Equiva Services - MSDS
MATERIAL SAFETY DATA SHEET
EQUILON MSDS: 16450ET 01/04/99
TEXACO EXTENDED LIFE 50/50 COOLANT/AF PG
TELEPHONE NUMBER:
24 HOUR EMERGENCY ASSISTANCE GENERAL MSDS ASSISTANCE
EQUIVA SERVICES: 877-276-7283 877-276-7285
CHEMTREC: 800-424-9300
NAME AND ADDRESS:
EQUILON ENTERPRISES LLC
PRODUCT STEWARDSHIP
P.O. BOX 674414
HOUSTON, TX 77267-4414
LEGEND:
N.D. - NOT DETERMINED N.A. - NOT APPLICABLE N.T- NOT TESTED
< - LESS THAN > - GREATER THAN
________________________________________________________________________________
1.NAME
________________________________________________________________________________
MATERIAL IDENTITY
Product Code and Name:
16450 TEXACO EXTENDED LIFE 50/50 COOLANT/AF PG
Chemical Name and/or Family or Description:
Antifreeze
_______________________________________________________________________________
2. COMPOSITION/INFORMATION ON INGREDIENTS
_______________________________________________________________________________
THE CRITERIA FOR LISTING COMPONENTS IN THE COMPOSITION SECTION IS AS FOLLOWS:
CARCINOGENS ARE LISTED WHEN PRESENT AT 0.1 % OR GREATER; COMPONENTS WHICH ARE
OTHERWISE HAZARDOUS ACCORDING TO OSHA ARE LISTED WHEN PRESENT AT 1.0 % OR
GREATER; NON-HAZARDOUS COMPONENTS ARE LISTED AT 3.0 % OR GREATER. THIS IS NOT
INTENDED TO BE A COMPLETE COMPOSITIONAL DISCLOSURE. REFER TO SECTION 14 FOR
APPLICABLE STATES' RIGHT TO KNOW AND OTHER REGULATORY INFORMATION.
Product and/or Component(s) Carcinogenic According to:
OSHA IARC NTP OTHER NONE
X
_ _ _ _ _
Composition: (Sequence Number and Chemical Name)
Seq. Chemical Name CAS Number Range in %
____ ____________________________________________ ______________ ____________
01 Water deionized 7732-18-5 50.00-64.99
02 1,2- propanediol 57-55-6 35.00-49.99
03 * Hexanoic acid, 2-ethyl-, potassium salt 3164-85-0 1.00-2.99
PRODUCT IS HAZARDOUS ACCORDING TO OSHA (1910.1200).
* COMPONENT IS HAZARDOUS ACCORDING TO OSHA.
Exposure Limits referenced by Sequence Number in the Composition Section
Seq. Limit
____ _________________________________________________________________________
None
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_______________________________________________________________________________
3. HAZARD IDENTIFICATION
_______________________________________________________________________________
EMERGENCY OVERVIEW
Appearance:
Pink liquid
Odor:
Mild odor
WARNING STATEMENT
_________________
CAUTION ! ASPIRATION HAZARD IF SWALLOWED -
CAN ENTER LUNGS AND CAUSE DAMAGE
ATTENTION ! CONTAINS 2-ETHYLHEXANOIC ACID OR ITS SALT WHICH MAY CAUSE
ADVERSE REPRODUCTIVE EFFECTS AND BIRTH DEFECTS BASED ON
ANIMAL DATA
HMIS NFPA
Health: 0 Reactivity: 0 Health: 0 Reactivity: 0
Flammability: 1 Special :- Flammability: 1 Special :-
POTENTIAL HEALTH EFFECTS
EYE SKIN INHALATION INGESTION
Primary Route of Exposure: X X X
_ _ _ _
EFFECTS OF OVEREXPOSURE
Acute:
Eyes:
May cause minimal irritation, experienced as temporary discomfort.
Skin:
Brief contact is not irritating. Prolonged contact, as with clothing
wetted with material, may cause defatting of skin or irritation, seen as
local redness with possible mild discomfort.
Other than the potential skin irritation effects noted above, acute (short
term) adverse effects are not expected from brief skin contact; see other
effects, below, and Section 11 for information regarding potential long
term effects.
Inhalation:
Vapors or mist, in excess of permissible concentrations, or in unusually
high concentrations generated from spraying, heating the material or as
from exposure in poorly ventilated areas or confined spaces, may cause
irritation of the nose and throat, headache, nausea, and drowsiness.
