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MSDS Material Safety Data Sheet
CAS

80-09-1 5397-34-2

File Name: 80-09-1_5397-34-2.asp

                        MATERIAL SAFETY DATA SHEET

Nease Corporation Product Inquiries: (888) 762-7373
10740 Paddys Run Road
Harrison, OH 45030
(513) 738-1255 Emergency: CHEMTREC 800-424-9300

SECTION 1 - PRODUCT INFORMATION

PRODUCT NAME: NAXCHEM?Bisphenol S-98B ISSUE DATE: 07/13/05
CHEMICAL NAME: 4,4'-Sulfonyldiphenol SUPERSEDES: 05/23/05
CAS NUMBER: 80-09-1
PRODUCT CODE: 3651
MSDS NO.: 1-17111


SECTION 2 - HAZARD IDENTIFICATION

Appearance & Odor: Light brown powder, no distinguishable odor.

Primary Routes of Exposure: Skin, Eyes, and Respiratory tract.

Health Hazard Warnings: CAUTION! May cause slight skin irritation and slight to moderate eye irritation. Prolonged
or repeated overexposure to dusts can cause upper respiratory tract irritation. Dusts at sufficient concentrations can
form explosive mixtures with air.

Inhalation: Prolonged or repeated overexposure to dusts may cause upper respiratory tract irritation.

Skin Contact: May cause slight skin irritation.

Eye Contact: Contact with eyes can cause slight to moderate irritation.

Ingestion: May cause irritation to the membranes of the mouth, throat and gastrointestinal tract.


SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS

CHEMICAL NAME CAS REGISTRY NO. PERCENT

4,4'-Sulfonyldiphenol 80-09-1 > 98
2,4'-Sulfonyldiphenol 5397-34-2 <2


SECTION 4 - FIRST AID MEASURES

Eyes: Immediately flush eyes with water for 10 - 15 minutes. Hold eyelids apart and roll eyes up and down to assure
complete washing. Seek medical attention.

Skin: Thoroughly flush the affected area with plenty of water for at least 15 minutes. Remove contaminated clothing
and equipment.

Inhalation: Immediately move the patient to fresh air and call a physician. If breathing is difficult, give oxygen. If not
breathing, begin artificial respiration.
MATERIAL SAFETY DATA SHEET

Page 2 of 4 MSDS No.: 1-17111

SECTION 4 - FIRST AID MEASURES (CONT.)

Ingestion: If swallowed, call a physician. Never give anything by mouth to an unconscious person. Induce vomiting
only at the instructions of a physician or nurse.

Other Specific Instructions: In the event of exposure, seek medical attention immediately. Do not give chemical
antidotes unless directed to do so by the physician.


SECTION 5 - FIRE FIGHTING MEASURES

Flash Point: Not applicable Auto Ignition: No data available

Explosive Limits; UEL/LEL: In sufficient concentrations, dusts can form explosive mixtures with air.

Extinguishing Agents: Use water spray, dry chemical, carbon dioxide, or foam extinguishing agents. Do not apply a
direct water stream on material.

Fire & Explosion Hazards: As in any fire prevent human exposure to fire, smoke, fumes or products of combustion.
Firefighters should wear recommended exposure control equipment including a self-contained breathing apparatus.
Cool containers with water that are exposed to flames. Avoid placing a solid stream of water on spilled material.

Hazardous Combustion Products: Thermal decomposition produces oxides of sulfur and carbon.


SECTION 6 - ACCIDENTAL RELEASE MEASURES

Personal Protective Equipment: Appropriate protective equipment must be worn when handling a spill of
NAXCHEM?Bisphenol S-98B. See Section 8 - Exposure Control, for recommendations.

Spill or Leak Information: Sweep or scoop material into containers for reuse or disposal. Avoid breathing and
generating dusts. Flush spill area with plenty of water. Collect water for proper disposal.


SECTION 7 - HANDLING AND STORAGE

Handling Conditions: Emptied container may retain product residues. Follow all warnings and precautions even after
container is emptied. Ground and bond container when transferring this material to prevent static build up.

Storage Conditions: Keep container tightly closed when not in use.


SECTION 8 - EXPOSURE CONTROL

Exposure Limits: None established

Eye Protection: Use chemical safety goggles.

