Inhalation: If inhaled: Move person to fresh air. If person is not
breathing, call 911 or an ambulance, then give artificial respiration,
Health and Environmental: May be fatal if swallowed. Causes substan-
preferably by mouth-to-mouth if possible. Call a poison control center
tial but temporary eye injury. Harmful if inhaled or absorbed through the
or doctor for further treatment advice.
skin. May cause respiratory tract irritation. May cause sensitization by
skin contact. Vapors may cause drowsiness and dizziness. Notes to Physician: Persons suffering a temporary allergic reaction
may respond to treatment with antihistamines or steroid creams and/or
Hazardous Decomposition Products: May decompose at high
systemic steroids.
temperatures forming toxic gases.
Early signs of intoxication include dilation of pupils, muscular incoordination
Physical Properties:
and muscular tremors. Toxicity following accidental ingestion of
Appearance: Yellow to red brown liquid
abamectin can be minimized by early administration of chemical
Odor: Not determined
adsorbents (e.g. activated charcoal). If toxicity from exposure has
Unusual Fire, Explosion and Reactivity Hazards: Combustible liquid.
progressed to cause severe vomiting, the extent of resultant fluid and
Can release vapors that form explosive mixtures at temperatures at or
electrolyte imbalance should be gauged. Appropriate supportive parenteral
above the flash point. Heavy vapors can flow along surfaces to distant
fluid replacement therapy should be given along with other required
ignition sources and flash back.
supportive measures (such as maintenance of blood pressure levels and
During a fire, irritating and possibly toxic gases may be generated by proper respiratory functionality) as indicated by clinical signs, symptoms
thermal decomposition or combustion. and measurements. In severe cases, observations should continue for
at least several days until clinical condition is stable and normal.
4. FIRST AID MEASURES
Since abamectin is believed to enhance GABA activity in animals, it is
Have the product container, label or Material Safety Data Sheet
probably wise to avoid drugs that enhance GABA activity (barbiturates,
with you when calling a poison contol center or doctor, or going
benzodiazepines, valproic acid) in patients with potentially toxic
for treatment.
abamectin exposure.
Ingestion: If swallowed: Immediately call a poison control center or
Medical Condition Likely to be Aggravated by Exposure: None known.
doctor for treatment advice. Do not give any liquid to the person.
Do not induce vomiting unless told to do so by a poison control center 5. FIRE FIGHTING MEASURES
or doctor. Do not give anything by mouth to an unconscious person. Fire and Explosion:
Eye Contact: If in eyes: Hold eye open and rinse slowly and gently with Flash Point (Test Method): 161癋
water for 15-20 minutes. Remove contact lenses, if present, after 5 min- Flammable Limits (% in Air):
utes, then continue rinsing eye. Call a poison control center or doctor for Lower: Not applicable
treatment advice.
Upper: Not applicable
Skin Contact: If on skin or clothing: Take off contaminated clothing. Autoignition Temperature: Not available
Immediately rinse skin with plenty of water for 15-20 minutes. Call a
Flammability: Combustible liquid
poison control center or doctor for treatment advice.
GH_MSDS_09-01
MSDS (Material Safety Data Sheet)
GreyhoundTM Insecticide Page 2 of 3
P.O. Box 34645 Omaha, NE 68134 Toll-Free: 800-698-4641 Phone: 402-339-4459 Fax: 402-339-5011 www.ArborSystems.com
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Unusual Fire, Explosion and Reactivity Hazards: Combustible liquid. when exposure levels are unknown, or under any circumstances where
Can release vapors that form explosive mixtures at temperatures at or air-purifying respirators may not provide adequate protection.
above the flash point. Heavy vapors can flow along surfaces to distant
9. PHYSICAL AND CHEMICAL PROPERTIES
ignition sources and flash back.
Appearance: Yellow or red brown liquid
During a fire, irritating and possibly toxic gases may be generated by
Odor: Not determined
thermal decomposition or combustion.
Melting Point: Not applicable
In Case of Fire: Use appropriate extinguishing media for combustibles
Boiling Point: Not available
in the area. Wear full protective clothing and self-contained breathing
Specific Gravity/Density: 0.96 g/cm3 (68?7癋 [20?5癈])
apparatus. Evacuate nonessential personnel from the area to prevent
pH: 2.6?.6 (1% in deionized H2O)
human exposure to fire, smoke, fumes or products of combustion.