Prolonged or repeated overexposure may result in the absorption of
potentially harmful amounts of material.
Ingestion:
If more than several mouthfuls are swallowed, abdominal discomfort, nausea,
and diarrhea may occur. Aspiration may occur during swallowing or vomiting
resulting in lung damage.
Sensitization Properties:
Unknown.
Chronic:
No adverse effects have been documented in humans as a result of chronic
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exposure. Section 11 may contain applicable animal data.
Medical Conditions Aggravated by Exposure:
There is no evidence that this product aggravates an existing medical
condition.
Other Remarks:
None
_______________________________________________________________________________
4. FIRST AID MEASURES
_______________________________________________________________________________
Eyes:
Flush eyes with plenty of water for several minutes. Get medical
attention if eye irritation persists.
Skin:
Wash skin with plenty of soap and water until all traces of material are
removed. Remove and clean contaminated clothing (See Other Instructions).
Destroy non-resistant footwear. Get medical attention if skin irritation
persists or contact has been prolonged.
Ingestion:
If person is conscious and can swallow, give two glasses of water (16 oz.)
but do not induce vomiting. If vomiting occurs, give fluids again. Have
medical personnel determine if evacuation of stomach or induction of
vomiting is necessary. Do not give anything by mouth to an unconscious or
convulsing person.
Inhalation:
If irritation, headache, nausea, or drowsiness occurs, remove to fresh air.
Get medical attention if breathing becomes difficult or respiratory
irritation persists.
Other Instructions:
Aspiration of this product during induced emesis may result in severe lung
injury. If evacuation of stomach is necessary, use method least likely to
cause aspiration, such as gastric lavage after endotracheal intubation.
Contact a Poison Center for additional treatment information.
_______________________________________________________________________________
5. FIRE-FIGHTING MEASURES
_______________________________________________________________________________
Ignition Temperature - AIT (degrees F):
Not determined.
Flash Point (degrees F):
225 (PMCC)
Flammable Limits (%):
Lower: Not determined.
Upper: Not determined.
Recommended Fire Extinguishing Agents And Special Procedures:
Use water spray, dry chemical, foam, or carbon dioxide to extinguish
flames. Use water spray to cool fire-exposed containers. Water or
foam may cause frothing.
Unusual or Explosive Hazards:
None
Extinguishing Media Which Must Not Be Used:
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Not determined.
Special Protective Equipment for Firefighters:
Other than normal protective fire-fighting equipment, no special equipment
or procedures required.
_______________________________________________________________________________
6. ACCIDENTAL RELEASE MEASURES (Transportation Spills: CHEMTREC (800)424-9300)
_______________________________________________________________________________
Procedures in Case of Accidental Release, Breakage or Leakage:
Contain spill if possible, contain with absorbent materials such as clay or
soil, and shovel up. Avoid skin and eye contact.
If more than 33,333 pounds of product is spilled, then report spill
according to SARA 304 and/or CERCLA 102(a) requirements, unless product
qualifies for the petroleum exemption (CERCLA Section 101(14)).
_______________________________________________________________________________
7. HANDLING AND STORAGE
_______________________________________________________________________________
Precautions to be Taken in
Handling:
Minimum feasible handling temperatures should be maintained.
Storage:
Periods of exposure to high temperatures should be minimized. Water
contamination should be avoided.
_______________________________________________________________________________
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
_______________________________________________________________________________
Protective Equipment (Type)
Eye/Face Protection:
Safety glasses, chemical type goggles, or face shield recommended to
prevent eye contact.
Skin Protection:
Protective clothing such as coveralls or lab coats should be worn. Launder
or dry-clean when soiled. Gloves and boots resistant to chemicals and
petroleum distillates required.
Respiratory Protection:
Airborne concentrations should be kept to lowest levels possible. If
vapor, mist or dust is generated and the occupational exposure limit of the
product, or any component of the product, is exceeded, use appropriate
NIOSH or MSHA approved air purifying or air supplied respirator after
determining the airborne concentration of the contaminant. Air supplied
respirators should always be worn when airborne concentration of the
contaminant or oxygen content is unknown.
Ventilation:
Local exhaust ventilation recommended if generating vapor, dust, or mist.
If exhaust ventilation is not available or inadequate, use MSHA or NIOSH
approved respirator as appropriate.
Exposure Limit for Total Product:
None established for product.
