00077095001 English Page i of 6
24 Hour Emergency Phone Numbers:
Medical/Poison Control:
1-800-327-3874
1-513-558-5111
Transportation/National Response
Center:
Company 1-800-535-5053
1-352-323-3500
IMPORTANT: Provide this inform at ion to employees, customers, and users of this product. Read this MSDS before handling or disposing of
this product This product is covered hy the OSHA Hazard Communication Standard anil this document has been prepared in accordance with
requirements of this standard. All abbreviated lerms used in this MSDS are further described in Section 16.
iSection 1 - Chemical Product/ Company Information
This Material Safety Data Sheet is available in Canadian Krench and Hispani
On peut demader cette fiche signaletique (MSDS) a la langue ft
Los Dates de Sergurldad de! Produeto pucdcn obtenerse en Espj
Product Name: OAP?BEATS THE NAIL?VOC Construction Revision Date: 09/10/2007
Adhesive
Product UPC Number: 070798270589, 070798270503, 070798274501, Supercedes: 08/01/2003
070798274587, 070798274808
Product Use/Class: GP Construction Adhesive Latex MSDS Number: 00077095001
Manufacturer: DAP Inc.
2400 Boston Street Suite 200
Baltimore, MD 21224-4723
888-327-8477 (non-emergency matters)
[Section 2 - Hazards Identification
Emergency Overview: A colored paste product with s y slight ammonia odor. WARNING! May cause eye, skin, r
throat and respiratory tract irritation. Harmful if swaliow r absorbed through the skin.
Refer to other MSDS sections for other detailed information.
Effects Of Overexposure - Eye Contact: May cause eye irritation.
Effects Of Overexposure - Skin Contact: May cause skin irritation. Harmful if absorbed through the skin.
Effects Of Overexposure - Inhalation: Harmful if inhaled. Inhalation may cause irritation to the respiratory tract (nose,
mouth, mucous membranes).
Effects Of Overexposure - Ingestion: Harmful if swallowed.
Effects Of Overexposure - Chronic Hazards: Repeated or prolonged exposure may cause respiratory system damage.
Prolonged and repeated skin contact may cause irritation and possibly dermatitis. Overexposure may cause kidney,
cardiovascular, skin and liver damage.
Formaldehyde vapor is a known animal cardnooon arinnrrlinn to OSHA and WTP anrf is considered nossihlv carcinoaanu*
to humans by inhalation. The International Agency for Research on Cancer considers formaldehyde to be a human
nardnoaen
Page 2 of6
00077095001 English
This product contains vinyi acetate whicn is classified as a ciass 2B carcinogen by IARC. Vinyl acetate was found to
cause cancer in the respiratory tract of laboratory animals. There is no evidence that vinyl acetate causes cancer in
humans. The IARC published a monograph on viny! acetate (1995). In this monograph, IARC indicates "there is
inadequate evidence in humans for carcinogenicity of vinyl acetate. There is limited evidence in experimental animals for
the carcinogenicity of vinyl acetate." Normally, this lack of conclusive evidence would place a substance in the IARC 3
classification (not classified as a human carcinogen). However, because vinyl acetate is metabolized to acetaldehyde,
which has an IARC 2B (possibly carcinogenic to humans) classification, it also has been listed under Category 2B.
Primary Route(s) Of Entry: Skin Contact. Inhalation, Ingestion, Eye Contact
Medical Conditions which May be Aggravated by Exposure: None known.
Carcinogenicity:
NTP
Chemical Name OSHA IARC
CAS No. ACCIH
Su B d human
Silica, crystalline ** Not Listed. Hufflan catting KiK^t, carcinogen.
H808-6Q-7
Confinneil animal
Not Listed Possible carcinogen. No.Li.ed
108*5-4 Vinyl acetate
Suspected human Human carcmogen.
50-00-0 Potential cane" hazard Anticipated carcim.gen.
Formaldehyde
75-07-0 Not Listed.
Acetaldehvdc Anticipated carcinogen.
?*?*?
relevance to humans.
Section 3 - Composition / Information On Ingredients
Chemical Name CASRN Wt%
.imestone 30-60
13 1 7-65-3
vlaenesiurn aluminum silicate 2174-11-7 -5
0. - .5
Jrea 7-13-6
0. - .0
Silica, crystalline 4808-60-7
(Ammonia 0. - .0
664-41-7
Viny! aceiate < .7
08-05-4
-ormaldehyde
50-00-0
Acetal dehyde 75-07-0 O.002
{Section 4 - First Aid Measures
First Aid - Eye Contact: In case of contact, immediately flush eyes with large quantrties of water for at least 15 minutes
until irritation subsides. Get medical attention immediately.
