Material Safety Data Sheet
MSDS ID: WT-282
* * * Section 1 - Chemical Product and Company Identification * * *
Product Name: PRAESTOL CM 262
Chemical Name: Anionic emulsion copolymer
Manufacturer Information
Emergency Telephone Number: 1-800-ASHLAND (1-800-274-5263)
Ashland, Inc.
24-hours everyday
P.O. Box 2219 Regulatory Information Number: 1-800-325-3751
Phone: Non-emergency # (800) 242-2271
Columbus, OH 43216
(614) 790-3333
General Comments
Emergency telephone numbers are to be used only in the event of chemical emergencies involving a spill, leak,
fire, exposure or accident involving the product. All Non-emergency questions should be directed to the Toll Free,
Non-Emergency number above.
* * * Section 2 - Hazards Identification * * *
Emergency Overview
Irritant to eyes and skin. Inhalation of heated vapors may irritate the respiratory tract.
Potential Health Effects: Eyes
Irritant
Potential Health Effects: Skin
Irritant
Potential Health Effects: Ingestion
May be harmful if swallowed. Seek medical attention.
This material can get into the lungs during swallowing or vomiting. This results in lung inflammation and other
lung injury.
Potential Health Effects: Inhalation
Avoid prolonged inhalation of heated and/or concentrated vapors.
HMIS Ratings: Health: 1 Fire: 1 Reactivity: 0 Pers. Prot.: B
Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe * = Chronic hazard
* * * Section 3 - Composition / Information on Ingredients * * *
CAS # Component Percent
25085-02-3 2-Propenoic acid, sodium salt, polymer with 2-propenamide 30-40
64742-47-8 Petroleum distillates, hydrotreated light 20-30
Poly(oxy-1,2-ethanediyl), -(4-nonylphenyl)--hydroxy-,branched
127087-87-0 1-3
Component Information/Information on Non-Hazardous Components
This product does not contain any components considered to health hazards under 29 CFR 1910.1200 and 49
CFR.
甊egistered trademark, Ashland
Page 1 of 6 Issue Date: 05/10/06 Rev: 1.0000 Print Date: 6/1/2006
Material Safety Data Sheet
PRAESTOL CM 262 MSDS ID: WT-282
* * * Section 4 - First Aid Measures * * *
First Aid: Eyes
Immediately flush eyes with water for at least 15 minutes, while holding eyelids open. Seek medical attention.
First Aid: Skin
Flush thoroughly with water.
First Aid: Ingestion
If ingested, get immediate medical attention. Do not induce vomiting unless instructed to do so by medical
personnel.
First Aid: Inhalation
Inhalation of mists into lungs may cause pulmonary disorder. Move victim to fresh air. Consult physician regarding
any continued discomfort.
* * * Section 5 - Fire Fighting Measures * * *
General Fire Hazards
Petroleum hydrocarbon component, if separated from product, is combustible. Vapors can ignite explosively.
Flashpoint of product > 200oF.
Upper Flammable Limit (UFL): Not determined
Lower Flammable Limit (LFL): Not determined
Method Used: Pensky Marten Closed Cup (PMCC)
Flash Point: >200oF
Flammability Classification: Not determined
Auto Ignition: Not determined
Hazardous Combustion Products
On thermal decomposition oxides of carbon and nitrogen.
Extinguishing Media
Dry chemical, foam, carbon dioxide, water fog.
Fire Fighting Equipment/Instructions
Firefighters should wear full protective clothing including self contained breathing apparatus.
NFPA Ratings: Health: 1 Fire: 1 Reactivity: 0
Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe
* * * Section 6 - Accidental Release Measures * * *
Containment Procedures
Remove sources of ignition. Contain spill with inert materials (sand, earth, absorbent). Wear protective gear
during cleanup.
Clean-Up Procedures
Do not allow spills to enter soil or surface water. Absorb spill with inert material. Shovel material into appropriate
container for disposal. Remove sources of ignition.
Evacuation Procedures
Isolate area. Keep unnecessary personnel away.
Special Procedures
Avoid skin contact and inhalation of vapors during disposal of spills. Wear appropriate protective equipment and
clothing during clean-up. Follow all local, state, federal and provincial regulations for disposal.
____________________________________________________________
Page 2 of 6 Issue Date: 05/10/06 Rev: 1.0000 Print Date: 6/1/2006
Material Safety Data Sheet
PRAESTOL CM 262 MSDS ID: WT-282
* * * Section 7 - Handling and Storage * * *
Handling Procedures
Handle as an eye and respiratory tract irritant.
Storage Procedures
Store in a dry, closed container.
* * * Section 8 - Exposure Controls / Personal Protection * * *
Component Exposure Limits
Petroleum distillates, hydrotreated light (64742-47-8)
ACGIH: 200 mg/m3 TWA (application restricted to conditions in which there are negligible
aerosol exposures)
Engineering Controls
Provide adequate ventilation to minimize worker exposure.
PERSONAL PROTECTIVE EQUIPMENT
Personal Protective Equipment: Eyes/Face
Wear safety glasses with side shields or goggles.
Personal Protective Equipment: Skin
Skin contact should be minimized. Impervious gloves (rubber or neoprene) are recommended.
Personal Protective Equipment: Respiratory
Not required under normal operating conditions.
Personal Protective Equipment: General
Obey reasonable safety precautions and practice good housekeeping. Wash thoroughly after handling.