_______________________________________________________________________________
9. PHYSICAL AND CHEMICAL PROPERTIES
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Appearance:
Pink liquid
Odor:
Mild odor
Boiling Point (degrees F):
228
Melting/Freezing point (degrees F):
-27
Specific Gravity (water=1):
1.04
pH of undiluted product:
8.3
Vapor Pressure:
< 1 mmHg at 77.0
Viscosity:
18 cSt at 40.0 C
VOC Content:
Not determined.
Vapor Density (air=1):
Not determined.
Solubility in Water (%):
> 10
Other: None
_______________________________________________________________________________
10. STABILITY AND REACTIVITY
_______________________________________________________________________________
This Material Reacts Violently With:
(If Others is checked below, see comments for details)
Air Water Heat Strong Oxidizers Others None of These
X
_ _ _ _ _ _
Comments:
None
Products Evolved When Subjected to Heat or Combustion:
Toxic levels of carbon monoxide, carbon dioxide, irritating aldehydes and
ketones, and combustion products or compounds of
potassium.
Hazardous Polymerizations: DO NOT OCCUR
_______________________________________________________________________________
11. TOXICOLOGICAL INFORMATION
_______________________________________________________________________________
TOXICOLOGICAL INFORMATION(ANIMAL TOXICITY DATA)
Median Lethal Dose
Oral:
LD50 Believed to be > 5.00 g/kg (rat) practically non-toxic
Inhalation:
Believed to be practically non-toxic
Dermal:
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LD50 Believed to be > 2.00 g/kg (rabbit) practically non-toxic
Irritation Index, Estimation of Irritation (Species)
Skin:
(Draize) Believed to be < .50 /8.0 (rabbit) no appreciable effect
Eyes:
(Draize) Believed to be < 15.00 /110 (rabbit) no appreciable effect
Sensitization:
Not determined.
Other:
2-ethylhexanoic acid (2-EXA) caused an increase in liver size and enzyme
levels when repeatedly administered to rats via the diet. When administered
to pregnant rats by gavage or in drinking water, 2-EXA caused
teratogencity (birth defects) and delayed postnatal development of the
pups. Additionaly, 2-EXA impaired female fertility in rats. Birth defects
were seen in the offspring of mice who were administered
sodium 2-ethylhexanoate via intraperitoneal injection during pregnancy.
_______________________________________________________________________________
12. DISPOSAL CONSIDERATIONS
_______________________________________________________________________________
Waste Disposal Methods
This product has been evaluated for RCRA characteristics and does not meet
the criteria of a hazardous waste if discarded in its purchased form.
Under RCRA, it is the responsibility of the user of the product to deter-
mine at the time of disposal, whether the product meets RCRA criteria for
hazardous waste. This is because product uses, transformations, mixtures,
processes, etc. may render the resulting materials hazardous.
Remarks
None
_______________________________________________________________________________
13. TRANSPORT INFORMATION
_______________________________________________________________________________
Transportation
DOT:
Proper Shipping Name:
Not regulated
This product contains a DOT Hazardous Substance or Substances, listed in
Section 14 of the MSDS. If the product's shipping container holds
at least 33,333 lbs, then the DOT information must be accompanied
with RQ notation, or, an otherwise 'Not Regulated' product will be
classified as Environmentally Hazardous (solid/liquid) N.O.S., Class 9,
unless the product qualifies for the petroleum exemption (49 CFR 171.8).
IMDG:
Proper Shipping Name:
Not evaluated
ICAO:
Proper Shipping Name:
Not evaluated
TDG:
Proper Shipping Name:
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Not regulated
_______________________________________________________________________________
14. REGULATORY INFORMATION
_______________________________________________________________________________
Federal Regulations:
SARA Title III:
Section 302/304 Extremely Hazardous Substances
Seq. Chemical Name CAS Number Range in %
____ ____________________________________________ ______________ ___________
None
Section 302/304 Extremely Hazardous Substances (CONT)
Seq. TPQ RQ
____ __________ __________
None
Section 311 Hazardous Categorization:
Acute Chronic Fire Pressure Reactive N/A
X
_ _ _ _ _ _
Section 313 Toxic Chemical
Chemical Name CAS Number Concentration
____________________________________________ ______________ _____________
None
CERCLA 102(a)/DOT Hazardous Substances: (+ indicates DOT Hazardous Substance)
Seq. Chemical Name CAS Number Range in %
____ ____________________________________________ ______________ ___________
01+ Sodium nitrite 7632-00-0 0.10-0.99
02+ Potassium hydroxide 1310-58-3 0.10-0.99
03+ Sodium hydroxide 1310-73-2 0.001884
CERCLA/DOT Hazardous Substances (Sequence Numbers and RQ's):
Seq. RQ
____ __________
01+ 100
02+ 1000
03+ 1000
TSCA Inventory Status:
This product, or its components, are listed on or are exempt from the
Toxic Substance Control Act (TSCA) Chemical Substance Inventory.
