GUIDELINES ON THE PREPARATION OF
MATERIAL SAFETY DATA SHEETS (MSDS)
Occupational Safety and Health Division
Ministry of Manpower
TABLE OF CONTENTS
A. Introduction 1
B. Standard and Format of MSDS 1
1. Identification of Substance and of the Company 5
2. Composition/Information on Ingredients 6
3. Hazards Identification 7
4. First-Aid Measures 7
5. Fire Fighting Measures 7
6. Accidental Release Measures 8
7. Handling and Storage 8
8. Exposure Controls/Personal Protection 9
9. Physical and Chemical Properties 10
10. Stability and Reactivity 12
11. Toxicological Information 13
12. Ecological Information 14
13. Disposal Considerations 14
14. Transport Information 15
15. Other Information 15
APPENDICES
1. Process of Determining Whether a Substance is Hazardous 16
2. Criteria for Classifying Hazardous Substances 17
3. Summary of Material Safety Data Sheet Key Information Items 20
GUIDELINES ON THE PREPARATION OF MATERIAL SAFETY
DATA SHEETS (MSDS)
INTRODUCTION
Chemicals are widely used in industry. Many of them are toxic, corrosive
or flammable. However, they can be safely handled if information on their
physical, chemical and hazardous properties together with the necessary
precautions to take is made available to users.
Chemical or material safety data sheets (MSDS) are used in many
countries to provide the information necessary for the safe handling of
hazardous1 or potentially hazardous substances. Therefore, MSDS play an
important role in the comprehensive approach to the control of chemical hazards
in the workplace.
However, unless the information supplied in the MSDS is adequately and
accurately prepared, effectively disseminated and correctly used, the MSDS
would not be able to meet its main objective of safeguarding and protecting the
lives and health of those handling the substance. Hence, there is a need to
ensure that Material Safety Data Sheets that are produced meet certain minimum
standards of acceptability.
These guidelines set a certain level of adequacy that an MSDS should
attain. They indicate what essential information an MSDS should contain. It also
acts as a tool in the preparation of the MSDS.
STANDARD AND FORMAT OF MSDS
There is currently no international standard for the preparation of MSDS.
Manufacturers/suppliers of chemicals may have different formats of presenting
the information required in the MSDS. Nonetheless, the information provided by
MSDS must be adequate and accurate. In general, information provided in
MSDS is the responsibility of the producer of the MSDS. All information should
be based on verifiable sources, for example documented studies, reports, and
reliable databases.
The MSDS is not a fixed length document. The amount of information
provided (in each sheet) may vary according to the amount of relevant
information available.
No information items should be left blank. If the information is not relevant
or not available, it should be clearly stated.
1
The process of determining whether a substance is hazardous is shown in Appendix 1.
The information content of an MSDS should be at least equivalent to that
described in these guidelines. (A summary of the information items is shown in
Appendix 3.) The key information items are listed as follows :
1) identification of the substance and of the company
2) composition/information on ingredients
3) hazards identification
4) first-aid measures
5) fire-fighting measures
6) accidental release measures
7) handling and storage
8) exposure controls/personal protection
9) physical and chemical properties
10) stability and reactivity
11) toxicological information
12) ecological information
13) disposal considerations
14) transport information
15) other information
Note : The above information items are compatible with ISO 11014 - 1:1994
General Guidelines
In the preparation of MSDS, the following general guidelines should be
adhered to :
Language
The language used in the MSDS must be clear, simple and concise.
Vague and ambiguous expressions should be avoided. Phrases such as `no
health effects', `safe under most conditions' are unacceptable. The MSDS should
be written in English but translations could be made available if the users require
them in other languages.
Information not available or not relevant
If information is not available, this should be indicated as `not available'. If
information is not relevant, this should be indicated as `not relevant'.
Abbreviations
Abbreviations such as `N/A' or `N/R' should not be used as their usage
could lead to confusion. For example, `N/A' may mean either `not available' or
`not applicable'. In general, where abbreviations are used, a legend explaining
the abbreviations should be included.
Page numbering
All pages of MSDS should be numbered and the total number of pages
should be given on every page, for example, `Page 1 of 3', `Page 2 of 3', `Page 3
of 3'.
Date of issue
Date of issue of MSDS must be indicated. The date of issue should be
expressed as month/year. The month should not be written as a number.
Units of measurement
Whenever possible, Standard International (SI) units should be used.