Skin Protection: Skin contact with material should be minimized through the use of suitable impervious gloves.
Natural rubber or neoprene gloves are recommended.

Respiratory Protection: Not required under normal handling conditions. If dusts can be generated, wear the
appropriate NIOSH approved air purifying particulate respirator for the dust concentrations at the point of use.
MATERIAL SAFETY DATA SHEET

Page 3 of 4 MSDS No.: 1-17111

SECTION 8 - EXPOSURE CONTROL (CONT.)

Ventilation: Good local exhaust ventilation should be provided.

Other Protective Equipment: Safety showers and eye wash stations where material is being handled. Wash hands
and face before eating, using tobacco products or using the washroom. Smoke or eat only in designated areas.
Take a warm shower and change clothing daily. Clothing and shoes used while handling this material should not be
worn or taken away from the workplace.


SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES

Appearance: Light brown powder Odor: No distinguishable odor

Melting Point: No data available Boiling Point: No data available

Evaporation Rate (butyl acetate=1): No data available pH: No data available

Vapor Pressure (mm Hg): Low Vapor Density (Air=1): No data available

Specific Gravity/Density: No data available Solubility in Water: No data available

Flash Point: Not applicable Auto Ignition: No data available


SECTION 10 - STABILITY AND REACTIVITY

Stability: Stable under normal conditions of storage and handling.

Incompatibility: Strong oxidizers.

Polymerization: Not expected to occur.

Decomposition: When heated to decomposition, may emit highly toxic oxides of sulfur and carbon.


SECTION 11 - TOXICOLOGICAL INFORMATION

Acute Data: The information shown in Section 2 - Hazard Identification, is based on toxicity profiles of similar materials
(RTECS Data) or on the components present in this material.

Ingestion: Oral LD50 (rat): 4456 mg/kg
Eye: Moderate Irritation

Sensitization: This product is not known to cause sensitization.

Carcinogenicity/Mutagenicity: 4,4'-Sulfonyldiphenol is not considered to be a human or animal carcinogen.

Teratogenicity/Reproductive Toxicity: 4,4'-Sulfonyldiphenol is not known to cause teratogenicity or reproductive
toxicity.


SECTION 12 - ECOLOGICAL INFORMATION

Ecotoxicological Data: The ecological toxicity of this statement is not known. This material should be considered
toxic to fish.
MATERIAL SAFETY DATA SHEET

Page 4 of 4 MSDS No.: 1-17111

SECTION 13 - DISPOSAL CONSIDERATIONS

Waste Disposal: This product if discarded as supplied, is considered non-hazardous as defined by RCRA. Dispose of
in accordance with local, state and federal regulations.


SECTION 14 - TRANSPORT CONSIDERATIONS

Shipping Description: DOT Non-Regulated

Hazard Class: NA ID No.: NA PG: NA Labels: None


SECTION 15 - REGULATORY CONSIDERATIONS

OSHA Regulatory Status: This product is a hazardous chemical under 29 CFR 1910.1200.

SARA Title III

Section 311/312: This material is categorized as an immediate health hazard according to EPA under Section
311/312 of SARA.

Section 313: This product contains the following chemicals subject to 313 reporting:
None above De Minimis limit

CERCLA: Not applicable

Pennsylvania Right-to-Know: Not applicable

California Proposition 65: Not applicable

Chemical Control Law Status:

The components of this product are in compliance with the inventory listing requirements of the Chemical Control
Laws in the following countries: United States of America, Canada (DSL), China, Europe and Japan.

WHMIS Ingredient Disclosure List:
4,4'-Sulfonyldiphenol 80-09-1

HMIS Health Rating: 2 HMIS Fire Rating: 1

HMIS Physical Hazard Rating: 0 HMIS Other: NA


SECTION 16 - OTHER CONSIDERATIONS

Prepared by Regulatory Staff Phone No.: (814) 238-2424 MSDS No.: 1-17111
Issue Date: 7/13/05
Emergency Phone No.: CHEMTREC 800-424-9300
This information is furnished free of charge and is based on technical data that Nease Corporation believes to be reliable. It is intended for use by trained persons having technical skill and at their
own discretion and risk. Since conditions of use are outside our control, we make no warranties, expressed or implied, and assume no liability in connection with any use of this information. Nothing
herein is to be taken as a license to operate under or a recommendation to infringe any patents.

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