MATERIAL SAFETY DATA SHEET UPDATES AVAILABLE AT WWW.GREENBOOK.NET 1
Cheminova
Obtain medical attention or advice as indicated for faces, absorb spill with inert, non-combustible absor-
GLYFOS AQUATIC other exposure. bent material, such as hydrated lime, Fuller’s earth or
other absorbent clays. Scoop up and place contami-
Revision Date: January 6, 2006 Eyes: Immediately flush with plenty of water or eye-
nated absorbent material into suitable containers for
wash solution, occasionally opening eyelids, until no
SECTION 1 � PRODUCT AND COMPANY IDENTI- later disposal (see Section 13). Clean the spill area
evidence of chemical remains. Remove contact
FICATION with soap and water, then rinse thoroughly. Do not
lenses after a few minutes and flush again. Get medi-
flush to sewer or allow to enter confined spaces.
cal attention immediately.
Product identifier: GLYFOS AQUATIC
Large spills that soak into the ground should be dug
Skin: Remove contaminated clothing and shoes.
Product use: Herbicide.
up, placed in suitable containers and disposed of
Wash with plenty of water and soap. Get medical
Supplier’s name and address:
appropriately (see Section 13). Notify the appropriate
attention if irritation develops.
Cheminova Inc.
author ities. Spills in water should be contained as
Ingestion: The product may cause gastrointestinal
1700 Route 23, Suite 300
much as possible by isolation of the contaminated
tract irritation. Immediately rinse mouth and dilute by
Wayne, NJ, USA
water. The contaminated water must be collected and
drinking milk. If not available, drink water. Do not
07470
removed for treatment or disposal. Uncontrolled dis-
induce vomiting. If vomiting occurs, rinse mouth and
Manufacturer’s name and address:
charge into water courses must be alerted to the
drink fluids again. Call a doctor or get medical
Cheminova A/S.
appropriate regulatory body. The used containers
attention.
P.O. Box 9
should be properly closed and labelled. Refer to
Inhalation: If experiencing any discomfort, immedi-
DK-7620 Lemvig
section 13 for disposal.
ately remove to fresh air and obtain medical advice if
Denmark
Prohibited materials: Do not use containers made
discomfort does not disappear.
Phone #: (973) 305-6600 (8 AM to 5:00 PM EST,
of iron, galvanized steel or unlined steel.
Note to physician: The irritating effects of this prod-
Monday to Friday)
Special spill response procedures: If a spill/
uct can be treated as usual against effects of acids or
Emergency Telephone #:
release in excess of EPA reportable quantity is made
acid fumes. Probable mucosal damage may contrain-
1-866-303-6950 (Medical Emergencies)
into the environment, immediately notify the national
dicate the use of gastric lavage.
1-800-424-9300 (24 Hr. Chemtrec Number)
response center (phone: 1-800-424-8002).
MSDS Prepared by: Cheminova Inc.
SECTION 5 � FIRE FIGHTING MEASURES EPA/CERCLA Reportable quantity: None known.
MSDS Preparation date: August 19, 2003
Fire hazards/condi tions of flammability: Combus-
Revision date: January 6, 2006 SECTION 7 � HANDLING AND STORAGE
tible liquid. This material may burn when exposed to
Revision reasons: Refer to Section 16.
extreme heat, flame and other ignition sources. Safe handling procedures: This material is a harm-
SECTION 2 � COMPOSITION/INFORMATION ON Closed containers may build up pressure if exposed ful liquid. In an industrial environment it is recom-
INGREDIENTS to excess heat. Product can react with iron, galva- mended to avoid all personal contact with the prod-
nized steel or unlined steel to produce flammable uct, preferably by use of closed systems and remote
% ACGIH OSHA
hydrogen gas. Flammable hydrogen gas can produce system control. Otherwise it is recommended to han-
TLV (mg/m3) PEL (mg/m3)
Ingredients CAS # (weight)
a highly combustible mixture with air and this mixture
*Glyphosate as 38641-94-0 40 - 70 N/Av N/Av dle the material by mechanical means as much as
isopropylamine salt
could flash or explode if ignited by heat, sparks and possible. Wear appropriate protective equipment dur -
flame.
*Note: The product contains about 650 g/L of the ing handling. Use only in well ventilated area. Avoid
active ingredient Glyphosate as its isopropylamine Flammability classification (OSHA 29 CFR contact with eyes, skin and clothing. Do not inhale
salt, equivalent to 480 g/L of the free acid Glyphosate 1910.1200): Class IIIB Combustible Liquid. vapors or mists. Keep away from all unprotected per-
(CAS # 1071-83-6). sons and children. Do not use near sources of heat,
Flash point (Method): >212°F / 100°C (Estimated).
