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MATERIAL SAFETY DATA SHEET
Penreco?Drakeol?Mineral Oil - USP
Grades
1. PRODUCT AND COMPANY IDENTIFICATION
Penreco?Drakeol?Mineral Oil - USP Grades
Product Name:
Penreco?Drakeol?19
Synonyms:
Penreco?Drakeol?21
Penreco?Drakeol?25
Penreco?Drakeol?32
Penreco?Drakeol?33
Penreco?Drakeol?34
Penreco?Drakeol?35
Penreco?Drakeol?350
Penreco?Drakeol?35G
Penreco?Drakeol?400
Petroleum Hydrocarbon
Chemical Family:
Penreco
Responsible Party:
138 Petrolia Street
Karns City, PA 16041-9799
For Additional MSDSs 1-800-762-0942
1-800-245-3952
Technical Information:
EMERGENCY OVERVIEW
24 Hour Emergency Telephone Numbers:
California Poison Control System: (800) 356-3129
Spill, Leak, Fire or Accident
Call CHEMTREC
North America: (800)424-9300
Others: (703)527-3887 (collect)
Health Hazards/Precautionary Measures: None Anticipated
Physical Hazards/Precautionary Measures: Keep away from all sources of ignition.
Transparent, water-white
Appearance:
Physical form: Liquid
Odor: Odorless
HMIS Hazard Class
NFPA Hazard Class:
Health: 0 (Least) Health: 0 (Least)
Flammability:1 (Slight) Flammability: 1 (Slight)
Reactivity: 0 (Least) Physical Hazard: 0 (Least)
2. COMPOSITION/INFORMATION ON INGREDIENTS
No hazardous components identified per 29 CFR 1910.1200.
___________________________________________________________________________________________
OTHER COMPONENTS % WEIGHT EXPOSURE GUIDELINE
Agency Type
Limits
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(See: Oil Mist, If Generated)
100
White Mineral Oil
CAS# 8042-47-5
____________________________________________________________________________________________
REFERENCE EXPOSURE GUIDELINE
Limits Agency Type
5 mg/m3 ACGIH TWA
Oil Mist, If Generated
10 mg/m3 ACGIH STEL
CAS# None
5 mg/m3 OSHA TWA
2500 mg/m3 NIOSH IDLH
5 mg/m3 NOHSC TWA
Note: State, local or other agencies or advisory groups may have established more stringent limits.
Consult an industrial hygienist or similar professional, or your local agencies, for further information.
1%=10,000 PPM.
All components are listed on the TSCA inventory.
3. HAZARDS IDENTIFICATION
Potential Health Effects:
Eye: Not known to be an eye irritant.
Skin: Not known to be a skin irritant. No harmful effects from skin absorption have been reported.
Inhalation (Breathing): No harmful effects reported.
Ingestion (Swallowing): No harmful effects reported from ingestion.
Signs and Symptoms: Effects of overexposure may include irritation of the nose and throat,
irritation of the digestive tract and diarrhea.
No evidence of cancer has been demonstrated in several well conducted animal studies.
Cancer:
Target Organs: No data available for this material.
Developmental: No data available for this material.
None Known
Pre-Existing Medical Conditions:
4. FIRST AID MEASURES
Eye: If irritation or redness develops, move victim away from exposure and into fresh air. Flush eyes
with clean water. If symptoms persist, seek medical attention.
Skin: First aid is not normally required. However, it is good practice to wash any chemical from the
skin.
Inhalation (Breathing): First aid is not normally required. If breathing difficulties develop, move victim away from
source of exposure and into fresh air. Seek immediate medical attention.
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Ingestion (Swallowing): First aid is not normally required; however, if swallowed and symptoms develop, seek
medical attention.
Note To Physicians: Acute aspirations of large amounts of oil-laden material may produce a
serious aspiration pneumonia. Patients who aspirate these oils should be followed for the
development of long-term sequelae. Inhalation exposure to oil mists below current workplace
exposure limits is unlikely to cause pulmonary abnormalities.
