TITE-R-BOND
Chemwatch Material Safety Data Sheet
Issue Date: 31-Mar-2006 CHEMWATCH 4919-44
A317EC CD 2006/1 Page 1 of 15
Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME
TITE-R-BOND
SYNONYMS
"Tite-R-Bond GL 2287A", "primer promoter PZQ-6533010 Tite-R-Bond GL 2287A"
PROPER SHIPPING NAME
ETHYL ACETATE
PRODUCT USE
The use of a quantity of material in an unventilated or confined space may
result in increased exposure and an irritating atmosphere developing. Before
starting consider control of exposure by mechanical ventilation. Primer /
promoter for adhesives. Used for the preparation of plastics, metals and painted
surfaces.
SUPPLIER
Company: Foam Sealant Pty Ltd
Address:
48-52 Micro Circuit PO Box 4323
Dandenong South Dandenong South B.C.
VIC 3164 VIC 3164
AUS
Telephone: 61 3 9702 9989
Fax: 61 3 9799 6304
Section 2 - HAZARDS IDENTIFICATION
STATEMENT OF HAZARDOUS NATURE
HAZARDOUS SUBSTANCE. DANGEROUS GOODS. According to the
Criteria of NOHSC, and the ADG Code.
POISONS SCHEDULE
None
RISK
Highly flammable.
Irritating to eyes.
May cause CANCER.
Possible risk of harm to the unborn child.
HARMFUL-May cause lung damage if swallowed.
Vapours may cause drowsiness and dizziness.
SAFETY
Keep locked up.
Keep container in a well ventilated place.
Avoid exposure - obtain special instructions before use.
To clean the floor and all objects contaminated by this material, use water and
detergent.
Keep container tightly closed.
This material and its container must be disposed of in a safe way.
Keep away from food, drink and animal feeding stuffs.
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TITE-R-BOND
Chemwatch Material Safety Data Sheet
Issue Date: 31-Mar-2006 CHEMWATCH 4919-44
A317EC CD 2006/1 Page 2 of 15
Section 2 - HAZARDS IDENTIFICATION
Take off immediately all contaminated clothing.
In case of contact with eyes, rinse with plenty of water and contact Doctor or
Poisons Information Centre.
Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS
NAME CAS RN %
ethyl acetate 141-78-6 >60
toluene 108-88-3 1-9
acrylic acid homopolymer 9003-01-4 1-9^
isopropanol 67-63-0 <1^
propylene imine 75-55-8 <0.1
Section 4 - FIRST AID MEASURES
SWALLOWED
- If swallowed do NOT induce vomiting.
- If vomiting occurs, lean patient forward or place on left side (head-down
position, if possible) to maintain open airway and prevent aspiration.
- Observe the patient carefully.
- Never give liquid to a person showing signs of being sleepy or with reduced
awareness; i.e. becoming unconscious.
- Give water to rinse out mouth, then provide liquid slowly and as much as
casualty can comfortably drink.
- Seek medical advice.
EYE
If this product comes in contact with the eyes:
- Immediately hold eyelids apart and flush the eye continuously with running
water.
- Ensure complete irrigation of the eye by keeping eyelids apart and away from
eye and moving the eyelids by occasionally lifting the upper and lower lids.
- Continue flushing until advised to stop by the Poisons Information Centre or a
doctor, or for at least 15 minutes.
- Transport to hospital or doctor without delay.
- Removal of contact lenses after an eye injury should only be undertaken by
skilled personnel.
SKIN
If skin contact occurs:
- Immediately remove all contaminated clothing, including footwear
- Flush skin and hair with running water (and soap if available).
- Seek medical attention in event of irritation.
INHALED
- If fumes or combustion products are inhaled remove from contaminated area.
- Lay patient down. Keep warm and rested.
- Prostheses such as false teeth, which may block airway, should be removed,
where possible, prior to initiating first aid procedures.
- Apply artificial respiration if not breathing, preferably with a demand valve
resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if
necessary.
- Transport to hospital, or doctor.
NOTES TO PHYSICIAN
Treat symptomatically.
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TITE-R-BOND
Chemwatch Material Safety Data Sheet
Issue Date: 31-Mar-2006 CHEMWATCH 4919-44
A317EC CD 2006/1 Page 3 of 15
Section 5 - FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA
- Foam.
