Bayer Environmental Science
Material Safety Data Sheet MSDS Number: 102000012056
MSDS Version 2.0
CHIPCO 26019 FLO BRAND FUNGICIDE
Revision Date: 07/05/2006
SECTION 1. CHEMICAL PRODUCT AND COMPANY INFORMATION
CHIPCO 26019 FLO BRAND FUNGICIDE
Product Name
102000012056
MSDS Number
432-888
EPA Registration No.
A fungicide for the prevention and control of certain diseases of turfgrass and
Product Use
ornamentals. Not for residential use.
Bayer Environmental Science
2 T.W. Alexander Drive
Research Triangle PK, NC 27709
USA
For MEDICAL, TRANSPORTATION or other EMERGENCY call: 1-800-334-7577 (24 hours/day)
For Product Information call: 1-800-331-2867
SECTION 2. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous Component Name CAS-No. Average % by Weight
Iprodione 36734-19-7 23.30
1,2-Propanediol 57-55-6
SECTION 3. HAZARDS IDENTIFICATION
NOTE: Please refer to Section 11 for detailed toxicological information.
Caution! Harmful if swallowed, inhaled or absorbed through the skin. Avoid
Emergency Overview
contact with skin, eyes and clothing. Avoid breathing spray mist.
aromatic
Odor
white
Appearance
Eye contact, Ingestion, Inhalation, Skin contact
Routes of Exposure
Immediate Effects
May cause eye irritation. Do not get in eyes.
Eye
May cause skin irritation. Harmful if absorbed through skin.
Skin
Harmful if swallowed. May cause nausea, vomiting, abdominal pain, loss of
Ingestion
coordination.
Harmful if inhaled. May cause upper respiratory tract irritation.
Inhalation
Page 1 of 8 Bayer Environmental Science
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CropScience
Bayer Environmental Science
Material Safety Data Sheet MSDS Number: 102000012056
MSDS Version 2.0
CHIPCO 26019 FLO BRAND FUNGICIDE
Skin contact may aggravate existing skin disease. Inhalation of product may
Medical Conditions
aggravate existing chronic respiratory problems such as asthma, emphysema or
Aggravated by Exposure
bronchitis.
SECTION 4. FIRST AID MEASURES
When possible, have the product container or label with you when calling a
General
poison control center or doctor or going for treatment.
Hold eye open and rinse slowly and gently with water for 15-20 minutes.
Eye
Remove contact lenses, if present, after the first 5 minutes, then continue rinsing
eye. Call a physician or poison control center immediately.
Wash off immediately with plenty of water for at least 15 minutes. Take off
Skin
contaminated clothing and shoes immediately. Call a physician or poison control
center immediately.
Call a physician or poison control center immediately. Rinse out mouth and give
Ingestion
water in small sips to drink. DO NOT induce vomiting unless directed to do so by
a physician or poison control center. Never give anything by mouth to an
unconscious person. Do not leave victim unattended.
Move to fresh air. If person is not breathing, call 911 or an ambulance, then give
Inhalation
artificial respiration, preferably mouth-to-mouth if possible. Call a physician or
poison control center immediately.
Notes to Physician
May pose an aspiration pneumonia hazard.
Hazards
There is no specific antidote. Appropriate supportive and symptomatic treatment
Treatment
as indicated by the patient's condition is recommended.
SECTION 5. FIRE FIGHTING MEASURES
65.5 癈 / 149.9 癋
Flash Point
2.6 %(V)
Lower Flammability
Limit
12 %(V)
Upper Flammability Limit
Under fire conditions, toxic, corrosive fumes are emitted.
Fire and Explosion
Hazards
Extinguishing media - small fires, dry chemical, carbon dioxide (CO2)
Suitable Extinguishing
Media
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Bayer Environmental Science
Material Safety Data Sheet MSDS Number: 102000012056
MSDS Version 2.0
CHIPCO 26019 FLO BRAND FUNGICIDE
Extinguishing media - large fires, foam, water spray
Keep unnecessary people away, isolate hazard area and deny entry. Dike area
Fire Fighting
to prevent runoff and contamination of water sources. Keep out of smoke. Fight
Instructions
fire from upwind position.
Equipment or materials involved in pesticide fires may become contaminated.
Collect contaminated fire extinguishing water separately. This must not be
discharged into drains.
