Great Oak, Inc.
Material Safety Data Sheet MSDS Number: GO01
DeerPro Winter Animal Repellent Date 4/15/07
SECTION 1. CHEMICAL PRODUCT AND COMPANY INFORMATION
Product Name DeerPro Winter Animal Repellent
MSDS Number GO01
EPA Registration No. 84178-1
Great Oak, Inc
10 Great Oak Lane
PO Box 1109
Redding, CT 06875
For MEDICAL, TRANSPORTATION or other EMERGENCY call: INFOTRAC- (800) 535-5053
For Product Information call: 1-877-486-DEER (1-877-486-3337)
SECTION 2. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous Component Name CAS-No. Average % by Weight
Thiram 137-26-8 25.80
SECTION 3. HAZARDS IDENTIFICATION
NOTE: Please refer to Section 11 for detailed toxicological information.
Emergency Overview Caution! Harmful if swallowed or absorbed through skin. Moderate
eye irritation. Prolonged or frequently repeated skin contact may cause
allergic reactions in some individuals. Avoid contact with skin, eyes
and clothing. Do not breathe vapors or spray mist.
Physical State liquid
Appearance green liquid
Routes of Exposure Inhalation, Ingestion, Skin Absorption, Eye contact
Immediate Effects
Eye Moderate eye irritation. Do not get in eyes.
Skin May cause skin irritation. Prolonged or frequently repeated skin
contact may cause allergic reactions in some individuals. Harmful if
absorbed through skin. Avoid contact with skin and clothing.
Ingestion Use of alcoholic beverages may enhance toxic effects. Harmful if
swallowed. Do not take internally.
Inhalation May cause irritation of the mucous membranes. May cause respiration
tract irritation. Do not breathe vapors or spray mist.
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Great Oak, Inc.
Material Safety Data Sheet
DeerPro Winter Animal Repellent
Medical conditions Individuals with allergic history or pre-existing dermatitis
Aggravated by Exposure should use extra care in handling this product.
SECTION 4. FIRST AID MEASURES
General When possible, have the product container or label with you when
calling a poison control center or doctor or going for treatment.
Eye Hold eye open and rinse slowly and gently with water for 15-20
minutes. Remove contact lenses, if present, after the first 5 minutes,
then continue rinsing eye. Call a physician or poison control center
immediately.
Skin Wash off immediately with plenty of water for at least 15 minutes.
Take off contaminated clothing and shoes immediately. Call a
physician or poison control center immediately.
Ingestion Call a physician or poison control center immediately. Rinse out
mouth and give water in small gulps to drink. DO NOT induce
vomiting unless directed to do so by a physician or poison control
center. Never give anything by mouth to an unconscious person. Do
not leave victim unattended.
Inhalation Move to fresh air. If person is not breathing, call 911 or an ambulance,
then give artificial respiration, preferably mouth-to-mouth if possible.
Call a physician or poison control center immediately.
Notes to Physician Ingestion may provoke the following symptoms:
Signs and nausea
Symptoms vomiting
breathing difficulties
More severe effects if alcohol is consumed.
Treatment There is no specific antidote. Appropriate supportive and symptomatic
treatment as indicated by the patient's condition is recommended.
SECTION 5. FIRE FIGHTING MEASURES
Flash Point >93.4 篊 / > 200.1 篎
Fire and Explosion Heating or fire can release toxic gas.
Hazards
Suitable Extinguishing foam, carbon dioxide (CO2), dry chemical, water spray
Media
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Great Oak, Inc.
Material Safety Data Sheet
DeerPro Winter Animal Repellent
Fire Fighting Keep out of smoke. Fight fire from upwind position. Cool closed
Instructions containers exposed to fire with water spray. Dike area to prevent
runoff and contamination of water sources. Equipment or materials
involved in pesticide fires may become contaminated.
Firefighters should wear NIOSH approved self-contained breathing
apparatus and full protective clothing.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal Precautions Keep unauthorized people away. Isolate hazard area. Avoid contact
with spilled product or contaminated surfaces.