However, non-standard units that are commonly used (such as degree Celsius
and mmHg) are acceptable.
Review and Re-Issue of MSDS
Manufacturers and suppliers of chemicals should review and if necessary
re-issue an MSDS:
a) whenever there is a change in formulation which affects the properties of
the substance, alters the form or appearance of the substance or alters
the mode of application of the substance;
b) whenever there is a change to the substance which alters its health and/or
safety hazard or risk;
c) whenever new health and/or safety information on the substance becomes
available; or
d) to reflect new regulations, standards, codes of practices or guidelines.
In any event, such review should be no longer than five years after the last
date of issuing an MSDS.
MSDS and Expert Advice
While the MSDS provides adequate information for most users, it should
be kept in mind that it is not a substitute for expert advice. Expert advice may
include advice on the development of better control measures such as
engineering controls and safe handling practices.
MSDS To Cover All Uses
MSDS for a substance should as far as possible cover all major uses.
1. IDENTIFICATION OF SUBSTANCE AND OF THE COMPANY
1.1 Product Name
This is the name by which the product is known and should be exactly as
shown on the product label. A product name may be a trade name, code name or
code number as specified by the manufacturer or supplier of the substance.
1.2 Chemical Name
If the product is not a mixture, the actual chemical name should be given
in the manner prescribed by the International Union of Pure and Applied
Chemistry (IUPAC).
1.3 Chemical Formula
The molecular formula and structural formula of the chemical should also
be indicated.
1.4 Other Names
Other names or synonyms by which the product is commonly known
should be given if applicable.
1.5 Company's Name and Address
The name of the manufacturer or supplier of the chemicals should be
given in the MSDS. If the manufacturer is foreign, the local address of the
importer/agent/supplier must be provided.
1.6 Telephone Number
The local business telephone number including emergency telephone
number and facsimile number should be included. Telex and other electronic
access numbers (such as Internet address) may also be included.
2. COMPOSITION/INFORMATION ON INGREDIENTS
The information given should be adequate to enable the user to identify
the risks associated with the substance. It should be clear enough so that the
user will be able to conduct his own monitoring and surveillance.
2.1 Ingredients
This subsection should describe the chemical composition of the
hazardous substance. It should be completed both for pure substances and for
mixtures. In the case of mixtures, the names of all hazardous ingredients should
be given. An ingredient is any component or substance, in a mixture or
combination. The use of common class names such as `aromatic amine',
`hydrocarbon solvent' or aliphatic hydrocarbon' should be avoided. In addition,
functional names (e.g. `retardant', `additive', `inhibitor' and `penetrator') should not
be used.
Hazardous ingredients comprising more than 1% of the total composition
should be indicated in the ingredients list. For hazardous ingredients controlled
under the Poisons Act, the cut-off percentage under the Act should be adhered
to. Carcinogens and suspected carcinogens present in quantities more than
0.1% of the total composition must be declared. All ingredients should be listed
with the ingredient representing the highest proportion first and so on in
descending order. Percentage compositions should add up to 100%.
If the exact amount of the ingredient in the formulation cannot be
specified, then the proportion ranges of each ingredient in the product should be
indicated so as to provide as much information as possible about the potential
hazards of a formulation. The following proportion ranges are recommended :
>60% 30-60% 10-30% <10%
All hazardous ingredients with acute or chronic effects as described in
Appendix 2 must be declared. Generic names are not permitted for the
hazardous ingredients.
For some complex mixtures (e.g. petroleum distillates), it may be difficult
to identify the ingredients. In such cases, as much information as possible on the
chemicals should be provided. Chemical classes should be distinguished where
possible, for example, aliphatic or aromatic hydrocarbon, aliphatic alcohol or
phenol, silica or silicates.
3. HAZARDS IDENTIFICATION
The most important hazards of the substance should be concisely
indicated here. Attention should be given to the critical hazards to man and the
environment. Describe the most important adverse human health effects (both
acute and long term) and symptoms relating to man and the foreseeable misuses
of the substance.
Examples of the type of hazards to be stated includes the following :
? corrosive
? flammable
? reactive
? toxic
? explosive.
In addition, hazard classifications such as UN classification number and
NFPA2 rating may be included where available.
