Product Name: Blair(R) Matte Spray Fix Page 1 of 7
LOCTITE CORPORATION 10/20/98
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 01 of 07
Blair(R) Matte Spray Fix
10016
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Item No.: 10016
Product Type: Aerosol matte fix
2. COMPOSITION, INFORMATION ON INGREDIENTS
Ingredients CAS No. %
ACETONE 67-64-1 35-40
BUTANE 106-97-8 10-15
PROPANE 74-98-6 10-15
XYLENES* 1330-20-7 5-10
n-AMYL ACETATE 628-63-7 3-5
DIACETONE ALCOHOL 123-42-2 3-5
ISOPROPYL ACETATE 108-21-4 3-5
METHYL ETHYL KETONE* 78-93-3 3-5
Methyl isobutyl ketone* 108-10-1 3-5
Polymer Proprietary 1-10
ETHYL BENZENE* 100-41-4 1-3
Light aliphatic
solvent naphtha 64742-89-8 1-3
* This component is listed as a SARA Section 313 Toxic Chemical.
Ingredients which have exposure limits
Exposure Limits (TWA) ACGIH OSHA OTHER
Ingredients (TLV) (PEL)
ACETONE 500 ppm TWA 750 ppm TWA None
1188 mg/m3 1800 mg/m3
BUTANE 800 ppm TWA 800 ppm TWA None
1900mg/M3 1900mg/M3
PROPANE 2500 ppm 1000 ppm None
1800 mg/m3
XYLENES 100 ppm TWA 100 ppm TWA None
434 mg/m3 435 mg/m3
n-AMYL ACETATE None 100 ppm 100 ppm
532 mg/m3 525 mg/3
DIACETONE ALCOHOL 50 ppm 50 ppm None
238 mg/m3 240 mg/m3
ISOPROPYL ACETATE 250 ppm TWA 250 ppm TWA None
1040mg/M3 950mg/M3
METHYL ETHYL KETONE 200 ppm TWA 200 ppm TWA None
590 mg/m3 590 mg/m3
Methyl isobutyl ketone 50 ppm 50 ppm None
LOCTITE CORPORATION 10/20/98
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 02 of 07
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Product Name: Blair(R) Matte Spray Fix Page 2 of 7
Item No.: 10016
2. COMPOSITION, INFORMATION ON INGREDIENTS (continued)
205 mg/m3 205 mg/m3
ETHYL BENZENE 100 ppm 100 ppm None
434 mg/m3 435 mg/m3
Light aliphatic
solvent naphtha 5mg/m3 TWA mist 5mg/m3 TWA mist None
Exposure Limits (STEL) ACGIH OSHA
Ingredients (TLV) (PEL)
ACETONE 750 ppm 1000 ppm
1782 mg/m3 2400 mg/m3
PROPANE Asphyxiant Asphyxiant
XYLENES 150 ppm 150 ppm
651 mg/m3 655 mg/m3
ISOPROPYL ACETATE 310 ppm 310 ppm
1290mg/M3 1185mg/M3
METHYL ETHYL KETONE 300 ppm 300 ppm
885 mg/m3 885 mg/m3
Methyl isobutyl ketone 75 ppm 75 ppm
307 mg/m3 300 mg/m3
ETHYL BENZENE 125 ppm 125 ppm
543 mg/m3 545 mg/m3
Light aliphatic
solvent naphtha 10 mg/m3 None
3. HAZARDS IDENTIFICATION
Toxicity: Irritation of eyes, skin and respiratory system.
May cause nervous system depression. Extreme
overexposure may result in unconsciousness and
possibly death.
Reports have associated repeated and prolonged
overexposure to solvents with permanent brain and
nervous system damage.
Prolonged exposure to solvents ingredients may
cause adverse effects to the liver, urinary, and
reproductive systems.
Methyl ethyl ketone may increase the nervous
system effects of other solvents.
Primary Routes of Entry: Exposure may be by inhalation and/or skin or eye
contact, depending on conditions of use. To
minimize exposure, follow recommendations for
proper use, ventilation, and personal protective
equipment.
