----------------------- MATERIAL SAFETY DATA SHEET -----------------------
Lebanon Turf PROSCAPE 14-2-14 PCNB
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Proscape 14-2-14 PCNB is also known as Lebanon Fertilizer -----------------------------------------------------------
with 12.5% PCNB 21-54456 IV. FIRE AND EXPLOSION HAZARD DATA
----------------------------------------------------------- -----------------------------------------------------------
MSDS #: 3303 FLASH POINT (method Used): ND
MANUFACTURER: LEBANON CHEMICAL CORPORATION AUTO IGNITION TEMPERATURE: ND
PO BOX 180 LOWER EXPLOSION LIMITS: ND
LEBANON PA 17042-0180 UPPER EXPLOSION LIMITS: ND
INFORMATION: (800) 532-0090 NFPA/HMIS RATING:
CHEMTREC: (800) 424-9300 HEALTH: 3
DATE ISSUED: 9/26/97 FIRE: 1
SUPERSEDES: REACTIVITY: 0
----------------------------------------------------------- EXTINGUISHING MEDIA:
I. PRODUCT IDENTIFICATION FOAM:
----------------------------------------------------------- WATER SPRAY: X
PRODUCT: Lebanon Fertilizer with 12.5% PCNB ALCOHOL FOAM:
CHEMICAL NAME/SYNONYMS: PCNB, Terraclor OTHER:
CHEMICAL FAMILY: Halogenated Nitrobenzene DRY CHEMICAL: X
----------------------------------------------------------- CO2:
II. PRODUCT INFORMATION: INGREDIENTS SPECIAL FIRE-FIGHTING TECHNIQUES: Protect against
----------------------------------------------------------- inhalation of combustion products. Contain run-off.
Chemical Name TLV/TWA % (by wt.) PROVIDE FOR THE PROTECTION OF EMPLOYEES AND RESIDENTS:
----------------------------------------------------------- a)Evacuate residents who are downwind to the fire.
Pentachloronitrobenzene 0.5 mg/cu meter 10% b)Prevent unauthorized entry to fire area.
CAS#: 82-68-8-6 c)Persons who may have been exposed to contaminated
Paraffinic Oil ND <1% smoke should be examined by a physician and treated
CAS#: 64741-88-4 appropriately.
Formulated with one or more of the following ingredients. d)Dike area to prevent runoff and contamination of
Check specific product label. water sources.
Urea 10 mg/M3 (dust) 0-90 NOTIFY LOCAL AUTHORITIES THAT FIREMEN SHOULD:
CAS#: 57-13-6 5 mg/M3 (resp) a)Wear protective clothing and use self contained
Potassium Chloride 10 mg/M3 0-85 breathing apparatus.
CAS#: 7447-40-7 b)Be immediately relieved from duty, if exposed to
Potassium Sulfate 10 mg/M3 0-85 contaminated smoke, and check for symptoms of
CAS#: 7778-80-5 poisoning. These should not be mistaken for heat
Monoammonium Phosphate 15 mg/M3 (dust) 0-85 exhaustion or smoke inhalation. Fertilizer will
CAS#: 7722-76-1 5 mg/M3 TLV become slippery when wet. Guard against falls.
Diammonium Phosphate 15 mg/M3 (dust) 0-85 UNUSUAL FIRE AND EXPLOSION HAZARDS: Toxic irritating gases
CAS#: 7783-28-0 5 mg/M3 (resp) may be formed above 160 deg C (320 deg F). At high
Ammonium Sulfate 15 mg/M3 (dust) 0-85 temperatures, nitrogen containing fertilizer can form
CAS#: 7783-20-2 cyanuric acid, hydrogen cyanide and ammonia. Ammonium
Calcium Carbonate ND 0-85 carbamate may also be formed. Contamination with strong
CAS#: 1317-65-3 acids may create an explosion hazard.