- Dry chemical powder.
- BCF (where regulations permit).
- Carbon dioxide.
- Water spray or fog - Large fires only.
FIRE FIGHTING
- Alert Fire Brigade and tell them location and nature of hazard.
- May be violently or explosively reactive.
- Wear breathing apparatus plus protective gloves.
- Prevent, by any means available, spillage from entering drains or water
course.
- Consider evacuation (or protect in place).
- Fight fire from a safe distance, with adequate cover.
- If safe, switch off electrical equipment until vapour fire hazard removed.
- Use water delivered as a fine spray to control the fire and cool adjacent
area.
- Avoid spraying water onto liquid pools.
- Do not approach containers suspected to be hot.
- Cool fire exposed containers with water spray from a protected location.
- If safe to do so, remove containers from path of fire.
When any large container (including road and rail tankers) is involved in a fire,
consider evacuation by 1000 metres in all directions.
FIRE/EXPLOSION HAZARD
- Liquid and vapour are highly flammable.
- Severe fire hazard when exposed to heat, flame and/or oxidisers.
- Vapour forms an explosive mixture with air.
- Severe explosion hazard, in the form of vapour, when exposed to flame or
spark.
- Vapour may travel a considerable distance to source of ignition.
- Heating may cause expansion / decomposition with violent rupture of
containers.
- On combustion, may emit toxic fumes of carbon monoxide (CO).
Other combustion products include.
carbon dioxide (CO2) and nitrogen oxides (NOx).
FIRE INCOMPATIBILITY
Avoid contamination with strong oxidising agents as ignition may result.
HAZCHEM
3[Y]E
Personal Protective Equipment
Breathing apparatus.
Chemical splash suit.
Section 6 - ACCIDENTAL RELEASE MEASURES
EMERGENCY PROCEDURES
MINOR SPILLS
- Remove all ignition sources.
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TITE-R-BOND
Chemwatch Material Safety Data Sheet
Issue Date: 31-Mar-2006 CHEMWATCH 4919-44
A317EC CD 2006/1 Page 4 of 15
Section 6 - ACCIDENTAL RELEASE MEASURES
- Clean up all spills immediately.
- Avoid breathing vapours and contact with skin and eyes.
- Control personal contact by using protective equipment.
- Contain and absorb small quantities with vermiculite or other absorbent
material.
- Wipe up.
- Collect residues in a flammable waste container.
MAJOR SPILLS
- Clear area of personnel and move upwind.
- Alert Fire Brigade and tell them location and nature of hazard.
- May be violently or explosively reactive.
- Wear breathing apparatus plus protective gloves.
- Prevent, by any means available, spillage from entering drains or water
course.
- Consider evacuation (or protect in place).
- No smoking, naked lights or ignition sources.
- Increase ventilation.
- Stop leak if safe to do so.
- Water spray or fog may be used to disperse /absorb vapour.
- Contain spill with sand, earth or vermiculite.
- Use only spark-free shovels and explosion proof equipment.
- Collect recoverable product into labelled containers for recycling.
- Absorb remaining product with sand, earth or vermiculite.
- Collect solid residues and seal in labelled drums for disposal.
- Wash area and prevent runoff into drains.
- If contamination of drains or waterways occurs, advise emergency services.
PROTECTIVE ACTIONS FOR SPILL
PROTECTIVE ACTION ZONE
half
evacuation
downwind
direction
distance
down wind distance
wind isolation
distance
direction
half
evacuation downwind
INITIAL direction distance
ISOLATION
ZONE
From IERG (Canada/Australia)
Isolation Distance 50 metres
Downwind Protection Distance 300 metres
IERG Number 18
FOOTNOTES
1 PROTECTIVE ACTION ZONE is defined as the area in which people are at risk
of harmful exposure. This zone assumes that random changes in wind direction
confines the vapour plume to an area within 30 degrees on either side of the
predominant wind direction, resulting in a crosswind protective action distance
equal to the downwind protective action distance.
