Date Prepared: 01/25/10
Supersedes: 05/14/07
ChemMasters
Product Name: Lube Plus 4070
MATERIAL SAFETY DATA SHEET
1. Chemical Product and Company Information
Product Name: Lube Plus 4070
ChemMasters In Case of Emergency Contact:
300 Edwards Street CHEMTREC 800/424-9300
Madison, Ohio 44057
440-428-2105
2. Hazards Identification
Combustible Liquid
May cause skin and respiratory irritation and/or sensitization
Harmful if inhaled or swallowed
Causes eye irritation
WHMIS Classification: Class B, Division 3; Class D, Division 2B (Flammable & Toxic)
Symbol: Flammable & Stylized T
Potential Health Hazards - Acute
Eye: Causes eye irritation. Direct contact with the liquid or exposure to its vapors may cause burning, tearing and
redness. Effects of contact may not show for several hours.
Skin: May cause irritation and/or sensitization. Prolonged or repeated exposure may cause redness and burning, drying
and cracking of the skin and dermatitis. Persons with preexisting skin disorders may be more susceptible to the effects
of this material.
Inhalation: Harmful if inhaled. May effect the brain or nervous system causing dizziness, headache or nausea. Can
irritate the nose and throat. May cause allergic respiratory reaction similar to an asthma attack. Persons with impaired
lung function or respiratory disorders may be more susceptible to vapors.
Ingestion: Harmful if swallowed. Liquid is moderately toxic; may produce CNS depression. May result in vomiting.
Aspiration of vomitus into the lungs must be avoided as even small quantities may result in aspiration pneumonitis.
Potential Health Effects - Chronic
Individuals who have developed skin or respiratory sensitization can develop acute health hazard symptoms with
exposure to minute amounts of TDI. See Section 11 for supplemental information.
Carcinogenicity: NTP IARC Monographs OSHA Regulated
NO NO NO
1
Date Prepared: 01/25/10
Supersedes: 05/14/07
Product Name: Lube Plus 4070
3. Composition / Information on Ingredients
Hazardous Components CAS # Exposure Limits % by Wt
OSHA ACGIH
Toluene Diisocyanate 584-84-9 0.005 ppm (0.040 mg/m3 ) TWA 0.005 ppm (0.36 mg/m) TWA <1%
0.020 ppm (0.150 mg/m3)STEL 0.020 ppm (0.140 mg/m3) STEL
(TDI, all isomers)
Contains less than 1% Free Monomer
Polymeric Isocyanate Mixture 0.02 ppm (0.20 mg/m3) Ceiling 0.005 ppm (0.51 mg/m) TWA 60-70%
Propylene Glycol Methyl Ether Acetate 108-65-6 Not Established 10-15%
N-Methylpyrrolidone 872-50-4 Not Established 10-15%
4. First Aid Measures
Eye: Immediately flush with plenty of clean water for 15 minutes. SEEK MEDICAL ATTENTION IF IRRITAION
PERSISTS.
Skin: Remove contaminated clothing. Clean affected area(s) thoroughly with soap and water. SEEK MEDICAL
ATTENTION IF IRRITAION PERSISTS.
Inhalation: Remove to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration.
Get medical attention.
Ingestion: DO NOT Induce vomiting. Give 1-2 cups of milk or water to drink. Seek medical attention!
5. Fire Fighting Measures
Flash Point (method used): 116oF (PMCC)
Flammable Limits (% volume in air): Lower = No data available Upper = No data available
Auto Ignition Temperature: No data available
Extinguishing Media: Extinguish with water fog, dry chemical, CO2 or foam. Water fog may cause frothing and should
be applied carefully.
Hazard Combustion Products: Carbon monoxide, carbon dioxide, nitrogen oxides, diisocyanates, hydrogen
cyanide.
Fire Fighting Instructions: Closed containers may rupture violently when exposed to heat. Toxic and /or irritating
vapors may be released during a spill. Combustion by products may be hazardous. Product will react with water.
Use water only to cool containers or to disperse vapors. Reaction is not violent. Do not enter confined fire space
without full bunker gear including a positive pressure, NIOSH approved, self-contained breathing apparatus.
6. Accidental Release Measures
Spill: Avoid personal contact. If spill is indoors, ventilate area. Keep out of drains, sewers or waterways. Take up
with absorbent material. Shovel into suitable containers, transport to a well-ventilated area (outside) and treat with
a neutralizing solution (water plus 3-8% ammonium hydroxide or 5-10% sodium carbonate).
7. Handling and Storage
Handling: Do not cut, drill, grind, weld or perform similar operations on or near containers. Do not pressurize
drums to empty them. Avoid inhalation of vapors and personal contact with product. Use only with adequate ventilation.
Storage: Store containers tightly closed with adequate ventilation in a cool, dry area.
8. Exposure Controls / Personal Protection
Exposure Controls: Mechanical and local exhaust should be used for indoor use.
Personal Protection: NIOSH approved organic solvent respirator, impervious gloves, chemical splash goggles, and
protective clothing to minimize skin contact.
