M878-1527 MARINER L/V COLOR COAT
MATERIAL SAFETY DATA SHEET
RPM Wood Finishes Group
3194 Hickory Boulevard
Hudson, North Carolina 28638
828-728-8266
EMERGENCY PHONE (CHEM TREC): . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1-800-424-9300
FOR ALL INTERNATIONAL TRANSPORTATION ACCIDENTS. . . . . . . . . . . . . . . . .1-703-527-3887 (collect)
Health: 2 Flammability: 1 Reactivity 0
PRODUCT NAME: M878-1527 MARINER L/V COLOR COAT
I. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
REVISION DATE: 28/05/03
SUPERCEDES: 16/04/03
MSDS NO. M878-1527
OSHA HAZ. CLASS: Mucous membrane (respiratory tract) irritant. Lung toxin - may
cause lung damage.
II. COMPOSITION/INFORMATION ON INGREDIENTS
CHEMICAL NAME % CAS # PEL
PUD nonvolatiles 21-30 proprietary No PEL established
1-methyl-2-pyrollidone 1-10 872-50-4 No PEL established
propylene glycol monomethyl ether 1-10 107-98-2 No PEL established
acrylic non volatiles 1-10 proprietary No PEL established
fumed silica 1-10 112945-52-5 No PEL established
titanium dioxide 1-10 13463-67-7 total dust: 15 mg/m3 TWA
Pigment blue 15 1-10 147-14-8 No PEL established
Triethylamine <1 121-44-8 25 ppm TWA; 100 mg/m3 TWA
carbon black <1 1333-86-4 3.5 mg/m3 TWA
formaldehyde <1 50-00-0 0.75 ppm TWA
III. HAZARDS IDENTIFICATION
Inhalation., Ingestion., Eye contact., Skin contact., Absorption.
Routes of Entry:
Respiratory disease including asthma and bronchitis. Eye disease. Kidney disease.
Medical Conditions Aggravated:
Liver disease. Skin disease including eczema and sensitization.
Immediate (Acute) Health Effects
Can cause severe respiratory irritation, dizziness, weakness, fatigue, nausea,
Inhalation:
headache and possible unconsciousness.
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Substance is corrosive. Causes severe skin burns. No hazard in normal industrial use.
Skin Contact:
Can cause moderate skin irritation, defatting, and dermatitis. Not likely to cause
permanent damage.
Can cause mechanical irritation if dusts are generated. Can cause moderate irritation,
Eye Contact:
tearing and reddening, but not likely to permanently injure eye tissue. Contact with
the eyes may cause moderate to severe eye injury. Eye contact may result in tearing
and reddening, but not likely to permanently injure eye tissue. Temporary vision
impairment (cloudy or blurred vision) is possible.
Substance is harmful if absorbed through the skin. Large exposures may be fatal.
Skin Absorption:
Harmful if absorbed through the skin. May cause severe irritation and systemic
damage.
Harmful if swallowed. Irritating to mouth, throat, and stomach. Can cause abdominal
Ingestion:
discomfort, nausea, vomiting and diarrhea.
Target Organ Acute Toxicity:
Propylene glycol monomethyl ether eyes, skin, respiratory system, CNS
Titanium dioxide respiratory system (in animals: lung tumors)
Triethylamine skin, eyes, respiratory system, CVS, liver, kidney
Carbon black respiratory system, eyes, lymphatic cancer
Formaldehyde (and formalin) eyes, skin, respiratory system, nasal cancer
Long-Term (Chronic) Health Effects:
No data available. Contains a substance that is a probable cancer hazard based on
Carcinogenicity:
animal studies using doses likely to be encountered in the workplace.
No data. No data available to indicate product or any components present at greater
Reproductive and Developmental
Toxicity: than 0.1% may cause birth defects.
No data available to indicate product or any components present at greater than 0.1%
Mutagenicity:
is mutagenic or genotoxic.
Upon prolonged and/or repeated exposure, can cause severe respiratory irritation,
Inhalation:
dizziness, weakness, fatigue, nausea, headache and possible unconsciousness.
Prolonged or repeated contact may cause irritation. Upon prolonged or repeated
Skin Contact:
contact, can cause moderate skin irritation, defatting, and dermatitis. Not likely to
cause permanent damage.
Upon prolonged or repeated contact, dust contact can cause mechanical irritation.
Eye Contact:
Upon prolonged or repeated contact, can cause severe irritation. Eye contact may
result in corneal injury. Symptoms may include discomfort or pain, excess blinking
and tear production, with marked redness and swelling of the conjunctiva. Temporary
vision impairment (cloudy or blurred vision) is possible.
Upon prolonged or repeated exposure, toxic if absorbed through the skin. Likely to
Skin Absorption:
cause systemic damage.
Lungs. Respiratory Tract. Eyes. Kidneys. Liver. Nervous System. Respiratory
Target Organ Chronic Toxicity:
Tract. Skin.
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No additional health information available.
