SIGMA-ALDRICH
Material Safety Data Sheet
Date Printed: 16/NOV/2004
Date Updated: 12/MAR/2004
Version 1.2
According to 91/155/EEC
Classified as Hazardous according to the criteria of EU Annex 1 and
NOHSC.
1 - Product and Company Information
Product Name ANTIMONY(III) CHLORIDE, 99%
Product Number 215783
Company Sigma-Aldrich Pty, Ltd
Unit 2, 14 Anella Avenue
Castle Hill NSW 1765
Australia
Technical Phone # +61 2 9841 0555
Fax +61 2 9841 0500
Emergency Phone # +61 2 9841 0566
2 - Composition/Information on Ingredients
Product Name CAS # EC no Annex I
Index Number
ANTIMONY (III) CHLORIDE 10025-91-9 233-047-2 051-001-00-8
Formula SbCl3
Molecular Weight 228.11 AMU
Synonyms Antimoine (trichlorure d') (French) * Antimonio
(tricloruro di) (Italian) * Antimonous chloride
* Antimontrichlorid (German) * Antimony butter *
Antimony chloride (Sb2Cl6) * Antimony
trichloride * Antimoontrichlride (Dutch) *
Butter of antimony * Chlorid antimonity (Czech)
* Chlorure antimonieux (French) * C.I. 77056 *
Stibine, trichloro- * Trichlorostibine *
Trichlorure d'antimoine (French)
3 - Hazards Identification
SPECIAL INDICATION OF HAZARDS TO HUMANS AND THE ENVIRONMENT
Causes burns. Toxic to aquatic organisms, may cause long-term
adverse effects in the aquatic environment.
4 - First Aid Measures
AFTER INHALATION
If inhaled, remove to fresh air. If not breathing give
artificial respiration. If breathing is difficult, give oxygen.
AFTER SKIN CONTACT
In case of skin contact, flush with copious amounts of water for
at least 15 minutes. Remove contaminated clothing and shoes.
Call a physician.
AFTER EYE CONTACT
In case of contact with eyes, flush with copious amounts of
water for at least 15 minutes. Assure adequate flushing by
separating the eyelids with fingers. Call a physician.
AFTER INGESTION
If swallowed, wash out mouth with water provided person is
conscious. Call a physician immediately. Do not induce vomiting.
5 - Fire Fighting Measures
CONDITIONS OF FLAMMABILITY
Water hydrolyzes material liberating acidic gas which in contact
with metal surfaces can generate flammable and/or explosive
hydrogen gas.
EXTINGUISHING MEDIA
Suitable: Carbon dioxide, dry chemical powder, or appropriate
foam.
Unsuitable: Do not use water.
SPECIAL RISKS
Specific Hazard(s): Emits toxic fumes under fire conditions.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS
Wear self-contained breathing apparatus and protective clothing
to prevent contact with skin and eyes.
6 - Accidental Release Measures
PERSONAL PRECAUTION PROCEDURES TO BE FOLLOWED IN CASE OF LEAK OR SPILL
Evacuate area.
PROCEDURE(S) OF PERSONAL PRECAUTION(S)
Wear self-contained breathing apparatus, rubber boots, and heavy
rubber gloves.
METHODS FOR CLEANING UP
Sweep up, place in a bag and hold for waste disposal. Ventilate
area and wash spill site after material pickup is complete.
7 - Handling and Storage
HANDLING
Directions for Safe Handling: Do not breathe dust. Do not get in
eyes, on skin, on clothing. Avoid prolonged or repeated exposure.
STORAGE
Conditions of Storage: Store under inert gas. Keep tightly
closed. Store in a cool dry place.
Incompatible Materials: Do not allow contact with water
SPECIAL REQUIREMENTS: Store under inert gas. Reacts violently
with water.
8 - Exposure Controls / Personal Protection
ENGINEERING CONTROLS
Safety shower and eye bath. Use only in a chemical fume hood.
GENERAL HYGIENE MEASURES
Wash contaminated clothing before reuse. Discard contaminated
shoes. Wash thoroughly after handling.
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EXPOSURE LIMITS - DENMARK
Source Type Value
OEL TWA 0.5 mg/m3
EXPOSURE LIMITS - UNITED KINGDOM
Source Type Value
OEL TWA 0.5MG(SB)/M3
PERSONAL PROTECTIVE EQUIPMENT
Respiratory Protection: Government approved respirator.
Hand Protection: Compatible chemical-resistant gloves.
Eye Protection: Chemical safety goggles.
9 - Physical and Chemical Properties
Appearance Physical State: Solid
Color: White
Form: Crystalline Powder
Property Value At Temperature or Pressure
pH N/A
BP/BP Range 283 掳C 760 mmHg
MP/MP Range 73.4 掳C
Flash Point N/A
Flammability N/A
Autoignition Temp N/A
Oxidizing Properties N/A
Explosive Properties N/A
Explosion Limits N/A
Vapor Pressure 0.21 mmHg 20 掳C
SG/Density 3.14 g/cm3
Partition Coefficient N/A
Viscosity N/A
Vapor Density 7.9 g/l
Saturated Vapor Conc. N/A
Evaporation Rate N/A
Bulk Density N/A
Decomposition Temp. N/A
Solvent Content N/A
Water Content N/A
Surface Tension N/A
Conductivity N/A
Miscellaneous Data N/A
Solubility N/A
10 - Stability and Reactivity
STABILITY
Stable: Stable.