Sulfur 5 ppm (SO2) 0-20 -----------------------------------------------------------
CAS#: 7704-39-9 V. HEALTH HAZARDS
Iron Oxide 15 mg/M3 (dust) 0-10 -----------------------------------------------------------
CAS#: 1309-37-1 PRIMARY ROUTE(S) OF ENTRY: Skin, eyes, inhalation,
Iron Sulfate 15 mg/M3 (dust) 0-10 ingestion.
CAS#: 7728-78-7 SIGNS & SYMPTOMS OF EXPOSURE:
Manganese Oxide 15 mg/M3 (dust) 0-10 ACUTE: Skin sensitizer. Repeated contact could produce
CAS#: 1317-35-7 allergic dermatitis. Eye irritation, nausea, vomiting,
Magnesium Sulfate 15 mg/M3 (dust) 0-10 corneal damage possible.
CAS#: 7478-88-9 CHRONIC: Chloracne, skin sensitization and allergic
----------------------------------------------------------- dermatitis.
III. PHYSICAL AND CHEMICAL CHARACTERISTICS EMERGENCY FIRST-AID PROCEDURES:
----------------------------------------------------------- EYES: Hold eyelids open and flush with a steady, gentle
BOILING POINT: NA stream of water for at least 15 minutes. Get medical
MELTING POINT: 133 deg C (urea) attention.
VAPOR PRESSURE (mm Hg): NA SKIN: Immediately wash skin with plenty of soap and water
VAPOR DENSITY (air = 1): NA while removing contaminated clothing and shoes. Wash
SOLUBILITY IN WATER: Partially soluble in water and organic clothing separately before reuse.
solvents INHALATION: Remove victim to fresh air. If not breathing,
pH: ND administer cardiopulmonary resuscitation or artificial
SPECIFIC GRAVITY (water = 1): NA respiration. If breathing is difficult, administer
BULK DENSITY (lbs./cu. ft.): 45-65 lbs/cu. ft. oxygen. Get medical attention.
EVAPORATION RATE: ND INGESTION: Drink an eight ounce glass of water containing
PERCENT VOLATILE: Low two tablespoons activated charcoal. Contact physician.
APPEARANCE AND ODOR: Light gray granules, mothball or musty
odor.
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----------------------- MATERIAL SAFETY DATA SHEET -----------------------
Lebanon Turf PROSCAPE 14-2-14 PCNB
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NOTES TO PHYSICIAN: Repeated minimal contact with skin may -----------------------------------------------------------
cause sensitization. Tests in animals indicate PCNB to be IX. STORAGE AND HANDLING
an experimental animal carcinogen. -----------------------------------------------------------
A 78 week feeding study conducted by the National Cancer PRECAUTIONS: Storage away from sources of direct heat in a
Institute in mice and rats at levels up to 8,187 and dry area.
14,635 ppm PCNB respectively did not result in an OTHER PRECAUTIONS: Store unused product in original
increased incidence of tumors. container only, in cool, dry area out of reach of
A 104 week feeding study conducted in rats at levels of children and animals. Do not store in areas where
20; 3,000; and 6,000 PCNB resulted in an elevated temperatures frequently exceed 100 deg F (37.8 deg C).
incidence of thyroid follicular adenoma and carcinoma. Do not contaminate water, food or feed by storage or
The NOEL for chronic toxicity and oncogenicity is disposal.
determined to be 20 ppm. -----------------------------------------------------------
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Skin irritation X. FEDERAL REGULATORY INFORMATION:
may be aggravated in person with existing skin lesions. -----------------------------------------------------------
TOXICITY INFORMATION: SARA TITLE III; SEC. 311/312 HAZARD CATEGORIES:
ORAL LD50: IMMEDIATE (acute) HEALTH: Y
ACUTE (rat): 12.3 g/kg body weight DELAYED (Chronic) HEALTH: Y
DERMAL LD50: FIRE: N
ACUTE (rabbits): >4,000 mg/kg body weight SUDDEN RELEASE OF PRESSURE: N
EYE EFFECTS (rabbit): Negative REACTIVITY: N
SKIN IRRITATION (rabbit): Negative SEC 302: NA
POSITIVE TERATOGEN OR MUTAGEN CARCINOGEN (NTP): No SEC 304: NA
POTENTIAL CARCINOGEN (IARC or OSHA): No SEC 313: Y
----------------------------------------------------------- CERCLA RQ: 100 lbs (PCNB)
VI. REACTIVITY CAA RQ: lb (PCNB)
----------------------------------------------------------- EPA REG. NO.: 10404-38
STABILITY: Stable at ambient temperatures and pressures. HM 181 SHIPPING NAME: Not Regulated.