Methods for Cleaning Up Take up with absorbent material (e.g. sand, diatomaceous earth or a
proprietary absorbent material). Keep in suitable, closed containers for
disposal. Clean contaminated floors and objects thoroughly, observing
environmental regulations.
Additional Advice Use personal protective equipment. Do not allow product to enter
streams, sewers or other waterways.
SECTION 7. HANDLING AND STORAGE
Handling Procedures Handle and open containers in a manner as to prevent spillage.
Storage Procedures Store in a cool, dry place and in such a manner as to prevent cross
contamination with other pesticides, fertilizers, food, and feed. Store in
original container and out of the reach of children, preferably in a
locked storage area.
Work/Hygienic Wash hands thoroughly with soap and water after handling and before
Procedures eating, drinking, chewing gum, using tobacco, using the toilet or
applying cosmetics.
Take off contaminated clothing and shoes immediately. Then wash
thoroughly and put on clean clothing.
Remove Personal Protective Equipment (PPE) immediately after
handling this product. Before removing gloves clean them with soap
and water. As soon as practical, wash thoroughly and change into
clean clothing.
Min/Max Storage Do not transport or store below 0 篊 / 32 篎
Temperatures Do not transport or store above 49 篊 / 10 篎
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Great Oak, Inc.
Material Safety Data Sheet
DeerPro Winter Animal Repellent
SECTION 8. EXPOSURE CONTROLS / PERSONAL PROTECTION
General Protection Follow all label instructions. Train employees in safe use of the
product.
Follow manufacture's instructions for cleaning/maintaining PPE. If no
such instructions for washable, use detergent and warm/tepid water.
Keep and wash PPE separately from other laundry.
Engineering Controls Maintain exposure levels below the exposure limit through the use of
general and local exhaust ventilation.
Eye/Face Protection tightly fitting safety goggles
Hand Protection Chemical resistant nitrile gloves
Body Protection Wear long-sleeved shirt and long pants and shoes plus socks.
Respiratory Protection When respirators are required, select NIOSH approved equipment
based on actual or potential airborne concentrations and in accordance
with the appropriate regulatory standards and/or Industrial
recommendations.
Exposure Limits
1,2-Propanediol 57-55-6 WEEL TWA 10 mg/m3
Form of Exposure Aerosol.
Urea 57-13-6 WEEL TWA 10mg/m3
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance green liquid
Physical State liquid
pH 7.64 (as a 1% w/w solution)
Bulk Density 1.123 g/ml
Melting/Freezing Point -9.4 - -6.7 篊 / 15.1 ?19.9 篎
Water Solubility miscible
SECTION 10. STABILITY AND REACTIVITY
Chemical Stability Stable
Conditions to Avoid Excessive heat and fire.
Exposure to extreme cold.
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Great Oak, Inc.
Material Safety Data Sheet
DeerPro Winter Animal Repellent
Incompatibility strong acids and oxidizing agents
copper
Hazardous In case of fire hazardous decomposition products may be produced
Decomposition Products such as:
nitrogen oxides (NOx)
Sulphur oxides
carbon disulphide
hydrogen sulfide
SECTION 11. TOXICOLOGICAL INFORMATION
Acute Oral Toxicity female rat: LD50: >5,000 mg/kg
Acute Dermal Toxicity male & female rat: LD50: > 5,000 mg/kg
Acute Inhalation Toxicity male & female rat: LD50: > 2.06 mg/l
Exposure time: 4 h
Skin Irritation Slightly irritating.
Eye Irritation Mildly irritating.
Sensitization Not considered to be a contact sensitizer.
Chronic Toxicity THIRAM has shown mutagenic activity in the Ames Test, but non-
mutagenic in mammalian cell studies. Since Thiram was not mutagenic
in vivo, the FAO (Food and Agricultural Organization) concludes that
Thiram does not present a genotoxic hazard to humans. Chronic
feeding studies with laboratory animals did not exhibit carcinogenic
effects.
Assessment Carcinogenicity
ACGIH
Thiram 137-26-8 Group A4
NTP
None.
