MATERIAL SAFETY DATA SHEET UPDATES AVAILABLE AT WWW.GREENBOOK.NET 1
Clear y
lenses, if present, after the first 5 minutes, then con- It is recommended that all dust control equipment
TRISTAR鈩? 70 WSP - tinue rinsing eye. Call a poison control center or doc- and material transport systems involved in handling
ACETAMIPRID INSECTI- tor for treatment advice. of this product contain explosion relief vents or explo-
sion suppression system or an oxygen deficient envi-
Inhalation: Move person to fresh air. If person is not
CIDE ronment. In addition, all conductive elements of the
breathing, call 911 or an ambulance, then give artifi-
system that contact this material should be electri-
cial respiration, preferably mouth-to-mouth if possi-
Please read the entire document. This Material
cally bonded and grounded. This powder should not
ble. Call a poison control center or doctor for fur ther
Safety Data Sheet contains impor tant environmental,
be flowed through non-conductive ducts or pipes.
treatment advice.
health and toxicology infor mation for your employees,
Use only appropriately classed electrical equipment.
Note to Physician: There is no specific antidote. All
and anyone who will use, transport, store, dispose of
Storing Procedures: Do not store in or around the
treatment should be based on observed signs and
or handle this product. Please make sure this infor -
home. Store unused product in a cool, ventilated, dry,
symptoms of distress in the patient. Consideration
mation is given to them. It also contains infor mation to
locked area. Never transfer this product to another
should be given to the possibility that overexposure to
help you meet community right-to-know/emergency
container for storage. Do not allow prolonged storage
materials other than this product may have occurred.
response reporting requirements under SARA Title
in areas where temperatures frequently exceed
III and many other laws. If you resell this product, this SECTION 5: FIRE AND EXPLOSION INFORMA- 115掳F (46掳C).
MSDS must be given to the buyer or the infor mation TION Work/Hygienic Procedures: Personal hygiene is an
contained herein must be incorporated in your
impor tant work practice exposure control measure
Flammability:
MSDS.
and the following general measures should be taken
Combustion: Will form dust explosive mixtures in air.
when working with or handling this material:
SECTION 1: PRODUCT AND COMPANY IDENTIFI- Dust explosive rating of ST-1 (KsT=165 barmeter per
Wash hand before eating, drinking, chewing gum,
CATION second).
using tobacco or using the toilet.
Flash Point (Method): N/A
PRODUCT NAME: TRISTAR鈩? 70 WSP Remove clothing immediately if pesticide gets inside.
Extinguishing Media: Dry chemical, alcohol foam,
CLEARY PRODUCT CODE: 7010 Then wash thoroughly and put on clean clothing.
water spray, carbon dioxide (CO2)
EPA REGISTRATION NUMBER(S): 8033-22-1001 Remove Personal Protective Equipment (PPE)
Special Fire Fighting Procedures: Firefighters
CHEMICAL NAME: Acetamiprid, (E)-N1-[(6-chloro- immediately after handling this product. Wash the
should wear NIOSH/MSHA approved self-contained
3-pyridyl)methyl]-N2-cyano-N1-methylacetamidine outside of gloves before removing.
breathing apparatus and full protective clothing. Keep
CHEMICAL FAMILY: Nicotinoid Discard clothing and other absorbent materials that
unnecessary people away, isolate hazard area and
CHEMICAL FORMULATION: C10 H11 Cl N4 have been drenched or heavily contaminated with
deny entry. Stay upwind if possible. Keep out of low
this product鈥檚 concentrate. Do not reuse them. Follow
PRODUCT USE DESCRIPTION: For Commercial
areas. Persons who may have been exposed to con-
manufacturer鈥檚 instructions for cleaning/maintaining
Use Only. Ornamental use only. Not for Woodlands or
taminated smoke should be immediately examined
Personal Protective Equipment (PPE). If no such
forest management.
by a physician and checked for symptoms of poison-
instructions for washables, use detergent and hot
COMPANY
ing. The symptoms should not be mistaken for heat
water. Keep and wash PPE separately from other
Cleary Chemical Cor poration exhaustion or smoke inhalation.
laundry.
178 Ridge Road, Suite A
Unusual Fire and Explosion Hazards: Like all Do not enter or allow worker entry into treated areas
Dayton, New Jersey 08810
organic and most dry chemicals, as a powder or dust, during the restricted entry inter val (REI) of 12 hours.