This material is classified as hazardous under OSHA flame or ignition sources. This product should be
Lower flammable limit (% by volume): N/Av
regulations (29CFR 1910.1200). mixed, stored or applied using only stainless
Upper flammable limit (% by volume): N/Av
steel, fibreglass, plastic or plastic-lined contain-
Explosion data:
SECTION 3 � HAZARDS IDENTIFICATION ers and equipment. This product can react with con-
Sensitivity to mechanical impact: Not sensitive.
tainers made of iron, galvanized steel and unlined
EMERGENCY OVERVIEW Sensitivity to static discharge: Not expected to be
steel to produce flammable hydrogen gas which may
Clear, colorless to light amber, viscous liquid, slight sensitive to static discharge.
form a highly combustible gas mixture with air. Keep
amine-like odor. Auto-ignition temperature: N/Av
away from bases and incompatibles. Use caution
Caution! Reacts with materials made of iron, galva- Suitable extinguishing media: For small fires, use
when opening containers. Keep container tightly
nized steel and unlined steel, liberating (releasing) dry chemical or carbon dioxide. For large fires, use
closed when not in use. Wash thoroughly after han-
hydrogen, which may ignite. May cause eye irritation. water spray or foam.
dling. Do not contaminate water when disposing of
Contains material which may cause liver and kidney Special fire-fighting procedures/equipment:
equipment washwaters.
effects. May be dangerous for the environment. Firefighters should wear proper chemically protective
Storage recommendations: Store in a cool (<100°F
This product may be toxic to all green plants. equipment and self-contained breathing apparatus
/ 38°C), dry, well ventilated area away from incompat-
The product may be harmful to fish, aquatic inver te- operated in positive pressure mode. Move containers
brates and aquatic plants. ibles. Store above �14°F / �10°C to avoid crystalliza-
from fire area if it can be done without risk. Dike area
tion. If crystallization has occurred, raise temperature
***POTENTIAL HEALTH EFFECTS*** to prevent water run-off. Water spray may be useful in
to 68°F/20°C and mix well. Protect container from
Target organs: Eyes, skin, respiratory system, cooling equipment and containers. Approach fire
physical damage. No smoking in the area. Inspect
digestive system. from upwind to avoid hazardous vapours and toxic
containers periodically for damage or leaks. Store in
Signs and symptoms of short-term (acute) expo- decomposition products. Fight fire from protected
closed, labelled containers. The storage room should
sure: location or maximum possible distance. Avoid heavy
be constructed of incombustible material, closed, dry,
Inhalation: Inhalation may cause irritation to the hose streams. Avoid spreading burning material with
ventilated and with imper meable floor, without
nose, throat and upper respiratory tract. water jet. The product does not present any unusual
access of unauthor ised persons or children. The
Skin contact: Direct skin contact may cause slight irri- fire hazard. It is advisable for firemen to avoid direct
room should only be used for storage of chemicals.
tation. contact with the product.
Food, drink, feed and seed must be kept away. A
Eye contact: Direct eye contact may cause moderate Hazardous combustion products: Carbon oxides,
hand wash station should be available.
irritation and reversible eye injury. Symptoms may in- nitrogen oxides, phosphorous oxides.
Special packaging materials: Always keep in con-
clude pain, redness and tearing.
SECTION 6 � ACCIDENTAL RELEASE MEA- tainers made of the same materials as the supply
Ingestion: This product is not expected to be harmful
SURES container.
by oral administration route. Ingestion of large
amounts could cause irritation. Symptoms may inclu- Personal precautions: Restrict access to area until SECTION 8 � EXPOSURE CONTROLS AND PER-
de nausea, vomiting and diarrhea. completion of clean-up. Ensure clean-up is con- SONAL PROTECTION
Effects of long-term (chronic) exposure: Pro- ducted by trained personnel only. All persons dealing
longed or repeated overexposure may cause liver Ventilation and engineering controls: If handled
with clean-up should wear the appropriate chemically
and kidney effects. indoors, general room ventilation may not be suffi-
protective equipment. Refer to Section 8, EXPO-
Carcinogenicity: See TOXICOLOGICAL INFORMA- cient. Provide mechanical exhaust ventilation to keep
SURE CONTROLS AND PERSONAL PROTEC-
TION (Section 11). concentrations below specified TLV’s and PEL’s.
TION, for additional infor mation on acceptable per-
Other impor tant hazards: See TOXICOLOGICAL sonal protective equipment. Respiratory protection: This product is not likely to
INFORMATION (Section 11). present an airbourne exposure concern during nor -
Environmental precautions: Ensure spilled product
Potential environmental effects: This product may mal handling. In the event of an accidental discharge
does not enter drains, sewers, waterways, or con-
be toxic to all green plants. The product may be harm- of the material during manufactur ing or handling,
fined spaces.
ful to fish, aquatic inver tebrates and aquatic plants. which produces a heavy vapor or mist, workers
Spill response/Cleanup: It is recommended to have
See ECOLOGICAL INFORMATION (Section 12). should put on respiratory protection. Wear respira-
a predeter mined plan for the handling of spills. Empty
tors approved by MSHA / NIOSH. Advice should be
vessels for the collection of spills should be available.