Other:
None.
State Regulations:
California Proposition 65:
The following detectable components of this product are substances,
or belong to classes of substances, known to the State of California
to cause cancer and/or reproductive toxicity.
Chemical Name CAS Number
____________________________________________ ______________
None
International Regulations:
Export Notification (TSCA-12b):
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This product may be subject to export notification under TSCA
section 12(b); contains:
Sodium nitrite
Diethylene glycol monobutyl ether
WHMIS Classification:
Class D, Div 2, Subdiv A: Teratogen and reproductive toxicity
Canada Inventory Status:
Not determined.
EINECS Inventory Status:
Not determined.
Australia Inventory Status:
Not determined.
Japan Inventory Status:
Not determined.
_______________________________________________________________________________
15. ENVIRONMENTAL INFORMATION
_______________________________________________________________________________
Aquatic Toxicity:
Not determined.
Mobility:
Not determined.
Persistence and Biodegradability:
This product is estimated to have a moderate (>= 30%) rate of
biodegradation in a test for ready biodegradation.
Potential to Bioaccumulate:
This product is estimated to have a low potential to bioconcentrate.
Remarks:
None
_______________________________________________________________________________
16. OTHER INFORMATION
_______________________________________________________________________________
It is recommended that all exposures to this product be minimized by
strictly adhering to recommended occupational controls procedures to avoid
any potential adverse health effects.
THE INFORMATION CONTAINED IN THIS DATA SHEET IS BASED ON THE DATA AVAILABLE
TO US AT THIS TIME, AND IS BELIEVED TO BE ACCURATE BASED UPON THAT DATA. IT IS
PROVIDED INDEPENDENTLY OF ANY SALE OF THE PRODUCT, FOR PURPOSE OF HAZARD
COMMUNICATION. IT IS NOT INTENDED TO CONSTITUTE PRODUCT PERFORMANCE
INFORMATION, AND NO EXPRESS OR IMPLIED WARRANTY OF ANY KIND IS MADE WITH
RESPECT TO THE PRODUCT, UNDERLYING DATA OR THE INFORMATION CONTAINED
HEREIN. YOU ARE URGED TO OBTAIN DATA SHEETS FOR ALL PRODUCTS YOU BUY,
PROCESS, USE OR DISTRIBUTE, AND ARE ENCOURAGED TO ADVISE THOSE WHO MAY
COME IN CONTACT WITH SUCH PRODUCTS OF THE INFORMATION CONTAINED HEREIN.
TO DETERMINE THE APPLICABILITY OR EFFECT OF ANY LAW OR REGULATION WITH
RESPECT TO THE PRODUCT, YOU SHOULD CONSULT WITH YOUR LEGAL ADVISOR OR THE
APPROPRIATE GOVERNMENT AGENCY. WE WILL NOT PROVIDE ADVICE ON SUCH
MATTERS, OR BE RESPONSIBLE FOR ANY INJURY FROM THE USE OF THE PRODUCT
DESCRIBED HEREIN. THE UNDERLYING DATA, AND THE INFORMATION PROVIDED HEREIN
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AS A RESULT OF THAT DATA, IS THE PROPERTY OF EQUIVA SERVICES, LLC AND IS NOT TO
BE THE SUBJECT OF SALE OR EXCHANGE WITHOUT THE EXPRESS WRITTEN CONSENT OF
EQUIVA SERVICES, LLC.
Date: 1999-01-04 New X Revised, Supersedes: 1998-08-04
__________ _ _ __________
Inquiries regarding MSDS should be directed to:
Equiva Services LLC
Manager Product Stewardship
P.O. Box 674414
Houston, TX 77267-4414
_______________________________________________________________________________
17. PRODUCT LABEL Label Date: 1999-01-04
_______________________________________________________________________________
READ AND UNDERSTAND MATERIAL SAFETY DATA SHEET BEFORE HANDLING OR DISPOSING
OF PRODUCT. THIS LABEL COMPLIES WITH THE REQUIREMENTS OF THE OSHA HAZARD
COMMUNICATION STANDARD (29 CFR 1910.1200) FOR USE IN THE WORKPLACE. THIS
LABEL IS NOT INTENDED TO BE USED WITH PACKAGING INTENDED FOR SALE TO CONSUMERS
AND MAY NOT CONFORM WITH THE REQUIREMENTS OF THE CONSUMER PRODUCT SAFETY ACT
OR OTHER RELATED REGULATORY REQUIREMENTS.
