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MATERIAL SAFETY DATA SHEET
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SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
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PRODUCT NAME : SONNEBORN 200 ADHESIVE
IDENTIFICATION NUMBER: SB200 DATE PRINTED: 03/19/99
PRODUCT USE/CLASS : Adhesive
SUPPLIER: MANUFACTURER:
ChemRex Inc.
Sonneborn Building Products
889 Valley Park Drive
Shakopee, MN 55379
EMERGENCY TELEPHONE: EMERGENCY TELEPHONE:(800)424-9300
24 HRS A DAY 7 DAYS A WEEK
PREPARER: Scott Shinn, PHONE: 612-496-6000, PREPARE DATE: 01/08/99
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SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS
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WT/WT %
ITEM ------------ CHEMICAL NAME ------------- CAS NUMBER LESS THAN
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01 n-hexane 110-54-3 5.0 %
02 Silica, quartz 14808-60-7 1.0 %
03 Calcium carbonate 471-34-1 60.0 %
04 magnesium carbonate 546-93-0 5.0 %
05 Naptha petroleum hydrotreated light 64742-49-0 20.0 %
---------------------- EXPOSURE LIMITS --------------------
ACGIH OSHA COMPANY
ITEM TLV-TWA TLV-STEL PEL-TWA PEL-CEILING TLV-TWA SKIN
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01 50 ppm N.E. 180 mg/m3 N.E. N.E. NO
02 .1 mg/m3 N.E. .1 mg/m3 N.E. N.E. NO
03 10 mg/m3 N.E. 15 mg/m3 N.E. N.E. NO
04 10 mg/m3 N.E. 15 mg/m3 N.E. N.E. NO
05 1760 mg/m 3500 mg/m 1760 mg/m3 N.E. N.E. NO
(See Section 16 for abbreviation legend)
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SECTION 3 - HAZARDOUS IDENTIFICATION
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EFFECTS OF OVEREXPOSURE - EYE CONTACT: Irritating, but will not
permanently injure eye tissue.
EFFECTS OF OVEREXPOSURE - SKIN CONTACT: Causes skin irritation. Allergic
reactions are possible.
(Continued on Page 2)
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Product: SB200 Preparation Date: 01/08/99 Page 2
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SECTION 3 - HAZARDS IDENTIFICATION
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EFFECTS OF OVEREXPOSURE - INHALATION: Headaches, dizziness, nausea,
decreased blood pressure, changes in heart rate and cyanosis may result
from over-exposure to vapor. Prolonged inhalation may be harmful.
EFFECTS OF OVEREXPOSURE - INGESTION: Irritating to mouth, throat and
stomach.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: Chronic overexposure to
n-Hexane may cause peripheral polyneuropathy and central nerve damage.
This product contains solvents. Reports associate repeated and prolonged
occupational overexposure to solvents with permanent brain and nervous
system damage. Reports also indicate that solvents cause liver damage,
kidney damage, and mucous membrane irritation. Be warned that intentional
misuse by deliberately inhaling the vapors and/or the product contents (a
process often called "sniffing") may be harmful or fatal. Preexisting
respiratory or skin condition(s) may be aggravated by exposure. This
product contains silicon dioxide [quartz] which has been listed as a
suspected human carcinogen by NTP and IARC.
PRIMARY ROUTE(S) OF ENTRY: SKIN CONTACT INHALATION EYE CONTACT
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SECTION 4 - FIRST AID MEASURES
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FIRST AID - EYE CONTACT: Flush eye with water for 15 minutes. Get medical
attention.
FIRST AID - SKIN CONTACT: Remove contaminated clothing and shoes. Wash
affected area(s) throughly with soap and water. If irritation persist,
seek medical attention.
FIRST AID - INHALATION: Remove to fresh air. If not breathing, give
artificial respiration. If breathing is difficult, give oxygen. Get
immediate medical attention.
FIRST AID - INGESTION: Get medical attention immediately. If swallowed,
DO NOT induce vomiting. Give victim a glass of water or milk. Call a
physician or poison control center immediately. Never give anything by
mouth to an unconscious person. Should vomiting occur, be sure to keep
victum's head below hips to avoid aspiration of vomitus into lungs.