SECTION 4 � FIRST AID MEASURES sought from respiratory protection specialists.
Eliminate all sources of heat, sparks and flame. Ven-
Emergency and first aid procedures: Immediate tilate area of release. Stop leak if you can do so with- Protective gloves: Wear imper vious chemical
medical attention is required in case of eye contact. out risk. For spills on the floor or other imper vious sur- gloves, such as barrier laminate, butyl rubber, nitrile
Database and format copyright © by Vance Communication Corporation. All rights reserved.
MATERIAL SAFETY DATA SHEET UPDATES AVAILABLE AT WWW.GREENBOOK.NET 2
rubber or viton. Advice should be sought from glove CAS - Chemical Abstract Ser vice
Carcinogenicity: This product does not contain any
suppliers. CERCLA - Comprehensive Environmental
materials which are classified as carcinogenic by
Response, Compensation, and Liability Act of 1980
IARC, ACGIH, OSHA or NTP.
Eye protection: Wear safety glasses with side
CFR - Code of Federal Regulations
Teratogenicity, mutagenicity, other reproductive
shields or chemical splash goggles to prevent vapors
EPA - Environmental Protection Agency
or mists from enter ing the eyes. If using a full face effects: None known.
HMIS - Hazardous Materials Identification System
shield, always use safety glasses or goggles along Sensitization to material: None known.
IARC - Inter national Agency for Research on Cancer
with the face shield to ensure adequate protection of Synergistic materials: Not available.
Inh - Inhalation
the eyes. Conditions aggravated by exposure: Pre-existing
MSHA - Mine Safety and Health Administration
Other protective equipment: Wear appropriate pro- eye disorders.
N/Ap - Not Applicable
tective clothing to prevent skin contact. Other protec-
SECTION 12 � ECOLOGICAL INFORMATION N/Av - Not Available
tive equipment, such as an eyewash station and
NIOSH - National Institute for Occupational Safety
safety shower, may be required depending on expo- Chemical fate information: Glyphosate is rapidly
and Health
sure and on workplace standards. deactivated by absorption to clay par ticles. Glypho-
NTP - National Toxicology Program
Permissible exposure levels: See Section 2. sate binds strongly to soil. The product, however,
OEHHA - Office of Environmental Health Hazard
General hygiene considerations: Avoid breathing should not be allowed to enter drains or water
Assessment
vapors or mists. Avoid contact with eyes, skin and courses or be deposited where it can affect ground or
OSHA - Occupational Safety and Health Act
clothing. Wash thoroughly with soap and water after surface waters. Do not discharge product
PEL - Per missible Exposure Limit
handling and before eating, drinking, chewing gum, unmonitored into the environment.
PMCC - Pensky Mar tins Closed Cup
using tobacco or using the toilet. Remove contami- Ecotoxicological information: This product is the
RCRA - Resource Conser vation and Recovery Act
nated clothing and wash before re-use. After work, active ingredient in herbicides and may be toxic to all
SARA - Superfund Amendments & Reauthorization
take off all work clothes and shoes. Take a shower, green plants. The product may be harmful to fish,
Act
using water and soap. Wear only clean clothes when aquatic inver tebrates and aquatic plants. Glyphosate
TLV - Threshold Limit Value
leaving job. acute toxicity is:
TSCA - Toxic Substances Control Act
Fish -
TWA - Time Weighted Average
SECTION 9 � PHYSICAL AND CHEMICAL PROP- 96-Hr LC50, Rainbow trout (Salmo gairdneri) = >1000
WHMIS - Workplace Hazardous Materials Infor ma-
ERTIES mg/L.
tion System
96-Hr LC50, Bluegill sunfish (Lepomis macrochirus) =
Physical state, odor and appearance: Clear, color-
References:
>1000 mg/L
less to light amber, viscous liquid, slight amine-like
1. ACGIH, Threshold Limit Values and Biological
Inver tebrates - 48-Hr EC50, Daphnids (Daphnia
odor.
Exposure Indices for 2003.
magna) = 930 mg/L.
Odor threshold: N/Av
2. Canadian Centre for Occupational Health and
Algae - 72-Hr IC50, Green Algae (Scenedesmus
Specific gravity (water = 1): 1.230 g/mL @ 68°F/ Safety, CCInfoWeb databases, 2003
subspicatus) = 72.9 mg/L.
