POTASSIUM BICHROMATE(CRYSTALS) #M1245
Page 1 of 9
MATERIAL SAFETY DATA SHEET
POTASSIUM BICHROMATE(CRYSTALS) #M1245
Section 1 - Product and Company Identification
POTASSIUM BICHROMATE(CRYSTALS) #M1245
Product Identification: POTASSIUM BICHROMATE(CRYSTALS) #M1245
Date of MSDS: 06/20/1983 Technical Review Date: 12/06/1999
FSC: 6810 NIIN: 00-264-6525
Submitter: D DG
Status Code: C
MFN: 01
Article: N
Kit Part: N
Manufacturer's Information
Manufacturer's Name: OCCIDENTAL CHEMICAL CORPORATION
Post Office Box: 809050
Manufacturer's Address1: CUSTOMER SERVICE, OCCIDENTAL TOWER
Manufacturer's Address2: DALLAS, TX 75380
Manufacturer's Country: US
General Information Telephone: 800-752-5151, 716-286-3400
Emergency Telephone: 800-733-3665/716-278-7021
Emergency Telephone: 800-733-3665/716-278-7021
MSDS Preparer's Name: N/K
Proprietary: N
Reviewed: Y
Published: Y
CAGE: 0AH54
Special Project Code: N
Item Description
Item Name: POTASSIUM DICHROMATE,TECHNICAL
Item Manager: S9G
Specification Number: NK
POTASSIUM BICHROMATE(CRYSTALS) #M1245
Type/Grade/Class: NK Page 2 of 9
Unit of Issue: BT Quantitative Expression: 00000000005LB
Unit of Issue Quantity: 4
Type of Container:
Contractor Information
Contractor's Name: CHEMICAL COMMODITIES AGENCY, INC.
Contractor's Address1: 27447 PACIFIC STREET
Contractor's Address2: HIGHLAND, CA 92346-2640
Contractor's Telephone: 909-864-2310
Contractor's CAGE: 60777
Contractor Information
Contractor's Name: OCCIDENTAL CHEMICAL CORPORATION
Contractor's Address1: 5005 LYNDON B JOHNSON FWY
Contractor's Address2: DALLAS, TX 75244-6198
Contractor's Telephone: 800-752-5151/972-404-3800
Contractor's CAGE: 0AH54
Section 2 - Compositon/Information on Ingredients
POTASSIUM BICHROMATE(CRYSTALS) #M1245
Ingredient Name: POTASSIUM BICHROMATE (SARA III)
Ingredient CAS Number: 7778-50-9 Ingredient CAS Code: M
RTECS Number: HX7680000 RTECS Code: M
=WT: =WT Code:
=Volume: =Volume Code:
>WT: >WT Code:
>Volume: >Volume Code:
% Low WT: % Low WT Code:
% High WT: % High WT Code:
% Low Volume: % Low Volume Code:
% High Volume: % High Volume Code:
% Text: 100.0
% Enviromental Weight:
Other REC Limits: N/P
OSHA PEL: C,0.1 MG/M3 CRO3 OSHA PEL Code: M
OSHA STEL: OSHA STEL Code:
ACGIH TLV: 0.5 MG CR/M3; 9293 ACGIH TLV Code: M
POTASSIUM BICHROMATE(CRYSTALS) #M1245
ACGIH STEL: N/P ACGIH STEL Code: Page 3 of 9
EPA Reporting Quantity: 10 LBS
DOT Reporting Quantity: 10 LBS
Ozone Depleting Chemical: N
Section 3 - Hazards Identification, Including Emergency Overview
POTASSIUM BICHROMATE(CRYSTALS) #M1245
Health Hazards Acute & Chronic: ACUTE:INHALATION MAY CAUSE IRRITATION OF THE
NASAL SEPTUM & RESPIRATORY TRACT. SKIN:MAY FORM CHROME SORES,MAY
DAMAGE TO KIDNEY. EYES:SEVERE IRRITATION,DAMAGE OF EYES. CHRONIC:
CONJUNCTIVITIS,CHROME SOR ES,NASAL SEPTUM.
Signs & Symptoms of Overexposure:
SKIN:MAY CAUSE IRRITATION;EYES:CAUSES IRRITATION TO CONJUNCTIVITIES;INH:
IRRITATES RESPRTRY SYSTEM.
Medical Conditions Aggravated by Exposure:
NO DATA AVAILABLE.
LD50 LC50 Mixture: ORAL LD50 (RAT) IS 57 MG/KG
Route of Entry Indicators:
Inhalation: YES
Skin: YES
Ingestion: YES
Carcenogenicity Indicators
NTP: YES
IARC: YES
OSHA: YES
Carcinogenicity Explanation: CHROMIMIUM IS SUSPECTED CARCINOGEN,CAUSES NASAL
CANCER.
