Anitec
Material Safety Data Sheet N EWSPAPER COM PANY
Subtractive Plate Finisher XL
1. Chemical Product and Company Identification
: Subtractive Plate Finisher XL
Common Name
337
MSDS#
Version 2.54
: CIN 10095233; PCD 6325; E-0014.100
Synonym
Validation Date 2000-09-06
: 300 5770; 300 5771; 300 5772; 300 5773; 300 5774; 300
Catalogue number
5775
Responsible Name Kodak Polychrome
: Industrial applications. Graphic Arts Imaging.
Area of Application
Graphics
: Anitec Newspaper Company
Supplier
383 Dwight Street
Holyoke, MA 01040
USA
Tel. (413) 538-9624
Emergency telephone : In Case of Emergency (medical/roadside) (24hrs) CALL 1-800-451-8346
number
: Kodak Polychrome Graphics, Environmental Solutions Department;
For other EHS
11465 Johns Creek Parkway, #260, Duluth, GA 30097; USA
Information
Phone: 1-877-574-7274 ext. 511, Additional phone: (770) 232-2133
E-mail: PEP@kpgraphics.com, Fax: (770) 232-2150;
2. Composition, Information on Ingredients
Name CAS # % by Weight Exposure Limits
1) Water 7732-18-5 80-90 Not available.
2) Sodium hexametaphosphate 10124-56-8 5-10 Not available.
3) Sodium citrate 68-04-2 1-5 Not available.
4) Sodium hydrogen sulfate 7681-38-1 1-5 Not available.
5) Polyethylene Glycol 25322-68-3 1-5 TWA: 1 (ppm) from OSHA (PEL) [United States]
TWA: 1 (ppm) from ACGIH (TLV) [United States]
TWA: 1.8 (mg/m3) from ACGIH (TLV) [United States]
TWA: 1 (mg/m3) from OSHA (PEL) [United States]
6) Phosphoric acid 7664-38-2 <1
STEL: 3 (mg/m3) from OSHA (PEL) [United States]
3. Hazards Identification
: Liquid.
Physical State and
Appearance
Emergency Overview WARNING!
:
CAUSES EYE IRRITATION. CAUSES SKIN IRRITATION.
Avoid contact with eyes, skin and clothing. Harmful if swallowed Wash thoroughly after handling.
Absorbed through skin. Eye contact. Inhalation.
:
Routes of Entry
Potential Acute Health Effects
Eyes : Hazardous in case of eye contact (irritant).
: Sensitization of the product: Not available.
Skin
Hazardous in case of skin contact (irritant). Skin inflammation is characterized by itching, scaling, reddening, or,
occasionally, blistering.
Inhalation : Practically non-toxic by inhalation.
Ingestion : Slightly hazardous in case of ingestion.
: CARCINOGENIC EFFECTS: Not available.
Potential Chronic
MUTAGENIC EFFECTS: Not available.
Health Effects
TERATOGENIC EFFECTS: Not available.
Medical Conditions : Repeated or prolonged exposure is not known to aggravate medical condition.
Aggravated by
Overexposure:
See Toxicological Information (section 11)
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Subtractive Plate Finisher XL
4. First Aid Measures
: Check for and remove any contact lenses. In case of contact with eyes, rinse immediately with plenty of
Eye Contact
water. Seek medical attention.
: After contact with skin, wash immediately with plenty of water. If irritation persists, seek medical attention.
Skin Contact
Inhalation : Allow the victim to rest in a well-ventilated area. If irritation persists, seek medical attention.
: Have conscious person drink several glasses of water or milk. INDUCE VOMITING by sticking finger in
Ingestion
throat. Seek medical attention.
5. Fire Fighting Measures
: Non-flammable.
Flammability of the
Product
: Not applicable.
Auto-Ignition
Temperature
: carbon oxides (CO, CO2) sulfur oxides (SO2, SO3...) Phosphorus oxides
Hazardous thermal
(de)composition
products
: Not applicable.
Fire Hazards in
Presence of Various
Substances
: Risks of explosion of the product in presence of mechanical impact: Not available.
Explosion Hazards in
Risks of explosion of the product in presence of static discharge: Not available.
Presence of Various
Substances
: Use DRY chemicals, CO2, water spray or foam.
Fire Fighting Media
and Instructions
: Be sure to use an approved/certified respirator or equivalent.