Firefighters should wear NIOSH approved self-contained breathing apparatus
and full protective clothing.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Avoid contact with spilled product or contaminated surfaces. Isolate hazard area.
Personal Precautions
Keep unauthorized people away. Refer to protective measures listed in sections
7 and 8.
Dike area to prevent runoff and contamination of water sources. Clean up
Methods for Cleaning Up
immediately, observing precautions outlines in Section 8. Take up with
absorbent material (e.g. sand, diatomaceous earth or a proprietary absorbent
material). Place in a container for disposal. Clean contaminated floors and
objects thoroughly, observing environmental regulations.
Contaminated soil may have to be removed and disposed. Place contaminated
Additional Advice
material in appropriate container for disposal. Information regarding waste
disposal, see section 13. Do not allow product to contact vegetation. Do not
allow product to enter streams, sewers or other waterways. Contact Bayer for
further assistance if necessary.
SECTION 7. HANDLING AND STORAGE
Handle and open container in a manner as to prevent spillage.
Handling Procedures
Keep product and empty container away from heat and sources of ignition. Store
Storing Procedures
in an area away from food, feedstuffs, fertilizers and seed.
Handle in accordance with good industrial hygiene and safety practice. Wash
Work/Hygienic
hands thoroughly with soap and water after handling and before eating, drinking,
Procedures
chewing gum, using tobacco, using the toilet or applying cosmetics. Remove
clothing immediately if pesticide gets inside. Then wash thoroughly and put on
clean clothing.
SECTION 8. EXPOSURE CONTROLS / PERSONAL PROTECTION
These recommendations provide general guidance for handling this product.
General Protection
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Bayer Environmental Science
Material Safety Data Sheet MSDS Number: 102000012056
MSDS Version 2.0
CHIPCO 26019 FLO BRAND FUNGICIDE
Because specific work environments and material handling practices vary, safety
procedures should be developed for each intended application. While developing
safe handling procedures, do not overlook the need to clean equipment and
piping systems for maintenance and repairs. Waste resulting from these
procedures should be handled in accordance with Section 13: Disposal
Considerations.
Follow manufacturer's instructions for cleaning/maintaining PPE. If no such
instructions for washables, use detergent and warm/tepid water. Keep and wash
PPE separately from other laundry.
Use only with adequate ventilation/personal protection. See below for any
Engineering Controls
OSHA/ACGIH exposure limits.
Safety glasses with side-shields
Eye/Face Protection
Wear suitable gloves.
Hand Protection
Wear long-sleeved shirt and long pants and shoes plus socks.
Body Protection
When respirators are required, select NIOSH approved equipment based on
Respiratory Protection
actual or potential airborne concentrations and in accordance with the
appropriate regulatory standards and/or Industry recommendations.
Exposure Limits
This product contains material which are Trade Secret and may have
Occupational Exposure Limits. If more information is required, call the product
information number listed in Section 1.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
white
Appearance
aromatic
Odor
4.5 - 7.5
pH
1.03 at 20 癈
Specific Gravity
100 癈 / 212 癋
Boiling Point
dispersible
Water Solubility
SECTION 10. STABILITY AND REACTIVITY
Stable under recommended storage conditions.
Chemical Stability
Heat, flames and sparks.
Conditions to Avoid
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Bayer Environmental Science
Material Safety Data Sheet MSDS Number: 102000012056
MSDS Version 2.0
CHIPCO 26019 FLO BRAND FUNGICIDE
Exposure to open flame.
Static electricity.
elevated temperatures
strong bases
Incompatibility
strong acids
strong oxidizing agents
Thermal decomposition
Hazardous
nitrogen oxides (NOx)
Decomposition Products
Sulphur oxides
hydrogen chloride (HCl)
SECTION 11. TOXICOLOGICAL INFORMATION
Acute toxicity data has been bridged froma a very similar formulation containing a similar percentage of the
active ingredient, Iprodione. The non-acute information pertains to the technical-grade active ingredient.
male rat: LD50: > 5,000 mg/kg
Acute Oral Toxicity
female rat: LD50: 4,619 mg/kg
male/female rat: LD50: > 2,000 mg/kg
Acute Dermal Toxicity
male/female rat: LC50: > 0.8 mg/l
Acute Inhalation Toxicity
Exposure time: 4 h
Determined in the form of liquid aerosol.
Maximum attainable concentration.
No deaths
(actual)
male/female rat: LC50: > 3.2 mg/l
Exposure time: 1 h
Determined in the form of liquid aerosol.
