3M MATERIAL SAFETY DATA SHEET 3M(TM) Acryl-Marine Putty - White, P.N. 05962, 05963 11/18/2005
Material Safety Data Sheet
Copyright, 2005, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly
utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is
obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit
thereon.
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: 3M(TM) Acryl-Marine Putty - White, P.N. 05962, 05963
MANUFACTURER: 3M
DIVISION: Marine & Specialty Vehicle
ADDRESS: 3M Center
St. Paul, MN 55144-1000
EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours)
Issue Date: 11/18/2005
Supercedes Date: 05/14/2004
Document Group: 10-2849-7
Product Use:
Specific Use: Filler for boat pinholes, scratches and other defects
SECTION 2: INGREDIENTS
Ingredient C.A.S. No. % by Wt
TALC 14807-96-6 30 - 40
TITANIUM DIOXIDE 13463-67-7 7 - 13
TOLUENE 108-88-3 7 - 13
N-BUTYL ACETATE 123-86-4 5 - 10
MAGNESIUM CARBONATE 546-93-0 1 - 10
XYLENE 1330-20-7 5 - 10
ACRYLIC POLYMER Trade Secret 5 - 10
CELLULOSE ACETATE BUTYRATE 9004-36-8 5 - 10
BUTYL BENZYL PHTHALATE 85-68-7 1- 5
ISOPROPYL ALCOHOL 67-63-0 1- 5
ETHYLBENZENE 100-41-4 1- 5
DOLOMITE 16389-88-1 < 1.5
TREATED CLAY 71011-26-2 < 1.5
ETHYL ACRYLATE 140-88-5 < 0.1
BENZENE 71-43-2 < 0.05
SECTION 3: HAZARDS IDENTIFICATION
3.1 EMERGENCY OVERVIEW
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3M MATERIAL SAFETY DATA SHEET 3M(TM) Acryl-Marine Putty - White, P.N. 05962, 05963 11/18/2005
Specific Physical Form: Paste
Odor, Color, Grade: viscous, white, solvent odor
General Physical Form: Liquid
Immediate health, physical, and environmental hazards: Flammable liquid and vapor. Closed containers exposed to heat from
fire may build pressure and explode. Vapors may travel long distances along the ground or floor to an ignition source and flash back.
Contains a chemical or chemicals which can cause cancer. May cause target organ effects. Contains a chemical or chemicals which
can cause birth defects or other reproductive harm.
3.2 POTENTIAL HEALTH EFFECTS
Eye Contact:
Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision.
Skin Contact:
Moderate Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness.
May be absorbed through skin and cause target organ effects.
Inhalation:
Upper Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose
and throat pain.
During grinding, scraping, sanding:
Pneumoconiosis: Sign/symptoms may include persistent cough, breathlessness, chest pain, increased amounts of sputum, and
changes in lung function tests.
May be absorbed following inhalation and cause target organ effects.
Ingestion:
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, nausea, diarrhea and vomiting.
May be absorbed following ingestion and cause target organ effects.
Target Organ Effects:
Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea,
slowed reaction time, slurred speech, giddiness, and unconsciousness.
Central Neuropathy: Signs/symptoms may include irritability, memory impairment, personality changes, sleep disorders, and
decreased ability to concentrate.
Blood Effects: Signs/symptoms may include generalized weakness and fatigue, skin pallor, and fever.
Liver Effects: Signs/symptoms may include loss of appetite, weight loss, fatigue, weakness, abdominal tenderness and jaundice.
Kidney Effects: Signs/symptoms may include reduced or absent urine production, increased serum creatinine, lower back pain,
increased protein in urine, and increased blood urea nitrogen (BUN).
Contains a chemical or chemicals which can cause birth defects or other reproductive harm.
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3M MATERIAL SAFETY DATA SHEET 3M(TM) Acryl-Marine Putty - White, P.N. 05962, 05963 11/18/2005
Carcinogenicity:
Contains a chemical or chemicals which can cause cancer.
Ingredient C.A.S. No. Class Description Regulation
BENZENE 71-43-2 Group 1 International Agency for Research on Cancer
BENZENE 71-43-2 Known human carcinogen National Toxicology Program Carcinogens
BENZENE 71-43-2 Cancer hazard OSHA Carcinogens
ETHYL ACRYLATE 140-88-5 Group 2B International Agency for Research on Cancer
ETHYLBENZENE 100-41-4 Group 2B International Agency for Research on Cancer
SECTION 4: FIRST AID MEASURES
4.1 FIRST AID PROCEDURES
The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are
followed.
Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention.
Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical
attention. Wash contaminated clothing and clean shoes before reuse.
Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention.
If Swallowed: Do not induce vomiting. Give victim two glasses of water. Never give anything by mouth to an unconscious
person. Get immediate medical attention.
SECTION 5: FIRE FIGHTING MEASURES
5.1 FLAMMABLE PROPERTIES
No Data Available
Autoignition temperature
63 篎 [Test Method: Closed Cup]
Flash Point
1.00 %
Flammable Limits - LEL
15.00 %
Flammable Limits - UEL
Class IB Flammable Liquid
OSHA Flammability Classification:
5.2 EXTINGUISHING MEDIA
Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide).
5.3 PROTECTION OF FIRE FIGHTERS
Special Fire Fighting Procedures: Water may not effectively extinguish fire; however, it should be used to keep fire-exposed
containers and surfaces cool and prevent explosive rupture. Water may be used to blanket the fire. Wear full protective equipment
(Bunker Gear) and a self-contained breathing apparatus (SCBA).
Unusual Fire and Explosion Hazards: Flammable liquid and vapor. Closed containers exposed to heat from fire may build
pressure and explode. Vapors may travel long distances along the ground or floor to an ignition source and flash back.
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3M MATERIAL SAFETY DATA SHEET 3M(TM) Acryl-Marine Putty - White, P.N. 05962, 05963 11/18/2005
Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition
information.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Accidental Release Measures: Refer to other sections of this MSDS for information regarding physical and health hazards,
respiratory protection, ventilation, and personal protective equipment. Call 3M-HELPS line (1-800-364-3577) for more information
on handling and managing the spill. Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up
by qualified personnel. Remove all ignition sources such as flames, smoking materials, and electrical spark sources. Use only non-
sparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to
disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and
could cause flammable gases or vapors in the spill area to burn or explode. Contain spill. For larger spills, cover drains and build
dikes to prevent entry into sewer systems or bodies of water. Cover spill area with a fire-extinguishing foam. An aqueous film
forming foam (AFFF) is recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or
commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an
absorbent material does not remove a toxic, corrosivity or flammability hazard. Collect as much of the spilled material as possible
using non-sparking tools. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the
area with fresh air. Read and follow safety precautions on the solvent label and MSDS. Collect the resulting residue containing
solution. Place in a metal container approved for transportation by appropriate authorities. Seal the container. Dispose of collected
material as soon as possible.
In the event of a release of this material, the user should determine if the release qualifies as reportable according to
local, state, and federal regulations.
SECTION 7: HANDLING AND STORAGE
7.1 HANDLING
Keep out of the reach of children. Contents may be under pressure, open carefully. Avoid eye contact with vapors, mists, or spray.
Avoid skin contact. Avoid breathing of vapors, mists or spray. Avoid breathing of dust created by cutting, sanding, grinding or
machining. Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Avoid static
discharge. Keep away from heat, sparks, open flame, pilot lights and other sources of ignition. Avoid contact with oxidizing agents.
7.2 STORAGE
Keep container in well-ventilated area. Keep container tightly closed. Store away from heat. Store out of direct sunlight. Store away
from acids. Store away from oxidizing agents.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 ENGINEERING CONTROLS
Use with appropriate local exhaust ventilation. Provide appropriate local exhaust ventilation on open containers. Provide appropriate
local exhaust for cutting, grinding, sanding or machining.
8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE)
8.2.1 Eye/Face Protection
Avoid eye contact with vapors, mists, or spray.
The following eye protection(s) are recommended: Safety Glasses with side shields, Indirect Vented Goggles.
8.2.2 Skin Protection
Avoid skin contact.
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3M MATERIAL SAFETY DATA SHEET 3M(TM) Acryl-Marine Putty - White, P.N. 05962, 05963 11/18/2005
Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with
your glove and/or protective clothing manufacturer for selection of appropriate compatible materials.
Gloves made from the following material(s) are recommended: Polyvinyl Alcohol (PVA), Polyethylene/Ethylene Vinyl Alcohol.
8.2.3 Respiratory Protection
Avoid breathing of vapors, mists or spray. Avoid breathing of dust created by cutting, sanding, grinding or machining.
Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with
OSHA regulations: Half facepiece or fullface air-purifying respirator with organic vapor cartridges and N95 particulate prefilters.
Consult the current 3M Respiratory Selection Guide for additional information or call 1-800-243-4630 for 3M technical assistance.
8.2.4 Prevention of Swallowing
Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water.
