Lilly Miller Microcop Fungicide; Lilly Miller Sta-Stuk "m"
Lilly Miller Brands
Health Hazard 1
0
Fire Hazard 0
MATERIAL SAFETY DATA SHEET 0 0
Reactivity 0
Personal Protection A
HMIS RATING NFPA RATING
SECTION I - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Trade Name: Lilly Miller Microcop Fungicide MSDS Number: LM-025
Generic Name: Garden fungicide EPA Reg. No.: 802-12
Manufacturer: Lilly Miller Brands Revision Number: New
16201 SE 98th Avenue Date Issued: June 22, 2001
Address:
Clackamas, OR 97015 Manufacturer's Phone Number: 503-650-4400
COMPOSITION/INFORMATION ON INGREDIENTS
SECTION II -
Chemical Name CAS Number % TLV PEL
10 mg/m3 15 mg/m3
Copper sulfate 7758-98-7 95
10 mg/m3(PNOC) 15 mg/m3(PNOR)
Clay None 3
Lignosulfonic acid 8062-15-5 2
Key: TLV = ACGIH, 8 hr. time weighted average (TWA); PEL = OSHA permissible exposure limit.
PNOC = Particulates Not Otherwise Classified (ACGIH - Inhalable)
PNOR = Particulates Not Otherwise Regulated (OSHA - Total dust)
SECTION III - HAZARDS IDENTIFICATION
Emergency Overview: This product represents a minimal risk to health under recommended application
conditions. Wash hands and exposed skin with soap and water after using this product.
Health: 1 Fire: 0 Reactivity: 0 Personal Protection: A
HMIS Rating:
Potential Health Effects:
Routes of Entry: Inhalation, skin contact, eye contact, ingestion.
Inhalation: Overexposure to dust or mists may cause transitory upper respiratory irritation.
Skin Contact: May cause itching and irritation.
Eye Contact: Dusts and mists may cause stinging and irritation. Can cause substantial but temporary injury to
the eye.
Ingestion: Ingestion of large quantities may be irritating to the G.I. system.
Medical Conditions Aggravated by Exposure: May aggravate pre-existing respiratory conditions.
Carcinogenicity: Not listed by NTP or IARC. Not regulated as a carcinogen by OSHA.
Revised: June 22, 2001 Page 1 of 4
Lilly Miller Microcop Fungicide; Lilly Miller Sta-Stuk "m"
SECTION IV - FIRST AID MEASURES
Inhalation: Move to an area free from risk of further exposure. Treat symptomatically if required. No adverse
effects anticipated by this route of exposure incidental to proper handling.
Eye Contact: Flush with clean, lukewarm water at low pressure. Seek medical attention if irritation persists.
Skin Contact: Wash affected areas thoroughly with soap and warm water immediately after use of this product.
Ingestion: Ingestion of large quantities may be irritating to the GI tract, drink 1 to 2 glasses of water and induce
vomiting by touching back of throat with finger.
SECTION V - FIREFIGHTING MEASURES
Health: 0 Fire: 0 Reactivity: 0 Other: 0
NFPA Rating:
Flash point and Method: This product is non-flammable.
Extinguishing Method: Not required.
Fire or Explosion Hazards: This product will not burn.
Special Firefighting Procedures: Not applicable.
SECTION VI - ACCIDENTAL RELEASE MEASURES
Clean-up Procedures: Pick up or shovel material into waste container taking care to minimize dust. Wet down if
necessary to control dust. Vacuum clean dust.
Personal Precautions: If dusty conditions exist, wear a face mask approved for use with dusts such as 3M 8511
N-95 or equivalent.
Environmental Precautions: This pesticide is toxic to fish and aquatic organisms. Dike as necessary to keep spills
from entering lakes and waterways.
SECTION VII - HANDLING AND STORAGE
Storage Temperature: Not affected by extremes of ambient temperature.
Shelf Life: Indefinite.
Special Sensitivity: None.
Handling and Storage Precautions: Avoid eye contact and avoid breathing dusts if generated. Good
housekeeping is recommended to prevent the accumulation of dust.
SECTION VIII - EXPOSURE CONTROLS/PERSONAL PROTECTION
Respiratory Protection: If dusty conditions exist, wear a face mask approved for use with dusts such as 3M 8511
N-95 or equivalent.
Eye Protection: Use safety glasses if there is potential for exposure to particles which could cause mechanical
injury to the eyes.
Skin Protection: None needed under normal conditions of use.
Engineering Controls: Product is to be used out of doors.