Supplemental Health Hazard
Information:
IV. FIRST AID
Remove to fresh air. If breathing is difficult, have a trained individual administer
Inhalation:
oxygen. If not breathing, give artificial respiration and have a trained individual
administer oxygen. Get medical attention immediately.
Immediately flush eyes with plenty of water for at least 20 minutes retracting eyelids
Eyes:
often. Tilt the head to prevent chemical from transferring to the uncontaminated eye.
Get immediate medical attention and monitor the eye daily as advised by your
physician.
Immediately flush skin with plenty of water. Remove clothing. Get medical attention
Skin Contact:
immediately. Wash clothing separately from other articles before reuse. Wash with
soap and water. Wash with soap and water. Get medical attention if irritation
develops or persists. Wash with soap and water. Remove contaminated clothing and
launder. Get medical attention if irritation develops or persists.
Do not induce vomiting and seek medical attention immediately. Drink two glasses
Ingestion:
of water or milk to dilute. Provide medical care provider with this MSDS.
No additional first aid information available.
Notes to MD:
V. FIRE FIGHTING MEASURES
Flammability Summary:
o
>200 (CALC.) F
Flash Point:
Vapors may be ignited by heat, sparks, flames or other sources of ignition at or above
Fire Hazards:
the low flash point giving rise to a Class B fire. Vapors are heavier than air and may
travel to a source of ignition and flash back.
Use methods suitable to fight surrounding fire. Use alcohol resistant foam, carbon
Extinguishing Media:
dioxide, or dry chemical extinguishing agents. Water spray or fog may also be
effective for extinguishing if swept across the base of the fire. Water can also be used
to absorb heat and keep exposed material from being damaged by fire.
Do not enter fire area without proper protection including self-contained toxic
Fire Fighting Instructions:
breathing apparatus and full protective equipment. Fight fire from a safe distance and
a protected location due to the potential of hazardous vapors and decomposition
products. Flammable component(s) of this material may be lighter than water and
burn while floating on the surface. Use water spray/fog for cooling.
Hazardous Combustion Products: Carbon monoxide Nitrogen containing gases Toxic fumes. Toxic gases
VI. ACCIDENTAL RELEASE MEASURES
Exposure to the spilled material may be irritating or harmful. Follow personal
Health Consideration for Spill
Response: protective equipment recommendations found in Section VIII of this MSDS.
Additional precautions may be necessary based on special circumstances created by
the spill including; the material spilled, the quantity of the spill, the area in which the
spill occurred. Also consider the expertise of employees in the area responding to the
spill.
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Prevent the spread of any spill to minimize harm to human health and the
Spill Mitigation Procedures
General Methods: environment if safe to do so. Wear complete and proper personal protective
equipment following the recommendation of Section VIII at a minimum. Dike with
suitable absorbent material like granulated clay. Gather and store in a sealed container
pending a waste disposal evaluation.
VII. HANDLING AND STORAGE
Avoid contact with material. Minimize dust generation and accumulation. Wash
Handling:
thoroughly after handling. Remove contaminated clothing and wash before reuse. Use
spark-proof tools and explosion-proof equipment. Harmful or irritating material.
Avoid contact and avoid breathing the material. Use only in a well ventilated area.
Store in a cool dry place away from ignition sources. Keep container closed when not
Storage:
in use. Keep away from sources of ignition. Store in a cool dry place. Isolate from
incompatible materials.
VIII. ENGINEERING CONTROLS AND PERSONAL PROTECTIVE EQUIPMENT
Check ventilation codes. Local exhaust ventilation or other engineering controls are
Engineering Controls:
normally required when handling or using this product to avoid overexposure.
Protective Equipment
Respirators should be selected by and used under the direction of a trained health and
Respiratory Tract:
safety professional following requirements found in OSHA's respirator standard (29
CFR 1910.134) and ANSI's standard for respiratory protection (Z88.2-1992). A
written respiratory protection program, including provisions for medical certification,
training, fit testing, exposure assessments, maintenance, inspection, cleaning, and
convenient, sanitary storage should be implemented.
Wear chemically resistant safety glasses with side shields when handling this product.
Eyes:
Wear additional eye protection such as chemical splash goggles and/or face shield
when the possibility exists for eye contact with splashing or spraying liquid, or
airborne material. Do not wear contact lenses. Have an eye wash station available.
Avoid skin contact by wearing chemically resistant gloves, an apron and other
Skin:
protective equipment depending upon conditions of use. Inspect gloves for chemical
break-through and replace at regular intervals. Clean protective equipment regularly.
Wash hands and other exposed areas with mild soap and water before eating,
drinking, and when leaving work.
IX. PHYSICAL DATA
COLORED LIQUID
Physical State:
MILD AMINE
Odor:
28.9311
Solids Vol %:
34.1555
Solids Wt %:
1.3842
Material VOC lbs/gal:
166.2286
Material VOC gms/l:
3.0091
Coatings VOC lbs/gal:
361.3624
Coatings VOC gms/l:
8.9433
Weight per gallon:
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X. STABILITY AND REACTIVITY
Stable. Stable under normal conditions.