IARC
Thiram 137-26-8 Overall evaluation: 3
OSHA
None.
SECTION 12. ECOLOGICAL INFORMATION
Environmental Toxic to fish. Do not apply directly to water, to areas where surface
Precautions water is present or to intertidal areas below the mean high water mark.
Do not contaminate surface or ground water by leaning equipment or
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Great Oak, Inc.
Material Safety Data Sheet
DeerPro Winter Animal Repellent
disposal of wastes, including equipment wash water. Drift or run-off
from treated areas may be hazardous to aquatic organisms in
neighboring areas. Apply this product only as specified on the label.
SECTION 13. DISPOSAL CONSIDERATIONS
General Disposal Pesticide wastes are toxic. Improper disposal of excess pesticide, spray
Guidance mixture, or rinsate is a violation of Federal Law. If these wastes cannot
be disposed of by use according to label instructions, contact your State
Pesticide or Environmental Control Agency, or the Hazardous Waste
representative at the nearest EPA Regional Office for guidance. Open
dumping is prohibited.
Container Disposal Do not re-use empty containers. Triple rinse containers. Then offer for
recycling or reconditioning or puncture and dispose of in a sanitary
landfill or incineration, or if allowed by State and Local authorities, by
burning. If burned, stay out of smoke.
RCRA Classification: The RCRA Classifications may be on the individual component(s) and
not necessarily on the product as a whole.
137-26-8 Thiram
US. EPA Resource Conservation and Recovery Act (RCRA)
Composite List of Hazardous Wastes and Appendix VIII Hazardous
Constituents (40 CFR 261): U244
137-26-8 Thiram
US. EPA Resource Conservation and Recovery Act (RCRA) U List of
Hazardous Wastes (40 CFR 261.33(f) and 40 CFR 302 [CERCLA]):
U244
SECTION 14. TRANSPORT INFORMATION
TRANSPORTATION CLASSIFICATION:
RQ, Environmentally Hazardous Substances, Liquid, N.O.S. (Thiram) // 9 // UN3082 // PG III
IMDG CLASSIFICATION:
RQ, Environmentally Hazardous Substances, Liquid, N.O.S. (Thiram) // 9 // UN3082 // PG III // Marine
Pollutant
FREIGHT CLASSIFICATION:
Insecticides or Fungicides, N.O.I.; other than poison
SECTION 15. REGULATORY INFORMATION
EPA Registration No. 84178-1
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Great Oak, Inc.
Material Safety Data Sheet
DeerPro Winter Animal Repellent
US Federal Regulations
TSCA list
Thiram
US Toxic Substances Control Act (TSCA) Section 12(b) Export Notification (40 CFR 707, Subpt D)
None.
SARA Title III ?Section 302 ?Notification and Information
None.
SARA Title III ?Section 313 ?Toxic Chemical Release Reporting
Thiram 137-26-8 1.0%
US States Regulatory Reporting
CA Prop65
This product does not contain any substances known to the State of California to cause
cancer.
This product does not contain any substances known to the State of California to cause
reproductive harm.
US States Right-To-Know Ingredients
Thiram 137-26-8 CA, CT, IL, MN, NJ, PA, RI
Canadian Regulations
Canadian Domestic Substance List
Thiram 137-26-8
Environmental
CERCLA
Thiram 137-26-8 10 lbs
Clean Water Section 307 Priority Pollutants
None.
Safe Drinking Water Act Maximum Contaminant Levels
None.
International Regulations
European Inventory of Existing Commercial Substances (EINECS)
Thiram 137-26-8
SECTION 16. OTHER INFORMATION
NFPA 704 (National Fire Protection Association):
Health ?2 Flammability ?1 Reactivity ?1 Others ?none
0 = minimal hazard, 1 = slight hazard, 2 = moderate hazard, 3 = severe hazard, 4 = extreme hazard
This information is provided in good faith but without express or implied warranty. The customer assumes
all responsibility for safety and use not in accordance with label instructions. The product names are
registered trademarks of Great Oak.
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