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| MATERIAL SAFETY DATA SHEET |
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| SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION |
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THIS MATERIAL SAFETY DATA SHEET IS AVAILABLE IN SPANISH UPON REQUEST.
LOS DATOS DE SEGURIDAD DEL PRODUCTO PUEDEN OBTENERSE EN ESPANOL SI LO
REQUIERE.
PRODUCT NAME : BLACKTOP ASPHALT FILLER AND SEALANT
UPC NUMBER : 7079818020
PRODUCT USE/CLASS : Butyl Rubber Caulk
MANUFACTURER: 24 HOUR EMERGENCY:
DAP INC. TRANSPORTATION: 1-800-535-5053 (352-323-3500)
2400 BOSTON STREET MEDICAL : 1-800-327-3874 (513-558-5111)
BALTIMORE, MD 21224
PREPARE DATE : 10/14/1997 GENERAL INFORMATION:
REVISION NO. : 11 DAP INC. : 1-888-DAP-TIPS (1-888-327-8477)
REVISION DATE: 04/26/2000
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| SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS |
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WT/WT %
ITEM ------------ CHEMICAL NAME ------------- CAS NUMBER RANGE
---------------------------------------------------------------------------
EMERGENCY OVERVIEW: DANGER! Combustible liquid and vapor. Harmful or fatal
if swallowed.
POTENTIAL HEALTH EFFECTS:
EFFECTS OF OVEREXPOSURE - EYE CONTACT: May cause eye irritation.
EFFECTS OF OVEREXPOSURE - SKIN CONTACT: May cause skin irritation. May
irritate skin. Prolonged or repeated contact can result in defatting and
drying of the skin which may result in skin irritation and dermatitis
(rash).
EFFECTS OF OVEREXPOSURE - INHALATION: Vapor harmful if inhaled. Vapor
may irritate nose and upper respiratory tract. Vapor inhalation may affect
the brain or nervous system causing dizziness, headache or nausea.
EFFECTS OF OVEREXPOSURE - INGESTION: This material may be harmful or
fatal if swallowed. If ingested, this product may cause vomiting,
diarrhea, and depressed respiration.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: Reports have associated
permanent brain and nervous system damage with prolonged and repeated
occupational overexposure to solvents.
MEDICAL CONDITIONS WHICH MAY BE AGGRAVATED BY CONTACT: None known.
PRIMARY ROUTE(S) OF ENTRY: SKIN CONTACT INHALATION
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| SECTION 4 - FIRST AID MEASURES |
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EYE CONTACT: Flush with large quantities of water until irritation
subsides.
SKIN CONTACT: Wash with soap and water.
INHALATION: Remove to fresh air.
INGESTION: DO NOT INDUCE VOMITING.
COMMENTS: Call 1-800-327-3874 if irritation or complications arise from any
above exposures.
(Continued on Page 3)
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Product Name: BLACKTOP ASPHALT FILLER AND SEALANT
Revision Date: 04/26/2000 Page 3
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| SECTION 5 - FIRE FIGHTING MEASURES |
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FLASH POINT: 129 F LOWER EXPLOSIVE LIMIT: N.A.
(CLEVELAND OPEN CUP) UPPER EXPLOSIVE LIMIT: N.A.
AUTOIGNITION TEMPERATURE: N.E.
NFPA FLAMMABILITY CLASS: II
EXTINGUISHING MEDIA: CO2 DRY CHEMICAL FOAM
UNUSUAL FIRE AND EXPLOSION HAZARDS: Combustible liquid. Containers may
explode if exposed to extreme heat. Eliminate sources of ignition: heat,
electrical equipment, sparks, and flames. Do not put in contact with
oxidizing or caustic materials.
SPECIAL FIREFIGHTING PROCEDURES: Full protective equipment, including
self-contained breathing apparatus, is recommended to protect from
combustion products. Cool exposed containers with water.
SPILL OR LEAK PROCEDURES: Dike spill area. Absorb remaining liquid with
absorbent material and place into containers.
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| SECTION 7 - HANDLING AND STORAGE |
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HANDLING INFORMATION: KEEP OUT OF REACH OF CHILDREN. Avoid skin and eye
contact. Avoid breathing vapors. Use only in a well ventilated area.
STORAGE INFORMATION: Store away from caustics and oxidizers. Keep away
from heat, spark, and flame. Keep containers tightly closed when not in
use. Keep containers from excessive heat and freezing. Do not store at
temperatures above 120 degrees F.
OTHER PRECAUTIONS: Intentional misuse by deliberately concentrating and
inhaling vapors may be harmful or fatal. Do not take internally.
ENGINEERING CONTROLS: Provide sufficient mechanical ventilation (local or
general exhaust) to maintain exposure below PEL and TLV. Vapors are heavier
than air and will collect in low areas. Check all low areas (basements,
sumps, etc.) for vapor before entering.
(Continued on Page 4)
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Product Name: BLACKTOP ASPHALT FILLER AND SEALANT
Revision Date: 04/26/2000 Page 4
RESPIRATORY PROTECTION: A respiratory protection program that meets OSHA
1910.134 and ANSI Z88.2 requirements must be followed whenever workplace
conditions warrant a respirator's use. If 8 hour exposure limit or value
is exceeded for any component, use an approved NIOSH/OSHA respirator.
Consult your safety equipment supplier and the OSHA regulation, 29
1910.134 for respirator requirements.
EYE PROTECTION: Goggles or safety glasses with side shields.
SKIN PROTECTION: Solvent impervious gloves.
OTHER PROTECTIVE EQUIPMENT: Provide eyewash and solvent impervious apron
if body contact may occur.
HYGIENIC PRACTICES: Remove contaminated clothing and wash before reuse.