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SECTION 5 - FIRE FIGHTING MEASURES
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FLASH POINT: <0 F LOWER EXPLOSIVE LIMIT: 1.0 %
(TAGLIABUE CLOSED CUP) UPPER EXPLOSIVE LIMIT: 8.0 %
AUTOIGNITION TEMPERATURE: N/D
EXTINGUISHING MEDIA: ALCOHOL FOAM CO2 DRY CHEMICAL FOAM WATER FOG
UNUSUAL FIRE AND EXPLOSION HAZARDS: Fire produces irritating or poisonous
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Product: SB200 Preparation Date: 01/08/99 Page 3
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SECTION 5 - FIRE FIGHTING MEASURES
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gas. Vapors can travel to a source of ignition and flash back. "Empty"
containers retain product residue (liquid and/or vapor) and can be
dangerous. DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR
EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER
SOURCES OF IGNITION; CONTAINERS MAY EXPLODE AND CAUSE INJURY OR DEATH.
Solid stream of water or foam may cause frothing.
SPECIAL FIREFIGHTING PROCEDURES: Containers exposed to fire should be kept
cool with water spray. Containers can build up pressure if exposed to heat
(fire). As in any fire, wear self-contained breathing apparatus
pressure-demand (MSHA/NIOSH approved or equivalent) and full protective
gear.
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SECTION 6 - ACCIDENTAL RELEASE MEASURES
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STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Ventilate the
area and remove all sources of ignition. Evacuate unneccessary personnel.
Large spills should be handled carefully. Put on respiratory protection
and necessary personal protective equipment. Dike or impound spilled
liquid. Absorb spill with inert material (e.g. dry sand or earth), then
place in a chemical waste container. Repeat sorbent/sweep cycle until the
spill has dried up. Avoid runoff into storm sewers and ditches which lead
to waterways.
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SECTION 7 - HANDLING AND STORAGE
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HANDLING: Use only in a well ventilated area. Keep out of reach of
children. Ground and bound containers when transferring material. If user
operations generate dust, fume, or mist, use ventilation to keep exposure
to airborne contaminents below the exposure limit.
STORAGE: Keep away from heat, sparks and flame. Keep container closed
when not in use.
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SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION
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ENGINEERING CONTROLS: Local exhaust ventilation may be necessary to
control any air contaminants to within their TLVs during the use of this
product.
RESPIRATORY PROTECTION: Wear NIOSH/MSHA approved respiratory protection
when the product is mixed or applied in a poorly ventilated area or if
workplace levels of ingredients exceed the TLV. Follow applicable federal,
state, and local regulations.
OTHER PROTECTIVE EQUIPMENT: Where contact is likely, wear chemical
resistant gloves, chemical safety goggles with a face sheild, and clean
protective clothing to cover arms and legs to keep exposure to a minimum.
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Product: SB200 Preparation Date: 01/08/99 Page 4
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SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION
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HYGIENIC PRACTICES: Do not take internally. Remove contaminated clothing
and wash before reuse. Avoid breathing vapors from heated material. Avoid
contact with eyes, skin, and clothing.
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SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
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BOILING RANGE : 149 - 159 F VAPOR DENSITY : Is heavier than air
ODOR : Strong solvent ODOR THRESHOLD : N/D
APPEARANCE : Smooth semi-pasteEVAPORATION RATE: Is faster than Butyl
SOLUBILITY IN H2O : Slight <0.1% Acetate
FREEZE POINT : N/D SPECIFIC GRAVITY: 1.3600
VAPOR PRESSURE : N/D pH @ 0.0 % : N/D
PHYSICAL STATE : Paste VISCOSITY : N/D
COEFFICIENT OF WATER/OIL DISTRIBUTION: N/D
(See Section 16 for abbreviation legend)
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SECTION 10 - STABILITY AND REACTIVITY
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CONDITIONS TO AVOID: Sources of ignition. Long term exposure to elevated
temperatures.
INCOMPATIBILITY: Avoid contact with oxidizing material.
HAZARDOUS DECOMPOSITION PRODUCTS: No Information.
HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.
STABILITY: This product is stable under normal storage conditions.
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SECTION 11 - TOXICOLOGICAL PROPERTIES
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PRODUCT DERMAL LD50: No Information PRODUCT ORAL LD50: No Information
PRODUCT LC50: No Information
COMPONENT TOXICOLOGICAL INFORMATION:
---- CHEMICAL NAME ---- -- DERMAL LD50 -- --- ORAL LD50 --- ------ LC50 -----
n-hexane No Information 45 ml/kg 48000 ppm/4H
Silica, quartz No Information No Information No Information
Calcium carbonate No Information 6450 mg/kg No Information
magnesium carbonate No Information > 9000 mg/kg No Information
Naptha petroleum hydrot No Information No Information No Information
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Product: SB200 Preparation Date: 01/08/99 Page 5
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SECTION 12 - ECOLOGICAL INFORMATION
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ECOLOGICAL INFORMATION: No Information.