2 PROTECTIVE ACTIONS should be initiated to the extent possible, beginning with
those closest to the spill and working away from the site in the downwind
direction. Within the protective action zone a level of vapour concentration
may exist resulting in nearly all unprotected persons becoming incapacitated
and unable to take protective action and/or incurring serious or irreversible
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TITE-R-BOND
Chemwatch Material Safety Data Sheet
Issue Date: 31-Mar-2006 CHEMWATCH 4919-44
A317EC CD 2006/1 Page 5 of 15
Section 6 - ACCIDENTAL RELEASE MEASURES
health effects.
3 INITIAL ISOLATION ZONE is determined as an area, including upwind of the
incident, within which a high probability of localised wind reversal may
expose nearly all persons without appropriate protection to life-threatening
concentrations of the material.
4 SMALL SPILLS involve a leaking package of 200 litres (55 US gallons) or less,
such as a drum (jerrican or box with inner containers). Larger packages leaking
less than 200 litres and compressed gas leaking from a small cylinder are also
considered "small spills".
LARGE SPILLS involve many small leaking packages or a leaking package of
greater than 200 litres, such as a cargo tank, portable tank or a "one-tonne"
compressed gas cylinder.
5 Guide 129 is taken from the US DOT emergency response guide book.
6 IERG information is derived from CANUTEC - Transport Canada.
EMERGENCY RESPONSE PLANNING GUIDELINES (ERPG)
The maximum airborne concentration below which it is believed that nearly all
individuals could be exposed for up to one hour WITHOUT experiencing or developing
life-threatening health effects is:
ethyl acetate 2000 ppm
irreversible or other serious effects or symptoms which could
impair an individual's ability to take protective action is:
ethyl acetate 400 ppm
other than mild, transient adverse effects
without perceiving a clearly defined odour is:
ethyl acetate 400 ppm
The threshold concentration below which most people.
will experience no appreciable risk of health effects:
ethyl acetate 400 ppm
American Industrial Hygiene Association (AIHA)
Ingredients considered according to the following cutoffs
Very Toxic (T+) >= 0.1% Toxic (T) >= 3.0%
R50 >= 0.25% Corrosive (C) >= 5.0%
R51 >= 2.5%
else >= 10%
where percentage is percentage of ingredient found in the mixture
Personal Protective Equipment advice is contained in Section 8 of the MSDS.
Section 7 - HANDLING AND STORAGE
PROCEDURE FOR HANDLING
- Avoid all personal contact, including inhalation.
- Wear protective clothing when risk of exposure occurs.
- Use in a well-ventilated area.
- Prevent concentration in hollows and sumps.
- DO NOT enter confined spaces until atmosphere has been checked.
- Avoid smoking, naked lights, heat or ignition sources.
- When handling, DO NOT eat, drink or smoke.
- Vapour may ignite on pumping or pouring due to static electricity.
- DO NOT use plastic buckets.
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TITE-R-BOND
Chemwatch Material Safety Data Sheet
Issue Date: 31-Mar-2006 CHEMWATCH 4919-44
A317EC CD 2006/1 Page 6 of 15
Section 7 - HANDLING AND STORAGE
- Earth and secure metal containers when dispensing or pouring product.
- Use spark-free tools when handling.
- Avoid contact with incompatible materials.
- Keep containers securely sealed.
- Avoid physical damage to containers.
- Always wash hands with soap and water after handling.
- Work clothes should be laundered separately.
- Use good occupational work practice.
- Observe manufacturer's storing and handling recommendations.
- Atmosphere should be regularly checked against established exposure standards
to ensure safe working conditions.
SUITABLE CONTAINER
- Metal can or drum
- Packaging as recommended by manufacturer.
- Check all containers are clearly labelled and free from leaks.
STORAGE INCOMPATIBILITY
Segregate from strong oxidisers and strong alkalis.
STORAGE REQUIREMENTS
- Store in original containers in approved flame-proof area.
- No smoking, naked lights, heat or ignition sources.
- DO NOT store in pits, depressions, basements or areas where vapours may be
trapped.
- Keep containers securely sealed.
- Store away from incompatible materials in a cool, dry well ventilated area.
- Protect containers against physical damage and check regularly for leaks.
- Observe manufacturer's storing and handling recommendations.