8.3 EXPOSURE GUIDELINES
Ingredient Authority Type Limit Additional Information
BENZENE ACGIH TWA 0.5 ppm Skin Notation*; Table A1
BENZENE ACGIH STEL 2.5 ppm Skin Notation*; Table A1
BENZENE OSHA TWA 1 ppm Standard Appendix
BENZENE OSHA STEL 5 ppm Standard Appendix
ETHYL ACRYLATE ACGIH TWA 5 ppm Table A4
ETHYL ACRYLATE ACGIH STEL 15 ppm Table A4
ETHYL ACRYLATE OSHA TWA 5 ppm Skin Notation*; Table Z-1A
ETHYL ACRYLATE OSHA STEL 25 ppm Skin Notation*; Table Z-1A
ETHYLBENZENE ACGIH TWA 100 ppm Table A3
ETHYLBENZENE ACGIH STEL 125 ppm Table A3
ETHYLBENZENE OSHA TWA 100 ppm Table Z-1A
ETHYLBENZENE OSHA STEL 125 ppm Table Z-1A
ISOPROPYL ALCOHOL ACGIH TWA 200 ppm Table A4
ISOPROPYL ALCOHOL ACGIH STEL 400 ppm Table A4
ISOPROPYL ALCOHOL OSHA TWA 400 ppm Table Z-1A
ISOPROPYL ALCOHOL OSHA STEL 500 ppm Table Z-1A
MAGNESIUM CARBONATE ACGIH TWA 10 mg/m3
MAGNESIUM CARBONATE OSHA TWA, respirable 5 mg/m3 Table Z-1
MAGNESIUM CARBONATE OSHA TWA, as total dust 15 mg/m3 Table Z-1
N-BUTYL ACETATE ACGIH TWA 150 ppm
N-BUTYL ACETATE ACGIH STEL 200 ppm
N-BUTYL ACETATE OSHA TWA 150 ppm Table Z-1A
N-BUTYL ACETATE OSHA STEL 200 ppm Table Z-1A
POLYETHYLENE GLYCOLS AIHA TWA, as aerosol 10 mg/m3
TALC ACGIH TWA, respirable 2 mg/m3 Table A4
TALC CMRG TWA, as respirable 0.5 mg/m3
dust
TALC OSHA TWA, respirable 2 mg/m3 Table Z-1A
TITANIUM DIOXIDE ACGIH TWA 10 mg/m3 Table A4
TITANIUM DIOXIDE CMRG TWA, as respirable 5 mg/m3
dust
TITANIUM DIOXIDE OSHA TWA, Vacated, as 10 mg/m3
dust
TITANIUM DIOXIDE OSHA TWA, as total dust 15 mg/m3 Table Z-1
TOLUENE ACGIH TWA 50 ppm Skin Notation*; Table A4
TOLUENE CMRG STEL 75 ppm Skin Notation*
TOLUENE OSHA TWA, Vacated 100 ppm
TOLUENE OSHA STEL, Vacated 150 ppm
TOLUENE OSHA TWA 200 ppm Table Z-2
TOLUENE OSHA CEIL 300 ppm Table Z-2
XYLENE ACGIH TWA 100 ppm Table A4
XYLENE ACGIH STEL 150 ppm Table A4
XYLENE OSHA TWA 100 ppm Table Z-1A
XYLENE OSHA STEL 150 ppm Table Z-1A
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3M MATERIAL SAFETY DATA SHEET 3M(TM) Acryl-Marine Putty - White, P.N. 05962, 05963 11/18/2005
* Substance(s) refer to the potential contribution to the overall exposure by the cutaneous route including mucous membrane and eye,
either by airborne or, more particularly, by direct contact with the substance. Vehicles can alter skin absorption.
VAC Vacated PEL:Vacated Permissible Exposure Limits [PEL] are enforced as the OSHA PEL in some states. Check with your local
regulatory agency.
SOURCE OF EXPOSURE LIMIT DATA:
ACGIH: American Conference of Governmental Industrial Hygienists
CMRG: Chemical Manufacturer Recommended Guideline
OSHA: Occupational Safety and Health Administration
AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL)
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Paste
Specific Physical Form:
viscous, white, solvent odor
Odor, Color, Grade:
Liquid
General Physical Form:
No Data Available
Autoignition temperature
63 篎 [Test Method: Closed Cup]
Flash Point
1.00 %
Flammable Limits - LEL
15.00 %
Flammable Limits - UEL
180 篎 [Details: CONDITIONS: Isopropyl Alcohol]
Boiling point
4.00 [Ref Std: AIR=1]
Vapor Density
<=27 psia [@ 131.0000000000 篎] [Details: MITS data]
Vapor Pressure
1.480 - 1.530 [Ref Std: WATER=1]
Specific Gravity
Not Applicable
pH
No Data Available
Melting point
Nil
Solubility in Water
Approximately 1.9 Units not avail. or not appl. [Ref Std:
Evaporation rate
TOLUENE=1]
3.74 lb/gal [Test Method: calculated SCAQMD rule 443.1]
Volatile Organic Compounds
29.74 %
Percent volatile
448.49 g/l [Test Method: calculated SCAQMD rule 443.1]
VOC Less H2O & Exempt Solvents
100000 - 200000 centipoise
Viscosity
SECTION 10: STABILITY AND REACTIVITY
Stability: Stable.