Stability Information:
Avoid: heat, sparks, flame and oxidizing agents. High temperatures. None known.
Conditions to Avoid:
Metals. Strong oxidizing agents. Acids. Strong acids. Strong alkalies.
Chemical Incompatibility:
Hazardous Polymerization will not occur.
Hazardous Polymerization:
XI. TOXICOLOGICAL INFORMATION
Chemical Name CAS Number LD50/LC50
2-Pyrrolidinone, 1-methyl- 872-50-4 Oral LD50 Rat : 3914 mg/kg; Oral LD50 Mouse : 5130 mg/kg; Dermal LD50
Rabbit : 8 gm/kg
2-Propanol, 1-methoxy- 107-98-2 Inhalation LC50 Rat : 10000 ppm/5H; Oral LD50 Mouse : 11700 mg/kg;
Dermal LD50 Rabbit : 13 gm/kg
Silica, amorphous fumed 112945-52-5 Oral LD50 Rat : 3160 mg/kg
Triethylamine 121-44-8 Inhalation LC50 Mouse : 6 gm/m3; Oral LD50 Rat : 460 mg/kg; Oral LD50
Mouse : 546 mg/kg; Dermal LD50 Rabbit : 570 uL/kg
Carbon black 1333-86-4 Oral LD50 Rat : >15400 mg/kg; Dermal LD50 Rabbit : >3 gm/kg
Formaldehyde 50-00-0 Inhalation LC50 Rat : 203 mg/m3; Inhalation LC50 Mouse : 454 gm/m3/4H;
Oral LD50 Rat : 100 mg/kg; Oral LD50 Mouse : 42 mg/kg; Dermal LD50
Rabbit : 270 uL/kg
XII. ECOLOGICAL INFORMATION
No data available. This material is not expected to be harmful to the ecology.
Overview (for ingredients):
XIII. DISPOSAL CONSIDERATIONS
Spent or discarded material is a hazardous waste.
Waste Description for Spent
Product:
Perform waste water treatment. Dispose of in a landfill. Disposal is not likely to be
Disposal Methods:
regulated.
D001
Potential EPA Waste Codes:
Components Subject to USEPA Land Disposal Restrictions:
Triethylamine 121-44-8 0.97 %
XIV. TRANSPORTATION INFORMATION
NON REGULATED
DOT
XV. REGULATORY INFORMATION
Chemical Name Regulation CASRN %
N-Methyl-2-pyrrolidinone SARA 313 Reportable: 872-50-4 9.16
Triethylamine SARA 313 Reportable: 121-44-8 0.97
Formaldehyde SARA 313 Reportable: 50-00-0 0.00
Formaldehyde SARA 313 Reportable: 50-00-0 0.00
Formaldehyde Extremely Haz. Substances: 50-00-0 0.00
TPQ = 500 pounds; RQ = 100 pounds SARA Threshold Planning Quantity: 50-00-0 0.00
(does not meet toxicity criteria but
because of high production volume and
recognized toxicity is considered a
chemical of concern)
1333-86-4 0.21
Carbon Black California Proposition 65 Cancer List:
50-00-0 0.00
Formaldehyde (gas) California Proposition 65 Cancer List:
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50-00-0 0.00
Formaldehyde (gas) California Proposition 65 Cancer List:
872-50-4 9.16
1-Methyl-2-pyrrolidone California Proposition 65
Developmental Toxicity:
proprietary 22.34
PUD nonvolatiles New Jersey Right To Know:
872-50-4 9.16
1-methyl-2-pyrollidone New Jersey Right To Know:
107-98-2 3.96
propylene glycol monomethyl ether New Jersey Right To Know:
proprietary 2.51
acrylic non volatiles New Jersey Right To Know:
112945-52-5 2.28
fumed silica New Jersey Right To Know:
XVI. ADDITIONAL INFORMATION
IMPORTANT: WHILE THE DESCRIPTIONS, DATA AND INFORMATION
Other Information:
CONTAINED HEREIN ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE
ACCURATE, IT IS PROVIDED FOR YOUR GUIDANCE ONLY. BECAUSE MANY
FACTORS MAY AFFECT PROCESSING OR APPLICATION/USE, WE RECOMMEND
THAT YOU PERFORM AN ASSESSMENT TO DETERMINE THE SUITABILITY OF A
PRODUCT FOR YOUR PARTICULAR PURPOSE PRIOR TO USE. NO WARRANTIES
OF ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDING FITNESS FOR A
PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED, DATA
OR INFORMATION SET FORTH. IN NO CASE SHALL THE DESCRIPTIONS,
INFORMATION,OR DATA PROVIDED BE CONSIDERED A PART OF OUR TERMS
AND CONDITIONS OF SALE. FURTHER, THE DESCRIPTIONS, DATA AND
INFORMATION FURNISHED HEREUNDER ARE GIVEN GRATIS. NO OBLIGATION
OR LIABILITY FOR THE DESCRIPTION, DATA AND INFORMATION GIVEN ARE
ASSUMED. ALL SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK.
MSDS glossary.
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