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Page 1 of 4
MATERIAL SAFETY DATA SHEET
NAME: DURACELL ALKALINE BATTERIES
Effective Date: Rev:
CAS NO: Not applicable 06/25/2004 8
A. -- IDENTIFICATION
Mixture
Formula:
Composition* (1% or greater) %
35-40
Manganese Dioxide (1313-13-9) Molecular Weight: NA
10-25 Synonyms: Alkaline Manganese Dioxide Batteries
Zinc (7440-66-6)
5-10 MN1300 (D); MN1400 (C); MN1500 (AA) MN2400
Potassium Hydroxide (35%) (1310-58-3)
(AAA); MX1300 (D); MX1400 (C); MX1500 (AA);
Graphite, natural (7782-42-5) or synthetic 1-5 MX2400 (AAA); MX2500 (AAAA); MX1604 (9V);
(7440-44-0) MN908 (Lantern 6V); MN918 (Lantern 4.5V);
MN1604 (9V); MN9100 (N), MN1203 (4.5V); 5K69
(Flatpack); 7K67 (Flatpack) (J) and batteries comprised
of these cells.
B. -- PHYSICAL DATA
Boiling Point Melting Point Freezing Point
癋 癈 癋 癈 癋 癈
NA NA NA NA NA NA
Specific Gravity (H2O=1) Vapor Density (air=1) Vapor Pressure @ 癋
NA NA NA mm Hg
Evaporation Saturation in Air Autoignition Temperature
( =1) (by volume @ 癋) 癋 癈
Ether
NA NA NA
% Volatiles Solubility in Water
NA NA NA
pH
Appearance/Color Copper top battery. Contents dark in color.
Flash Point and
NA
Test Method(s)
Flammable Limits in Air
(% by volume) % %
NA NA
Lower Upper
C. -- REACTIVITY
Stability Stable Unstable Polymerization may occur will not occur
X X
Conditions to Avoid Conditions to Avoid
Do not heat, crush, disassemble, short circuit or Not applicable
recharge.
Incompatible Materials Hazardous Decomposition Products
Contents incompatible with strong oxidizing agents. Thermal degradation may produce hazardous fumes
of zinc and manganese; hydrogen gas; caustic vapors
of potassium hydroxide and other toxic by-products.
Footnotes
NA=Not Available
Please note: Some Duracell alkaline batteries contain the Duracell Power CheckTM battery energy gauge which is a small
conductive strip located underneath the PVC battery label that indicates the amount of charge in the battery. It is composed of
minute quantities of conductive materials. Due to the small quantity of materials and their solid form, a health or environmental
risk is unlikely.
GMEL# 2002.8
Page 2 of 4
D. -- HEALTH HAZARD DATA
Occupational Exposure Limits (PELs, TLVs, etc.)
8-Hour TWAs: Manganese Dioxide (as Mn) - 5 mg/m3 (Ceiling) (OSHA); 0.2 mg/m3 (ACGIH/Duracell)
Potassium Hydroxide - 2 mg/m3 (Ceiling) (ACGIH)
Graphite (all kinds except fibrous)-2 mg/ m3 (ACGIH); (synthetic)-15 mg/m3 (total, OSHA );
5 mg/m3 (respirable, OSHA)
These levels are not anticipated under normal consumer use conditions.
Warning Signals
Not applicable
Routes/Effects of Exposure
These chemicals and metals are contained in a sealed can. For consumer use, adequate hazard warnings are
included on both the package and on the battery. Potential for exposure should not exist unless the battery
leaks, is exposed to high temperatures or is mechanically, physically, or electrically abused. Contains
concentrated (35%) potassium hydroxide, which is caustic. Anticipated potential leakage of potassium
hydroxide is 2 to 20 ml, depending on battery size. A similar amount of zinc/zinc oxide may also leak.
1. Inhalation Respiratory (and eye) irritation may occur if fumes are released due to heat or an abundance of
leaking batteries.
2. Ingestion Not anticipated due to size of batteries; choking may occur with the smaller AAA and AAAA
batteries. Irritation, including caustic burns/injury, may occur following exposure to a leaking
battery.