Section 4 - First Aid Measures
POTASSIUM BICHROMATE(CRYSTALS) #M1245
First Aid:
INHALE:REMOVE TO FRESH AIR, GIVE CPR/O*2 IF NEED;EYES:FLUSH W LG AMTS H*2O
FOR 15 MIN;SKIN:FLUSH W LG AMTS H*2O;INGEST:RINSE MOUTH;CLOTHG PENETRTD W/
SOLNS/DUST SHOULD BE REMOVE PROMPTLY & WASHD BEFORE RE-USE;GET MED
ATTN FOR ANY PROBLEM.
POTASSIUM BICHROMATE(CRYSTALS) #M1245
Page 4 of 9
Section 5 - Fire Fighting Measures
POTASSIUM BICHROMATE(CRYSTALS) #M1245
Fire Fighting Procedures:
USE NIOSH/MSHA APPROVED SCBA IN AN ENCLOSED AREA.
Unusual Fire or Explosion Hazard:
IN PRESENCE OF STRONG ACIDS IT MAY IGNITE OXDIZABLE SUBSTANCES
Extinguishing Media:
CO*2, FOAM, DRY CHEM.
Flash Point: Flash Point Text: N/A
Autoignition Temperature:
Autoignition Temperature Text: N/K
Lower Limit(s): N/A
Upper Limit(s): N/A
Section 6 - Accidental Release Measures
POTASSIUM BICHROMATE(CRYSTALS) #M1245
Spill Release Procedures:
SOLIDS MAY BE SHOVELED UP.AREA SHOULD BE FLUSHED W/H*2O.REMAINING
TRACES SHOULD BE NEUTRALIZED W/SODA ASH.DISSOLVED SOLIDS MAY THEN BE
TREATED BY APPROPRIATE WASTE DISPOSAL METHOD.
Section 7 - Handling and Storage
POTASSIUM BICHROMATE(CRYSTALS) #M1245
Handling and Storage Precautions:
Other Precautions:
Section 8 - Exposure Controls & Personal Protection
POTASSIUM BICHROMATE(CRYSTALS) #M1245
Repiratory Protection:
USE NIOSH/MSHA APPROVED RESPIRATOR FOR DUST/MIST,IF ABOVE PEL/TLV.
Ventilation:
LOCAL EXHAUST PREFERRED,MECHANICAL EXHAUST ACEPTABLE.
Protective Gloves:
RUBBER/PLASTIC
POTASSIUM BICHROMATE(CRYSTALS) #M1245
Eye Protection: FACE SHIELD AND GOGGLES/CHEMICAL GOGGLES Page 5 of 9
Other Protective Equipment: SKIN AND EYES PROTECTION IS REQUIRED;EYE-WASH,
SAFETY SHOWER,BOOTS,RUBBER SUITS.
Work Hygenic Practices: AVOID CONTACT WITH SKIN AND EYES.DO NOT BREATHE
VAPORS/MIST.WASH THOROUGHLY AFTER EACH USE.
Supplemental Health & Safety Information: MSDS RECEIVED ON MAY 19,1988;DIAMOND
SHAMROCK HAS BEEN BOUGHT BY OCCIDONTAL CHEMICAL.
Section 9 - Physical & Chemical Properties
POTASSIUM BICHROMATE(CRYSTALS) #M1245
HCC: D2
NRC/State License Number: N/R
Net Property Weight for Ammo: N/R
Boiling Point: Boiling Point Text: N/R
Melting/Freezing Point: Melting/Freezing Text: 748F/398C
Decomposition Point: Decomposition Text: N/K
Vapor Pressure: N/R Vapor Density: N/R
Percent Volatile Organic Content:
Specific Gravity: 2.68
Volatile Organic Content Pounds per Gallon:
pH: 3.6-4
Volatile Organic Content Grams per Liter:
Viscosity: N/P
Evaporation Weight and Reference: N/R
Solubility in Water: MODERATE
Appearance and Odor: PH IS OF SOLUTION.
Percent Volatiles by Volume: N/R
Corrosion Rate: N/K
Section 10 - Stability & Reactivity Data
POTASSIUM BICHROMATE(CRYSTALS) #M1245
Stability Indicator: YES
Materials to Avoid:
STRONG ACIDS/OXIDIZBLE MATL IF IN PRESENCE OF STRONG ACIDS.
Stability Condition to Avoid:
MILDLY OXIDZG IN SOLN BUT STRNGLY OXDZBLE IN STRNG ACID SOLN
Hazardous Decomposition Products:
NONE
Hazardous Polymerization Indicator: NO
Conditions to Avoid Polymerization:
N/A
POTASSIUM BICHROMATE(CRYSTALS) #M1245
Section 11 - Toxicological Information Page 6 of 9
POTASSIUM BICHROMATE(CRYSTALS) #M1245
Toxicological Information:
N/P
Section 12 - Ecological Information
POTASSIUM BICHROMATE(CRYSTALS) #M1245
Ecological Information:
N/P
Section 13 - Disposal Considerations
POTASSIUM BICHROMATE(CRYSTALS) #M1245
Waste Disposal Methods:
REDUCE HEXAVALENT CHROMIUM TO TRIVALENT BY TREATING WITH SOD BISULFITE,
SOD SULFITE,SO*2 OR FESO*4 OR CHLORIDE PRECIPITATE REDUCE CHROMIUM AS
HYDROUS CHROMIC OXIDE BY NEUTRLZNG TO PH 7.5 WITH SODA ASH, NAOH OR LIME.