Prevent use of contaminated buildings, area, and equipment until Solubility in H2O: Abamectin: 0.007?.01 mg/l @ 68癋 (20癈)
decontaminated. Water runoff can cause environmental damage. Vapor Pressure: Abamectin: 7.5 x 10(-8) mmHg @ 77癋 (25癈)
If water is used to fight fire, dike and collect runoff.
10. STABILITY AND REACTIVITY
6. ACCIDENTAL RELEASE MEASURES Stability: Stable under normal use and storage conditions
In Case of Spill or Leak: Control the spill at its source. Contain the spill Hazardous Polymerization: Will not occur
to prevent from spreading or contaminating soil or from entering sewage
Conditions to Avoid: None known
and drainage systems or any body of water. Clean up spills immediately,
Materials to Avoid: None known
observing precautions outlined in Section 8. Cover entire spill with
Hazardous Decomposition Products: May decompose at high
absorbing material and place into compatible disposal container.
temperatures forming toxic gases
Scrub area with hard water detergent (e.g. commercial products
such as Tide, Joy, Spic and Span). Pick up wash liquid with additional 11. TOXICOLOGICAL INFORMATION
absorbent and place into compatible disposal container. Once all
Acute Toxicity/Irritation Studies (Finished Product)
material is cleaned up and placed in a disposal container, seal container
Ingestion: Oral (LD50 Rat): ~ 300 mg/kg body weight
and arrange for disposition.
Dermal: Dermal (LD50 Rabbit): > 1800 mg/kg body weight
Inhalation: Inhalation (LC50 Rat): 3.5 mg/1 air ?4 hours
7. HANDLING AND STORAGE
Eye Contact: Substantial but temporary eye injury (Rabbit)
Store the material in a well-ventilated, secure area out of reach of
Skin Contact: Moderately irritating (Rabbit)
children and domestic animals. Do not store food, beverages, or tobacco
Skin Sensitization: Sensitizing (Guinea Pig)
products in the storage area. Prevent eating, drinking, tobacco use, and
cosmetic application in areas where there is a potential for exposure to Reproductive/Developmental Effects
the material. Wash thoroughly with soap and water after handling. Abamectin: Reproductive toxin in animal studies only at doses
acutely toxic to the maternal animal
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Chronic/Subchronic Toxicity Studies
THE FOLLOWING RECOMMENDATIONS FOR EXPOSURE CONTROLS/
Abamectin: Central nervous system effects in animals
PERSONAL PROTECTION ARE INTENDED FOR THE MANUFACTURE,
FORMULATION, PACKAGING, AND USE OF THIS PRODUCT. Carcinogenicity
FOR COMMERCIAL APPLICATIONS AND/OR ON-FARM APPLICATIONS, Abamectin: None observed
CONSULT THE PRODUCT LABEL. Other Toxicity Information: None
Ingestion: Prevent eating, drinking, tobacco usage and cosmetic Toxicity of Other Components:
application in areas where there is a potential for exposure to the
Butylated Hydroxytoluene (BHT): Listed as an IARC (Group 3)
material. Wash thoroughly with soap and water after handling.
carcinogen not classifiable as human (no data available) with limited
Eye Contact: Where eye contact is likely, use chemical splash goggles.
animal evidence. Exposure may result in irritation to eyes, skin
Facilities storing or utilizing this material should be equipped with an
and respiratory tract. Ingestion may cause diarrhea, respiratory
eyewash facility and a safety shower.
depression, tremors, and chronic pulmonary edema or congestion
Skin Contact: Where contact is likely, wear chemical-resistant gloves and hemorrhage.
(such as barrier laminate, butyl rubber, nitrile rubber or Viton), coveralls,
Mineral Oil: May cause respiratory irritation when inhaled as a mist.
socks, and chemical-resistant footwear. For overhead exposure, wear
n-Methylpyrrolidone ( < 30%): May cause respiratory tract
=
chemical-resistant headgear.
irritation. Repeated or prolonged exposure may cause drying and
Inhalation: A combination particulate/ organic vapor respirator may be cracking of the skin.
necessary until effective engineering controls are installed to comply with
occupational exposure limits. Use a NIOSH approved respirator with an
organic vapor (OV) cartridge or canister with an HE prefilter.