Materials and Conditions to Avoid: None known
Hazardous Polymerization: Hazardous polymerization will not occur.
Hazardous Decomposition or By-Products
Substance Condition
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3M MATERIAL SAFETY DATA SHEET 3M(TM) Acryl-Marine Putty - White, P.N. 05962, 05963 11/18/2005
Carbon monoxide Not Specified
Carbon dioxide Not Specified
Toxic Vapor, Gas, Particulate Not Specified
SECTION 11: TOXICOLOGICAL INFORMATION
Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its
components.
SECTION 12: ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
Not determined.
CHEMICAL FATE INFORMATION
Not determined.
SECTION 13: DISPOSAL CONSIDERATIONS
Waste Disposal Method: Incinerate in a permitted hazardous waste incinerator. As a disposal alternative, dispose of waste product
in a permitted hazardous waste facility.
EPA Hazardous Waste Number (RCRA): D001 (Ignitable), D018 (Benzene)
Since regulations vary, consult applicable regulations or authorities before disposal.
SECTION 14:TRANSPORT INFORMATION
ID Number(s):
60-9800-0924-9, 60-9800-2096-4
Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this
material.
SECTION 15: REGULATORY INFORMATION
US FEDERAL REGULATIONS
Contact 3M for more information.
311/312 Hazard Categories:
Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes
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3M MATERIAL SAFETY DATA SHEET 3M(TM) Acryl-Marine Putty - White, P.N. 05962, 05963 11/18/2005
Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA):
Ingredient C.A.S. No % by Wt
TOLUENE 108-88-3 7 - 13
XYLENE 1330-20-7 5 - 10
ETHYLBENZENE 100-41-4 1- 5
This material contains a chemical which requires export notification under TSCA Section 12[b]:
Ingredient (Category if applicable) C.A.S. No Regulation Status
N-BUTYL ACETATE 123-86-4 Toxic Substances Control Act (TSCA) 4 Test Applicable
Rule Chemicals
STATE REGULATIONS
Contact 3M for more information.
CALIFORNIA PROPOSITION 65
Ingredient C.A.S. No. Classification
ETHYL ACRYLATE 140-88-5 **Carcinogen
TOLUENE 108-88-3 *Developmental Toxin
BENZENE 71-43-2 *Developmental Toxin
BENZENE 71-43-2 **Carcinogen
BENZENE 71-43-2 *Male reproductive toxin
* WARNING: contains a chemical or chemicals which can cause birth defects or other reproductive harm.
** WARNING: contains a chemical which can cause cancer.
CHEMICAL INVENTORIES
The components of this product are in compliance with the chemical notification requirements of TSCA.
All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS),
or are exempt polymers whose monomers are listed on EINECS.
Contact 3M for more information.
Additional Information: For technical service and product information/support, call 1-877-366-2746 (1-877-3M MARINE).
INTERNATIONAL REGULATIONS
Contact 3M for more information.
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3M MATERIAL SAFETY DATA SHEET 3M(TM) Acryl-Marine Putty - White, P.N. 05962, 05963 11/18/2005
This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: OTHER INFORMATION
NFPA Hazard Classification
Health: 2 Flammability: 3 Reactivity: 0 Special Hazards: None
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are
presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the
inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to
be generated in significant quantities.
Reason for Reissue: The MSDS has been revised because 3M has adopted the 16-section ANSI/ISO format. The potential hazards
of the product have not changed. We encourage you to reread the MSDS and review the information.
Revision Changes:
Copyright was modified.
Section 3: Immediate physical hazard(s) was modified.
Section 5: Fire fighting procedures information was modified.
Section 5: Unusual fire and explosion hazard information was modified.
Section 15: Inventories information was modified.
Section 15: California proposition 65 ingredient information was modified.
Section 9: Property description for optional properties was modified.
Section 15: TSCA section 12[b] information was modified.
DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M
MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of
use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely
within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may
have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy.
In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M.
3M MSDSs are available at www.3M.com
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