Schering-Plough HealthCare Products, Inc.
3030 Jackson Avenue
Memphis, TN 38151
MATERIAL SAFETY DATA SHEET
Schering-Plough urges each user or recipient of this MSDS to read the entire data sheet to become aware of the hazards associated with this material.
SECTION 1. IDENTIFICATION OF SUBSTANCE AND CONTACT INFORMATION
MSDS NAME: Coppertone Lotions (Low/No Oil)
SYNONYM(S): Coppertone Kids Colorblock Spray (Blue, Green) SPF 30
Coppertone Kids Glitter Lotion SPF30
Coppertone Kids Sport Lotion SPF 30
Coppertone Kids Sport Lotion Spray SPF 30
Coppertone Kids Spray SPF 45
Coppertone Kids Spray and Play SPF-30
Coppertone Kids Spray 'n Splash Spray Lotion SPF 30
Coppertone Kids Trigger Spray Lotion SPF 30
Coppertone Oil Free Lotion SPF 8-45
Coppertone Oil Free Faces SPF-30
Coppertone Sport Lotion SPF 8-50
Coppertone Sport Trigger Lotion Spray SPF 30
Coppertone Waterproof Sunscreen Lotion SPF 4 -8
Coppertone Waterbabies Spray Lotion SPF 30-45
MSDS NUMBER: SP000038
EMERGENCY NUMBER(S): Schering-Plough Security Control Center (908) 820-6921 (24 hours)
Safety/Environmental Affairs (901) 320-2384
Transportation Emergencies - CHEMTREC:
(800) 424-9300 (Inside Continental USA)
(703) 527-3887 (Outside Continental USA)
INFORMATION: Safety/Environmental Affairs (901) 320-2384
SCHERING-PLOUGH MSDS HELPLINE: (800) 770-8878 (US and Canada)
(908) 629-3657 (Worldwide)
Monday to Friday, 9am to 5pm (US Eastern Time)
SECTION 2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Lotion
Color according to product specification
Product-specific odor
Consumers: Refer to the package insert or product label for appropriate consumer-specific information about this product when used according to
manufacturer's directions.
POTENTIAL HEALTH EFFECTS:
Although some ingredients used in the manufacture of this product are considered hazardous on an individual basis, the final formulation of this product
is considered non-hazardous when used according to manufacturer's directions.
These products have been shown to be not irritating and not sensitizing to human skin. Eye contact may cause slight eye irritation with temporary
stinging, redness, tearing, and increased blinking.
Coppertone Lotions (Low/No Oil) MSDS NUMBER: SP000038
Latest Revision Date: 20-Jul-2006 Page 1 of 6 Published Date: 20-Jul-2006
LISTED CARCINOGENS
CHEMICAL NAME CAS NUMBER OSHA IARC NTP ACGIH
Triethanolamine 102-71-6 3
Classification
not possible
from current
data.
Listed.
Fields in the above table that do not contain data indicate that the materials have not been classified as human or animal carcinogens.
No carcinogens or potential carcinogens listed by OSHA, IARC, NTP or ACGIH are present in concentrations >0.1% in this mixture. Triethanolamine is
classified by IARC as a Group 3 carcinogen (unclassifiable as to carcinogenicity in humans). Starch is classified by ACGIH as a Group A4 carcinogen
(not classifiable as a human carcinogen).
SECTION 3. COMPOSITION AND INFORMATION ON INGREDIENTS
PRODUCT USE: Consumer product
CHEMICAL FORMULA: Mixture.
The formulations for these products are proprietary information. These formulations have the same hazardous profile; however, the presence of
hazardous ingredients may vary by formulation. Only hazardous ingredients in concentrations of 1% or greater and/or carcinogenic ingredients in
concentrations of 0.1% or greater are listed in the Chemical Composition table. Active ingredients in any concentration are listed.
CHEMICAL COMPOSITION
CHEMICAL NAME CAS NUMBER PERCENT
Homosalate 118-56-9 0-15
Octocrylene 6197-30-4 0-10
Octinoxate 5466-77-3 0-7.5
Oxybenzone 131-57-7 0-6
Octisalate 118-60-5 0-5
Avobenzone 70356-09-1 0-3
Sorbitol 50-70-4 <10
Polyethylene Glycol 25322-68-3 <10
Aluminum Starch Octenylsuccinate 9087-61-0 <10
Propylene Glycol 57-55-6 <10
Stearic Acid 57-11-4 <10
Germaben II Mixture <10
Triethanolamine 102-71-6 <10
ADDITIONAL INFORMATION: This MSDS is written to provide health and safety information for individuals who will be handling the final
product formulation during research, manufacturing, and distribution. For health and safety information for
individual ingredients used during manufacturing, refer to the appropriate MSDS for each ingredient. Refer
to the package insert or product label for handling guidance for the consumer.
SECTION 4. FIRST AID MEASURES
INHALATION: Remove to fresh air. If any trouble breathing, get immediate medical attention. Administer artificial
respiration if breathing has ceased. If irritation or symptoms occur or persist, consult a physician.
