W. R. GRACE
MATERIAL SAFETY DATA SHEET
Product Name: Grace Vycor Butyl
MSDS ID Number: M-85766 MSDS Date: 07/05/2006
SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Grace Vycor Butyl, Grace Ultra
Product Name:
M-85766
MSDS Number:
New
Cancelled MSDS Number:
07/05/2006
MSDS Date:
Butyl Rubber Based Adhesive Sheet with Polyolefin Film or Mesh
Chemical Family Name:
Flashing Tape
Product Use:
Mixture-NA
Chemical Formula:
CAS # (Chemical Abstracts Service Mixture-NA
Number):
Manufactured by:
W.R.Grace & Co.-Conn. Grace Canada, Inc.
62 Whittemore Avenue 294 Clements Road West
Cambridge, MA 02140 Ajax, Ontario L1S 3C6
In Case of Emergency Call:
In USA: (617) 876-1400 In Canada: (905) 683-8561
SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS
Ingredient CAS# Percent (max)
No Hazardous Components
SECTION 3 - HAZARDS IDENTIFICATION
Emergency Overview:
Removal of release liner may generate a static electrical discharge (spark).
Release liners are slippery. Remove from work area immediately after membrane application.
HMIS Rating:
Health: 0
Flammability: 1
Reactivity: 0
Personal Protective Equipment: B (See Section 8)
Potential Health Effects:
Inhalation: There are no known health effects due to inhalation. Due to the physical nature of this
product, inhalation is unlikely.
Eye Contact: Due to the physical nature of this product eye contact is unlikely. If eye contact does
occur irritation may result.
Skin Contact: There are no known health effects due to skin contact.
Skin Absorption: Not expected to be harmful if absorbed through the skin.
Ingestion: Due to the physical nature of this product, ingestion is not likely.
SECTION 4 - FIRST AID MEASURES:
Skin Contact: In case of skin contact, wash skin with soap and water.
If discomfort or irritation persists, consult a physician.
Eye Contact: If eye irritation develops due to contact with residue on hands, flush eyes with water for
at least 15 minutes while holding eyelids open.
If discomfort or irritation persists, consult a physician.
Ingestion: Do not induce vomiting.
Never give anything by mouth to an unconscious person.
If discomfort persists, consult a physician.
Inhalation: If symptoms develop, get fresh air. If symptoms persist, consult a physician.
Page 1 of 4
W. R. GRACE
MATERIAL SAFETY DATA SHEET
Product Name: Grace Vycor Butyl
MSDS ID Number: M-85766 MSDS Date: 07/05/2006
SECTION 5 - FIRE AND EXPLOSION HAZARD DATA
Flash Point: Not Applicable
Flash Point Method: Not Applicable
Lower Explosion Limit: Not Available
Upper Explosion Limit: Not Available
Auto-Ignition Temperature: Not Available
NFPA Rating:
Health: 0
Flammability: 1
Reactivity: 0
Extinguishing Media: In case of fire, use water spray, dry chemical, Carbon dioxide or foam.
Special Fire Fighting Procedures: Wear self-contained breathing apparatus and complete personal
protective equipment when potential for exposure to vapors or products of combustion exist. Water
may be used to cool containers to prevent pressure build-up and possible auto-ignition or explosion.
Avoid breathing hazardous vapors or products of combustion. Keep upwind. Isolate area and keep
unnecessary people away. Prevent run-off from fire control or dilution from entering streams or drinking
water supplies.
Unusual Fire and Explosion Hazards: Removal of release paper may create a static electric
discharge (sparks). Do not remove where sparks may ignite flammable vapors.
SECTION 6 - ACCIDENTAL RELEASE MEASURES:
Spills/Leaks: Due to the physical nature of this product spills will not occur. Clean up waste material
and dispose.
SECTION 7 - HANDLING AND STORAGE
Precautionary Measures:
Avoid contact with eyes.
Practice good personal hygiene to avoid ingestion.
Slippery when wet or covered with frost.
To avoid skin contact, use gloves or barrier creams.
Promptly cleanse hands with waterless hand cleaner, clean fingernails and wash with soap and water
after handling.
Release liners are slippery. Remove from work area immediately.
Do not remove release liner where sparks may ignite flammable vapors.
FOR PROFESSIONAL USE ONLY. KEEP OUT OF CHILDREN'S REACH.
SECTION 8 - EXPOSURE CONTROLS AND PERSONAL PROTECTIVE EQUIPMENT
EXPOSURE GUIDELINES (US)
Ingredient ACGIH TLV OSHA PEL Other
TWA STEL Ceiling TWA STEL Ceiling
EXPOSURE GUIDELINES (CANADA)
Employers should consult local Provincial regulatory limits for exposure guidelines which may vary locally.
Not generally required.
Engineering Controls:
Personal Protective Equipment:
Respiratory Protection: Respiratory protection is not required during normal use.
Skin Protection: Normal Work Gloves.
Eye Protection: Not required for normal use.
Work/Hygienic Practices: Use good personal hygiene practices.
Avoid rubbing eyes while handling. Due to the physical nature of this product, ingestion is unlikely.