First Aid -Skin Contact: Wash off immediately with soap and plenty of water for at least 15 minutes. Get medical aid if
symptoms persist. Remove and wash contaminated clothing.
First Aid - Inhalation: If inhaled, remove to fresh air. If breathing is difficult, leave the area to obtain fresh air. if
continued breathing difficulty is experienced, get medical attention immediately.
First Aid - Ingestion: If swallowed, DO NOT INDUCE VOMITING. Get medical attention immediately.
Note to Physician: None.
COMMENTS: Call Medical Emergency at 1-800-327-3874 if any irritation or complication arises from any of the above
mutes of entrv.
Page 3 of6
00077095001 English
jSection 5 - Fire Fighting Measures
Extinguishing Media: Carbon Dioxide, Dry Chemical, Foam, Water Fog
Unusual Fire And Explosion Hazards: No special protective measures against fire required.
Special Firefighting Procedures: Wear self-contained breathing apparatus pressure-demand (NiOSH approved or
equivalent) and full protective gear. Use water spray to cool exposed surfaces.
[Section 6 - Accidental Release Measures
Steps To Be Taken If Material Is Released Or Spilled: Wear proper protective equipment as specified in Section 8. Use
absorbent material or scrape up dried material and place in container.
jjSection 7 - Handling And Storage
Handling: KEEP OUT OF REACH OF CHILDREN! DO NOT TAKE INTERNALLY. Avoid breathing vapor and contact
with eyes, skin and clothing. Use only with adequate ventilation. Open all windows and doors or use other means to
ensure cross-ventilation and fresh air entry during application and drying. Odor is not an adequate warning for hazardous
conditions. Wash thoroughly after handling.
Storage: Do not store at temperatures above 120 degrees F. Store containers away from excessive heat and freezing.
Close container after each use. Store away from caustics and oxidizers.
Section 8 - Exposure Controls / Personal Protection
OSHA COL Skn
5MGM3
.imesone 1317-65-3 N.E.
IOMGM3 ,E
fraction]
4808^0-7 HE
iilica,ciystaHine 0.05 MGM3 N.E. N.E. N.E No
MGM3
25 PPM 35 PPM 50 PPM NE.
NE ?
finvl acetate ilK-OS-4 15 PPM
IOPPM NE NE NE,
' TOTM
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7S-07-0 ' RE ?*?br>
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Exposure Notes:
50-00-0 Formaldehyde is a specially regulated substance for which an OSHA chemical-specific exposure standard exits.
Detailed information regarding this substance may be found in 29 CFR 1910.1048. Medical surveillance information
regarding this substance may be found in Appendix C to 29 CFR 1910.1048.
Precautionary Measures: Please refer to other sections and subsections of this MSDS.
Engineering Controls: Good general ventilation should be sufficient to control airborne levels. Ensure adequate
ventilation, especially in confined areas. Local ventilation of emission sources may be necessary to maintain ambient
concentrations below recommended exposure limits.
Respiratory Protection: In case of insufficient ventilation, wear suitable respiratory equipment. A NIOSH-approved air
purifying respirator with an organic vapor cartridge or canister may be necessary under certain circumstances where
airborne concentrations are expected to exceed exposure limits. A respiratory protection program that meets the OSHA
1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use.
Skin Protection: Rubber gloves.
Eye Protection: Goggles or safety glasses with side shields.
00077095001 English Page 4 of 6
Other protective equipment: Not required under normal use.
Hygienic Practices: Wash hands before breaks and at the end of workday. Remove and wash contaminated clothing
before re-use.
Note: An employee's skin exposure to substances having a "YES" in the "SKIN" column in the table above shall be prevented or reduced to the axtanl
necessary under the circumstances tn rough the use of gloves, coveralls, goggles or other appropriate personal protective equipment, engineering controls or work
practices.
| Section 9 - Physical And Chemical Properties
Boiling Range: Not Established Vapor Density: Heavier Than Air
Odor: Very Slight Ammonia Odor Threshold: Not Established
Color: Colored Evaporation Rate: Slower Than n-Butyl Acetate
Not Established 1.5
Solubility in H20: Specific Gravity:
pH:
Freeze Point: Not Established Between 7.0 and 12.9
Vapor Pressure: Not Established Viscosity: Not Established
Physical State: Paste Flammability: Non- Flammable
Flash Point, F: >200F Method: (Seta Closed Cup)
Lower Explosive Limit, %: Not Established Upper Explosive Limit, %:Not Established
When reportea. vapor pressure of this product has been calculated theoretically baaed on its constituent makeup and has not been determined experimentally.
(See section 16 for abbreviation legend)
[ Section 10 - Stability And Reactivity
Conditions To Avoid: Excessive heat and freezing.