Revised: June 22, 2001 Page 2 of 4
Lilly Miller Microcop Fungicide; Lilly Miller Sta-Stuk "m"
SECTION IX - PHYSICAL AND CHEMICAL PROPERTIES
Physical Form: Bluish powder.
Odor: Negligible Specific Gravity: N/D
Bulk Density: N/D pH: N/D
Solubility in Water: Suspended solution % Volatile by Weight (VOC): Nil
SECTION X - REACTIVITY
Stability : This is stable material.
Hazardous Polymerization: Will not occur.
Incompatibilities: None in designed use.
Decomposition Products: CO, CO2, irritating hydrocarbon particulate.
SECTION XI - TOXICOLOGICAL/ECOLOGICAL INFORMATION
Ecological Concerns: Lilly Miller Microcop Fungicide is a general purpose garden fungicide. This product is
toxic to fish and aquatic organisms. Dike as necessary to keep spills from entering lakes and waterways.
SECTION XII - DISPOSAL CONSIDERATIONS
Waste Disposal Method: This material is a general purpose garden fungicide and may be disposed of by applying
in accordance with manufacturer's recommendations. Keep wastes out of rivers, lakes and streams.
SECTION XIII - TRANSPORTATION INFORMATION
DOT Shipping Name: Not regulated DOT Label: None
Technical Shipping Name: None DOT Placard: None
DOT Hazard Class: None UN/NA Number: None
SECTION XIV - REGULATORY INFORMATION
OSHA Status: This product is regulated under OSHA criteria as a nuisance dust.
EPA Reg. No.: 802-12
TSCA Status: All applicable chemicals are registered under TSCA.
CERCLA Reportable Quantity: Not regulated under CERCLA.
SARA Title III: Not regulated under SARA Title III.
Section 302, Extremely Hazardous: N/A
Section 311/312 Hazard Categories: N/A.
Section 313 Toxic Chemicals: N/A
RCRA Status: Not regulated under RCRA
Revised: June 22, 2001 Page 3 of 4
Lilly Miller Microcop Fungicide; Lilly Miller Sta-Stuk "m"
SECTION XV - APPROVALS
Reason for issue: New MSDS Approval Date: June 22, 2001
Prepared by: Compliance Consulting Group, Inc. Supersedes Date None
303-795-2060
SECTION XVI - DISCLAIMER
As of the date of this document, the foregoing information is believed to be accurate and is provided in good faith to
comply with applicable federal and state laws. However, no warranty or representation of law or fact, with respect
to such information, is intended or given.
Revised: June 22, 2001 Page 4 of 4
Lilly Miller Microcop Fungicide; Lilly Miller Sta-Stuk "m"
Lilly Miller Brands
Health Hazard 0
0
Fire Hazard 0
MATERIAL SAFETY DATA SHEET 0 0
Reactivity 0
Personal Protection A
HMIS RATING NFPA RATING
SECTION I - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Trade Name: Lilly Miller Sta-Stuk "m" MSDS Number: LM-026
Generic Name: Adhesion enhancer Revision Number: New
Manufacturer: Lilly Miller Brands Date Issued: June 22, 2001
16201 SE 98th Avenue Manufacturer's Phone Number: 503-650-4400
Address:
Clackamas, OR 97015
COMPOSITION/INFORMATION ON INGREDIENTS
SECTION II -
Chemical Name CAS Number % TLV PEL
5 mg/m3 5 mg/m3
Potassium resinate mixture 12
Propylene glycol 57-55-6 10 N/A N/A
Potassium oleate 143-18-0 3 N/A N/A
Water 7732-18-5 75 N/A N/A
Key: Exposure limits are for oil mists or aerosols. TLV = ACGIH, 8 hr. time weighted average (TWA); PEL = OSHA
permissible exposure limit.
SECTION III - HAZARDS IDENTIFICATION
Emergency Overview: This product presents a minimal risk to health. Wash hands and exposed skin with soap
and water after using this product.
Health: 0 Fire: 0 Reactivity: 0 Personal Protection: A
HMIS Rating:
Potential Health Effects:
Routes of Entry: Inhalation, skin contact, eye contact, ingestion.
Inhalation: Overexposure to mist may cause transitory upper respiratory irritation.
Skin Contact: Essentially non-irritating to the skin.
Eye Contact: Hazard to the eye is dependent upon the material with which this product is mixed.
Ingestion: Ingestion of large quantities may be irritating to the G.I. system.
Medical Conditions Aggravated by Exposure: Mists may aggravate pre-existing respiratory conditions.
Carcinogenicity: Not listed by NTP or IARC. Not regulated as a carcinogen by OSHA.