5. FIRE FIGHTING MEASURES
Flash Point: >370癋/>187.8癈 ASTM D-92(COC)
Flammable Properties:
OSHA Flammability Class: Not applicable
LEL/UEL%: No Data
Autoignition Temperature: No Data
Unusual Fire & Explosion Hazards: This material may burn, but will not ignite readily. Vapors are heavier than air
and can accumulate in low areas. If container is not properly cooled, it can rupture in the heat of a fire.
Extinguishing Media: Dry chemical, carbon dioxide, foam, or water spray is recommended. Water or foam may
cause frothing of materials heated above 212癋. Carbon dioxide can displace oxygen. Use caution when applying
carbon dioxide in confined spaces.
Fire Fighting Instructions: For fires beyond the incipient stage, emergency responders in the immediate hazard
area should wear bunker gear. When the potential chemical hazard is unknown, in enclosed or confined spaces, or
when explicitly required by DOT, a self contained breathing apparatus should be worn. In addition, wear other
appropriate protective equipment as conditions warrant (see Section 8).
Isolate immediate hazard area, keep unauthorized personnel out. Stop spill/release if it can be done with minimal
risk. Move undamaged containers from immediate hazard area if it can be done with minimal risk.
Water spray may be useful in minimizing or dispersing vapors and to protect personnel. Cool equipment exposed to
fire with water, if it can be done with minimal risk. Avoid spreading burning liquid with water used for cooling
purposes.
6. ACCIDENTAL RELEASE MEASURES
This material may burn, but will not ignite readily. Keep all sources of ignition away from spill/release. Stay
upwind and away from spill/release. Notify persons down wind of the spill/release, isolate immediate hazard area
and keep unauthorized personnel out. Stop spill/release if it can be done with minimal risk. Wear appropriate
protective equipment including respiratory protection as conditions warrant (see Section 8).
Prevent spilled material from entering sewers, storm drains, other unauthorized drainage systems, and natural
waterways. Dike far ahead of spill for later recovery or disposal. Spilled material may be absorbed into an
appropriate absorbent material.
Notify fire authorities and appropriate federal, state, and local agencies. Immediate cleanup of any spill is
recommended. If spill of any amount is made into or upon navigable waters, the contiguous zone, or adjoining
shorelines, notify the National Response Center (phone number 800-424-8802).
7. HANDLING AND STORAGE
Handling: Do not enter confined spaces such as tanks or pits without following proper entry
procedures such as ASTM D-4276 and 29CFR 1910.146. The use of appropriate respiratory protection is advised
when concentrations exceed any established exposure limits (see Sections 2 and 8).
Do not wear contaminated clothing or shoes. Use good personal hygiene practices.
"Empty" containers retain residue and may be dangerous. Do not pressurize, cut, weld, braze, solder, drill,
grind, or expose such containers to heat, flame, sparks, or other sources of ignition. They may explode and
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cause injury or death. "Empty" drums should be completely drained, properly bunged, and promptly shipped to
the supplier or a drum reconditioner. All containers should be disposed of in an environmentally safe
manner and in accordance with governmental regulations.
Before working on or in tanks which contain or have contained this material, refer to OSHA regulations, ANSI
Z49.1 and other references pertaining to cleaning, repairing, welding, or other contemplated operations.
Storage: Keep container(s) tightly closed. Use and store this material in cool, dry, well-ventilated
areas away from heat and all sources of ignition. Store only in approved containers. Keep away from any
incompatible material (see Section 10). Protect container(s) against physical damage.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering controls: If current ventilation practices are not adequate to maintain airborne concentrations below
the established exposure limits (see Section 2), additional engineering controls may be required.
Personal Protective Equipment (PPE):
Respiratory: A NIOSH certified air purifying respirator with a Type 95 (R or P) particulate
filter may be used in conjunction with an organic vapor cartridge under conditions where
airborne concentrations are expected to exceed exposure limits (see Section 2).