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE CONTROLS
Source Material TWA TWA STEL STEL Peak Peak
ppm mg/m鲁 ppm mg/m鲁 ppm mg/m鲁
_________________________ ________________ _____ _____ _____ _____ _____ _____
Australia Exposure Ethyl acetate 200 720 400 1440
Standards
Australia Exposure Toluene 50 191 150 574
Standards
Australia Exposure Propylene imine 2 4.7
Standards
EMERGENCY EXPOSURE LIMITS
Material Revised IDLH Revised IDLH
Value (ppm) Value (mg/m3)
Ethyl acetate 2,000 [LEL]
Toluene 500
Propylene imine 100
NOTES
Values marked LEL indicate that the IDLH was based on 10% of the lower explosive
limit for safety considerations even though the relevant toxicological data
indicated that irreversible health effects or impairment of escape existed
only at higher concentrations.
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TITE-R-BOND
Chemwatch Material Safety Data Sheet
Issue Date: 31-Mar-2006 CHEMWATCH 4919-44
A317EC CD 2006/1 Page 7 of 15
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
ODOUR SAFETY FACTOR (OSF)
OSF=17 (TOLUENE)
Exposed individuals are NOT reasonably expected to be warned, by smell, that the
Exposure Standard is being exceeded.
Odour Safety Factor (OSF) is determined to fall into either Class C, D or E.
The Odour Safety Factor (OSF) is defined as:
OSF= Exposure Standard (TWA) ppm/ Odour Threshold Value (OTV) ppm
Classification into classes follows:
Class OSF Description
A 550 Over 90% of exposed
individuals are aware by
smell that the Exposure
Standard (TLV-TWA for
example) is being
reached, even when
distracted by working
activities
B 26-550 As "A" for 50-90% of
persons being distracted
C 1-26 As "A" for less than 50%
of persons being
distracted
D 0.18-1 10-50% of persons aware
of being tested perceive
by smell that the
Exposure Standard is
being reached
E <0.18 As "D" for less than 10%
of persons aware of
being tested
.
REPRODUCTIVE HEALTH GUIDELINES
Established occupational exposure limits frequently do not take into
consideration reproductive end points that are clearly below the thresholds for
other toxic effects. Occupational reproductive guidelines (ORGs) have been
suggested as an additional standard. These have been established after a
literature search for reproductive no-observed-adverse effect-level (NOAEL) and
the lowest-observed-adverse-effect-level (LOAEL). In addition the US EPA's
procedures for risk assessment for hazard identification and dose-response
assessment as applied by NIOSH were used in the creation of such limits.
TLV
Ingredient ORG UF Endpoint CR Adeq
toluene 9.6 mg/m鲁 10 D NA -
These exposure guidelines have been derived from a screening level of risk
assessment and should not be construed as unequivocally safe limits. ORGS
represent an 8-hour time-weighted average unless specified otherwise.
CR = Cancer Risk/10000; UF = Uncertainty factor:
TLV believed to be adequate to protect reproductive health:
LOD: Limit of detection
Toxic endpoints have also been identified as:
D = Developmental; R = Reproductive; TC = Transplacental carcinogen
Jankovic J., Drake F.: A Screening Method for Occupational Reproductive
American Industrial Hygiene Association Journal 57: 641-649 (1996).
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TITE-R-BOND
Chemwatch Material Safety Data Sheet
Issue Date: 31-Mar-2006 CHEMWATCH 4919-44
A317EC CD 2006/1 Page 8 of 15
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
INGREDIENT DATA
ETHYL ACETATE:
Odour Threshold Value: 6.4-50 ppm (detection), 13.3-75 ppm (recognition)
The TLV-TWA provides a significant margin of safety from the standpoint of
adverse health effects. Unacclimated subjects found the odour
objectionably strong at 200 ppm. Mild nose, eye and throat irritation was
experienced at 400 ppm. Workers exposed regularly at concentrations
ranging from 375 ppm to 1500 ppm for several months showed no unusual
signs or symptoms.
TOLUENE:
Exposure limits with "skin" notation indicate that vapour and liquid may be
absorbed through intact skin. Absorption by skin may readily exceed vapour
inhalation exposure. Symptoms for skin absorption are the same as for
inhalation. Contact with eyes and mucous membranes may also contribute to
overall exposure and may also invalidate the exposure standard.
Odour Threshold Value: 0.16-6.7 (detection), 1.9-69 (recognition)
NOTE: Detector tubes measuring in excess of 5 ppm, are available.
