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MSDS Material Safety Data Sheet
CAS

107-21-1 25265-77-4

File Name: 107-21-1_25265-77.asp

Material Safety Data Sheet




Metallic StuccoTexTM Coat
Version 1.2 06/28/2006

1. PRODUCT AND COMPANY INFORMATION
BASF CORPORATION
Company :
3550 St. John's Bluff Road, South
Jacksonville, FL 32224

Telephone : 904-996-6000

Emergency telephone number : (800) 424-9300
(703) 527-3887 (Outside Continental US)

Product name : Metallic StuccoTexTM Coat

MSDS ID No. : 11537

TSCA Inventory : All components of this product are included, or are exempt from inclusion, in the EPA
Toxic Substances Control Act (TSCA) Chemical Substance Inventory.

Canadian DSL : All components of this product are included, or are exempt from inclusion, in the
Canadian Domestic Substance List (DSL).

Product Use Description : Coating


2. HAZARDOUS INGREDIENTS
Chemical CAS No. TLV STEL PEL CEIL Weight %
ETHYLENE GLYCOL 107-21-1 N.E. N.E. N.E. 100 mg/m3 1.00 - 5.00 %
ESTER ALCOHOL 25265-77-4 N.E. N.E. N.E. N.E. 1.00 - 5.00 %




3. HAZARDS IDENTIFICATION
PHYSICAL
HMIS?Rating HEALTH FLAMMABILITY HAZARD
1 1 0

WHMIS Class : D2B

Primary Routes of Entry : Inhalation
Skin contact

Effects of Overexposure

Inhalation : Inhalation of high vapor concentrations may cause symptoms like headache, dizziness,
tiredness, nausea and vomiting. Inhalation of high vapor concentrations can cause CNS-
depression and narcosis. Prolonged inhalation can be harmful.

Skin : Prolonged skin contact may defat the skin and produce dermatitis. Prolonged or
repeated exposure can cause skin irritation and redness.

Eyes : Can cause slight irritation.

Ingestion : Can cause slight irritation.
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Material Safety Data Sheet




Metallic StuccoTexTM Coat
Version 1.2 06/28/2006


Chronic exposure : This product contains solvents. Reports associate repeated and prolonged occupational
overexposure to solvents with permanent brain and nervous system damage. Reports
also indicate that solvents cause liver damage, kidney damage, and mucous membrane
irritation. Be warned that intentional misuse by deliberately inhaling the vapors and/or
the product contents (a process often called "sniffing") can be harmful or fatal.

Carcinogenicity
ACGIH IARC NTP OSHA
ETHYLENE GLYCOL Not classifiable as a N.E. N.E. N.E.
human carcinogen.
ESTER ALCOHOL N.E. N.E. N.E. N.E.


4. FIRST AID MEASURES
Eye contact : Flush eyes with water, lifting upper and lower lids occasionally for 15 minutes. Seek
medical attention.

Skin contact : Remove contaminated clothing. Wash thoroughly with soap and water. If irritation
persists seek medical attention. Wash contaminated clothing before reuse.

Ingestion : Do not induce vomiting without medical advice. If conscious, drink plenty of water. If a
person feels unwell or symptoms of skin irritation appear, consult a physician. If a person
vomits, place him/her in the recovery position. Never give anything by mouth to an
unconscious person.

Inhalation : Remove victim from exposure. If difficulty with breathing, administer oxygen. If breathing
has stopped administer artificial respiration, preferably mouth-to-mouth. Seek immediate
medical attention.


5. FIRE-FIGHTING MEASURES
Flash point : > 200.01 癋 (93.34 癈)

Autoignition temperature : no data available

Lower explosion limit : no data available

Upper explosion limit : no data available

Suitable extinguishing media : Carbon dioxide, foam, dry chemical & water fog.

Fire and Explosion Hazards : Containers can build up pressure if exposed to heat (fire). Cool closed containers
exposed to fire with water spray.

Special Fire-fighting Procedures : As in any fire, wear pressure demand self-contained breathing apparatus (NIOSH
approved or equivalent) and full protective gear.


6. ACCIDENTAL RELEASE MEASURES
Methods for cleaning up : Wear appropriate protective equipment (refer to section 8). Take action to eliminate
source of leak; prevent from entry into open streams or sewers; contain spill by diking;
vacuum up liquid or use absorbent media; remove to storage for disposal and rinse
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Material Safety Data Sheet




Metallic StuccoTexTM Coat
Version 1.2 06/28/2006

residual stain with water.


7. HANDLING AND STORAGE
Handling : Use only in area provided with appropriate ventilation. Keep out of reach of children. For
personal protection see section 8.

Storage : Store in cool, dry place. Keep container tightly closed.


8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Eye protection : Wear as appropriate:
safety glasses with side-shields
goggles
face-shield

Hand protection : Wear as appropriate:
Wear Chemically resistant gloves.

Body Protection : Wear as appropriate:
impervious clothing
preventive skin protection

Respiratory protection : In case of insufficient ventilation wear suitable respiratory equipment. When workers are
facing concentrations above the exposure limit they must use NIOSH approved
respirators.