Protective Clothing
(Fire)
: May emit toxic fumes under fire conditions.
Special Remarks on
Fire Hazards
6. Accidental Release Measures
: Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste
Small Spill and Leak
disposal container. If necessary: Neutralize the residue with a dilute solution of sodium carbonate.
Finish cleaning by spreading water on the contaminated surface and dispose of according to local and
regional authority requirements.
: Absorb with an inert material and put the spilled material in an appropriate waste disposal. Finish
Large Spill and Leak
cleaning by spreading water on the contaminated surface and dispose of according to local and regional
authority requirements.
7. Handling and Storage
: Do not ingest. Avoid contact with eyes, skin, and clothing. Wear suitable protective clothing. Ventilation
Handling
is normally required when handling or using this product.
Storage : Store at room temperature 25癈 (77癋) or lower. Prevent from freezing
8. Exposure Controls, Personal Protection
: Use good general ventilation(>10 air changes/hour) and engineering controls (local exhaust, filter's,
Engineering Controls
process enclosures if necessary) to maintain airborne levels below ACGIH Threshold Limit Values (TLV)
and OSHA Permissible Exposure Limits(PEL). Ensure that eyewash station and safety shower is proximal
to the work-station location.
Personal Protection
Eyes : Splash goggles.
Body : Lab coat.
Respiratory : Wear appropriate respirator when ventilation is inadequate.
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Subtractive Plate Finisher XL
Hands : Gloves (impervious).
Feet : Not applicable.
:
Protective Clothing
(Pictograms)
: Splash goggles. Lab coat. Gloves (impervious). Wear appropriate respirator when ventilation is
Personal Protection in
inadequate.
Case of a Large Spill
Exposure Limits
Product Name
Not available.
1) Water
Not available.
2) Sodium hexametaphosphate
Not available.
3) Sodium citrate
Not available.
4) Sodium hydrogen sulfate
TWA: 1 (ppm) from OSHA (PEL) [United States]
5) Polyethylene Glycol
TWA: 1 (ppm) from ACGIH (TLV) [United States]
TWA: 1.8 (mg/m3) from ACGIH (TLV) [United States]
TWA: 1 (mg/m3) from OSHA (PEL) [United States]
6) Phosphoric acid
STEL: 3 (mg/m3) from OSHA (PEL) [United States]
Consult local authorities for acceptable exposure limits.
9. Physical and Chemical Properties
: Liquid. : Odorless.
Physical State and Odor
Appearance
: Not applicable.
Molecular Weight
: Colorless.
Color
: Not applicable.
Molecular Formula
: 3.8 [Acidic.]
pH (1% Soln/Water)
: >100癈 (212癋)
Boiling/Condensation
Point
: <0癈 (32癋)
Melting/Freezing Point
: 1.1 (Water = 1)
Specific Gravity
Vapor Pressure : 2.4 kPa (@ 20癈)
: 0.6 (Air = 1)
Vapor Density
: 90% (w/w).
Volatility
:-
VOC by EPA Method
24
: 55.13 g/l (0.46 lbs/Gal.).
VOC Calculated
: Not available.
Ionicity (in Water)
: See solubility in water.
Dispersion Properties
: Easily soluble in cold water
Solubility
10. Stability and Reactivity
Stability and Reactivity The product is stable.
:
Conditions of Instability : Not available.
Incompatibility with strong oxidising agents
:
Various Substances
Hazardous : carbon oxides (CO, CO2) sulfur oxides (SO2, SO3...) Phosphorus oxides
Decomposition Products
: Will not occur.
Hazardous
Polymerization
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Subtractive Plate Finisher XL
11. Toxicological Information
: Water:
Toxicity to Animals
ORAL (LD50): Acute: >90000 mg/kg [Rat].
Sodium hexametaphosphate:
ORAL (LD50): Acute: 6200 mg/kg [Rat].
Sodium citrate:
ORAL (LD50): Acute: 11700 mg/kg [Rat].
Sodium hydrogen sulfate
LD50: Not available.
LC50: Not available.
Polyethylene Glycol:
ORAL (LD50): Acute: 27500 mg/kg [Rat]. 31000 mg/kg [Mouse]. 17300 mg/kg [Rabbit].
DERMAL (LD50): Acute: >20000 mg/kg [Rabbit]. 19600 mg/kg [Guinea pig].