DISPOSE IAW FED,STATE/LOCALLAWS.
Section 14 - MSDS Transport Information
POTASSIUM BICHROMATE(CRYSTALS) #M1245
Transport Information:
N/P
Section 15 - Regulatory Information
POTASSIUM BICHROMATE(CRYSTALS) #M1245
SARA Title III Information:
N/P
Federal Regulatory Information:
N/P
State Regulatory Information:
N/P
Section 16 - Other Information
POTASSIUM BICHROMATE(CRYSTALS) #M1245
Other Information:
N/P
HMIS Transportation Information
POTASSIUM BICHROMATE(CRYSTALS) #M1245
Product Identification: POTASSIUM BICHROMATE(CRYSTALS) #M1245 Page 7 of 9
Transporation ID Number: 63266
Responsible Party CAGE: 0AH54
Date MSDS Prepared: 06/20/1983
Date MSDS Reviewed: 12/06/1999
MFN: 12/06/1999
Submitter: D DG
Status Code: C
Container Information
Unit of Issue: BT
Container Quantity: 4
Type of Container:
Net Unit Weight: 5.0 LBS
Article without MSDS: N
Technical Entry NOS Shipping Number: POTASSIUM DICHROMATE
Radioactivity:
Form:
Net Explosive Weight:
Coast Guard Ammunition Code:
Magnetism: N/P
AF MMAC Code:
DOD Exemption Number:
Limited Quantity Indicator:
Multiple Kit Number: 0
Kit Indicator: N
Kit Part Indicator: N
Review Indicator: Y
Additional Data:
RQ = 10 LBS. PSN PER MFR.
Department of Transportation Information
DOT Proper Shipping Name: TOXIC SOLIDS, OXIDIZING, N.O.S.
DOT PSN Code: QMN
Symbols: G
DOT PSN Modifier:
Hazard Class: 6.1
UN ID Number: UN3086
DOT Packaging Group: I
Label: POISON, OXIDIZER
Special Provision(s):
Packaging Exception: NONE
POTASSIUM BICHROMATE(CRYSTALS) #M1245
Non Bulk Packaging: 211 Page 8 of 9
Bulk Packaging: 242
Maximimum Quanity in Passenger Area: 1 KG
Maximimum Quanity in Cargo Area: 15 KG
Stow in Vessel Requirements: C
Requirements Water/Sp/Other:
IMO Detail Information
IMO Proper Shipping Name: TOXIC SOLID, OXIDIZING, N.O.S. o
IMO PSN Code: OTS
IMO PSN Modifier:
IMDG Page Number: 6270-4
UN Number: 3086
UN Hazard Class: 6.1
IMO Packaging Group: I/II
Subsidiary Risk Label: OXIDIZING AGENT
EMS Number: 6.1-04
Medical First Aid Guide Number: T
IATA Detail Information
IATA Proper Shipping Name: TOXIC SOLID, OXIDIZING, N.O.S. *
IATA PSN Code: YJM
IATA PSN Modifier:
IATA UN Id Number: 3086
IATA UN Class: 6.1
Subsidiary Risk Class: 5.1
UN Packaging Group: I
IATA Label: TOXIC & OXIDIZER
Packaging Note for Passengers: 606
Maximum Quantity for Passengers: 1KG
Packaging Note for Cargo: 607
Maximum Quantity for Cargo: 15KG
Exceptions: A5
AFI Detail Information
AFI Proper Shipping Name: TOXIC SOLID, OXIDIZING, N.O.S.
AFI Symbols: *
AFI PSN Code: YIJ
AFI PSN Modifier:
AFI UN Id Number: UN3086
AFI Hazard Class: 6.1
AFI Packing Group: I
AFI Label: 5.1
Special Provisions: P5
Back Pack Reference: A10.6
HAZCOM Label Information
POTASSIUM BICHROMATE(CRYSTALS) #M1245
Product Identification: POTASSIUM BICHROMATE(CRYSTALS) #M1245 Page 9 of 9
CAGE: 0AH54
Assigned Individual: N
Company Name: OCCIDENTAL CHEMICAL CORPORATION
Company PO Box:
Company Street Address1: 5005 LYNDON B JOHNSON FWY
Company Street Address2: DALLAS, TX 75244-6198 US
Health Emergency Telephone:
Label Required Indicator: Y
Date Label Reviewed: 12/16/1998
Status Code: C
Manufacturer's Label Number:
Date of Label: 12/16/1998
Year Procured: N/K
Organization Code: F
Chronic Hazard Indicator: N/P
Eye Protection Indicator: N/P
Skin Protection Indicator: N/P
Respiratory Protection Indicator: N/P
Signal Word: N/P
Health Hazard:
Contact Hazard:
Fire Hazard:
Reactivity Hazard:
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