4. FIRST-AID MEASURES
Information on first-aid with respect to the three possible routes of entry
(i.e. inhalation, skin or eye contact and ingestion) should be given. First-aid
instruction should include the initial care that can be given without sophisticated
equipment and without a wide selection of medication available. If medical
attention is required, the instructions should state this, including its urgency. If
specific first-aid treatments for example, antidotes, eye wash or shower facilities
are required , these should be stated on the MSDS.
The information on first-aid must be brief and easy to understand by the
casualties, bystanders and first-aiders.
5. FIRE FIGHTING MEASURES
Information on fighting fires, including types of fire-fighting agents,
precautions to be observed, protective clothing and breathing apparatus to be
worn by firefighters, should be included. Any potentially dangerous interaction
with other substances or combustion products should be given.
Recommendations on whether evacuation is necessary should also be included.
2
NFPA : National Fire Protection Agency
6. ACCIDENTAL RELEASE MEASURES
The steps to be taken in case of a spill or leak should be mentioned in the
MSDS. The information should include:
a) personal protective equipment to be used including breathing
apparatus;
b) procedures to stop or minimise a spill or leak;
c) methods to clean up the spill or leak, for example, `neutralising agent
or absorbent' to be used;
d) precautions to be observed by the clean up crew;
e) any special equipment required for clean up, and
f) environmental precautions such as keeping away from drains, surface-
and ground-water and soil and alerting or evacuating the
neighbourhood.
Recommendations for small and large spills should be stated separately.
7. HANDLING AND STORAGE
7.1 Handling
Safe handling information should include advice on technical measures
such as local and general ventilation, measures to prevent aerosol generation
and any specific requirements relating to the substance (e.g. procedures or
equipment which are prohibited)
7.2 Storage
Safe storage information should include :
a) type of storage container;
b) siting or location of store;
c) construction of the storage area; and
d) conditions of storage, for example, temperature, ventilation conditions,
storage incompatibilities.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 Engineering Controls
This subsection should include information that would aid the user to
select and utilise engineering control measures suitable for the hazardous
product. These are measures which are used to control exposure to chemical
hazards. Engineering controls include :
a) elimination or substitution of hazardous substances;
b) modification, isolation or segregation of process;
c) containment controls, enclosure of sources or mechanical handling;
d) local exhaust ventilation with scrubbing unit if necessary;
e) dilution ventilation; and
f) safe work practices and other engineering controls.
If a particular application requires special precautionary measures, these
should be stated. A cautionary warning should be given where it is anticipated
that a misuse or wrong use of a substance could result in a hazard to the user.
8.2 Personal Protection
Where engineering control measures cannot be implemented or fail,
personal protection should be used to control exposure. It may be used together
with engineering controls or it may be the only mode of exposure control.
Measure for personal protection should include protection for :
? skin
? eyes
? respiratory system.
For skin protection, the types of gloves or aprons should be clearly stated,
for example, `impervious gloves' is not sufficient, whereas `PVC gloves' or `rubber
gloves' would be acceptable. For respiratory protection, the types of respirators
under the conditions of exposure should be stated. Vague information such as
`use approved face mask' is not acceptable, whereas `use approved half-face
filter respirator suitable for organic vapours' would be acceptable.
9. PHYSICAL AND CHEMICAL PROPERTIES
The data included in this subsection should apply to the hazardous
substance as used at work. If the substance is a mixture, the physical data
should describe the mixture and NOT the individual ingredients.
Where relevant, the units of measurement should always be clearly
stated. If a ratio is used (for dimensionless quantities), it should be specified. For
example, write `evaporation rate is x given that the evaporation rate of butyl
acetate is equal to 1'.
The physical and chemical properties are useful for estimating the
potential for exposure, handling spills, designing ventilation systems and helping
in the design, planning and checking of safety controls and procedures.
Certain physical properties should always be stated on the MSDS. The
core information is listed below.
? Appearance: should be described in terms of colour, odour, state and form.
For example, `yellow viscous liquid with sweet odour' or `white crystalline
powder with no odour'.
? Odour: should be described briefly if it is perceptible.
? Boiling and Melting points: should be indicated with reference to atmospheric
pressure (760 mmHg) and should be indicated in degrees Celsius (癈). The
corresponding temperature on the Kelvin scale may also be included.
? Vapour pressure: should be expressed in Pascal's (Pa) or as millimeter of
mercury (mmHg) at 25癈 under normal atmospheric pressure, and the
appropriate units clearly stated.
? Specific gravity: expressed as the ratio of the density of the product to the
density of water at 25癈 under normal atmospheric pressure.