High concentrations of toluene in the air produce depression of the
central nervous system (CNS) in humans. Intentional toluene exposure
(glue-sniffing) at maternally-intoxicating concentration has also produced
birth defects. Foetotoxicity appears at levels associated with CNS
narcosis and probably occurs only in those with chronic toluene-induced
kidney failure. Exposure at or below the recommended TLV-TWA is thought
to prevent transient headache and irritation, to provide a measure of
safety for possible disturbances to human reproduction, the prevention of
reductions in cognitive responses reported amongst humans inhaling
greater than 40 ppm, and the significant risks of hepatotoxic, behavioural
and nervous system effects (including impaired reaction time and
incoordination). Although toluene/ethanol interactions are well
recognised, the degree of protection afforded by the TLV-TWA among
drinkers is not known.
PROPYLENE IMINE:
Propyleneimine possesses a lesser toxicity than ethyleneimine and the
recommended value for TLV-TWA is much higher.
PERSONAL PROTECTION
EYE
- Safety glasses with side shields; or as required,
- Chemical goggles.
- Contact lenses may pose a special hazard; soft contact lenses may absorb and
concentrate irritants. A written policy document, describing the wearing of lens
or restrictions on use, should be created for each workplace or task. This
should include a review of lens absorption and adsorption for the class of
chemicals in use and an account of injury experience. Medical and first-aid
personnel should be trained in their removal and suitable equipment should be
readily available. In the event of chemical exposure, begin eye irrigation
immediately and remove contact lens as soon as practicable. Lens should be
removed at the first signs of eye redness or irritation - lens should be removed
in a clean environment only after workers have washed hands thoroughly. [CDC
NIOSH Current Intelligence Bulletin 59].
HANDS/FEET
- Barrier cream with polyethylene gloves or Butyl rubber gloves or Wear chemical
protective gloves, eg. PVC.
Wear safety footwear.
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TITE-R-BOND
Chemwatch Material Safety Data Sheet
Issue Date: 31-Mar-2006 CHEMWATCH 4919-44
A317EC CD 2006/1 Page 9 of 15
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
OTHER
- Overalls.
- Eyewash unit.
RESPIRATOR
Selection of the Class and Type of respirator will depend upon the level of
breathing zone contaminant and the chemical nature of the contaminant.
Protection Factors (defined as the ratio of contaminant outside and inside the
mask) may also be important.
Breathing Zone Maximum Half-face Full-Face
Level ppm Protection Factor Respirator Respirator
(volume)
1000 10 AX-AUS -
1000 50 - AX-AUS
5000 50 Airline * -
5000 100 - AX-2
10000 100 - AX-3
100+ Airline**
* - Continuous Flow ** - Continuous-flow or positive pressure demand.
The local concentration of material, quantity and
conditions of use determine the type of personal
protective equipment required.
For further information consult site specific
CHEMWATCH data (if available), or your
Occupational Health and Safety Advisor.
ENGINEERING CONTROLS
Use in a well-ventilated area.
General exhaust is adequate under normal operating conditions. Local exhaust
ventilation may be required in specific circumstances. If risk of overexposure
exists, wear approved respirator. Correct fit is essential to obtain adequate
protection. Provide adequate ventilation in warehouse or closed storage areas.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE
Slightly cloudy, highly flammable liquid with a sweet solvent odour;
partly mixes with water. Solubility in water: 8%. Soluble in xylene and
methyl ethyl ketone (MEK).
PHYSICAL PROPERTIES
Liquid.
Does not mix with water.
Floats on water.
Molecular Weight: Not available Boiling Range (C): 77
Melting Range (C): Not available Specific Gravity (water=1): 0.89
Solubility in water (g/L): Partly miscible pH (as supplied): Not applicable
pH (1% solution): Not applicable. Vapour Pressure (kPa): 10.1 @ 20 C
Volatile Component (%vol): 98.5 Evaporation Rate: 6.15 BuAc=1
Relative Vapour Density (air=1): 3.0 Flash Point (C): -3 (PMCC)
Lower Explosive Limit (%): 2.2 Upper Explosive Limit (%): 11.0
Autoignition Temp (C): 427 ethyl acet. Decomposition Temp (掳 Not available
C):
State: Liquid Viscosity: Not available
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TITE-R-BOND
Chemwatch Material Safety Data Sheet
Issue Date: 31-Mar-2006 CHEMWATCH 4919-44
A317EC CD 2006/1 Page 10 of 15
Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION
CONDITIONS CONTRIBUTING TO INSTABILITY
- Presence of incompatible materials.