16450 TEXACO EXTENDED LIFE 50/50 COOLANT/AF PG
WARNING STATEMENT
_________________
CAUTION ! ASPIRATION HAZARD IF SWALLOWED -
CAN ENTER LUNGS AND CAUSE DAMAGE
ATTENTION ! CONTAINS 2-ETHYLHEXANOIC ACID OR ITS SALT WHICH MAY CAUSE
ADVERSE REPRODUCTIVE EFFECTS AND BIRTH DEFECTS BASED ON
ANIMAL DATA
PRECAUTIONARY MEASURES
______________________
-Avoid prolonged breathing of vapor, mist, or gas.
-Avoid contact with eyes, skin, and clothing.
-Wash thoroughly after handling.
FIRST AID
_________
Eye Contact:
Flush eyes with plenty of water for several minutes. Get medical
attention if eye irritation persists.
Skin Contact:
Wash skin with plenty of soap and water until all traces of material are
removed. Remove and clean contaminated clothing (See Other Instructions).
Destroy non-resistant footwear. Get medical attention if skin irritation
persists or contact has been prolonged.
Ingestion:
If person is conscious and can swallow, give two glasses of water (16 oz.)
but do not induce vomiting. If vomiting occurs, give fluids again. Have
medical personnel determine if evacuation of stomach or induction of
vomiting is necessary. Do not give anything by mouth to an unconscious or
convulsing person.
Inhalation:
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If irritation, headache, nausea, or drowsiness occurs, remove to fresh air.
Get medical attention if breathing becomes difficult or respiratory
irritation persists.
Note to Physician:
Aspiration of this product during induced emesis may result in severe lung
injury. If evacuation of stomach is necessary, use method least likely to
cause aspiration, such as gastric lavage after endotracheal intubation.
Contact a Poison Center for additional treatment information.
FIRE
____
In case of fire, use water spray, dry chemical, foam or carbon dioxide.
Water may cause frothing. Use water spray to cool fire-exposed containers.
If more than 33,333 pounds of product is spilled, then report spill
according to SARA 304 and/or CERCLA 102(a) requirements, unless product
qualifies for the petroleum exemption (CERCLA Section 101(14)).
Chemical Name CAS Number Range in %
____________________________________________ _____________ ____________
Water deionized 7732-18-5 50.00-64.99
1,2- propanediol 57-55-6 35.00-49.99
* Hexanoic acid, 2-ethyl-, potassium salt 3164-85-0 1.00-2.99
PRODUCT IS HAZARDOUS ACCORDING TO OSHA (1910.1200).
* COMPONENT IS HAZARDOUS ACCORDING TO OSHA.
Pennsylvania Special Hazardous Substance(s) CAS Number Range in %
____________________________________________ _____________ ____________
None
HMIS NFPA
Health: 0 Reactivity: 0 Health: 0 Reactivity: 0
Flammability: 1 Special :- Flammability: 1 Special :-
Transportation
DOT:
Proper Shipping Name:
Not regulated
This product contains a DOT Hazardous Substance or Substances, listed in
Section 14 of the MSDS. If the product's shipping container holds
at least 33,333 lbs, then the DOT information must be accompanied
with RQ notation, or, an otherwise 'Not Regulated' product will be
classified as Environmentally Hazardous (solid/liquid) N.O.S., Class 9,
unless the product qualifies for the petroleum exemption (49 CFR 171.8).
CAUTION: Misuse of empty containers can be hazardous. Empty containers can
be hazardous if used to store toxic, flammable, or reactive
materials. Cutting or welding of empty containers might cause
fire, explosion or toxic fumes from residues. Do not pressurize
or expose to open flame or heat. Keep container closed and drum
bungs in place.
Name and Address:
Equilon Enterprises LLC
P.O. Box 674414
Houston ,TX 77267-4414
TRANSPORTATION EMERGENCY: (877)276-7283
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CHEMTREC: (800)424-9300
HEALTH EMERGENCY: (877)276-7283
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