Incompatibility: Incompatible with strong bases and oxidizing agents.
Hazardous Decomposition Products: Normal decomposition products, i.e., COx. NOx.
Hazardous Polymerization: Hazardous polymerization will not occur under normal conditions.
Stability: Stable under recommended storage conditions.
Section 11 - Toxicological Information |
Product LC50: Not Established
Product LD50: Not Established
CASRN Chemical Name LD50 LC50
'orniaMehvde Rat-20.1 mz'mS
rc-oo-o
Significant Data with Possible Relevance to Humans: This product contains trace amounts of free formaldehyde.
OSHA and NTP identify formaldehyde as a potential carcinogen. IARC identifies formaldehyde as a human carcinogen.
Formaldehyde has been shown to cause mutations in a variety of in -vitro test systems, the significance of which to
humans is unknown. There should be minimal risk when used with ventilation adequate to keep the atmospheric
concentration of formaldehyde below the recommended exposure limits.
Maintain adequate ventilation to prevent exposure above current OSHA / ACG1H exposure limits. Workplace monitoring of
the air to define formaldehyde exposure levels may be necessary.
0007709500! Knglish
(Section 12 - Ecological Information
Ecological Information: Ecological injuries are not known or expected under normal use.
[Section 13 - Disposal Information
Disposal Information: Dispose of material in accordance with all federal, state and local regulations. State and Local
regulations/restrictions are complex and may differ from Federal regulations. Responsibility for proper waste disposal is
with the owner of the waste.
EPA Waste Code if Discarded (40 CFR Section 261): None.
(Section 14 -Transportation Information
DOT Proper Shipping Not Regulated Packing Group: N.A.
Name:
DOT Technical Name: N.A. Hazard Subclass: N.A.
DOT Hazard Class: N.A, DOT UN/NA Number: None
Note: The shipping information provided is applicable for domestic ground transport only. Different categorization may
apply if shipped via other modes of transportation and/or to non-domestic destinations.
i Section 15 - Regulatory Information
CERCLA - SARA Hazard Category:
This product has been reviewed according to the EPA 'Hazard Categories' promulgated under Sections 311 and 312 of
the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable
definitions, to meet the following categories:
Immediate Health Hazard, Chronic Health Hazard
SARA Section 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the
Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
None
Toxic Substances Control Act:
All ingredients in this product are either on TSCA inventory list, or otherwise exempt,
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported
from the United States:
None
New Jersey Rlght-to-Know:
The following materials are non-hazardous, but are among the top five components in this product:
Chemical Narn^ ~ OAS NmiRT'
0007709500 1 English
Pennsylvania Right -to -Know:
The following non-hazardous ingredients are present in the product at greater than 3%:
California Proposition 65:
WARNING: This product contains chemicals known to the State of California to cause cancer, birth defects or other
reproductive harm.
[Section 16 - Other Information
Health :J Flammability: 1 Reactivity: 0 Personal Proteaion: X
Volatile Organic Compounds (VOC), less water less exempts: g/L 2.4 Ib/gaf: 0.0 wt:wt%: 0.1
Volatile Organic Compounds (VOC), less water less exempts, less LVP-VOCs: wt:wt%: 0.1
REASON FOR REVISION: Periodic Update
Legend: NA -Not Applicable ACGIH -American Conference of Governmental Industrial Hygienists
NE. - Not Established SARA - Superfund Amendments and Reauthorization Act of 19B6
N.D. - Not Determined NJRTK - New Jersey Right-b-Know Law
VOC - Volatile Organic Compound OSHA - Occupational Safety and Health Administration
PEL - Permissible Exposure Limit HMIS - Hazardous Maienals Identification System
TLV - Threshold Limit Value NTP - National Toxicology Program
CEIL-Ceiling Exposure Limit STEL- Short Term Exposure Limit
LD50 - Lethal Dose SO LCSO - Lethal Concentration 50
F - Degree Fahrenheit MSDS - Material Safety Data Sheet
C - Degree Celsius CASRN - The Chemical Abstracts Service Registry Number
DAP believes the data and statements contained herein are accurate as of the date hereof. They are offered in good faith as typical
values and not as a product specification. NO WARRANTY OF MER CHANT ABILITY, WARRANTY OF FITNESS FOR ANY
PARTICULAR PURPOSE OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, IS MADE WITH REGARD TO THE
INFORMATION HEREIN PROVIDED OR THE PRODUCT TO WHICH THE INFORMATION REFERS. Since this
document is intended only as a guide to the appropriate use and precautionary handling of the referenced product by a properly trained
person, il is therefore the responsibility of the user to (i) review the recommendations with due consideration for the specific context
of the intended use and (ii) determine if they are appropriate.
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