Signs and Symptoms
of Exposure: Headache, dizziness, nausea, and loss of
coordination are indications of excessive exposure
to vapors or spray mists. Redness and itching or
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MATERIAL SAFETY DATA SHEET Page 03 of 07
Item No.: 10016
3. HAZARDS IDENTIFICATION (continued)
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burning sensation may indicate eye or excessive
skin exposure.
Existing Conditions
Aggravated by Exposure: None generally recognized.
Literature Referenced Carcinogen
Ingredients Target Organ and Other Health Effects NTP IARC OSHA
ACETONE AC4 BLO CNS IRR NO NO NO
BUTANE CAR CNS IRR NO NO NO
PROPANE CAR CNS IRR NO NO NO
XYLENES AC4 CAR CNS IRR KID LIV NO NO NO
n-AMYL ACETATE CNS IRR NO NO NO
DIACETONE ALCOHOL CNS IRR KID NO NO NO
ISOPROPYL ACETATE CNS IRR NO NO NO
METHYL ETHYL KETONE CNS IRR NO N/A NO
Methyl isobutyl ketone FET IRR KID LIV NO NO NO
Polymer No Data NO NO NO
ETHYL BENZENE CNS IRR NO NO NO
Light aliphatic
solvent naphtha No Data NO NO NO
-------------------------------------------------------------------------------
Abbreviations
N/A Not Applicable AC4 ACGIH-Unclassifiable as human carc.
BLO Blood CAR Cardiac
CNS Central nervous system FET Fetotoxic
IRR Irritant KID Kidney
LIV Liver
4. FIRST AID MEASURES
Ingestion: Never give anything by mouth to an unconscious
person. Do not induce vomiting. Give conscious
patient several glasses of water. Seek medical
attention.
Inhalation: If affected, remove from exposure. Restore
breathing. Keep warm and quiet.
Skin Contact: Wash affected area thoroughly with soap and water.
Remove contaminated clothing and launder before
re-use.
Eye Contact: Flush eyes with large amounts of water for 15
minutes. Get medical attention.
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MATERIAL SAFETY DATA SHEET Page 04 of 07
Item No.: 10016
5. FIRE FIGHTING MEASURES
Flash Point: -20癋 (Propellant) Method: Tag closed cup
Recommended
Extinguishing Agents: Carbon dioxide, foam, dry chemical
Special Firefighting
Procedures: Full protective equipment including self-contained
breathing apparatus should be used. Water spray
may be ineffective. If water is used, fog nozzles
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Product Name: Blair(R) Matte Spray Fix Page 4 of 7
are preferable. Water may be used to cool
containers to prevent pressure build up and
possible autoignition or explosion when exposed to
extreme heat.
Hazardous Products formed
by Fire or Thermal Decomp Irritating organic vapors; oxides of carbon.
Unusual Fire or
Explosion Hazards: Isolate from heat, electrical equipment, sparks,
and open flame. Closed containers may explode when
exposed to extreme heat. Application to hot
surfaces requires special precautions. During
emergency conditions overexposure to decomposition
products may cause a health hazard. Symptoms may
not be immediately apparent. Obtain medical
attention.
Explosive Limits:
(% by volume in air)Lower 1.0%
(% by volume in air)Upper 12.8%
6. ACCIDENTAL RELEASE MEASURES
Steps to be taken in case
of spill or leak: Remove all sources of ignition. Maintain good
ventilation. Soak up with an inert absorbent.
Store in a closed container until disposal.
7. HANDLING AND STORAGE
Safe Storage: Keep away from heat, sparks, and open flame.