EMERGENCY TELEPHONE NUMBERS this product (when mixed with air in critical propor - Do not apply this product in a way that will contact
CLEARY CHEMICAL CORP. tions and in the presence of an ignition source) may workers or other persons, either directly or through
M-F 9-5 EST present an explosion hazard. drift. Only protected handlers may be in the area dur -
(800) 524-1662 OR
ing application. For any requirements specific to your
(732) 329-8399 SECTION 6: ACCIDENTAL RELEASE MEASURES
State or Tribe, consult the agency responsible for
PROSAR: (800) 324-7598
General and Disposal pesticide regulation.
CHEMTREC 24 HOUR: (800) 424-9300
Evacuation Procedures and Safety: Personnel Min/Max Storage: Min Temp: No data Max Temp:
handling this material should be thoroughly trained to
SECTION 2: INFORMATION ON INGREDIENTS 46掳C
handle spills and releases. Wear appropriate gear for
Active Ingredient(s)/ % by Wt. CAS# Exposure
SECTION 8: EXPOSURE CONTROLS/PERSONAL
the situation. See Personal Protection infor mation in
Hazardous Inert Ingredient(s) Limits
PROTECTION
Section 8.
Acetamiprid, (E)-N1-[(6-chloro-3- 73.0 135410-20-7
pyridl)methyl]-N2-cyano-N1-
Cleanup and Disposal of Spill: Sweep up and place Engineering Controls: Where engineering controls
methylacetamidine
in an appropriate closed container (see Section 7: are indicated by use conditions or a potential for
Amorphous silicon dioxide hydrate 7.9 112926-00-8
Handling and Storage). No sparking tools should be
(Amorphous silica)
excessive exposure exists, the following traditional
Hydrous Aluminum Silicate 15.0 1332-58-7
used. Avoid creation of dusty conditions. Clean up exposure control techniques may be used to effec-
Other Ingredients (Trade Secret) 13.2
residual material by washing area with water and tively minimize employee exposures: general area
detergent. Collect washings for disposal. Decontami- dilution/exhaust ventilation.
SECTION 3: HEALTH HAZARD INFORMATION
nate tools and equipment following cleanup. Protective Clothing: Applicators and other handlers
Inhalation: Harmful if inhaled. Avoid breathing dust Spill or Leak Procedures must wear long-sleeved shirts and long pants, water -
or spray mist. Containment of Spill: Stop leak if it can be done proof gloves, shoes plus socks and chemical resist-
Eye Contact: Avoid contact with eyes. without risk. Follow procedure under Cleanup and ant headgear for overhead exposure.
Skin Contact: Harmful if absorbed through skin. Disposal of Spill. Eye/Face Protection: Eye and face protection
Avoid contact with skin or clothing. Environmental and Regulatory Reporting: Do not requirements will vary dependent upon work environ-
Ingestion: Harmful if ingested. flush to drain. If spilled on the ground, the affected ment conditions and material handling practices.
Chronic Effects of Overexposure: This product area should be scraped clean and placed in an Appropriate ANSI Z87 approved equipment should
does not contain any ingredients designated by appropriate container for disposal. Prevent material be selected for the par ticular use intended for this
IARC, NTP, ACGIH or OSHA as probable or sus- from enter ing public sewer system or any waterway. material.
pected human carcinogens. Spills may be reportable to the National Response Eye contact should be prevented through use of
Other Toxic Effects: Inhalation of product may Center (800-424-8802) and to state and /or local chemical safety glasses with side shields or splash
aggravate existing chronic respiratory problems such agencies. proof goggles. An emergency eye wash must be
as asthma, emphysema or bronchitis. Skin contact readily accessible to the work area.
