Page: 1
Revision Date: 03/02/2007
SAFETY DATA SHEET
Print Date: 8/14/2007
MSDS Number: R0311642
PLIOBOND?7008 WATER BASED Version: 1.
PVC ADHESIVE 120439
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Ashland Regulatory Information Number 1-800-325-3751
P.O. Box 2219 Telephone 614-790-3333
Columbus, OH 43216 Emergency telephone number 1-800-ASHLAND
(1-800-274-5263)
Product name PLIOBOND?7008 WATER BASED PVC ADHESIVE
Product code 120439
Product Use Description No data
2. HAZARDS IDENTIFICATION
Emergency Overview
Appearance: liquid
CAUTION! Carcinogen.
Potential Health Effects
Routes of Exposure
Inhalation, Skin contact, Eye Contact, Ingestion
Eye Contact
May cause mild eye irritation. Symptoms include stinging, tearing, and redness.
Skin Contact
May cause mild skin irritation. Symptoms may include redness and burning of
skin.
Ingestion
Swallowing small amounts of this material during normal handling is not likely to
cause harmful effects. Swallowing large amounts may be harmful.
Inhalation
Breathing of vapor or mist is possible. Breathing small amounts of this material
during normal handling is not likely to cause harmful effects. Breathing large amounts
may be harmful. Symptoms are not expected at air concentrations below the
recommended exposure limits, if applicable (see Section 8.).
Aggravated Medical Condition
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Revision Date: 03/02/2007
SAFETY DATA SHEET
Print Date: 8/14/2007
MSDS Number: R0311642
PLIOBOND?7008 WATER BASED Version: 1.
PVC ADHESIVE 120439
Preexisting disorders of the following organs (or organ systems) may be
aggravated by exposure to this material:, lung (for example, asthma-like conditions)
Symptoms
Signs and symptoms of exposure to this material through breathing, swallowing,
and/or passage of the material through the skin may include:, stomach or intestinal upset
(nausea, vomiting, diarrhea), irritation (nose, throat, airways)
Target Organs
No data
Carcinogenicity
Vinyl acetate caused an increase in cancer of the nasal cavity in rats. The
relevance of this finding to humans is uncertain. The International Agency for Research
on Cancer (IARC) reclassified this chemical from Group 3 (not able to be classified) to
Group 2B (possibly carcinogenic in humans) in 1995. This classification is based on the
study in rats, along with knowledge that vinyl acetate is changed to acetaldehyde, a
known animal carcinogen, in the body.
Reproductive Hazard
There are no data available for assessing risk to the fetus from maternal exposure
to this material.
Other Information
Formaldehyde has been identified as a carcinogen by the International Agency for
Research on Cancer (IARC), the National Toxicology Program (NTP) and the
Occupational Safety and Health Administration (OSHA). Formaldehyde is irritating to
the eyes, nose, throat, and airways, and can cause an allergic reaction (causes narrowing
of the air passages of the lungs, sweating, flushing, hives, rapid heart rate, and lowered
blood pressure). In addition, formaldehyde can cause an allergic skin reaction (delayed
skin rash which may be followed by blistering, scaling and other skin effects). It is
harmful if inhaled, swallowed or absorbed through skin.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Components CAS-No. Concentration
VINYL ACETATE MONOMER 108-05-4 >=0.5-<1%
4. FIRST AID MEASURES
Eyes
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Revision Date: 03/02/2007
SAFETY DATA SHEET
Print Date: 8/14/2007
MSDS Number: R0311642
PLIOBOND?7008 WATER BASED Version: 1.
PVC ADHESIVE 120439
If symptoms develop, move individual away from exposure and into fresh air.
Flush eyes gently with water while holding eyelids apart. If symptoms persist or there is
any visual difficulty, seek medical attention.
Skin
Remove contaminated clothing. Wash exposed area with soap and water. If
symptoms persist, seek medical attention. Launder clothing before reuse.
Ingestion
Seek medical attention. If individual is drowsy or unconscious, do not give
anything by mouth; place individual on the left side with the head down. Contact a
physician, medical facility, or poison control center for advice about whether to induce
vomiting. If possible, do not leave individual unattended.
Inhalation
If symptoms develop, move individual away from exposure and into fresh air. If
symptoms persist, seek medical attention. If breathing is difficult, administer oxygen.
Keep person warm and quiet; seek immediate medical attention.
Notes to Physician
Hazards: No information available.
Treatment: No information available.
5. FIRE-FIGHTING MEASURES
Suitable Extinguishing Media
Water mist, carbon dioxide (CO2), dry chemical
Hazardous Combustion Products
May form:, acetic acid, acrolein, aldehydes, carbon dioxide and carbon
monoxide, various hydrocarbons
Precautions for Fire-Fighting
No special fire hazards are known to be associated with this product. Wear full
firefighting turn-out gear (full Bunker gear), and respiratory protection (SCBA).
6. ACCIDENTAL RELEASE MEASURES
Personal Precautions
No data
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Revision Date: 03/02/2007
SAFETY DATA SHEET
Print Date: 8/14/2007
MSDS Number: R0311642
PLIOBOND?7008 WATER BASED Version: 1.