Phosphoric acid:
ORAL (LD50): Acute: 1530 mg/kg [Rat].
DERMAL (LD50): Acute: 2740 mg/kg [Rabbit].
: Not available.
Chronic Effects on
Humans
: Hazardous in case of skin contact (irritant).
Other Toxic Effects on
Slightly hazardous in case of ingestion.
Humans
Non-hazardous in case of inhalation.
12. Ecological Information
: Not available.
Ecotoxicity
: The product itself and its products of degradation are not toxic.
Toxicity of the Products
of Biodegradation
13. Disposal Considerations
: Waste must be disposed of in accordance with federal, state and local environmental control regulations.
Waste Information
Consult your local or regional authorities.
14. Transport Information
: Not a DOT controlled material (United States).
DOT Classification
Not applicable.
Not applicable.
Not applicable.
: Not designated as a marine pollutant.
Marine Pollutant
: Not applicable.
Special Provisions for
Transport
: Not controlled under TDG (Canada).
TDG Classification
: Not controlled under ADR (Europe).
ADR/RID Classification
: Not controlled under IMDG.
IMO/IMDG
Classification Not applicable.
Not applicable.
Not applicable.
: Not controlled under IATA.
ICAO/IATA
Classification
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Subtractive Plate Finisher XL
Not applicable.
Not applicable.
15. Regulatory Information
Not controlled under the HCS (United States).
:
HCS Classification
: TSCA 8(b) inventory: Water; Sodium hexametaphosphate; Sodium citrate; Sodium hydrogen sulfate;
U.S. Federal Regulations
Polyethylene Glycol; Phosphoric acid
SARA 302/304/311/312 extremely hazardous substances: No products were found.
SARA 302/304 emergency planning and notification: Polyethylene Glycol
SARA 302/304/311/312 hazardous chemicals: No products were found.
SARA 311/312 MSDS distribution - chemical inventory - hazard identification: Sodium
hexametaphosphate: immediate health hazard; Sodium hydrogen sulfate: immediate health hazard;
Phosphoric acid: immediate health hazard
SARA 313 toxic chemical notification and release reporting: No products were found.
Clean Water Act (CWA) 307: No products were found.
Clean Water Act (CWA) 311: No products were found.
Clean air act (CAA) 112 accidental release prevention: No products were found.
Clean air act (CAA) 112 regulated flammable substances: No products were found.
Clean air act (CAA) 112 regulated toxic substances: Phosphorous compounds (10.4 by weight); arsenic,
cadmium, lead, acetaldehyde, 1,4-dioxane, ethylene oxide and formaldehyde (<1ppm each)
International
Regulations
WHMIS : CLASS D-2B: Material causing other toxic effects (TOXIC).
(Canada)
This product has been classified in accordance with hazard criteria of the Controlled Products Regulations
and the MSDS contains all the information required by the Controlled Products Regulations.
CEPA DSL: Water; Sodium hexametaphosphate; Sodium citrate; Sodium hydrogen sulfate; Polyethylene
Glycol; Phosphoric acid
:
DSCL (EEC) This product is not classified according to the EU regulations.
:
International WGK 1
Lists
:
State Regulations Pennsylvania RTK: All required components of this product are identified.
Massachusetts RTK: All required components of this product are identified.
New Jersey: All required components of this product are identified.
California prop. 65: This product may contain chemicals known to the State of California to cause cancer
(,1ppm arsenic, cadmium, lead, ethylene oxide, acetaldehyde, 1,4-dioxane and formaldehyde) or
reproductive toxicity (<1ppm lead and ethylene oxide)
16. Other Information
: CAUSES EYE IRRITATION. CAUSES SKIN IRRITATION.
Label Requirements
Hazardous Material : * 2 National Fire
Health
Fire Hazard
0
Information System 0 Protection
Fire Hazard
(U.S.A.) Association (U.S.A.) 1 0
Health Reactivity
0
Reactivity
Specific Hazard
B
Personal Protection
: Not available.
References
: Not available.
Other Special
Considerations
Validated by Kodak Polychrome Graphics on 2000-09-06. Verified by Kodak Polychrome Graphics.
Printed 2000-09-06.
In Case of Emergency CALL 1-800-451-8346
Notice to Reader
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Subtractive Plate Finisher XL
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its
subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be
used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.
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