- Product is considered stable.
- Hazardous polymerisation will not occur.
Section 11 - TOXICOLOGICAL INFORMATION
POTENTIAL HEALTH EFFECTS
ACUTE HEALTH EFFECTS
SWALLOWED
Considered an unlikely route of entry in commercial/industrial environments.
The liquid is moderately discomforting and may be harmful if swallowed Ingestion
may result in nausea, pain, vomiting. Vomit entering the lungs by aspiration may
cause potentially lethal chemical pneumonitis.
Acute intoxication may cause impaired coordination, exhilaration, slurred
speech, vertigo, flushed face.
EYE
The material may be irritating to the eye, with prolonged contact causing
inflammation. Repeated or prolonged exposure to irritants may produce
conjunctivitis.
SKIN
The material may cause skin irritation after prolonged or repeated exposure and
may produce on contact skin redness, swelling, the production of vesicles,
scaling and thickening of the skin.
Toxic effects may result from skin absorption.
Open cuts, abraded or irritated skin should not be exposed to this material.
INHALED
Inhalation hazard is increased at higher temperatures.
Acute effects from inhalation of high vapour concentrations may be chest and
nasal irritation with coughing, sneezing, headache and even nausea.
The main effects of simple esters are irritation, stupor and insensibility.
Headache, drowsiness, dizziness, coma and behavioural changes may occur.
Respiratory symptoms may include irritation, shortness of breath, rapid
breathing, throat inflammation, bronchitis, lung inflammation and pulmonary
oedema, sometimes delayed. Nausea, vomiting, diarrhoea and cramps are observed.
Liver and kidney damage may result from massive exposures.
CHRONIC HEALTH EFFECTS
Principal routes of exposure are by accidental skin and eye contact and by
inhalation of vapours especially at higher temperatures. As with any chemical
product, contact with unprotected bare skin; inhalation of vapour, mist or dust
in work place atmosphere; or ingestion in any form, should be avoided by
observing good occupational work practice.
TOXICITY AND IRRITATION
Not available. Refer to individual constituents.
unless otherwise specified data extracted from RTECS - Register of Toxic Effects
of Chemical Substances
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TITE-R-BOND
Chemwatch Material Safety Data Sheet
Issue Date: 31-Mar-2006 CHEMWATCH 4919-44
A317EC CD 2006/1 Page 11 of 15
Section 11 - TOXICOLOGICAL INFORMATION
ETHYL ACETATE:
TOXICITY IRRITATION
Oral (rat) LD50: 5620 mg/kg Eye (human): 400 ppm
Inhalation (rat) LC50: 1600 ppm/8h
Inhalation (human) TCLo: 400 ppm
TOLUENE:
TOXICITY IRRITATION
Oral (human) LDLo: 50 mg/kg Skin (rabbit): 20 mg/24h-Moderate
Oral (rat) LD50: 636 mg/kg Skin (rabbit): 500 mg - Moderate
Inhalation (human) TCLo: 100 ppm Eye (rabbit): 0.87 mg - Mild
Inhalation (man) TCLo: 200 ppm Eye (rabbit): 2 mg/24h - SEVERE
Inhalation (rat) LC50: >26700 ppm/1h Eye (rabbit): 100 mg/30sec - Mild
Dermal (rabbit) LD50: 12124 mg/kg
PROPYLENE IMINE:
TOXICITY IRRITATION
Oral (rat) LD50: 19 mg/kg Eye (rabbit):0.25 mg(open)SEVERE
Intraperitoneal (mouse) LD50: 355 mg/kg
Skin (guinea) pig: LD50 43 mg/kg
WARNING: This substance has been classified by the IARC as Group 2B: Possibly
Carcinogenic to Humans.
Section 12 - ECOLOGICAL INFORMATION
No data for Tite-R-Bond.