Conditions to Avoid: Heat.
Materials to Avoid: Strong bases Reacts violently with water.
HAZARDOUS DECOMPOSITION PRODUCTS
Hazardous Decomposition Products: Antimony/antimony oxides.
HAZARDOUS POLYMERIZATION
Hazardous Polymerization: Will not occur
11 - Toxicological Information
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RTECS NUMBER: CC4900000
ACUTE TOXICITY
LD50
Oral
Rat
525 mg/kg
LD50
Intraperitoneal
Mouse
13 MG/KG
LD50
Oral
Guinea pig
574 mg/kg
Remarks: Peripheral Nerve and Sensation:Spastic paralysis with
or without sensory change. Gastrointestinal:Peritonitis.
Gastrointestinal:Necrotic changes.
SIGNS AND SYMPTOMS OF EXPOSURE
Inhalation may result in spasm, inflammation and edema of the
larynxand bronchi, chemical pneumonitis, and pulmonary edema.
Symptoms of exposure may include burning sensation, coughing,
wheezing, laryngitis, shortness of breath, headache, nausea, and
vomiting. Material is extremely destructive to tissue of the
mucous membranes and upper respiratory tract, eyes, and skin. To
the best of our knowledge, the chemical, physical, and
toxicological properties have not been thoroughly investigated.
ROUTE OF EXPOSURE
Skin Contact: Causes burns.
Skin Absorption: May be harmful if absorbed through the skin.
Eye Contact: Causes burns.
Inhalation: Material is extremely destructive to the tissue of
the mucous membranes and upper respiratory tract. May be harmful
if inhaled.
Ingestion: Harmful if swallowed.
CHRONIC EXPOSURE - MUTAGEN
Hamster
10 UMOL/L
Cell Type: lung
Micronucleus test
Hamster
2500 UG/L
Cell Type: lung
Sister chromatid exchange
CHRONIC EXPOSURE - TERATOGEN
Species: Rat
Dose: 1874 MG/KG
Route of Application: Intramuscular
Exposure Time: (6-15D PREG)
Result: Effects on Embryo or Fetus: Fetotoxicity (except death,
e.g., stunted fetus).
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CHRONIC EXPOSURE - REPRODUCTIVE HAZARD
Species: Rat
Dose: 44 MG/KG
Route of Application: Oral
Exposure Time: (1-22D PREG/22D POST)
Result: Effects on Newborn: Growth statistics (e.g., reduced
weight gain).
Species: Rat
Dose: 4400 UG/KG
Route of Application: Oral
Exposure Time: (1-22D PREG/22D POST)
Result: Effects on Newborn: Delayed effects.
12 - Ecological Information
No data available.
13 - Disposal Considerations
SUBSTANCE DISPOSAL
Contact a licensed professional waste disposal service to dispose
of this material. Dissolve or mix the material with a combustible
solvent and burn in a chemical incinerator equipped with an
afterburner and scrubber. Observe all federal, state, and local
environmental regulations.
14 - Transport Information
RID/ADR
UN#: 1733
Class: 8
PG: II
Proper Shipping Name: Antimony trichloride
IMDG
UN#: 1733
Class: 8
PG: II
Proper Shipping Name: Antimony trichloride, solid
Marine Pollutant: No
Severe Marine Pollutant: No
IATA
UN#: 1733
Class: 8
PG: II
Proper Shipping Name: Antimony trichloride, solid
Inhalation Packing Group I: No
15 - Regulatory Information
CLASSIFICATION AND LABELING ACCORDING TO EU DIRECTIVES
ANNEX I INDEX NUMBER: 051-001-00-8
INDICATION OF DANGER: C N
Corrosive. Dangerous for the environment.
R-PHRASES: 34 51/53
Causes burns. Toxic to aquatic organisms, may cause long-term
adverse effects in the aquatic environment.
S-PHRASES: 26 45 61
In case of contact with eyes, rinse immediately with plenty of
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water and seek medical advice. In case of accident or if you
feel unwell, seek medical advice immediately (show the label
where possible). Avoid release to the environment. Refer to
special instructions/safety data sheets.
COUNTRY SPECIFIC INFORMATION
Germany
WGK: 2
SWITZERLAND
SWISS POISON CLASS: 1
16 - Other Information
WARRANTY
The above information is believed to be correct but does not
purport to be all inclusive and shall be used only as a guide. The
information in this document is based on the present state of our
knowledge and is applicable to the product with regard to
appropriate safety precautions. It does not represent any
guarantee of the properties of the product. Sigma-Aldrich Inc.,
shall not be held liable for any damage resulting from handling or
from contact with the above product. See reverse side of invoice
or packing slip for additional terms and conditions of sale.
Copyright 2004 Sigma-Aldrich Co. License granted to make unlimited
paper copies for internal use only.
DISCLAIMER
For R&D use only. Not for drug, household or other uses.
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