Oil Spot Seal Page 1 of 6
R&G MSDS Number: 013 8/14/07
MATERIAL SAFETY DATA SHEET
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Identification
----------------------
Product Name: Oil Spot Seal
Synonyms: None
CAS Number: Blend
Company Identification
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Reed & Graham, Inc.
690 Sunol Street
San Jose, CA 95126 USA
408-287-1400 (For product information)
800-424-9300 CHEMTREC (For emergencies)
2. COMPOSITION/INFORMATION ON INGREDIENTS
COMPONENT LISTING:
Chemical Name Amount CAS Number
------------- ----------- ------------
WATER < 50.0 % 7732-18-5
COPOLYMER < 50.0 % mixture
CARBON BLACK < 0.02 % 1333-86-4
SURFACTANT < 0.002 % non-hazardous
(See Section 8 for exposure guidelines)
(See Section 15 for regulatory information)
COMPOSITION COMMENT:
Concentration values are typical and may vary. All known pertinent hazards are addressed in this
MSDS.
HAZARDS DISCLOSURE:
This product contains hazardous materials as defined by the OSHA Hazard Communication Standard
29 CFR 1910.1200. As defined under Sara 311 and 312, this product contains materials that are
categorized as delayed health hazards.
MISCELLANEOUS:
This material does not have established exposure limits.
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R&G MSDS Number: 013 8/14/07
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW / CAUTION
May cause skin and eye irritation. Dilute with water. For hot product, immediately
immerse in or flush the affected area with large amounts of cold Water to dissipate
heat. Do not allow material to completely dry. Fumes from heated material may be
irritating. Aspiration hazard if swallowed ?can cause lung damage.
NFPA Rating - Health: 1
Flammability: 0
Reactivity: 0
Special Hazard: None
POTENTIAL HEALTH EFFECTS
EYE:
Direct contact may cause slight eye irritation.
SKIN:
Avoid prolonged or repeated contact with skin. Prolonged or repeated contact may cause slight skin
irritation.
INHALATION:
Avoid breathing vapors or mists. Prolonged or excessive inhalation may cause headache, nausea
and/or irritation of the nose, throat and lungs.
INGESTION:
Substance may be harmful if swallowed. Irritating to mouth, throat, and stomach.
SIGNS AND SYMPTOMS OF EXPOSURE:
Headache, nausea, slight skin, eye and/or respiratory irritation.
CHRONIC EFFECTS:
Ingredients have been listed by the International Agency for Research on Cancer (IARC) as possible
cancer causing agents.
CARCINOGENICITY INFORMATION:
Refer to Section 15.
MEDICAL CONDITIONS AGRAVATED BY EXPOSURE:
None known.
4. FIRST AID MEASURES
EYE CONTACT FIRST AID:
Hold eyelids apart and flush eyes with plenty of water for at least 15 minutes. Get medical attention if
irritation develops or persists.
SKIN CONTACT FIRST AID:
Wash skin with soap and water. Wear protective gloves to minimize skin contamination. Consult a
physician if irritation persists.
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R&G MSDS Number: 013 8/14/07
INHALATION FIRST AID:
Move subject to fresh air.
INGESTION FIRST AID:
If swallowed, give two glasses of water to drink. Consult a physician. Never give anything by mouth to
an unconscious person.
5. FIRE FIGHTING MEASURES
FLAMMABLE PROPERTIES
COC Flash Point: None
TCC Flash Point: None
Auto Ignition Temperature: N/A
FLAMMABLE LIMITS IN AIR
LEL: N/A
UEL: N/A
FLAMMABLE PROPERTIES:
Product is a non-combustible aqueous solution.
EXTINGUISHING MEDIA:
Use extinguishing media appropriate for surrounding fire.
FIRE FIGHTING INSTRUCTIONS:
As in any fire, wear self-contained breathing apparatus pressure-demand MSHA/NIOSH (approved or
equivalent) and full protective gear.
COMBUSTION PRODUCTS:
Non-combustible.
6. ACCIDENTAL RELEASE MEASURES
SAFEGUARDS (PERSONNEL):
Appropriate protective equipment must be worn when handling a spill of this material. See Section 8,
Exposure Controls/Personal Protection for recommendations. If exposed to material during clean-up
operations, see Section 4, First Aid Measures for actions to follow.
INITIAL CONTAINMENT:
Keep spectators away. Surface may be slippery; use care to avoid falling. Contain spills immediately
with inert materials (e.g. sand, earth).
LARGE SPILLS PROCEDURE:
Stop the source of the leak or release. Clean up releases as soon as possible, observing precautions
in Exposure Controls/Personal Protection. Contain liquid to prevent further contamination of soil,
surface water or groundwater. Large spillage should be dammed-off and pumped into containers.
SMALL SPILLS PROCEDURE:
Absorb spills with inert material.
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R&G MSDS Number: 013 8/14/07
7. HANDLING AND STORAGE
STORAGE CONDITIONS:
Keep from freezing; material may coagulate. The minimum recommended storage temperature for
this material is 1癈/34?The maximum recommended storage temperature for this material is
F.
49?C/120?F.