SECTION 7: HANDLING AND STORAGE
may aggravate existing skin disease. Exposure Limits:
Signs and Symptoms: Have the product container Amor phous silicon dioxide hydrate (Amor phous sil-
Handling Procedures: KEEP OUT OF REACH OF
or label with you when calling a poison control center ica) 112926-00-8
CHILDREN AND ANIMALS
or doctor or going for treatment. Personnel handling this product should be thoroughly ACGIH TWA 10 mg/m3
trained as to its hazards. Use nonsparking tools and
SECTION 4: FIRST AID MEASURES OSHA Z1A TWA 6 mg/m3
grounded/bonded equipment and containers when US CA OEL TWA PEL 5 mg/m3
Ingestion: Immediately call a poison control center transferring. Do not ingest. Do not breathe dust or Form of Exposure Respirable fraction.
or doctor for treatment advice. DO NOT induce vomit- mists. Avoid getting material on clothing. Use han- US CA OEL TWA PEL 5 mg/m3
ing unless directed to do so by a physician or poison dling, storage and disposal procedures that will pre- Form of Exposure Respirable fraction.
control center. Have a person sip a glass of water if vent contamination of water, food or feed. US CA OEL TWA PEL 10 mg/m3
able to swallow. Do not give anything by mouth to an THIS PRODUCT MAY PRESENT A DUST EXPLO- Form of Exposure Total dust.
unconscious person. SION HAZARD US CA OEL TWA PEL 5 mg/m3
Skin Contact: Take off contaminated clothing. Rinse Dry powders can build static electricity charges when Form of Exposure Respirable fraction.
skin immediately with plenty of water for 15-20 min- subjected to the friction of conveying, mixing or slid- US CA OEL TWA PEL 10 mg/m3
utes. Call a poison control center or doctor for treat- ing. Provide adequate precautions, such as electrical Form of Exposure Total dust.
ment advice. grounding, or inert atmospheres when material is US CA OEL TWA PEL 10 mg/m3
Eye Contact: Hold eye open and rinse slowly and used in the presence of flammable materials to Form of Exposure Total dust.
gently with water for 15-20 minutes. Remove contact prevent ignition.
Database and format copyright 漏 by Vance Communication Corporation. All rights reserved.
MATERIAL SAFETY DATA SHEET UPDATES AVAILABLE AT WWW.GREENBOOK.NET 2
Hydrous Aluminum Silicate 1332-58-7 designated and may not be valid where said product
Ecological Information: For ecotoxicological data
is used in combination with any other material or in
call the product infor mation phone number listed in
ACGIH TWA 2 mg/m3
any process. It is the user鈥檚 responsibility to deter -
Section 1.
NIOSH REL 5 mg/m3
mine the suitability of the infor mation for their pur -
Environmental Fate: For environmental fate data
Form of Exposure Respirable.
poses. No warranty of fitness for any par ticular pur -
call the product infor mation phone number listed in
NIOSH REL 10 mg/m3
pose, warranty of merchantability, or any other war-
Section 1.
Form of Exposure Total
ranty, expressed or implied, is made concerning the
US CA OEL TWA PEL 2 mg/m3 SECTION 13: DISPOSAL CONSIDERATIONS information provided.
Form of Exposure Respirable dust.
Reason for issue: Update
General Disposal Guidance: Do not contaminate
OSHA Z1 PEL 5 mg/m3
Prepared by: R. Fletcher
water, food, or feed by storage or disposal. Contami-
Form of Exposure Respirable fraction.
Effective date: 07/03
nation with this product will render water, food or feed
OSHA Z1 PEL 15 mg/m3
Replaces: 06/03
unfit for human or animal consumption. Wastes
Form of Exposure Total dust.
Document number: 7010
resulting from use of this product may be disposed of
OSHA Z1A TWA 5 mg/m3
TriStar is a trademark of the Nippon Soda Co., Ltd.
on site or at an approved waste disposal facility.
Form of Exposure Respirable fraction.
Document Number: 7010
Chemical additions, processing or otherwise alter ing
OSHA Z1A TWA 10 mg/m3
Issue Date: 07/03
this material may make the waste management infor -
Form of Exposure Total dust.
NDA = No Data Available
mation presented in this MSDS incomplete, inaccu-
N/A = Not Applicable
rate or otherwise inappropriate. Please be advised
SECTION 9: PHYSICAL AND CHEMICAL PROP-
N/E = Not Established
that state and local requirements for waste disposal
ERTIES
CLEARY CHEMICAL CORPORATION
may be more restrictive or otherwise different from
Solid Off-white Powder. No 178 Ridge Road,
Physical Appearance and odor: federal laws and regulations. Consult state and local
odor determined.
Dayton, NJ 08810-1501
regulations regarding the proper disposal of this
NDA
Boiling Point:
www.clearychemical.com
material.