Revised: June 22, 2001 Page 5 of 4
Lilly Miller Microcop Fungicide; Lilly Miller Sta-Stuk "m"
SECTION IV - FIRST AID MEASURES
Inhalation: Move to an area free from risk of further exposure. Treat symptomatically if required. No adverse
effects anticipated by this route of exposure incidental to proper handling.
Eye Contact: Flush with copious quantities of clean, lukewarm water at low pressure for at least 15 minutes. Seek
medical attention if irritation persists.
Skin Contact: Wash affected areas thoroughly with soap and warm water immediately after use of this product.
Ingestion: Ingestion of large quantities may be irritating to the GI tract, requiring symptomatic treatment.
SECTION V - FIREFIGHTING MEASURES
Health: 0 Fire: 0 Reactivity: 0 Other: 0
NFPA Rating:
Flash point and Method: Non-flammable
Lower Flammable Limit: N/A Upper Flammable Limit: N/A
Extinguishing Method: Foam, water spray, dry chemical, carbon dioxide.
Hazardous products of combustion: Fumes, smoke, carbon monoxide and particulate.
Special Firefighting Procedures: None for household quantities of this product.
SECTION VI - ACCIDENTAL RELEASE MEASURES
Clean-up Procedures: Wipe up material and place into waste container.
Personal Precautions: Wear gloves.
Environmental Precautions: Keep major spills from entering lakes and waterways.
SECTION VII - HANDLING AND STORAGE
Storage Temperature: Not affected by extremes of ambient temperature.
Shelf Life: Not determined.
Special Sensitivity: None.
Handling and Storage Precautions: No special requirements.
SECTION VIII - EXPOSURE CONTROLS/PERSONAL PROTECTION
Respiratory Protection: If misty conditions exist, wear a face mask approved for use with dusts and mists such as
3M 8511 N-95 or equivalent.
Eye Protection: Use safety glasses if there is potential for exposure to splashes or mists which could cause
irritation of the eyes.
Skin Protection: None needed under normal conditions of use.
Engineering Controls: Product is to be used out of doors with good general ventilation.
Revised: June 22, 2001 Page 6 of 4
Lilly Miller Microcop Fungicide; Lilly Miller Sta-Stuk "m"
SECTION IX - PHYSICAL AND CHEMICAL PROPERTIES
Physical Form: Pale yellow/ brown viscous liquid. Specific Gravity: Approx. 1.0
Vapor Pressure: N/A pH: essentially neutral
Solubility in Water: Soluble % Volatile by Weight (VOC): Nil
SECTION X - REACTIVITY
Stability : This is stable material.
Hazardous Polymerization: Will not occur.
Incompatibilities: None in designed use.
Decomposition Products: CO, CO2, irritating particulate.
SECTION XI - TOXICOLOGICAL/ECOLOGICAL INFORMATION
Ecological Concerns: Lilly Miller Sta-Stuk "m" represents a minimal ecological hazard.
SECTION XII - DISPOSAL CONSIDERATIONS
Waste Disposal Method: This material is a non hazardous sticking agent used to enhance the adhesion and
longevity of Lilly Miller Microcop Fungicide and may be disposed of by applying to trees and shrubs in accordance
with manufacturer's recommendations.
SECTION XIII - TRANSPORTATION INFORMATION
DOT Shipping Name: Not regulated DOT Label: None
Technical Shipping Name: None DOT Placard: None
DOT Hazard Class: None UN/NA Number: None
SECTION XIV - REGULATORY INFORMATION
OSHA Status: This product is regulated under OSHA criteria.
TSCA Status: All applicable chemicals are registered under TSCA.
CERCLA Reportable Quantity: Not regulated under CERCLA.
SARA Title III: Not regulated under SARA Title III.
Section 302, Extremely Hazardous: N/A
Section 311/312 Hazard Categories: N/A.
Section 313 Toxic Chemicals: N/A
RCRA Status: Not regulated under RCRA
Revised: June 22, 2001 Page 7 of 4
Lilly Miller Microcop Fungicide; Lilly Miller Sta-Stuk "m"
SECTION XV - APPROVALS
Reason for issue: New MSDS Approval Date: June 22, 2001
Prepared by: Compliance Consulting Group, Inc. Supersedes Date None
303-795-2060
SECTION XVI - DISCLAIMER
As of the date of this document, the foregoing information is believed to be accurate and is provided in good faith to
comply with applicable federal and state laws. However, no warranty or representation of law or fact, with respect
to such information, is intended or given.
Revised: June 22, 2001 Page 8 of 4
|