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| SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES |
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BOILING RANGE : N.E. VAPOR DENSITY : Is heavier than air
ODOR : Gasoline-like
APPEARANCE : Black paste EVAPORATION RATE: Is slower than Butyl
SOLUBILITY IN H2O : Negligible Acetate
SPECIFIC GRAVITY : 1.6061
VAPOR PRESSURE : 3.1 mm Hg @ 68 F.
PHYSICAL STATE : Paste
(See Section 16 for abbreviation legend)
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| SECTION 10 - STABILITY AND REACTIVITY |
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CONDITIONS TO AVOID: Excessive heat and freezing.
INCOMPATIBILITY: Strong oxidizers and caustics.
HAZARDOUS DECOMPOSITION PRODUCTS: Normal decomposition products, i.e. COx,
NOx
HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.
STABILITY: This product is stable under normal storage conditions.
(Continued on Page 5)
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Product Name: BLACKTOP ASPHALT FILLER AND SEALANT
Revision Date: 04/26/2000 Page 5
WASTE MANAGEMENT/DISPOSAL: Dispose of according to Federal, State, and
Local Standards. Discarded material should be incinerated at a permitted
facility. Liquids cannot be disposed of in a landfill. Do not reuse empty
container. State and Local regulations/restrictions are complex and may
differ from Federal regulations. Responsibility for proper waste disposal
is with the owner of the waste.
EPA WASTE CODE - If discarded (40 CFR 261): None, yields no liquid
component when evaluated by EPA method 1311 (TCLP)
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| SECTION 14 - TRANSPORTATION INFORMATION |
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DOT PROPER SHIPPING NAME: Shipped as a combustible liquid in accordance
with 49CFR173.150(f)(2)*
DOT HAZARD CLASS: N.A.*
DOT UN/NA NUMBER: NONE* PACKING GROUP: NONE*
* When transported domestically by ground.
When shipped by other modes of transportation this product is considered a
flammable liquid.
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| SECTION 15 - REGULATORY INFORMATION |
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U.S. FEDERAL REGULATIONS: AS FOLLOWS -
OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR
1910.1200)
(Continued on Page 6)
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Product Name: BLACKTOP ASPHALT FILLER AND SEALANT
Revision Date: 04/26/2000 Page 6
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| SECTION 15 - REGULATORY INFORMATION |
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SARA SECTION 313:
This product contains the following substances subject to the reporting
requirements of Section 313 of Title III of the Superfund Amendments and
Reauthorization Act of 1986 and 40 CFR Part 372:
--------- CHEMICAL NAME ----------- CAS NUMBER ----------- WT/WT % RANGE
None.
TOXIC SUBSTANCES CONTROL ACT:
This product contains the following chemical substances subject to the
reporting requirements of TSCA 12(B) if exported from the United States:
----------- CHEMICAL NAME ----------- CAS NUMBER -----------
Isopropyl Alcohol 67-63-0
Methyl chloride 74-87-3
NEW JERSEY RIGHT-TO-KNOW:
The following materials are non-hazardous, but are among the top five
components in this product:
----------- CHEMICAL NAME ----------- CAS NUMBER
Calcium Carbonate 1317-65-3
Nonasbestos tremolite 14567-73-8
Hydrous magnesium silicate 14807-96-6
Talc(nonasbestiform) 14807-96-6
PENNSYLVANIA RIGHT-TO-KNOW:
The following non-hazardous ingredients are present in the product at
greater than 3%:
----------- CHEMICAL NAME ----------- CAS NUMBER
Calcium Carbonate 1317-65-3
Nonasbestos tremolite 14567-73-8
Hydrous magnesium silicate 14807-96-6
Magnesium Carbonate 546-93-0
Talc(nonasbestiform) 14807-96-6
CALIFORNIA PROPOSITION 65:
WARNING: The chemical(s) noted below and contained in this product, are
known to the state of California to cause cancer, birth defects or other
reproductive harm:
----------- CHEMICAL NAME ----------- CAS NUMBER
None.
(Continued on Page 7)
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Product Name: BLACKTOP ASPHALT FILLER AND SEALANT
Revision Date: 04/26/2000 Page 7
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| SECTION 15 - REGULATORY INFORMATION |
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INTERNATIONAL REGULATIONS: AS FOLLOWS -
CANADIAN WHMIS: This MSDS has been prepared in compliance with Controlled
Product Regulations except for use of the 16 headings.
CANADIAN WHMIS CLASS: No information available.
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| SECTION 16 - OTHER INFORMATION |
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REASON FOR REVISION:
SECTION 1: ADDRESS CHANGE AND NEW EMERGENGY CONTACT PHONE NUMBERS
SECTION 4: Modification of medical information.
SECTION 14: Modification of transportation information.
VOC less water, less exempt solvent: 190-195 g/L(12.0-13.0%)
VOC material : 190-195 g/L
LEGEND: ACGIH - AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
N.A. - NOT APPLICABLE
N.E. - NOT ESTABLISHED
PEL - PERMISSIBLE EXPOSURE LIMIT
NTP - NATIONAL TOXICOLOGY PROGRAM
SARA - SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986
STEL - SHORT TERM EXPOSURE LIMIT
TLV - THRESHOLD LIMIT VALUE(8 HR. TIME WEIGHTED AVERAGE OR TWA)
VOC - VOLATILE ORGANIC COMPOUND
NJRTK - NEW JERSEY RIGHT TO KNOW LAW
N.D. - NOT DETERMINED
This data is offered in good faith as typical values and not as a product
specification. No warranty either expressed or implied, is hereby made.
The recommended industrial hygiene and safe handling procedures are
believed to be generally applicable. However, each user should review the
recommendations in specific context of the intended use and determine if
they are appropriate.
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< End OF MSDS >