Solubility in water: may be expressed in g/litre, g/100cm3 or parts per million
?br>
(ppm) at a specific temperature.
Other Properties
These other physical and chemical properties should include, where
relevant and available, :
a) shock sensitivity
b) corrosiveness
c) oxidising properties
d) reactivity with common substances, for example air or water
e) viscosity
f) evaporation rate
g) vapour density
h) odour threshold
i) pH, at stated concentration
j) solubility in organic solvents
k) per cent volatiles
l) volatile organic compounds
m) bulk density.
Fire and Explosion Data
In addition to the physical properties stated above, a group of properties
relating to the substances' fire and explosion hazard should be included in the
MSDS. The following information should be supplied :
? Flash point: the lowest temperature in degrees Celsius (癈) at which a liquid
will give off enough vapour to ignite if the vapour is flammable. Any
internationally recognised method for determining the flash point is
acceptable provided that the method used is stated.
? Flammability limits: indicates the range of concentrations of a flammable
vapour in air at which a flame can be propagated or an explosion can occur if
a source of ignition is present. Both the upper and lower explosive limits
should be stated where applicable. The limits should be expressed in terms of
percentage of vapour in air.
? Autoignition temperature: This is the lowest temperature at which self-
sustained combustion of a substance occurs. An important point to note is
that the closer the autoignition temperature is to the room temperature, the
higher is the fire risk.
10. STABILITY AND REACTIVITY
There are certain conditions under which a substance would decompose
or become very reactive giving rise to a dangerous situation. These conditions,
such as extreme temperature, pressure, light, shock, etc. should be clearly stated
in the MSDS. The hazardous decomposition products should also be indicated.
The possibility of polymerisation of the chemicals and the routes that could lead
to this should be highlighted.
In addition to the above, materials incompatible with the product should be
listed. Incompatibility here indicates that the product should not come into contact
with certain substances because the product may react violently and give off
toxic vapours or heat. For example, sodium hypochlorite is incompatible with
strong acids. When mixed, it gives off noxious chlorine gas.
The following should be addressed specifically :
? the need for and the presence of stabilisers
? the possibility of a hazardous exothermic reaction
? hazardous decomposition products
? possibility of degradation to unstable products
For organic peroxides, the Self Accelerating Decomposition Temperature
(SADT) should be stated where applicable.
11. TOXICOLOGICAL INFORMATION
Entries in this subsection should be clear and simple enough for the
layperson to understand. Technical jargon should be avoided as far as possible
and if they are used, they should be accompanied by a simple explanation, for
example, `dermatitis (inflammation of the skin)'. When quoting toxicity data, it is
important to indicate the routes of entry and the species of animal used in the
test.
General statements such as `toxic' with no supporting data or `safe if
properly used' are not acceptable. They can be misleading and do not provide a
description of health effects.
The following information should be included:
? Acute and chronic health effects relating to human exposure to the
substance, if available. Where there is no human data available, animal data
can be used with the species identified. If relevant negative data are
available, they should also be included. For example, `carcinogenicity studies
on rats have shown no significant increase in the incidence of cancer'.
? Any health effects following ingestion (swallowing), inhalation or skin
absorption due to poor hygiene or accidental contamination should be
included. If these effects are not known, a statement should be made.
? The range of symptoms of exposure from the first symptoms at the lowest
exposure levels to those of severe exposure. For example, `headaches and
dizziness may occur; large doses may result in death'.
? The dose, concentration or conditions of exposure likely to cause injury.
Where possible, dose should be linked to symptoms and effects and include
the period of exposure likely to cause harm. For example, ` 50 ppm
respiratory irritation, 250-350 ppm difficulty in breathing, 500 ppm
unconsciousness leading to death in 30 minutes.'
If it is not possible to obtain comprehensive information on the hazards of
a substance due to the fact that it has not been fully tested, data on the chemical
class, if appropriate, may be used. When such data are used, or when no data is
available, this should be stated in the MSDS.
In many cases, substances will be in the form of mixtures. However, most
of the information available from reference texts and databases refers to single
chemicals. In such cases, a summary of the health effects of individual
ingredients should be given.
Health effects should include hazard ratings and exposure limits. For
example, LD503, TLV4, IDLH5 and other permissible exposure levels. The source
of this information should be quoted.