(Contact Loctite Customer Service 1-800-243-4874 for shelf life information)
Handling: Keep away from heat, sparks or open flame. Vapors
will accumulate readily and may ignite explosively
Avoid breathing of vapor and spray mist. Avoid
contact with skin and eyes. During use and until
all vapors are gone: Keep area ventilated. Do not
smoke. Extinguish all flames, pilot lights, and
heaters. Turn off stoves, electric tools and
appliances, and other sources of ignition. Consult
NFPA Code. Use approved bonding and grounding
procedures. Do not puncture, incinerate, or expose
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EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 05 of 07
Item No.: 10016
7. HANDLING AND STORAGE (continued)
to temperature above 120癋. Heat from sunlight
radiators, stoves, hot water, and other heat
sources could cause container to burst. Do not
take internally. Keep out ot the reach of children
Intentional misuse by deliberately concentrating
and inhaling the contents can be harmful or fatal.
Wash hands after using.
8. EXPOSURE CONTROLS, PERSONAL PROTECTION
Eyes: Wear safety spectacles with unperforated
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sideshields.
Skin: Chemical resistant gloves.
Ventilation: Local exhaust preferable. General exhaust
acceptable if the exposure to materials in Section
II is maintained below applicable exposure limits.
Refer to OSHA Standards 1910.94, 1910.107,
1910.108.
Respiratory If personal exposure cannot be controlled below
applicable limits by ventilation, wear a properly
fitted organic/particulate respirator approved by
NIOSH/MSHA for protection against materials in
Section II
See Section 2 for Exposure Limits.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Clear liquid
Odor: Alcohol
Boiling Point: Range: Less than 0癋 to 340癋.
pH: Does not apply
Solubility in Water: Not available
Specific Gravity 0.74 (Base only)
Volatile Organic Compound
(EPA Method 24) 52.5%; 605 grams per liter of material
(Less federally exempt solvents)
Vapor Pressure: Not available
Vapor Density: More than 1 (base only)
Evaporation Rate
(Ether = 1) Faster
10. STABILITY AND REACTIVITY
Stability: Stable
Hazardous Polymerization: Will not occur
Incompatibility: None
Conditions to Avoid: Not available
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MATERIAL SAFETY DATA SHEET Page 06 of 07
Item No.: 10016
10. STABILITY AND REACTIVITY (continued)
Hazardous Decomposition
Products (non-thermal): None
11. TOXICOLOGICAL INFORMATION
See Section 3.
12. ECOLOGICAL INFORMATION
No data available
13. DISPOSAL CONSIDERATIONS
Recommended methods of
disposal: Do not incinerate. Depressurize container.
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Dispose of in accordance with federal, state and
and local regulations.
EPA Hazardous Waste
Number D001 - Hazardous waste per 40CFR 261.21
14. TRANSPORTATION INFORMATION
DOT (49 CFR 172)
Domestic Ground Transport
Proper Shipping Name: Consumer Commodity
Hazard Class or
Division: ORM-D
Identification Number: None
Marine Pollutant: None
IATA
Proper Shipping Name: Consumer Commodity (Not more than 500 ml);
Aerosols, flammable n.o.s. (More than 500 ml)
Class or Division: Class 9 (Not more than 500 ml);
Division 2.1 (More than 500 ml)
UN or ID Number: ID 8000 (Not more than 500 ml);
UN 1950 (More than 500 ml)
15. REGULATORY INFORMATION
CA Proposition 65: WARNING: This product contains chemicals known to
the State of California to cause cancer, birth
defects of other reproductive harm.
16. OTHER INFORMATION
Estimated NFPA(R) Code:
Health Hazard: 2
Fire Hazard: 4
LOCTITE CORPORATION 10/20/98
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 07 of 07
Item No.: 10016
16. OTHER INFORMATION (continued)
Reactivity Hazard: 0
Specific Hazard: Does not apply
Estimated HMIS(R) Code:
Health Hazard: 2*
Flammability Hazard: 4
Reactivity Hazards: 0
Personal Protection: See Section 8.
NFPA is a registered trademark of the National Fire Protection Assn.
HMIS is a registered trademark of the National Paint and Coatings Assn.
Prepared By: Stephen Repetto
Title: Research Chemist- Safety,Health&Regulatory Affairs
Company: Loctite Corporation
1001 Trout Brook Crossing, Rocky Hill CT 06067
(24hr.) Phone: (860) 571-5100
Revision Date: August 20, 1998 Revision: 0003
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