* * * Section 9 - Physical & Chemical Properties * * *
Off color liquid Mild hydrocarbon odor
Appearance: Odor:
Liquid Not Established
Physical State: pH:
Not Established Not Established
Vapor Pressure: Vapor Density:
Not Established Not applicable
Boiling Point: Melting Point:
Emulsion- soluble in water. ~1 (water = 1)
Solubility (H2O): Specific Gravity:
> 200oF (PMCC)
<1 (butyl acetate =1)
Evaporation Rate: Flash Point
* * * Section 10 - Chemical Stability & Reactivity Information * * *
Chemical Stability
Stable under usual application conditions.
Chemical Stability: Conditions to Avoid
None identified.
Incompatibility
Strong oxidizers.
Hazardous Decomposition
None identified.
____________________________________________________________
Page 3 of 6 Issue Date: 05/10/06 Rev: 1.0000 Print Date: 6/1/2006
Material Safety Data Sheet
PRAESTOL CM 262 MSDS ID: WT-282
Hazardous Polymerization
Hazardous polymerization will not occur.
* * * Section 11 - Toxicological Information * * *
Acute and Chronic Toxicity
A: General Product Information
Eye and skin irritant. May aggravate existing medical conditions such as rashes, allergies or other sensitive areas.
Symptoms may include reddening, swelling of affected areas with possible itching, burning or other discomfort.
B: Acute Toxicity-LD50/LC50
LC 50: Ceriodaphnia dubia
48 hours: 11.0 ppm
LC 50 Pimphales promelas
48 hours 31.4 ppm
Carcinogenicity
A: General Product Information
NTP: No
IARC: No
OSHA: No
B: Component Carcinogenicity
Petroleum distillates, hydrotreated light (64742-47-8)
ACGIH: A3 - Animal Carcinogen (as total hydrocarbon vapor)
* * * Section 12 - Ecological Information * * *
Ecotoxicity - Aquatic Toxicity
C.O.D.: 2,176,000 mg/l
B.O.D.: 548,000 mg/l
Environmental Fate
Not Established.
* * * Section 13 - Disposal Considerations * * *
US EPA Waste Number & Descriptions
A: General Product Information
Incinerate or dispose of solidified product according to local, state and federal regulations.
B: Component Waste Numbers
No EPA Waste Numbers are applicable for this product's components.
Disposal Instructions
Contain and collect using absorbent material if needed. Flush residuals to drain for normal biological treatment.
Place collected material into suitable containers for proper disposal.
____________________________________________________________
Page 4 of 6 Issue Date: 05/10/06 Rev: 1.0000 Print Date: 6/1/2006
Material Safety Data Sheet
PRAESTOL CM 262 MSDS ID: WT-282
* * * Section 14 - Transportation Information * * *
International Transportation Regulations
This product is not regulated as a hazardous material by the United States (DOT) or Canadian (TDG)
transportation regulations.
* * * Section 15 - Regulatory Information * * *
US Federal Regulations
A: General Product Information
None identified.
B: Clean Air Act
No information is available.
C: Component Analysis
No information is available.
State Regulations
Component Analysis - State
This product contains <0.1% residual acrylamide (CAS # 79-06-1), and the following states recognize acrylamide
as a carcinogen or suspected carcinogen: CA (Prop 65), MA, MN, NJ & PA.
California Proposition 65
The following statement is made in order to comply with the California Safe Drinking Water and Toxic
enforcement Act of 1986: This product contains the following substance(s) known to the state of
California to cause cancer:
Component CAS #
Acrylamide 79-06-1
1,4-Dioxane 123-91-1
Acetaldehyde 75-07-0
Formaldehyde 50-00-0
Ethylene oxide 75-21-8
The following statement is made in order to comply with the California Safe Drinking water and Toxic
Enforcement Act of 1986: This product contains the following substance(s) known to the State of
California to cause reproductive harm:
Component CAS #
Ethylene oxide 75-21-8
New Jersey RTK Label Information
Acrylamide 79-06-1
1,4-Dioxane 123-91-1
Acetaldehyde 75-07-0
Formaldehyde 50-00-0
Ethylene oxide 75-21-8
Pennsylvania RTK Label information
Acrylamide 79-06-1
1,4-Dioxane 123-91-1
Acetaldehyde 75-07-0
Formaldehyde 50-00-0
Ethylene oxide 75-21-8
____________________________________________________________
Page 5 of 6 Issue Date: 05/10/06 Rev: 1.0000 Print Date: 6/1/2006
Material Safety Data Sheet
PRAESTOL CM 262 MSDS ID: WT-282
Component Analysis - WHMIS IDL
No components are listed in the WHMIS IDL.
Component Analysis - Inventory
Component CAS # TSCA CAN EEC
2-Propenoic acid, sodium salt, polymer with 2- 25085-02-3 Yes DSL Not regulated as
propenamide a polymer
Petroleum distillates, hydrotreated light 64742-47-8 Yes DSL EINECS
Poly(oxy-1,2-ethanediyl), -(4-nonylphenyl)--hydroxy- 127087-87-0 Yes DSL Not regulated as
a polymer
,branched
* * * Section 16 - Other Information * * *
Other Information
The information accumulated herein is believed to be accurate but is not warranted to be whether originating with
the company or not. Recipients are advised to confirm in advance of need that the information is current,
applicable and suitable to their circumstances.
This is the end of MSDS ID: WT-282
____________________________________________________________
Page 6 of 6 Issue Date: 05/10/06 Rev: 1.0000 Print Date: 6/1/2006
|