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143-22-6 112-50-5 112-35-6 25322-68-3 9038-95-3 112-34-5 111-77-3 111-90-0

File Name: 143-22-6_112-50-5_112-35-6_25322-68-3_9038-95-3_112-34-5_111-77.asp

                                                                        Material Safety Data Sheet


STP?Heavy Duty Brake Fluid, DOT 3
1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

STP?Heavy Duty Brake Fluid, DOT 3
Manufactured for:
The Armor All / STP Products Company
1221 Broadway
Oakland, CA 94612
Telephone: (510)271-7000
Auto Brake Fluid
Product Type

ST0925, ST0925CAN, ST0925SP, ST0925PR, ST0926, ST0926CAN,
Stock
Z-302

RM3715, RM3725, RM3837, RM3941, RM3950
Formula
For Medical Emergencies Call: For Transportation Emergencies
Emergency Phone
1-800-446-1014 Call: 1-800-424-9300 (Chemtrec)
Numbers

2 COMPOSITION / INFORMATION ON INGREDIENTS
Hazardous Materials Material % CAS # Exposure Source
Limit
Triethylene Glycol
0-70 143-22-6 None Established (3)
Monobutyl Ether
Triethylene Glycol
0-45 112-50-5 None Established (3)
Monoethyl Ether
Triethylene Glycol
0-35 112-35-6 None Established (3)
Monomethyl Ether
Glycol Heavies 0-35 25322-68-3 None Established (3)
Polyalkylene Glycol 0-10 9038-95-3 None Established (3)
Diethylene Glycol
0-10 112-34-5 None Established (3)
Monobutyl Ether
Diethylene Glycol
0-5 111-77-3 None Established (3)
Monomethyl Ether
Diethylene Glycol
0-2 111-90-0 None Established (3)
Monoethyl Ether
None of the ingredients is listed as a carcinogen or potential carcinogen
by IARC, NTP or OSHA.

The Permissible Exposure Limits (PEL) reported above are the pre-1989 limits
that were reinstated by OSHA following a decision by the 11th Circuit Court of
Appeals. These PELs are being enforced by Federal OSHA. Be aware that
more restrictive limits may be enforced by some states. The Armor All / STP
Products Company recommends that the lower exposure limits be observed
as reasonable worker protection.

Document: MSDS0093, October 20, 1999 Page 1 of 7
Material Safety Data Sheet


STP?Heavy Duty Brake Fluid, DOT 3
2 COMPOSITION / INFORMATION ON INGREDIENTS (continued)
The source for exposure limits listed above are:
1. OSHA Permissible Exposure Limit (PEL)
2. ACGIH Threshold Limit Value (TLV)
3. Both the OSHA PEL and ACGIH TLV
4. Recommended by the Manufacturer

3 HAZARDS IDENTIFICATION
Principal Hazards Warning
?Clear amber liquid with a mild odor.
?Accidental ingestion of this material may cause gastrointestinal
disturbances including irritation, nausea, vomiting and diarrhea.
?Aspiration from ingestion may cause central nervous system
depression and kidney and liver damage.
?Breathing vapors or mists may cause mucous membrane irritation.
?May cause eye irritation or possible corneal injury.
?Prolonged skin contact may cause irritation.
See Section 11 for complete health hazard information
KEEP OUT OF REACH OF CHILDREN
4 FIRST AID
If swallowed, get immediate medical advice by calling a Poison Control
Swallowing
Center or emergency room. If advice is not available, then give 1 or 2
glasses of water or milk and induce vomiting. Take victim and product
container to the nearest emergency treatment center or hospital. Do
not attempt to give anything by mouth to an unconscious person.

Remove contaminated clothing. Wash all affected and exposed areas
Skin
with soap and water. If irritation or redness develops or persists, seek
medical attention.

Remove to fresh air if effects occur and seek medical attention.
Inhalation

Exposed eyes should be immediately flushed with copious amounts of
Eyes
water using a steady stream for a minimum of 15 minutes. If irritation,
pain, swelling or tearing develops, seek medical attention.

There is no specific antidote. Treatment should be directed at the
Notes To Physician
control of symptoms and clinical conditions.