Refer to data for ingredients, which follows:
ETHYL ACETATE:
log Pow (Verschueren 1983): 0.66/0.73
ThOD: 50.4
log Pow (Verschueren 1983): 0.66/0.73
BOD5: 15%
COD: 1.54 (83%)
ThOD: 1.82
Half-life Soil - High (hours): 168
Half-life Soil - Low (hours): 24
Half-life Air - High (hours): 353
Half-life Air - Low (hours): 35.3
Half-life Surface water - High (hours): 168
Half-life Surface water - Low (hours): 24
Half-life Ground water - High (hours): 336
Half-life Ground water - Low (hours): 48
Aqueous biodegradation - Aerobic - High (hours): 168
Aqueous biodegradation - Aerobic - Low (hours): 24
Aqueous biodegradation - Anaerobic - High (hours): 672
Aqueous biodegradation - Anaerobic - Low (hours): 96
Aqueous biodegradation - Removal secondary treatment - High (hours): 96%
Aqueous biodegradation - Removal secondary treatment - Low (hours): 99.90%
Photooxidation half-life water - High (hours): 9.60E+05
Photooxidation half-life water - Low (hours): 24090
Photooxidation half-life air - High (hours): 353
Photooxidation half-life air - Low (hours): 35.3
First order hydrolysis half-life (hours): 1.77E+04
Acid rate constant [M(H+)-HR]-1: 3.05E-08
Base rate constant [MOH)-HR]-1: 2.99E-05
log Kow: 0.66-0.73
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TITE-R-BOND
Chemwatch Material Safety Data Sheet
Issue Date: 31-Mar-2006 CHEMWATCH 4919-44
A317EC CD 2006/1 Page 12 of 15
Section 12 - ECOLOGICAL INFORMATION
Half-life (hr) air: 200
Half-life (hr) H2O surface water: 10
Henry's atm m鲁 /mol: 1.20E-04
BOD 5 if unstated: 0.1-1.24,16-36%
COD: 1.54,83%
ThOD: 1.82
TOLUENE:
Hazardous Air Pollutant: Yes
Fish LC50 (96hr.) (mg/l): 7.3-22.8
BCF<100: 13.2 (EELS
log Kow (Sangster 1997): 2.73
log Pow (Verschueren 1983): 2.69
BOD5: 5%
COD: 21%
ThOD: 3.13
Half-life Soil - High (hours): 528
Half-life Soil - Low (hours): 96
Half-life Air - High (hours): 104
Half-life Air - Low (hours): 10
Half-life Surface water - High (hours): 528
Half-life Surface water - Low (hours): 96
Half-life Ground water - High (hours): 672
Half-life Ground water - Low (hours): 168
Aqueous biodegradation - Aerobic - High (hours): 528
Aqueous biodegradation - Aerobic - Low (hours): 96
Aqueous biodegradation - Anaerobic - High (hours): 5040
Aqueous biodegradation - Anaerobic - Low (hours): 1344
Aqueous biodegradation - Removal secondary treatment - High (hours): 75%
Photolysis maximum light absorption - High (nano-m): 268
Photolysis maximum light absorption - Low (nano-m): 253.5
Photooxidation half-life water - High (hours): 1284
Photooxidation half-life water - Low (hours): 321
Photooxidation half-life air - High (hours): 104
Photooxidation half-life air - Low (hours): 10
The lower molecular weight hydrocarbons are expected to form a "slick" on the
surface of waters after release in calm sea conditions. This is expected to
evaporate and enter the atmosphere where it will be degraded through reaction
with hydroxy radicals.
Some of the material will become associated with benthic sediments, and it is
likely to be spread over a fairly wide area of sea floor. Marine sediments may
be either aerobic or anaerobic. The material, in probability, is biodegradable,
under aerobic conditions (isomerised olefins and alkenes show variable results).
Evidence also suggests that the hydrocarbons may be degradable under anaerobic
conditions although such degradation in benthic sediments may be a relatively
slow process.
Under aerobic conditions the material will degrade to water and carbon dioxide,
while under anaerobic processes it will produce water, methane and carbon
dioxide.
Based on test results, as well as theoretical considerations, the potential for
bioaccumulation may be high. Toxic effects are often observed in species such as
blue mussel, daphnia, freshwater green algae, marine copepods and amphipods.