12. ECOLOGICAL INFORMATION
An assessment of the possible effects, behaviour and environmental fate
of the substance should be given. Describe the most important characteristics
likely to have an effect on the environment due to the nature of the substance
and likely methods of use :
? mobility
? persistence and biodegradability
? bioaccumulative potential
? aquatic toxicity and other data relating to ecotoxicity, e.g behaviour in
sewage works.
13. DISPOSAL CONSIDERATIONS
Information on waste disposal methods for example incineration,
recycling, landfilling should be given. The types of disposal containers to be used
and precautions to be observed during waste handling should also be included.
Recommendations for small and large disposal should be distinguished from
each other.
14. TRANSPORT INFORMATION
Safe transport information should include the type of packaging, labelling,
placarding and handling of the chemical inaccordance with SS286:Part 4:1984.
Any special transport requirements or hazards such as shock sensitivity should
be stated, if necessary.
15. OTHER INFORMATION
Other information that can be included where relevant and applicable
includes the following.
? Regulatory information
? Training advice
3
LD50 : The lethal dose that will kill a group of exposed animals expressed as mg per kg of body weight.
4
TLV : Threshold limit value or the airborne concentration in ppm or mg/m3 to which workers may be
repeatedly exposed without adverse effects.
5
IDLH : Immediately dangerous to life or health
? Recommended uses and restrictions
? Written references and/or technical contact points
? Sources of key data used to compile the data sheet
Appendix 1
PROCESS OF DETERMINING WHETHER A SUBSTANCE IS HAZARDOUS
Does the substance comprise one chemical entity, or is it a
mixture of two or more chemical entities?
A mixture
One chemical
Has the mixture
Does the substance
been tested as a
meet the criteria as
whole?
laid-out in Appendix
2?
Yes No
No
Yes
Does any ingredient
meet the criteria as
laid out in Appendix
2?
No Yes
The substance is not a hazardous substance.
The substance is a hazardous substance.
If there is insufficient information available on the health effects or toxicity
to classify a substance, MSDS must be produced to warn the end-user of
the lack of information.
Appendix 2
CRITERIA FOR CLASSIFYING HAZARDOUS SUBSTANCES
Any substance which meets any of the following definitions is classified as
a hazardous substance.
Acute lethal effects
A substance is considered to be a hazardous substance if it falls within
any one of the categories listed in the table below.
Commonly used LD50 4-hr Vapour LD50
term Single Oral Dose Exposure Causing Skin for Rabbits
for Rats (g/kg) 2 to 4 Deaths in 6- (g/kg)
rat Groups (ppm)
Extremely toxic 0.001 or less Less than 10 0.005 or less
Highly Toxic 0.001 to 0.05 10 to 100 0.005 to 0.043
Moderately Toxic 0.05 to 0.5 100 to 1000 0.044 to 0.340
Slightly Toxic 0.5 to 5.0 1000 to 10000 0.35 to 2.81
Corrosive effects
A corrosive substance is one that causes visible destruction of, or
irreversible alterations in, living tissue by chemical action at the site of contact.
Irritant effects
An irritant is defined as a substance which is not corrosive but causes a
reversible inflammatory effect on living tissue by chemical action at the site of
contact.
An irritant causes :
?inflammation of the skin
?eye irritation
?irritation to the respiratory system
Sensitising effects
A sensitiser is defined as a substance that can cause a proportion of
exposed people or animals to develop an allergic reaction in normal tissue after
repeated exposure to the substance.
Carcinogenic effects
A substance is considered to be a carcinogen if it has been evaluated by
the International Agency for Research on Cancer, and found to be a carcinogen
or potential carcinogen.
Target organ effects
The following is a target organ categorisation of effects which may occur,
including examples of signs and symptoms and chemicals which have been
found to cause such effects. These examples are presented to illustrate the
range and diversity of effects and hazards found in the workplace, and the broad
scope employers/suppliers must consider in this area, but are not intended to be
comprehensive.
(a) Hepatotoxins: Chemicals which cause liver damage
Signs & Symptoms :Jaundice; liver enlargement
Chemicals: Carbon tetrachloride; nitrosamines
(b) Nephrotoxins: Chemicals which cause kidney damage
Signs & Symptoms: Edema, proteinuria
Chemicals: Halogenated hydrocarbons, uranium
(c) Neurotoxins: Chemicals which produce their primary toxic effects on the
nervous system
Signs & Symptoms: Narcosis; behavioural changes; decrease in motor
functions
Chemicals: Mercury, carbon disulphide
(d) Agents which act on the blood or hematopoietic system: Deprive the body
tissues of oxygen
Signs & Symptoms: Cyanosis; loss of consciousness
Chemicals: Carbon monoxide; cyanides
(e) Agents which damage the lung: Chemicals which irritate or damage the
pulmonary tissue
Signs & Symptoms: Cough; tightness in chest; shortness of breath
Chemicals: Silica; asbestos, chlorine, ammonia.