Document: MSDS0093, October 20, 1999 Page 2 of 7
Material Safety Data Sheet


STP?Heavy Duty Brake Fluid, DOT 3
5 FIRE FIGHTING MEASURES
250-275 癋 (121-135 0C)
Flash Point (Method) PMCC

Not determined
Upper Flammable Limit

Not determined
Lower Flammable Limit

Use water fog, foam, alcohol foam, carbon dioxide or dry chemical.
Extinguishing Media

Use self contained breathing apparatus and full protective clothing.
Special Firefighting
Use water to cool fire-exposed containers. A direct stream of water or
Procedures
foam may cause frothing.

None
Unusual Fire and
Explosion Hazards

Burning can produce carbon dioxide, carbon monoxide and oxides of
Combustion
nitrogen.
Decomposition

Not determined
Auto-ignition
Temperature

None determined.
Explosion Data


6 ACCIDENTAL RELEASE MEASURES
Wear appropriate personal protective equipment. Collect material with
Spill
suitable absorbent material. Place into an appropriate container for
disposal. Keep out of sewers and waterways.

7 HANDLING AND STORAGE
?Avoid contact with eyes.
Handling Procedures
?Avoid prolonged skin contact.
?Wash exposed skin with soap and water after use.
?Avoid breathing vapors and mists.
?Use only with adequate ventilation.
?Keep away from excessive heat or open flames
?Do not add nitrites or other nitrosating agents. A nitosamine, which
may cause cancer, may be formed.
?Store in a cool, well ventilated area. Keep container tightly closed
Storage Procedures
when not in use.




Document: MSDS0093, October 20, 1999 Page 3 of 7
Material Safety Data Sheet


STP?Heavy Duty Brake Fluid, DOT 3
8 EXPOSURE CONTROLS / PERSONAL PROTECTION
General ventilation should be adequate for normal use. For operations
Ventilation Procedures
where the product is heated or misted and exposures may be
excessive, mechanical ventilation such as local exhaust may be
needed to minimize exposure.
Chemical resistant gloves such as PVC coated gloves are
Gloves Protection
recommended to prevent prolonged/repeated skin contact.
Splash proof goggles are recommended to prevent eye contact.
Eye Protection
None needed under normal use conditions. For operations where the
Respiratory Protection
exposures may be excessive, a NIOSH/MSHA approved organic vapor
respirator with a dust/mist pre-filter or supplied air respirator is
recommended. Equipment selection depends on contaminant type and
concentration, select in accordance with 29 CFR 1910.134 and good
industrial hygiene practice. For firefighting, use self-contained
breathing apparatus.

Protective clothing if needed to avoid prolonged / repeated skin
Clothing
contact. Suitable washing and eye flushing facilities should be
Recommendation
available in the work area. Contaminated clothing should be removed
and laundered or dry-cleaned before re-use.
9 PHYSICAL AND CHEMICAL PROPERTIES
Not determined
Vapor Pressure
Not determined
pH
1.02-1.05
Specific Gravity
100%
Water Solubility
Not determined
Vapor Density
Not determined
Evaporation Rate
Characteristic odor
Odor
Clear amber to yellow liquid
Appearance
Not determined
Viscosity
Greater than 430 0F
Boiling Point
Less than -40 0F
Freezing Point
10 STABILITY AND REACTIVITY
Stable
Stability
Avoid strong oxidizing agents and peroxides.
Incompatibility

Document: MSDS0093, October 20, 1999 Page 4 of 7
Material Safety Data Sheet


STP?Heavy Duty Brake Fluid, DOT 3
10 STABILITY AND REACTIVITY (continued)
Contact with nitrites or other nitrosating agents may produce
Conditions to Avoid
nitrosamine, a known animal carcinogen.
Will not occur
Polymerization
Burning can produce carbon monoxide, carbon dioxide, and oxides of
Hazardous
nitrogen.
Decomposition


11 TOXICOLOGICAL INFORMATION
Accidental ingestion of a small amount may cause gastrointestinal
Oral Toxicity
discomfort with nausea, vomiting and diarrhea. A large ingestion may
produce central nervous system depression and kidney and liver
damage.
May cause moderate to severe eye irritation and possible corneal
Eye Irritation
damage.
Prolonged or repeated exposure may cause skin irritation.
Skin Irritation
A single prolonged exposure is not likely to result in material being
Dermal Toxicity
absorbed in harmful amounts. Prolonged or repeated skin exposure to
a very large amount of some of the ingredients of this formulation may
cause drowsiness.
High concentrations of vapors may cause respiratory irritation
Inhalation Toxicity
experienced as nasal discomfort and discharge.