CONDITIONS TO AVOID: Strong oxidizing agents. -----------------------------------------------------------
HAZARDOUS DECOMPOSITION PRODUCTS: Phosgene, hydrogen, and NA = Not Applicable ND = Not Determined
oxides of nitrogen under burning conditions. Urea also 4416, pursuant to the OSHA Hazard Communication Standard
decomposes to biuret and cyanuric acid. Urea reacts with (29 CFR 1910.1200).
sodium or calcium, hypochlorite to form explosive -----------------------------------------------------------
nitrogen trichloride. The information contained herein is based on available
HAZARDOUS POLYMERIZATION: Will not occur data. However, no warranty is expressed or implied
----------------------------------------------------------- regarding the accuracy of this data or the results to be
VII. SPILL, LEAK, AND DISPOSAL PROCEDURES obtained from the use thereof; and you should make your
----------------------------------------------------------- investigation to determine safety for the use you
IF MATERIAL IS SPILLED: Vacuum up to avoid creating dust. contemplate. Lebanon makes no warranty of merchantability
Reuse per label instructions or transfer into secure of fitness for a particular use, nor is there any other
containers for proper disposal. Use personal protective express or implied warranty except as may be specifically
gear. Reportable quantity: 100 lbs. (PCNB). provided otherwise on product.
Do not flush material to public sewer systems or any Lebanon Chemical Corp. assumes no responsibility or
waterways. Wear appropriate protective clothing and liability for any incidental or consequential damages
equipment during cleanup activities. Ensure adequate whether related to personal injury or property damage, to
decontamination of tools and equipment following cleanup. vendees, users or third parties, caused by the material;
WASTE DISPOSAL METHOD: Dispose according to Federal EPA Lebanon responsibility is limited to replacement of, or
procedures as outlined in the Resource Conservation repayment of, the purchase price for the material(s) with
Recovery act (RCRA) and follow state and local respect to which any damages are claimed. All vendees or
guidelines. Be certain containers are completely empty users assume all risk associated with the use of the
before disposal. material(s).
----------------------------------------------------------- -----------------------------------------------------------
VIII. SPECIAL PROTECTION INFORMATION DISCLAIMER OF EXPRESSED AND IMPLIED WARRANTIES: although
----------------------------------------------------------- preparer and owner have taken reasonable care in the
PROTECTIVE EQUIPMENT SUGGESTED FOR OUTDOOR APPLICATION: preparation of this document, we extend no warranties and
IMPERVIOUS GLOVES: X make no representation as to the accuracy or completeness
IMPERVIOUS BOOTS: X of the information contained herein, and assume no
DUST MASK: responsibility regarding the suitability of this
CLEAN CLOTHING: X information for the user's intended purposes or for the
RESPIRATOR (use NIOSH/MSHA approved): consequences of its use. Each user should make a
EYE GOGGLES/SAFETY GLASSES: X determination as to the suitability of the information for
PROTECTIVE EQUIPMENT SUGGESTED FOR CONFINED AREAS: their particular purpose(s). A request has been made to the
SUFFICIENT VENTILATION: X manufacturer to approve the contents of this material
DUST MASK: X safety data sheet. Upon receipt of any changes a new MSDS
EYEWASH STATION: X will be made available.
SPLASH GOGGLES/SAFETY GLASSES: X -----------------------------------------------------------
EMERGENCY SHOWER: X COMPAS Code: 43390830
IMPERVIOUS APRON:
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