3. Skin a. Contact
Irritation, including caustic burns/injury, may occur following exposure to a leaking battery.
b. Absorption
Not anticipated
4. Eye Contact Irritation, including caustic burns/injury, may occur following exposure to a leaking battery.
5. Other Not applicable
E. -- ENVIRONMENTAL IMPACT
1. Applicable Regulations - All ingredients listed in TSCA inventory.
2. DOT Hazard Class - Not applicable
3. DOT Shipping Name - Not applicable
Please note: These batteries are not regulated by U. S. DOT or international
agencies as hazardous materials or dangerous goods when shipped. Duracell uses
the article name 'Alkaline Batteries - Non-hazardous' on all domestic and
international bills of lading.
Environmental Effects
These batteries pass the U. S. EPA's Toxicity Characteristic Leaching Procedure and therefore, may be
disposed of with normal waste.
GMEL# 2002.8
Page 3 of 4
F. -- EXPOSURE CONTROL METHODS
Engineering Controls
General ventilation under normal use conditions.
Eye Protection
None under normal use conditions. Wear safety glasses when handling leaking batteries.
Skin Protection
None under normal use conditions. Use neoprene, rubber or latex gloves when handling leaking batteries.
Respiratory Protection
None under normal use conditions.
Other
Keep batteries away from small children.
G. -- WORK PRACTICES
Handling and Storage
Store at room temperature. Avoid mechanical or electrical abuse. DO NOT short or install incorrectly.
Batteries may explode, pyrolize or vent if disassembled, crushed, recharged or exposed to high temperatures.
Install batteries in accordance with equipment instructions. Do not mix battery systems, such as alkaline and
zinc carbon, in the same equipment. Replace all batteries in equipment at the same time. Do not carry
batteries loose in pocket or bag. Do not remove battery tester or battery label.
Normal Clean Up
Not applicable
Waste Disposal Methods
Individual consumers may dispose of spent (used) batteries with household trash. Duracell does not
recommend that spent batteries be accumulated (quantities of five gallons or more should be disposed of in a
secure landfill), in accordance with appropriate federal, state and local regulations. Do not incinerate, since
batteries may explode at excessive temperatures.
GMEL# 2002.8
Page 4 of 4
H. -- EMERGENCY PROCEDURES
Steps to be taken if material is released to the environment or spilled in the work area
Notify safety personnel of large spills. Caustic potassium hydroxide may be released from leaking or
ruptured batteries. Avoid eye or skin contact and inhalation of vapors. Increase ventilation. Clean-up
personnel should wear appropriate protective gear.
Fire and Explosion Hazard Extinguishing Media
Batteries may burst and release hazardous decomposition products when As appropriate for surrounding
exposed to a fire situation. See Sec. C. area.
Firefighting Procedures
Use self-contained breathing apparatus and full protective gear.
I. -- FIRST AID AND MEDICAL EMERGENCY PROCEDURES
Eyes
Not anticipated. If battery is leaking and material contacts eyes, flush with copious amounts of clear, tepid
water for 30 minutes. Contact physician at once.
Skin
Not anticipated. If battery is leaking, irrigate exposed skin with copious amounts of clear, tepid water for at
least 15 minutes. If irritation, injury or pain persists, consult a physician.
Inhalation
Not anticipated. If battery is leaking, contents may be irritating to respiratory passages. Remove to fresh air.
Contact physician if irritation persists.
Ingestion
Not anticipated. Rinse the mouth and surrounding area with clear, tepid water for at least 15 minutes. Consult
a physician immediately for treatment and to rule out involvement of the esophagus and other tissues.
Notes to Physician
1) The primary acutely toxic ingredient is concentrated (35%) potassium hydroxide.
2) Anticipated potential leakage of potassium hydroxide is 2-20 ml, depending on battery size.
3) This MSDS does not include or address the small button cell batteries, which can be ingested.
This MSDS covers the following discontinued product numbers: DAC100, 105,110,116-118,123-124, 130, 200,
610,810,820,918
The information contained in the Material Safety Data Sheet is based on data considered to be accurate, however, no warranty is
expressed or implied regarding the accuracy of the data or the results to be obtained from the use thereof.
MSDS-5 (2/00) GMEL# 2002.8
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