NDA
Vapor Pressure @20掳C mm Hg:
EMERGENCY PHONE NUMBERS:
Container Disposal: Do not reuse outer bag. Dis-
NDA
% Volatile:
M-F 9AM-5PM EDT
pose of outer bag in a sanitary landfill or by incinera-
NDA
Melting Point:
800-524-1662
tion, or if allowed by State and local author ities, by
NDA
Freezing Point: 732-329-8399
burning. If burned, stay out of smoke.
NDA
Specific Gravity (25掳C): 24-Hour CHEMTREC
SECTION 14: TRANSPORTATION INFORMATION
N/A
Evaporation Rate: 800-424-9300
Approximately 2.7 wt/wt %
Solubility in water: PROSAR
Not regulated for transpor tation per DOT regulations.
dispersible
800-324-7598 VID 9.11.06
8.5 - 9.5 at 1 wt/wt% dilution
pH:
SECTION 15: REGULATORY INFORMATION
in water at 22掳C
N/A
Vapor Density (air = 1): US Federal
13-17 lb/cu ft (loose)
Density: EPA Registration No. 8033-22-1001
TSCA list
Other Information: Physical and Chemical proper -
Hydrous Aluminum Silicate 1332-58-7
ties here represent typical proper ties of this product.
TSCA12b export notification
Contact the business area using the Product Infor -
None
mation phone number in Section 1 for its exact
SARA Title III - section 302 - notification and infor-
specifications.
mation
None
SECTION 10: STABILITY AND REACTIVITY
SARA Title III - section 313 - toxic chemical
Stability: This material is stable under nor mal han-
release reporting
dling and storage conditions described in Section 7.
None
Conditions to Avoid: None known
US States Regulatory
Incompatibility: Strong bases, strong acids and
CA Prop 65
strong oxidizing agents.
This product noes not contain any substances known
Hazardous Polymerization: Will not polymerize. to the State of Califor nia to cause cancer.
This product does not contain any substances known
SECTION 11: TOXICOLOGICAL INFORMATION
to the State of Califor nia to cause reproductive harm.
Toxicity Data: US State right-to-know ingredients
Oral (acute): Rat: LD50: = 1,064 mg/kg Amor phous silicon dioxide hydrate (Amor phous sil-
Dermal (acute): Rabbit: LD50: >2,000 mg/kg ica) 112926-00-8: PA
Inhalation (acute): Rat: LC50: >2.88 mg/l 4 h Acute Hydrous Aluminum Silicate 1332-58-7: IL,PA, RI
Respiratory Irritation: No test data found for product. Canadian Regulations
Skin Irritation: Rabbit: Slightly irritating Canadian Registrat. No.
Canadian Domestic Substance List
Eye Irritation: Rabbit: Mildly irritating
Amor phous silicon dioxide hydrate (Amor phous sil-
Sensitization: Guinea pig: Non-sensitizing
ica) 112926-00-8
Chronic Toxicity: In long term animal feeding stud-
Hydrous Aluminum Silicate 1332-58-7
ies there was no evidence of carcinogenicity. Not con-
Environmental
sidered a carcinogen or mutagen.
CERCLA
Assessment Carcinogenicity:
None
ACGIH
Clean Water Section 307 Priority Pollutants
Hydrous Aluminum Silicate 1332-58-7: Group A4
None
NTP
Safe Drinking Water Act Maximum Contaminant
None
Levels
IARC
None
Amor phous silicon dioxide hydrate (Amor phous sil-
International Regulations
ica) 112926-00-8
EU Classification
OSHA
None
None European Inventory of Existing Commercial Sub-
Reproductive & Developmental Toxicity: In repro- stances (EINECS)
ductive and developmental studies in animals, there None
was no effect on reproduction. Not considered a
reproductive toxicant. SECTION 16: OTHER INFORMATION
SECTION 12: ECOLOGICAL INFORMATION Health Flammability Reactivity Others
HMIS 2 1 0
Environmental Precautions: This product is toxic to NFPA 2 1 0
wildlife. This product is toxic to bees exposed to direct
Please note: Cleary Chemical Corp. believes that the
treatment. Do not apply this product while bees are
infor mation and recommendations contained herein
actively visiting the treated area. Do not contaminate
are accurate as of the date hereof. The infor mation
surface or ground water by cleaning equipment or
provided herein applies only to the specific product
disposal of wastes, including equipment washwater.
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