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SECTION 13 - DISPOSAL CONSIDERATIONS
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DISPOSAL METHOD: Review all local, state, and federal regulations
concerning health and pollution for appropriate disposal procedures.
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SECTION 14 - TRANSPORTATION INFORMATION
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DOT PROPER SHIPPING NAME: Adhesive
DOT TECHNICAL NAME:
DOT HAZARD CLASS: FLAMMABLE LIQUID HAZARD SUBCLASS: N/A
DOT UN/NA NUMBER: UN1133 PACKING GROUP: III RESP. GUIDE PAGE:
DOT PLACARD AT: 1000 lbs
DOT CLASS NUMBER: 3
UN PROPER SHIPPING NAME: Adhesive
UN HAZARD CLASS: FLAMMABLE LIQUID
UN CLASS NUMBER: AIR 3 MARINE 3.3
HAZARD SUBCLASS: AIR N/A MARINE N/A
UN UN/NA NUMBER: UN1133 UN PACKING GROUP: AIR III MARINE III
UN PLACARD AT: N/A
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SECTION 15 - REGULATORY INFORMATION
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U.S. FEDERAL REGULATIONS: AS FOLLOWS -
OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR
1910.1200)
CERCLA - SARA HAZARD CATEGORY:
This product has been reviewed according to the EPA 'Hazard Categories'
promulgated under Sections 311 and 312 of the Superfund Amendment and
Reauthorization Act of 1986 (SARA Title III) and is considered, under
applicable definitions, to meet the following categories:
IMMEDIATE HEALTH HAZARD CHRONIC HEALTH HAZARD FIRE HAZARD
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Product: SB200 Preparation Date: 01/08/99 Page 6
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SECTION 15 - REGULATORY INFORMATION
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SARA SECTION 313:
This product contains the following substances subject to the reporting
requirements of Section 313 of Title III of the Superfund Amendments and
Reauthorization Act of 1986 and 40 CFR Part 372:
----------- CHEMICAL NAME ----------- CAS NUMBER WT/WT % IS LESS THAN
n-hexane 110-54-3 5.0 %
TOXIC SUBSTANCES CONTROL ACT:
This product contains the following chemical substances subject to the
reporting requirements of TSCA 12(B) if exported from the United States:
----------- CHEMICAL NAME ----------- CAS NUMBER
n-hexane 110-54-3
CALIFORNIA PROPOSITION 65:
WARNING: The chemical(s) noted below and contained in this product, are
known to the state of California to cause cancer, birth defects or other
reproductive harm:
----------- CHEMICAL NAME ----------- CAS NUMBER
Silica, quartz 14808-60-7
INTERNATIONAL REGULATIONS: AS FOLLOWS -
CANADIAN WHMIS: This MSDS has been prepared in compliance with Controlled
Product Regulations except for use of the 16 headings.
CANADIAN WHMIS CLASS: No information available.
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SECTION 16 - OTHER INFORMATION
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HMIS RATINGS - HEALTH: 2 FLAMMABILITY: 3 REACTIVITY: 0
PERSONAL PROTECTION: B
PREVIOUS MSDS REVISION DATE: 02/11/97
REASON FOR REVISION: Change in extinguishing media
VOLATILE ORGANIC COMPOUNDS (VOCS): 2.31 lbs/gal, 277 grams/ltr
LEGEND: N.A. - Not Applicable, N.E. - Not Established,
N.D. - Not Determined
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(Continued on Page 7)
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Product: SB200 Preparation Date: 01/08/99 Page 7
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DISCLAIMER
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This information is furnished without warranty, representation, or license
of any kind, except that this information is accurate to the best of
ChemRex's knowledge, or is obtained from sources believed by ChemRex to be
accurate. No warranty is expressed or implied regarding the accuracy of
this information or the results to be obtained from its use thereof.
Chemrex assumes no responsibility for injuries proximately caused by use of
the Material if reasonable safety procedures are not followed as stipulated
in this Data Sheet. Additionally, ChemRex assumes no responsibility for
injuries proximately caused by abnormal use of the Material even if
reasonable safety procedures are followed. Buyer assumes the risk in its
use of the Material.
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