Hygienic Practices : Avoid contact with skin, eyes and clothing. Ensure adequate ventilation, especially in
confined areas. Wash hands before breaks and at the end of workday. When using, do
not eat, drink or smoke. Handle in accordance with good industrial hygiene and safety
practice.

Engineering Controls : Local exhaust ventilation can be necessary to control any air contaminants to within their
TLVs during the use of this product.


9. PHYSICAL AND CHEMICAL PROPERTIES
Color : pigmented

Physical State : liquid

Odor : slight ammoniacal

pH : 9 - 10

Odor Threshold : no data available

Vapor Pressure : no data available

Vapor Density : no data available

Boiling point/range : no data available

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Material Safety Data Sheet




Metallic StuccoTexTM Coat
Version 1.2 06/28/2006

Freeze Point : no data available

Water solubility : dilutable

Specific Gravity : 1.814

Viscosity : 105 - 115 KREB

Evaporation rate : Slower than Butyl acetate

Partition coefficient (n- : no data available
octanol/water)

VOC Concentration as applied : 160 g/l
(less water and exempt
solvents)


10. STABILITY AND REACTIVITY
Stability : Stable under recommended storage conditions.

Conditions to avoid : Prolonged exposure to high temperatures


Materials to avoid : Strong mineral acids, Lewis acids, oxidizing agents, strong bases.


Hazardous decomposition : Oxides of carbon
products nitrogen oxides (NOx)


Hazardous polymerization : Will not occur under normal conditions.


11. TOXICOLOGICAL INFORMATION
Acute inhalation toxicity
Type Value Species Exposure time
Product LC50 no data available

Component

ETHYLENE GLYCOL LC50 no data available
ESTER ALCOHOL LC50 no data available


Acute oral toxicity
Type Value Species
Product LD50 (Oral) no data available

Component



Page 4 of 6
Material Safety Data Sheet




Metallic StuccoTexTM Coat
Version 1.2 06/28/2006

ETHYLENE GLYCOL LD50 (Oral) 4,700 mg/kg rat
ESTER ALCOHOL LD50 (Oral) no data available


Acute dermal toxicity
Type Value Species

Product LD50 (Dermal) no data available

Component

ETHYLENE GLYCOL LD50 (Dermal) no data available
ESTER ALCOHOL LD50 (Dermal) no data available



12. ECOLOGICAL INFORMATION
Ecotoxicological Information : There is no data available for this product.


13. DISPOSAL CONSIDERATIONS
Recommendations: Use excess product in an alternate beneficial application. Handle disposal of waste
material in manner which complies with local, state, province and federal regulation.


14. TRANSPORT INFORMATION
DOT : Proper shipping name Not regulated

IATA : Proper shipping name Not regulated


15. REGULATORY INFORMATION
SARA 311/312 (RTK)
This product has been reviewed according to the EPA 'Hazard Categories' promulgated under Sections 311 and 312 of the
Superfund Amendments and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to
meet the following categories:

IMMEDIATE (ACUTE) HEALTH HAZARD DELAYED (CHRONIC) HEALTH HAZARD


SARA 313
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the
Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372:

Weight % CAS No. Chemical Name
1.00 - 5.00 % 107-21-1 ETHYLENE GLYCOL


CERCLA
CERCLA section 103(a) specifically requires the person in charge of a vessel or facility to report immediately to the National
Page 5 of 6
Material Safety Data Sheet




Metallic StuccoTexTM Coat
Version 1.2 06/28/2006

Response Center (NRC) a release of a hazardous substance whose amount equals or exceeds the assigned RQ. The
following hazardous substances are contained in this product.

RQ CAS No. Chemical Name
5,000 lbs 107-21-1 ETHYLENE GLYCOL


TSCA Section 12(b) Export Notification
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(b) if exported from
the United States:

CAS No. Chemical Name

There are no TSCA 12(b) Chemicals in this product.


California Proposition 65
The chemical(s) noted below and contained in this product, are known to the state of California to cause cancer, birth defects
or other reproductive harm. Unless otherwise specified in Section 2 of this MSDS, these chemicals are present at < 0.1%:

CAS No. Chemical Name
75-07-0 ACETALDEHYDE
75-21-8 ETHYLENE OXIDE
123-91-1 DIOXANE


16. OTHER INFORMATION
Legend : N.E. - Not Established
TLV - Threshold Limit Value
STEL - Short Term Exposure Limit
PEL - Permissible Exposure Limit
CEIL - Ceiling

Prepared By : Environment, Health and Safety Department


This information is furnished without warranty, representation, or license of any kind, except that this information is accurate to the
best of the manufacturer's knowledge, or is obtained from sources believed by the manufacturer to be accurate and is not intended
to be all inclusive. No warranty is expressed or implied regarding the accuracy of this information or the results to be obtained from
its use thereof. The manufacturer assumes no responsibility for injuries proximately caused by use of the Material if reasonable
safety procedures are not followed as stipulated in this Data Sheet. Additionally, the manufacturer assumes no responsibility for
injuries proximately caused by abnormal use of the Material even if reasonable safety procedures are followed. Buyer assumes the
risk in its use of the Material.

End of MSDS.




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