Extrapolated from the 4 hr LC50.
(actual)
rabbit: Slight irritation.
Skin Irritation
rabbit: Minimally irritating.
Eye Irritation
guinea pig: Non-sensitizing.
Sensitization
Iprodione caused effects in the liver, adrenal, ovary and testes in chronic feeding
Chronic Toxicity
studies.
Assessment Carcinogenicity
Iprodione produced benign liver and ovary tumors in mice when tested at a maximum tolerated dose.
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Bayer Environmental Science
Material Safety Data Sheet MSDS Number: 102000012056
MSDS Version 2.0
CHIPCO 26019 FLO BRAND FUNGICIDE
ACGIH
None.
NTP
None.
IARC
None.
OSHA
None.
REPRODUCTION: Iprodione did not cause reproductive toxicity in multi-
Reproductive &
generation studies in rats.
Developmental Toxicity
DEVELOPMENTAL TOXICITY: Iprodione was not a primary developmental
toxicant as only minor delays or variations in fetal development were observed
only at doses that caused maternal toxicity.
Iprodione is not considered to be a neurotoxicant.
Neurotoxicity
Based on the overall weight of evidence, iprodione was not genotoxic in a
Mutagenicity
battery of in vitro and in vivo studies.
SECTION 12. ECOLOGICAL INFORMATION
Toxic to invertebrates. Do not apply directly to water, to areas where surface
Environmental
water is present or to intertidal areas below the mean high water mark. Drift or
Precautions
run-off from treated areas may be hazardous to aquatic organisms in
neighboring areas. Do not contaminate surface or ground water by cleaning
equipment or disposal of wastes, including equipment wash water.
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Bayer Environmental Science
Material Safety Data Sheet MSDS Number: 102000012056
MSDS Version 2.0
CHIPCO 26019 FLO BRAND FUNGICIDE
SECTION 13. DISPOSAL CONSIDERATIONS
Do not contaminate water, food, or feed by disposal. Dispose in accordance with
General Disposal
all local, state/provincial and federal regulations. Follow advice on product label
Guidance
and/or leaflet.
Do not re-use empty containers. Triple rinse containers. Consult state and local
Container Disposal
regulations regarding the proper disposal of container.
SECTION 14. TRANSPORT INFORMATION
DOT CLASSIFICATION:
Not regulated for Domestic Surface Transportation
IMDG CLASSIFICATION:
FREIGHT CLASSIFICATION:
Insecticides or fungicides,N.O.I., other than poison
SECTION 15. REGULATORY INFORMATION
432-888
EPA Registration No.
US Federal Regulations
TSCA list
1,2-Propanediol 57-55-6
US. Toxic Substances Control Act (TSCA) Section 12(b) Export Notification (40 CFR 707, Subpt D)
None.
SARA Title III - Section 302 - Notification and Information
None.
SARA Title III - Section 313 - Toxic Chemical Release Reporting
None.
US States Regulatory Reporting
CA Prop65
This product contains a chemical known to the State of California to cause cancer.
Iprodione 36734-19-7
This product does not contain any substances known to the State of California to cause reproductive
harm.
US State Right-To-Know Ingredients
1,2-Propanediol 57-55-6 MN, RI
Canadian Regulations
Canadian Domestic Substance List
Page 7 of 8
Bayer Environmental Science
Material Safety Data Sheet MSDS Number: 102000012056
MSDS Version 2.0
CHIPCO 26019 FLO BRAND FUNGICIDE
1,2-Propanediol 57-55-6
Environmental
CERCLA
None.
Clean Water Section 307 Priority Pollutants
None.
Safe Drinking Water Act Maximum Contaminant Levels
None.
International Regulations
European Inventory of Existing Commercial Substances (EINECS)
Iprodione 36734-19-7
1,2-Propanediol 57-55-6
SECTION 16. OTHER INFORMATION
NFPA 704 (National Fire Protection Association):
Health - 1 Flammability - 1 Reactivity - 0 Others - none
0 = minimal hazard, 1 = slight hazard, 2 = moderate hazard, 3 = severe hazard, 4 = extreme hazard
Reason to Revise: New re-numbering system and update each section.
Revision Date: 07/05/2006
This information is provided in good faith but without express or implied warranty. The customer assumes all
responsibility for safety and use not in accordance with label instructions. The product names are registered
trademarks of Bayer.
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