20°C. (Chempendium and RTECs).
Solubility in water: The product is miscible with 3. Material Safety Data Sheet from manufacturer.
SECTION 13 � DISPOSAL CONSIDERATIONS
water (solubility free Glyphosate acid: 10.5 g/L @ 4. Inter national Agency for Research on Cancer
Handling for disposal: Handle waste according to
68°F/20°C). Monographs, Supplement 7, 1988.
recommendations in Section 7.
pH: 4.7 @ 77°F / 25°C (5% aqueous solution). 5. US EPA Title III List of Lists - October 2001 ver-
Methods of disposal: Do not contaminate water,
Boiling point: >212°F / 100°C sion.
foodstuffs, feed or seed by storage or disposal. Triple
Melting/freezing point: <32°F / 0°C. 6. Califor nia’s OEHHA Proposition 65 List - July 11,
rinse (or equivalent) containers, then offer for recy- 2003 version.
Vapour density (Air=1.0): N/Ap
cling or reconditioning, or puncture and dispose of in
Prepared by: Cheminova Inc.
Percent Volatile by Weight: N/Av
a sanitary landfill. Disposal must be in compliance
Telephone #: (973) 305-6600 (8 AM to 5:00 PM EST,
Evaporation rate (n-BuAc=1.0): N/Av with all Federal, State and local regulations. Contact
Monday to Friday)
Vapour pressure: 1.75 × 10�7 1mmHg (1.31 × 10�5 your local, state or federal environmental agency for
Preparation date: August 19, 2003
Pa) @ 77°F / 25°C (free Glyphosate acid). specific rules.
Revision date: January 6, 2006
Coefficient of n-Octanol/water distribution: Kow =
Revision reasons: 1. Update and add additional pre-
SECTION 14 � TRANSPORTATION INFORMA-
4.5 × 10�4 (free Glyphosate acid); Log Kow = �3.3
cautions - Sections 4, 5, 6, 7, 8, 10 VID 9.8.06
TION
(free Glyphosate acid)
Viscosity: 185 centipoise @ 77.9°F / 25.5°C; 69 US 49 CFR information: Not regulated for transport.
centipoise @ 114°F / 45.4°C. Canadian Transpor tation of Dangerous Goods
Flash Point: >212°F / 100°C Clear Language (CLR) information: Not regulated
for transport.
SECTION 10 � REACTIVITY AND STABILITY
DATA SECTION 15 � REGULATORY INFORMATION
Stability and reactivity: This product is stable at Canada:
ambient temperatures. This product can react with WHMIS information: This product is a Pest Control
containers made of iron, galvanized steel and unlined Product and is not regulated as a Controlled Product
steel to produce flammable hydrogen gas which may under the Hazardous Products Act (HPA). However,
form a highly combustible gas mixture with air. This for reference pur poses only, this product would have
gas mixture could flash or explode when exposed to the following WHMIS Classification if it were regu-
heat, sparks, flame, welder’s torch, lighted cigarettes lated as a Controlled Product under the HPA: Class
or other ignition sources. D2B (Materials causing other toxic effects, Toxic
Hazardous polymerization: Hazardous polymerisa- Material).
tion does not occur. The product does react with This product has been classified in accordance
caustic (alkaline) materials to liberate heat, however with the hazard criteria of the Controlled Prod-
this is an acid-base neutralization reaction and is not ucts Regulations (CPR) and this MSDS contains
polymerisation. all the information required by the CPR.
Conditions to avoid: Avoid heat, flame and direct United States:
sunlight. California Proposition 65 information: This prod-
Materials to avoid (incompatibles): Alkalies, iron, uct does not contain any chemicals known to the
galvanized steel and unlined steel. The product can state of Califor nia to cause cancer or reproductive
react with caustic (basic) materials in an acid-base harm.
chemical neutralisation reaction which may be haz- EPA/CERCLA Reportable Quantity (RQ): None
ardous because of heat release. known.
Hazardous decomposition products: None known. SARA TITLE III: Sec. 313, Toxic Chemicals Notifica-
Refer to ‘Hazardous combustion products�, Section tion, 40 CFR 372: This material is not known to con-
5. tain any Toxic Chemical constituents.
SECTION 11 � TOXICOLOGICAL INFORMATION SECTION 16 � OTHER INFORMATION
Routes of exposure: Skin contact, eye contact, HMIS Rating: *2 Health;
inhalation, and ingestion. 1 Flammability;
Toxicological data: 0 Reactivity
LC50 (mg/L/4 hrs) = >4.24 Legend:
LD50, oral, rat (mg/kg) = >5000 ACGIH - American Conference of Governmental
LD50, der mal, rat (mg/kg) = >4000 Industrial Hygienists
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