HANDLING (PHYSICAL ASPECTS):
Monomer vapors can be evolved if material is heated. See Exposure Controls/Personal Protection, for
types of ventilation required. This material may contain residual levels of vinyl acetate monomer and
acetaldehyde. Lack of adequate ventilation may result in airborne levels of vinyl acetate monomer
and/or acetaldehyde above established exposure limits in the workplace. Monitoring the workplace to
determine actual vinyl acetate/acetaldehyde levels is recommended.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE LIMIT INFORMATION:
COMPONENT CAS REG NO WEIGHT % OSHA TWA (ppm) OSHA STEL (ppm)
Vinyl acetate / Not Hazardous < 25.0 None None
acrylic copolymer
Individual acrylic Not Required < 0.05 Not Required Not Required
monomers
Vinyl acetate 108-05-4 < 0.25 10 20
Acetaldehyde 75-07-0 < 0.05 100 150
Water 7732-18-5 < 25.0 None None
Carbon black 1333-86-4 < 0.02 None None
Surfactant Not Hazardous < 0.002 None None
RESPIRATORY PROTECTION REQUIREMENTS:
When there is potential for airborne exposures in excess of applicable limits a respiratory protection
program meeting OSHA 1910.134 must be followed.
ENGINEERING CONTROLS:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety
shower. In areas where ventilation is not sufficient to maintain atmospheres below the TWA/STEL,
use local exhaust ventilation.
EYE / FACE PROTECTION REQUIREMENTS:
Where contact with this material is likely, wear chemical splash goggles.
SKIN PROTECTION REQUIREMENTS:
Selection of specific items such as gloves, boots, apron, or full-body suit will depend on operation and
potential exposure. Neoprene is the most suitable personal protection equipment material.
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R&G MSDS Number: 013 8/14/07
9. PHYSICAL AND CHEMICAL PROPERTIES
FORM: Liquid
COLOR: Black, opaque
ODOR: Sweet Odor
BOILING POINT: 100 C @ 760 mm Hg
VAPOR PRESSURE: 17 mm HG@ 20 C/68 F Water
VAPOR DENSITY: <1 Water (Air = 1)
SOLUBILITY IN WATER: Dispersible
SPECIFIC GRAVITY: 1.0 - 1.2 (Water = 1)
MELTING/FREEZING POINT: 0 C/ 32 F Water
pH: 4.5-5.5
% VOLATILES: > 50% Water
10. STABILITY AND REACTIVITY
STABILITY:
This compound is stable at ambient conditions. Avoid temperatures above 177 C/350 F. Thermal
decomposition is dependent on time and temperature.
POLYMERIZATION:
Hazardous polymerization will not occur.
INCOMPATIBILITY WITH OTHER MATERIALS:
None known.
DECOMPOSITION:
Decomposition will not occur if handled and stored properly. Thermal decomposition may yield the
following: acrylic monomers ?vinyl acetate monomer.
CONDITIONS TO AVOID:
Avoid extreme temperatures.
11. TOXICOLOGICAL INFORMATION
The toxicity data listed are typical.
Oral LD50 ?rat: > 5000 mg/kg
Dermal LD50 ?rabbit: > 5000 mg/kg
Skin Irritation ?rabbit: slight to moderate
Eye Irritation ?rabbit slight to moderate
12. ECOLOGICAL INFORMATION
No data available.
13. DISPOSAL CONSIDERATIONS
WASTE DISPOSAL:
Treat or dispose of waste material in accordance with all local, state/provincial, and national
requirements. Avoid disposal into waste water treatment facilities.
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R&G MSDS Number: 013 8/14/07
CONTAMINATED MATERIALS:
Treat as product waste.
CONTAINER DISPOSAL:
Unclean empty containers should be disposed of in the same manner as the contents.
14. TRANSPORTATION INFORMATION
D.O.T. HAZARD CLASS: Non-Hazardous
15. REGULATORY INFORMATION
WHMIS Hazard:
Controlled Product
SARA Title III ?Section 311/312
This product is categorized as a delayed health hazard.
SARA Title II ?Section 313
This product contains a chemical which is listed in Section 313 at or above de minimis
concentrations. The following listed chemical is present: vinyl acetate (108-05-4).
CERCLA Hazardous Substances
This material contains no hazardous or extremely hazardous substances as defined by CERCLA or
SARA Title III, and releases are therefore not reportable.
RCRA Hazardous Substances
This material as supplied does not meet the RCRA characteristic definition of ignitability, corrosivity or
reactivity. The toxicity characteristic (TC) has not been evaluated by the Toxicity Characteristic
Leaching Procedure (TCLP).
TSCA Chemical Substances Inventory
All components of this product are listed.
California Proposition 65
This product contains one or more chemicals known to the State of California to cause cancer and/or
reproductive harm.
16. OTHER INFORMATION
REASON FOR ISSUE: Update
PREPARED BY: Eric Richard
Mozammel Haq
APPROVED BY:
Environmental Compliance & Risk Manager
TITLE:
APPROVAL DATE: August 14, 2007
SUPERCEDES DATE: August 19, 2003
This information is furnished without warranty, expressed or implied, except that it is accurate to the
best knowledge of Reed & Graham. The data on this sheet are related only to the specific material
designated herein. Reed & Graham assumes no legal responsibility for use or reliance upon these
data.
END OF MSDS
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