DO NOT discharge into sewer or waterways.
log Kow: 2.1-3
log Koc: 1.12-2.85
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Section 12 - ECOLOGICAL INFORMATION
Koc: 37-250
log Kom: 1.39-2.89
Half-life (hr) air: 2.4-104
Half-life (hr) H2O surface water: 5.55-528
Half-life (hr) H2O ground: 168-2628
Half-life (hr) soil: <48-240
Henry's Pa m鲁 /mol: 518-694
Henry's atm m鲁 /mol: 5.94E-03
BOD 5 if unstated: 0.86-2.12,5%
COD: 0.7-2.52,21-27%
ThOD: 3.13
BCF: 1.67-380
Log BCF: 0.22-3.28
PROPYLENE IMINE:
Hazardous Air Pollutant: Yes
Half-life Soil - High (hours): 870
Half-life Soil - Low (hours): 87
Half-life Air - High (hours): 10.6
Half-life Air - Low (hours): 1.1
Half-life Surface water - High (hours): 870
Half-life Surface water - Low (hours): 87
Half-life Ground water - High (hours): 870
Half-life Ground water - Low (hours): 87
Aqueous biodegradation - Aerobic - High (hours): 672
Aqueous biodegradation - Aerobic - Low (hours): 168
Aqueous biodegradation - Anaerobic - High (hours): 2688
Aqueous biodegradation - Anaerobic - Low (hours): 672
Photooxidation half-life air - High (hours): 10.6
Photooxidation half-life air - Low (hours): 1.1
First order hydrolysis half-life (hours): 87
Acid rate constant [M(H+)-HR]-1: 870
Base rate constant [MOH)-HR]-1: 4.00E-03
Half-life (hr) soil: 420
Nitrif. inhib.: not sig
processes Abiotic: rapid hydrol
Section 13 - DISPOSAL CONSIDERATIONS
- Consult manufacturer for recycling options and recycle where possible .
- Consult State Land Waste Management Authority for disposal.
- Incinerate residue at an approved site.
- Recycle containers if possible, or dispose of in an authorised landfill.
Section 14 - TRANSPORTATION INFORMATION
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Section 14 - TRANSPORTATION INFORMATION
Labels Required
flammable liquid
HAZCHEM
3[Y]E
Land Transport UNDG:
Dangerous Goods Class: 3 Subrisk: None
UN Number: 1173 Packing Group: II
Shipping Name:ETHYL ACETATE
Air Transport IATA:
ICAO/IATA Class: 3 ICAO/IATA Subrisk: None
UN/ID Number: 1173 Packing Group: II
ERG Code: 3L
Shipping Name: Ethyl acetate
Maritime Transport IMDG:
IMDG Class: 3 IMDG Subrisk: None
UN Number: 1173 Packing Group: II
EMS Number: F-E,S-D
Shipping Name: ETHYL ACETATE
Section 15 - REGULATORY INFORMATION
POISONS SCHEDULE
None
REGULATIONS
ethyl acetate (CAS: 141-78-6) is found on the following regulatory lists;
Australia High Volume Industrial Chemical List (HVICL)
Australia Inventory of Chemical Substances (AICS)
International Council of Chemical Associations (ICCA) - High Production Volume
List
OECD Representative List of High Production Volume (HPV) Chemicals
toluene (CAS: 108-88-3) is found on the following regulatory lists;
Australia High Volume Industrial Chemical List (HVICL)
Australia Inventory of Chemical Substances (AICS)
Australia Poisons Schedule
International Agency for Research on Cancer (IARC) Carcinogens
OECD Representative List of High Production Volume (HPV) Chemicals
propylene imine (CAS: 75-55-8) is found on the following regulatory lists;
Australia - Queensland Hazardous Materials and Prescribed Quantities for Major
Hazard Facilities
Australia Inventory of Chemical Substances (AICS)
International Agency for Research on Cancer (IARC) Carcinogens
Section 16 - OTHER INFORMATION
This document is copyright. Apart from any fair dealing for the purposes of
private study, research, review or criticism, as permitted under the Copyright
Act, no part may be reproduced by any process without written permission from
CHEMWATCH. TEL (+61 3) 9572 4700.
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Issue Date: 31-Mar-2006 CHEMWATCH 4919-44
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Section 16 - OTHER INFORMATION
Issue Date: 31-Mar-2006
Print Date: 31-Mar-2006
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