SKIN CONTACT: In keeping with good hygienic practices, wash exposed areas thoroughly with soap and water.
EYE CONTACT: In case of eye contact, immediately rinse eyes thoroughly with plenty of water. If wearing contact lenses,
remove only after initial rinse, and continue rinsing eyes for at least 15 minutes. If irritation occurs or
persists, consult a physician.
INGESTION: Rinse mouth with water. If symptoms develop, consult a physician.
SECTION 5. FIRE FIGHTING MEASURES
FLAMMABILITY DATA:
Flash Point: Not determined (liquids) or not applicable (solids).
Coppertone Lotions (Low/No Oil) MSDS NUMBER: SP000038
Latest Revision Date: 20-Jul-2006 Page 2 of 6 Published Date: 20-Jul-2006
SPECIAL FIRE FIGHTING PROCEDURES:
Wear full protective clothing and self-contained breathing apparatus (SCBA).
SUITABLE EXTINGUISHING MEDIA:
Carbon dioxide (CO2), extinguishing powder or water spray.
See Section 9 for Physical and Chemical Properties.
SECTION 6. ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS:
Wear appropriate personal protective equipment as specified in Section 8. Keep personnel away from the clean-up area.
SPILL RESPONSE / CLEANUP:
All spills should be handled according to site requirements and based on precautions cited in the MSDS. In the case of liquids, use proper absorbent
materials. For laboratories and small-scale operations, incidental spills within a hood or enclosure should be cleaned by using a HEPA filtered vacuum or
wet cleaning methods as appropriate. For large dry or liquid spills or those spills outside enclosure or hood, appropriate emergency response personnel
should be notified. In manufacturing and large-scale operations, HEPA vacuuming prior to wet mopping or cleaning is required.
See Sections 9 and 10 for additional physical, chemical, and hazard information.
SECTION 7. HANDLING AND STORAGE
HANDLING:
Keep containers adequately sealed during material transfer, transport, or when not in use.
Appropriate handling of this material is dependent on many factors, including physical form, duration and frequency of process or task, and effectiveness
of engineering controls. Site-specific risk assessments should be conducted to determine the feasibility and the appropriateness of all exposure control
measures. See Section 8 (Exposure Controls) for additional guidance.
STORAGE:
Store in a cool, dry, well ventilated area.
See Section 8 for exposure controls and additional safe handling information.
SECTION 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION
EXPOSURE CONTROLS:
The health hazard risks of handling this material are dependent on many factors, including physical form, duration and frequency of process or task, and
effectiveness of engineering controls. Site-specific risk assessments should be conducted to determine the feasibility and the appropriateness of all
exposure control measures. Exposure controls for normal operating or routine procedures follow a tiered strategy. Engineering controls are the
preferred means of long-term or permanent exposure control. If engineering controls are not feasible, appropriate use of personal protective equipment
(PPE) may be considered as alternative control measures. Exposure controls for non-routine operations must be evaluated and addressed as part of
the site-specific risk assessment.
RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT (PPE):
Respiratory Protection: None required for consumer use of this product.
Respiratory protective equipment (RPE) may be required for certain laboratory and large-scale
manufacturing tasks if potential airborne breathing zone concentrations of substances exceed the relevant
exposure limit(s). Workplace risk assessment should be completed before specifying and implementing
RPE usage. Potential exposure points and pathways, task duration and frequency, potential employee
contact with the substance, and the ability of the substance to be rendered airborne during specific tasks
should be evaluated. Initial and ongoing strategies of quantitative exposure measurement should be
obtained as required by the workplace risk assessment. All RPE must conform to local and regional
specifications for efficacy and performance. Consult your site or corporate health and safety professional
for additional guidance.
Skin Protection: None required for consumer use of this product.
Gloves that provide an appropriate barrier to the skin are recommended if there is potential for contact with
this material. Consult your site safety staff for guidance.
Eye Protection: None required for consumer use of this product.
Safety glasses with side shields. Use of goggles or full face protection may be required based on hazard,
potential for contact, or level of exposure. Consult your site safety staff for guidance.
Coppertone Lotions (Low/No Oil) MSDS NUMBER: SP000038
Latest Revision Date: 20-Jul-2006 Page 3 of 6 Published Date: 20-Jul-2006
Body Protection: None required for consumer use of this product.
In small-scale or laboratory operations, lab coats or equivalent protection is required. Disposable Tyvek or
other dust impermeable suit should be considered based on procedure or level of exposure. Use of
additional PPE such as shoe coverings, gauntlets, hood, or head covering may be necessary. Consult
your site safety staff for guidance.
In large-scale or manufacturing operations, disposable Tyvek or other dust impermeable suit is
recommended and based on level of exposure. Use of additional PPE such as shoe coverings, gauntlets,
hood, or head covering may be necessary. Consult your site safety staff for guidance.