(f) Reproductive toxins: Chemicals which affect the reproductive system
including causing chromosomal damage (mutagenesis) and effects on
fetuses (teratogenesis)
Signs & Symptoms: Birth defects; sterility
Chemicals: Lead; DBCP
(g) Cutaneous hazards: Chemicals which affect the skin
Signs & Symptoms: Defatting of the skin; rashes; irritation, itch
Chemicals: Ketones; chlorinated compounds
(h) Eye hazards: Chemicals which affect the eye or visual capacity
Signs & Symptoms: Conjunctivitis; corneal damage
Chemicals : Organic solvents; acids; methanol
Flammable substances
Flammable substances include the following:
(a) any liquid or mixtures of liquids containing solids in solution or
suspension which have a flash point not greater than 61?Celsius
when tested according to any appropriate, internationally accepted
methods.
(b) any gas that has a lower flammability limit less than 13% by volume or
a flammability range greater than 12;
(c) any other combustible substances and substances liable to
spontaneous combustion; and
(d) substances which on contact with water, emit flammable gases.
Oxidizing substances
Oxidizing substances (agents) : substances which although not
necessarily combustible, may readily liberate oxygen or be the cause of oxidation
processess and which, as a result, may start a fire in other materials or stimulate
the combustion of other materials and therefore increase the violence of a fire.
Organic peroxides : substances which may act as oxidizing substances
and are liable to explosive decomposition. In either liquid or solid form, they may
react dangerously with other substances. Most will burn rapidly and are sensitive
to impact or friction.
Appendix 3
SUMMARY OF MATERIAL SAFETY DATA SHEET KEY INFORMATION ITEMS
1. Identification of Substance and of the Company
?Product name
?Chemical name
?Chemical formula
?Other names
?Company's name and address
?Telephone number
2. Composition/Information on Ingredients
?% by volume or weight
?Avoid common class names such as "aromatic amine", "hydrocarbon solvent"
and "aliphatic hydrocarbon. In addition funtional names such as "retardant",
"inhibitor", "penetrator" should not be used.
3. Hazards Identification
?Types of hazards include corrosive, flammable, reactive, toxic and explosive
substances
4. First-Aid Measures
?First-aid measures for the three possible routes of entry (i.e. inhalation, skin
or eye contact and ingestion)
5. Fire Fighting Measures
?Types of fire-fighting agents
?Precautions to be observed
?Protective clothing and breathing apparatus
6. Accidental Release Measures
?Personal protective equipment including breathing apparatus
?Steps to be taken
7. Handling and Storage
?Ventilation
?Storage container
?Conditions of storage (eg. temperature, incompatibles)
8. Exposure Controls/Personal Protection
?Engineering controls (eg. substitution, isolation, local exhaust ventilation)
?Personal protective equipment (skin, eyes, respiratory system)
9. Physical and Chemical Properties
?Appearance
?Odour
? Boiling and melting points
? Vapour pressure
? Specific gravity
? Solubility in water
? Other properties (eg. viscosity, vapour density, pH, bulk density, etc.)
? Fire and explosion data (ie. flash point, flammability limits, autoignition
temperature)
10. Stability and Reactivity
?Decomposition conditions
?Decomposition products
?Polymerisation
?Incompatible materials
?SADT for organic peroxides where applicable
11. Toxicological Information
?Routes of entry
?Acute effects
?Chronic effects
?Hazard ratings and permissible exposure level (eg. LD50, TLV)
12. Ecological Information
?Mobility
?Persistence and biodegradability
?Bioaccumulative potential
?Aquatic toxicity and data relating to ecotoxicity
13. Disposal Considerations
?Disposal methods
?Disposal containers
?Precautions during waste handling
14. Transport Information
?Type of packaging
?Labelling
?Placarding
?Special transport requirements (eg. shock sensitivity)
15. Other Information
?Regulatory information
?Training advice
?Recommended uses and restrictions
?Written references and/or technical contact points
?Sources of key data used to compile data sheet
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