Product: No information available.
Acute Toxicity Values
No evidence of sensitization from available data.
Sensitization
Prolonged or repeated skin contact with this product may possibly lead
Chronic Toxicity
to irritation and dermatitis. Prolonged or repeated inhalation or
ingestion may lead to central nervous system, gastrointestinal
disturbances and possible adverse reproductive effects.
A knowledge of the available toxicology information and of the physical
Medical Conditions
and clinical properties of this material suggests that overexposure is
Aggravated by Exposure
unlikely to aggravate existing medical conditions.

None of the components of this product is listed as a carcinogen or
Carcinogenicity
suspected carcinogen by IARC, NTP or OSHA.
No evidence of mutagencity from available data.
Mutagenicity
Reproductive Toxicity Minor components of this products, when tested separately, have
and Teratogenicity resulted in fetal toxicity in animal studies. One component caused birth
defects in animals following ingestion of large doses.

Document: MSDS0093, October 20, 1999 Page 5 of 7
Material Safety Data Sheet


STP?Heavy Duty Brake Fluid, DOT 3
12 ECOLOGICAL INFORMATION
Aquatic/Terrestrial No data is available at this time.
Toxicity
Environmental Fate
13 DISPOSAL CONSIDERATIONS
Incinerate, recycled, treat or landfilled in accordance with federal, state
Waste Disposal
and local regulations.
14 TRANSPORT INFORMATION
None - Not Regulated
U.S. DOT Non-Bulk
Shipping Description
None
ID Number
None
Hazard Class
None
Packing Group
None
Label
None
Markings
None
Placards
IMDG Code Shipping NONE - NOT REGULATED
Description
NONE
ID Number
NONE
Hazard Class
NONE
Packing Group
NONE
Label
NONE
Placards
IMDG PG NONE
Air - IATA Shipping None - Not regulated
Description
None
Technical Name
None
ID Number
None
Hazard Class
None
Packing Group
None
Markings
None
Label
15 REGULATORY INFORMATION
All of the components of this product are listed on the TSCA inventory.
U.S. TSCA Inventory/
This product is subject to export notification.
other TSCA Regulations.
None.
SARA Ext. Haz. Subst.




Document: MSDS0093, October 20, 1999 Page 6 of 7
Material Safety Data Sheet


STP?Heavy Duty Brake Fluid, DOT 3
15 REGULATORY INFORMATION (continued)
This product contains the following toxic chemicals subject to the
SARA Section 313
reporting requirements of section 313 of Title III of the Superfund
Amendments and Reauthorization Act of 1986 and 40 CFR Part 372
(SARA 313 - Toxic Chemical Release Reporting)
Chemical Name CAS# Weight %
Glycol Ethers Not available 85-100

This product is not subject to CERCLA reporting requirements,
CERCLA Hazardous
however, many states have more stringent release reporting
Substances (Section
requirements. Report spills required under federal, state and local
103)/RQ
regulations.
This product does not contain chemicals regulated under California
California Proposition 65
Proposition 65.
All of the components of this product are listed on the Canadian
Canada
Domestic Substances List (DSL).
All of the ingredients are listed on the EINECS inventory.
EEC EINECS
16 OTHER INFORMATION
Health: 2 Fire: 1 Reactivity: 1
NFPA Code
Health: 2* Fire: 1 Reactivity: 1
HMIS Code
Observe all requirements of plant, company or government regulations.
Precautionary Labels
"Empty" containers retain product residue and can be hazardous. Keep
out of the reach of children. Do not take internally.
Supersedes: July 23, 1999 Revised Sections: Sections 2
Revision Indicators
(Composition)
This MSDS is directed to professional users and bulk handlers of the
General
product or its ingredients. Consumer products are labeled in
accordance with Federal Hazardous Substances Act regulations and in
some instances might differ from the information provided herein.




Document: MSDS0093, October 20, 1999 Page 7 of 7

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