EXPOSURE LIMIT VALUES
CHEMICAL NAME CAS NUMBER ACGIH TLV (TWA) OSHA PEL (TWA)
5 mg/m3
Triethanolamine 102-71-6
Fields in the above table(s) that do not contain data indicate that exposure limits are not available for those endpoints.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
FORM: Lotion
COLOR: Color according to product specification
ODOR: Product-specific odor
pH: 3.5 to 6 at 100% concentration
SPECIFIC GRAVITY: 0.950 to 1.03
SOLUBILITY:
Water: Slightly soluble
See Section 5 for flammability/explosivity information.
SECTION 10. STABILITY AND REACTIVITY
STABILITY/ REACTIVITY:
Stable under normal conditions.
INCOMPATIBLE MATERIALS / CONDITIONS TO AVOID:
None known.
HAZARDOUS DECOMPOSITION PRODUCTS / REACTIONS:
No dangerous decomposition is expected if used according to manufacturer's specifications.
SECTION 11. TOXICOLOGICAL INFORMATION
Although some ingredients used in the manufacture of this product are considered hazardous on an individual basis, the final formulation of this product
is considered non-hazardous when used according to manufacturer's directions.
ACUTE TOXICITY DATA
PRODUCT / CHEMICAL NAME EXPOSURE ROUTE STUDY DESCRIPTION RESULT
Coppertone Lotions (Low/No Oil) Oral LD50 Practically not toxic
Eye Eye Irritation Slightly irritating
Skin Skin Sensitization Not sensitizing
Skin Irritation Practically not irritating
REPEAT DOSE TOXICITY DATA
These products have not been tested for repeat dose toxicity.
CARCINOGENICITY:
This material or product has not been evaluated for carcinogenicity.
ADDITIONAL INFORMATION:
Negative in a phototoxicity study. Negative in photoallergy study.
SECTION 12. ECOLOGICAL INFORMATION
ECOTOXICITY DATA
Coppertone Lotions (Low/No Oil) MSDS NUMBER: SP000038
Latest Revision Date: 20-Jul-2006 Page 4 of 6 Published Date: 20-Jul-2006
This product has not been tested for ecotoxicity.
ENVIRONMENTAL DATA
There are no environmental data available for this product.
SECTION 13. DISPOSAL CONSIDERATIONS
MATERIAL WASTE:
Disposal must be in accordance with applicable federal, state/provincial, and/or local regulations. Incineration is the preferred method of disposal, when
appropriate. Operations that involve the crushing or shredding of waste materials or returned goods must be handled to meet the recommended
exposure limit(s).
PACKAGING AND CONTAINERS:
Disposal must be in accordance with applicable federal, state/provincial, and/or local regulations.
SECTION 14. TRANSPORT INFORMATION
This material is not subject to the transportation regulations of DOT, IATA, IMO, and the ADR.
SECTION 15. REGULATORY INFORMATION
TSCA LISTING
CHEMICAL NAME TSCA
Homosalate Listed.
Octocrylene Listed.
Octinoxate Listed.
Oxybenzone Listed.
Octisalate Listed.
Avobenzone Listed.
Sorbitol Listed.
Polyethylene Glycol Listed
Aluminum Starch Octenylsuccinate Listed
Propylene Glycol Listed
Stearic Acid Listed
Triethanolamine Listed
U.S. STATE REGULATIONS
CHEMICAL NAME California CARTK NJRTK CTRTK MARTK
Proposition 65
Triethanolamine Listed.
CHEMICAL NAME PARTK MNRTK MIRTK ILRTK LARTK RIRTK
Polyethylene Glycol Listed.
Propylene Glycol Listed. Listed. Listed.
Triethanolamine Listed. Listed. Listed.
Fields in the above tables that do not contain data indicate that those materials have not been listed by local regulations.
SECTION 16. OTHER INFORMATION
Although reasonable care has been taken in the preparation of this document, we extend no warranties and make no representations as to the accuracy
or completeness of the information contained therein, and assume no responsibility regarding the suitability of this information for the user's intended
purposes or for the consequence of its use. Each individual should make a determination as to the suitability of the information for their particular
purpose(s).
DEPARTMENT ISSUING MSDS: Global Safety and Environmental Affairs
Occupational and Environmental Toxicology
Schering-Plough Corporation
1095 Morris Avenue
Union, NJ 07083 USA
Coppertone Lotions (Low/No Oil) MSDS NUMBER: SP000038
Latest Revision Date: 20-Jul-2006 Page 5 of 6 Published Date: 20-Jul-2006
SCHERING-PLOUGH MSDS HELPLINE: (800) 770-8878 (US and Canada)
(908) 629-3657 (Worldwide)
Monday to Friday, 9am to 5pm (US Eastern Time)
MSDS CREATION DATE: 12-Aug-1999
SUPERSEDES DATE: 22-Aug-2005
Coppertone Lotions (Low/No Oil) MSDS NUMBER: SP000038
Latest Revision Date: 20-Jul-2006 Page 6 of 6 Published Date: 20-Jul-2006
|