Incidental ingestion of residue on hands can be avoided by using good personal hygiene practices.
None beyond those noted above.
Page 2 of 4
W. R. GRACE
MATERIAL SAFETY DATA SHEET
Product Name: Grace Vycor Butyl
MSDS ID Number: M-85766 MSDS Date: 07/05/2006
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Solid
Physical State:
A black, butyl based layer on a back plastic sheet with a
Appearance/Odor:
white plastic release sheet.
Not Determined
Odor Threshold: (ppm)
Not Applicable
pH:
Not Applicable
Vapor Pressure: (Mm Hg)
Not Applicable
Vapor Density: (Air = 1)
Not applicable
Solubility In Water:
Not Applicable
Specific Gravity: (Water = 1)
Not Applicable
Evaporation Rate: (Butyl Acetate = 1)
Not Applicable
Boiling Point:
Unknown
Viscosity:
Bulk Density: (Pounds/Cubic Foot)(Pcf) Not Determined
Negligible
% Volatiles (gr/L): (70癋) (21癈)
SECTION 10 - STABILITY AND REACTIVITY
Stable
Chemical Stability:
None known for this product.
Conditions To Avoid:
Will not polymerize.
Hazardous Polymerization:
None known for this product.
Hazardous Decomposition
Products:
SECTION 11 - TOXICOLOGICAL INFORMATION
Ingredient(No data unless listed.) CAS Number LD50 and LC50
Carcinogenicity:
Ingredient IARC IARC IARC NTP NTP OSHA
Group 1 Group 2A Group 2B Known Suspect
Not applicable.
Mutagenicity:
Not applicable.
Teratogenicity:
Not applicable.
Reproductive Toxicity:
SECTION 12 - ECOLOGICAL INFORMATION
No data available for product.
Environmental Fate:
No data available for product.
Ecotoxicity:
SECTION 13 - DISPOSAL CONSIDERATIONS
Waste Disposal Procedures: Consult all regulations (federal, state, provincial, local) or a
qualified waste disposal firm when characterizing waste for disposal. According to EPA (40 CFR
?261), waste of this product is not defined as hazardous. Dispose of waste in accordance with
all applicable regulations.
SECTION 14 - TRANSPORTATION INFORMATION
Not Applicable
Proper Shipping Name:
Not Applicable
UN/NA Number:
Nonhazardous
Domestic Hazard Class:
Not Applicable
Surface Freight Classification:
Not Applicable
Label/Placard Required:
SECTION 15 - REGULATORY INFORMATION
REGULATORY CHEMICAL LISTS:
CERCLA (Comprehensive Response Compensation and Liability Act):
(None present unless listed below)
Chemical Name CAS # Wt % CERCLA RQ
SARA Title III (Superfund Amendments and Reauthorization Act)
Page 3 of 4
W. R. GRACE
MATERIAL SAFETY DATA SHEET
Product Name: Grace Vycor Butyl
MSDS ID Number: M-85766 MSDS Date: 07/05/2006
SARA Section 312/Tier I & II Hazard Categories:
Health Immediate (acute) No
Health Delayed (chronic) No
Flammable No
Reactive No
Pressure No
302 Reportable Ingredients (Identification Threshold 1%.):
Chemical Name CAS # Wt % SARA 302 TPQ
313 Reportable Ingredients (Chemicals present below reporting threshold are exempt):
Chemical Name CAS # Wt %
National Volatile Organic Compound Emission Standards For Architectural Coatings:
Not Applicable
Volatile Organic Content: (gr/L)
This product is not WHMIS controlled.
WHMIS Classification(s):
This product has been classified in accordance with the hazard criteria of the Controlled Products
Regulations (CPR). This MSDS contains all the information required by the CPR.
State Regulatory Information:
California Proposition 65: This product does not contain substances known to the state of California
to cause cancer, birth defects or other reproductive harm.
Massachusetts Hazardous Substance List(Identification threshold 0.001%(1ppm)):
Chemical Name CAS # Wt %
New Jersey Hazardous Substance List(Identification threshold (0.1%)):
Chemical Name CAS # Wt %
Pennsylvania Hazardous Substance List(Identification threshold 0.01%):
Chemical Name CAS # Wt %
CHEMICAL INVENTORY STATUS:
All chemicals in this product are listed or exempt from listing in the following countries:
US CANADA EUROPE AUSTRALIA JAPAN KOREA PHILIPPINES
TSCA DSL NDSL EINECS/ELINCS AICS ENCS ECL PICCS
Yes Yes No Yes Yes Yes Yes Yes
SECTION 16 - OTHER INFORMATION
Non-Hazardous Ingredient Disclosure:
Chemical Name CAS Number
EH&S Department
Prepared by:
EH&S Department
Approved by:
07/05/2006
Approved Date:
Disclaimer:
"The data included herein are presented in accordance with various environment, health and safety
regulations. It is the responsibility of a recipient of the data to remain currently informed on chemical
hazard information, to design and update its own program and to comply with all national, federal, state
and local laws and regulations applicable to safety, occupational health, right-to-know and environmental
protection."
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