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Date Prepared: 01/25/10
Supersedes: 05/14/07
Product Name: Lube Plus 4070
9. Physical and Chemical Properties
Appearance: Gray viscous liquid
Odor: Slightly Musty
Boiling Point: 212oF
Melting Point: Not applicable
Vapor Pressure (mm/Hg): No data available
Vapor Density (Air = 1): No data available
Solubility in Water: Reacts
Specific Gravity (H20 = 1): 1.2
Evaporation Rate (n-Butyl Acetate = 1): Not applicable
10. Stability and Reactivity
Chemical Stability: Stable
Conditions to Avoid: Exposure to water, acid, bases (alkalies, ammonia), alcohols, metal compounds, surface
active materials
Incompatibility (materials to avoid): Water, acid, bases (alkalies, ammonia), alcohols, metal compounds, surface
active materials
Hazardous Decomposition or By-products: Thermal decomposition may yield carbon monoxide, carbon dioxide,
oxides of nitrogen, diisocyanates and hydrogen cyanide.
Hazardous Polymerization: Will not occur
11. Toxicological Information
Toluene diisocyanate (TDI) has been designated a potential carcinogen by the National Toxicology Program and
IARC. This decision is based on NTP study suggesting that TDI given directly through a tube into the stomach (oral
gavage technique) caused an increase in tumors in laboratory animals.
Components Oral LD50 Dermal LD50 Inhalation LC50
(rat) (rabbit) (rat)
Toluene Diisocyanate (TDI) 5800 mg/kg 10 gm/kg --
12. Ecological Information
Possible land, air and water pollutant. No exact data available.
13. Disposal Considerations
Dispose of in accordance with all federal, state, and local regulations. If uncertain of local requirements, contact
the proper environmental authorities for information on waste disposal.
14. Transportation Information
For U S National Shipments in Containers <119 gal: Not Regulated
For U S National Shipments in Containers >119 gal:
Shipping Description: Adhesives, Combustible Liquid, UN1133, III
Hazard Class: Combustible Liquid
For International or Air Shipments: Adhesives, 3, UN1133, III
Hazard Class: Flammable Liquid
Emergency Response Guide Number: 128
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Date Prepared: 01/25/10
Supersedes: 05/14/07
Product Name: Lube Plus 4070
15. Regulatory Information
OSHA: This material is hazardous by definition of Hazardous Communications Standard (29 CFR 1910.1200)
CERCLA Reportable Quantity: 10,000 lbs.
SARA Title III:
Section 311/312 hazard categories: acute health, delayed health, fire
Section 311/312 reportable ingredients:
Components CAS # Maximum %
Methylenebis(phenylisocyanate) (MDI) 101-68-8 20%
N-Methylpyrrolidone 872-50-4 15%
PA Hazardous Substance List: CAS# %
Methylenebis(phenylisocyanate) (MDI) 101-68-8 10-20%
Toluene Diisocyanate 584-84-9 <1%
PA Non-Hazardous Substance List- >3%:
Poly(oxyalkylene)Polyol 25322-69-4 60-70
Diphenylmethane Diisocyanate (2,2;2,4) 26447-40-5 10-20
Propylene Glycol Methyl Ether Acetate 108-65-6 10-15
N-Methylpyrrolidone 872-50-4 10-15
16. Other Information
MSDS Status: Revised 1/25/10, Added WHMIS Classification Information
Industrial Abbreviation Legend below.
Industrial Abbreviation Legend
ACGIH American Conference of Governmental Industrial mg/m3 milligrams per cubic meter
Hygienists NIOSH National Institute for Occupational Safety and Health
CAA Clean Air Act (EPA) NTP National Toxicology Program
CERCLA Comprehensive Environmental Response, OSHA Occupational Safety and Health Administration
Compensation & Liability Act of 1980 (Superfund) (EPA) PEL Permissible Exposure Limit
CNS Central Nervous System ppm parts per million
CWA Clean Water Act (EPA) RCRA Resource Conservation and Recovery Act (EPA)
DOT Department of Transportation SARA EPA's Superfund Amendment and Reauthorization
EPA Environmental Protection Agency Act (EPA)
g/kg grams per kilogram STEL Short-Term Exposure Limit, ACGIH terminology
IARC Internal Agency for Research on Cancer TLV Threshold Limit Value
LC50 Lethal Concentration in which 50% of the test animals are TWA Time-Weighted Average
expected to die
LD50 Lethal Dose in which 50% of the test animals are
expected to die
THIS PRODUCT IS FORMULATED AND LABELED FOR
INDUSTRIAL AND COMMERCIAL APPLICATION ONLY
The information contained herein is given in good faith and based on data considered accurate. However, no warranty is
expressed or implied regarding the accuracy of these data or the results to be obtained from the use thereof. ChemMasters
assumes no responsibility for personal injury or property damage to vendees, users or third parties caused by the material.
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Such vendees or users assume all risks associated with the use of the material.
This is the last page of this MSDS.
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