Use a self-contained breathing apparatus in cases of emergency spills,
GH_MSDS_09-01
MSDS (Material Safety Data Sheet)
GreyhoundTM Insecticide Page 3 of 3
P.O. Box 34645 Omaha, NE 68134 Toll-Free: 800-698-4641 Phone: 402-339-4459 Fax: 402-339-5011 www.ArborSystems.com
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Target Organs: 15. REGULATORY INFORMATION
Active Ingredients: Abamectin: Skin, eye, CNS EPCRA SARA Title III Classification:
Inert Ingredients: Section 311/312 Hazard Classes:
Acute Health Hazard
Butylated Hydroxytoluene (BHT): Eye, skin, respiratory tract
Chronic Health Hazard
Mineral Oil: Respiratory tract
Fire Hazard
n-Methylpyrrolidone: Eye, skin
Section 313 Toxic Chemicals: n-Methylpyrrolidone (<=30%)
12. ECOLOGICAL INFORMATION (CAS No. 872-50-4)
Summary of Effects:
California Proposition 65: Not applicable
Abamectin: Toxic to fish and wildlife with long-lasting effects
CERCLA/SARA 302 Reportable Quantity (RQ): None
Eco-Acute Toxicity:
RCRA Hazardous Waste Classification (40 CFR 261): Not applicable
Abamectin:
TSCA Status: Exempt from TSCA, subject to FIFRA
Fish (Rainbow Trout) 96-hour LC50 3.6 ppb
Fish (Bluegill Sunfish) 96-hour LC50 9.6 ppb 16. OTHER INFORMATION
Bird (Bobwhite Quail) LD50 Oral > 2000 mg/kg Rating Key
NFPA Hazard Ratings HMIS Hazard Ratings
0 = Minimal
Bird (Bobwhite Quail) 8-day dietary LC50 3102 ppm Health: 2 Health: 2
1 = Slight
Bird (Mallard Duck) 8-day dietary LC50 383 ppm Flammability: 2 Flammability: 2 2 = Moderate
Bee (Contact) LD50 0.41 ug/bee 3 = Serious
Instability: 0 Reactivity: 0
4 = Extreme
Invertebrate (Water Flea) 48-hour EC50 0.34 ppb
Green Algae 9-day EC50 > 100 ppm
Revision: 12/09
Eco-Chronic Toxicity:
Supersedes: 12/97, 04/04, 05/06, 03/08, 05/08, 11/08
Abamectin:
and 08/09 versions
Invertebrate (Water Flea) 21-day LOEC 0.09 ppb
The information and recommendations contained herein are based upon data believed
Bird (Mallard Duck) Reproduction LOEL 64 ppm
to be correct. However, no guarantee or warranty of any kind, expressed or implied, is
Environmental Fate: made with respect to the information contained herein. It is the responsibility of the
Abamectin: user to comply with all laws and procedures applicable to the safe handling, storage,
and use of this product and to determine the suitability of the product for its intended
The information presented here is for the active ingredient,
use. IT IS A VIOLATION OF FEDERAL LAW TO USE THIS PRODUCT IN A MANNER
abamectin. INCONSISTENT WITH ITS LABELING.
Low bioaccumulation potential. Not persistent in soil. Stable in
water. Low mobility in soil. Mixes in water (after 24 h). GreyhoundTM is a trademark of ArborSystems.
13. DISPOSAL CONSIDERATIONS
Do not contaminate water, food or feed by storage or disposal.
Pesticide Storage: Store in original container in a cool, dry place.
Pesticide Disposal: Wastes resulting from the use of this product may
be disposed of on site or at an approved waste disposal facility.
Container Disposal: Non-refillable container; do not refill or reuse this
container. Completely empty pack into application equipment, then offer
for recycling, if available; or dispose of empty pack in a sanitary landfill;
or by incineration if allowed by State and local authorities.
14. TRANSPORT INFORMATION
This product is shipped in inner packaging not over 4 L (1.0 Gallon) each
and is therefore shipped under the "Limited quantities of Division 6.1
materials" exception, 49 CFR 173.153(b).
GH_MSDS_09-02
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