PVC ADHESIVE 120439
Environmental Precautions
No data
Methods for Cleaning Up
Persons not wearing protective equipment should be excluded from area of spill
until clean-up has been completed. Stop spill at source, dike area of spill to prevent
spreading, pump liquid to salvage tank. Remaining liquid may be taken up on sand, clay,
earth, floor absorbent, or other absorbent material and shoveled into containers. Absorb
liquid on vermiculite, floor absorbent or other absorbent material.
7. HANDLING AND STORAGE
Handling
No data
Storage
No data
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Guidelines
General Advice
These recommendations provide general guidance for handling this product.
Personal protective equipment should be selected for individual applications and should
consider factors which affect exposure potential, such as handling practices, chemical
concentrations and ventilation. It is ultimately the responsibility of the employer to
follow regulatory guidelines established by local authorities.
Exposure Controls
Provide sufficient mechanical (general and/or local exhaust) ventilation to
maintain exposure below TLV(s).
Eye Protection
Chemical splash goggles in compliance with OSHA regulations are advised;
however, OSHA regulations also permit other type safety glasses. Consult your safety
representative.
Skin and Body Protection
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Revision Date: 03/02/2007
SAFETY DATA SHEET
Print Date: 8/14/2007
MSDS Number: R0311642
PLIOBOND?7008 WATER BASED Version: 1.
PVC ADHESIVE 120439
Wear normal work clothing covering arms and legs.Wear resistant gloves such as:
Natural RubberWear resistant gloves such as:
Respiratory Protection
If workplace exposure limit(s) of product or any component is exceeded (see
exposure guidelines), a NIOSH-approved air supplied respirator is advised in absence of
proper environmental control. OSHA regulations also permit other NIOSH respirators
(negative pressure type) under specified conditions (see your industrial hygienist).
Engineering or administrative controls should be implemented to reduce exposure.
9. PHYSICAL AND CHEMICAL PROPERTIES
liquid
Physical state
No data
Form
No data
Colour
No data
Odour
No data
Boiling point/range
No data
pH
212.00 癋 / 100.00 癈
Flash point
No data
Evaporation rate
No data
Explosion limits
No data
Vapour pressure
No data
Vapour density
1.100 g/cm3
Density
No data
No data
Solubility
No data
Partition coefficient (n-
octanol/water)
No data
Autoignition temperature
10. STABILITY AND REACTIVITY
Stability
Stable.
Conditions to Avoid
None known.
Incompatible Products
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Revision Date: 03/02/2007
SAFETY DATA SHEET
Print Date: 8/14/2007
MSDS Number: R0311642
PLIOBOND?7008 WATER BASED Version: 1.
PVC ADHESIVE 120439
Avoid contact with:, alkali metals, peroxides, strong alkalis, strong mineral acids,
strong oxidizing agents
Hazardous Decomposition Products
May form:, acetic acid, acrolein, aldehydes, carbon dioxide and carbon monoxide,
various hydrocarbons
Hazardous Reactions
Product will not undergo hazardous polymerization.
Thermal Decomposition
No data
11. TOXICOLOGICAL INFORMATION
Acute Oral Toxicity
VINYL ACETATE MONOMER LD 50 Rat: 2,920 mg/kg
Acute Inhalation Toxicity
VINYL ACETATE MONOMER LC 50 Rat: 3,680 mg/l,
Acute Dermal Toxicity
VINYL ACETATE MONOMER LD 50 Rabbit: 2,335 mg/kg
12. ECOLOGICAL INFORMATION
Aquatic Toxicity
Acute and Prolonged Toxicity to Fish
No data
Acute Toxicity to Aquatic Invertebrates
No data
Environmental Fate and Pathways
No data
Page 6 / 8
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Revision Date: 03/02/2007
SAFETY DATA SHEET
Print Date: 8/14/2007
MSDS Number: R0311642
PLIOBOND?7008 WATER BASED Version: 1.
PVC ADHESIVE 120439
13. DISPOSAL CONSIDERATIONS
Waste Disposal Methods
Destroy by liquid incineration in accordance with applicable regulations. For
assistance with your waste management needs - including disposal, recycling and waste
stream reduction, contact Ashland Distribution Company, IC&S Environmental Services
Group at 800-637-7922.
14. TRANSPORT INFORMATION
Dangerous goods descriptions may not reflect package size, quantity, end-use or region-
specific exceptions that can be applied to shipments. Consult shipping documents for
material-specific descriptions.
15. REGULATORY INFORMATION
California Prop. 65
WARNING! This product contains a chemical known in the State of California to cause
cancer.
ACETALDEHYDE
FORMALDEHYDE
Chronic Health Hazard
SARA Hazard Classification
SARA 313 Component(s)
VINYL ACETATE 108-05-4 0.6%
MONOMER
Carcinogen
OSHA Hazards
Health Flammability Reactivity Other
2 1 0
HMIS
2 1 0
NFPA
16. OTHER INFORMATION
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Revision Date: 03/02/2007
SAFETY DATA SHEET
Print Date: 8/14/2007
MSDS Number: R0311642
PLIOBOND?7008 WATER BASED Version: 1.
PVC ADHESIVE 120439
The information accumulated herein is believed to be accurate but is not warranted to be
whether originating with the company or not. Recipients are advised to confirm in advance
of need that the information is current, applicable, and suitable to their circumstances.
This MSDS has been prepared by Ashland's Environmental Health and Safety Department
(1-800-325-3751).
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