Protection provided by air purifying respirators is limited (see manufacturer's respirator
selection guide). Use a NIOSH approved self-contained breathing apparatus (SCBA) or
equivalent operated in a pressure demand or other positive pressure mode if there is
potential for an uncontrolled release, exposure levels are not known, or any other
circumstances where air purifying respirators may not provide adequate protection. A
respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2
requirements must be followed whenever workplace conditions warrant a respirator's use.
Skin: Not required based on the hazards of the material. However, it is considered good
practice to wear gloves when handling chemicals.
Eye/Face: While contact with this material is not expected to cause irritation, the use of
approved eye protection to safeguard against potential eye contact is considered good
practice.
Other Protective Equipment: A source of clean water should be available in the work
area for flushing eyes and skin. Impervious clothing should be worn as needed.
Suggestions for the use of specific protective materials are based on readily available published
data. Users should check with specific manufacturers to confirm the performance of their products.
9. PHYSICAL AND CHEMICAL PROPERTIES
Note: Unless otherwise stated, values are determined at 20癈 (68癋) and 760 mm Hg (1 atm).
Appearance: Transparent, water-white
Physical State: Liquid
Odor: Odorless
pH: No Data
Vapor Pressure (mm Hg): <1
Vapor Density (air=1): >1
Boiling Point/Range: 590癋 / 310癈 (approximate)
Freezing/Melting Point: No Data
Solubility in Water: Insoluble
Specific Gravity: 0.86-0.88
Evaporation Rate (nBuAc=1): <1
Bulk Density: 7.17 lbs/gal
Flash Point: >370癋 / >187.8癈 ASTM D-92(COC)
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Flammable/Explosive Limits (%): No Data
10. STABILITY AND REACTIVITY
Stability: Stable under normal ambient and anticipated storage and handling conditions of temperature and
pressure.
Conditions To Avoid: Avoid all possible sources of ignition (see Sections 5 and 7).
Materials to Avoid (Incompatible Materials): Avoid contact with strong oxidizing
agents.
Hazardous Decomposition Products: carbon, nitrogen and sulfur oxides.
Hazardous Polymerization: Will not occur.
11. TOXICOLOGICAL INFORMATION
No definitive information available on carcinogenicity, mutagenicity, target organs or developmental toxicity.
12. ECOLOGICAL INFORMATION
Not evaluated at this time
13. DISPOSAL CONSIDERATIONS
This material, if discarded as produced, is not a RCRA "listed" hazardous waste. However, it should be fully
characterized for toxicity prior to disposal (40 CFR 261). Use which results in chemical or physical change or
contamination may subject it to regulation as a hazardous waste. Along with properly characterizing all waste
materials, consult state and local regulations regarding the proper disposal of this material.
Container contents should be completely used and containers should be emptied prior to discard. Container
rinsate could be considered a RCRA hazardous waste and must be disposed of with care and in full compliance
with federal, state and local regulations. Larger empty containers, such as drums, should be returned to the
distributor or to a drum reconditioner. To assure proper disposal of smaller empty containers, consult with
state and local regulations and disposal authorities.
14. TRANSPORT INFORMATION
DOT Shipping Description: Not hazardous
Material is unregulated unless in container of 3500 gal or more then provisions of 49 CFR Part 130 apply
Note:
for land shipment.
IMDG: Not regulated
IATA: Not regulated
15. REGULATORY INFORMATION
EPA SARA 311/312 (Title III Hazard Categories):
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No
Acute Health:
No
Chronic Health:
No
Fire Hazard:
No
Pressure Hazard:
No
Reactive Hazard:
SARA 313 and 40 CFR 372:
This material contains the following chemicals subject to the reporting requirements of SARA 313 and 40
CFR 372:
--None--
California Proposition 65:
Warning: This material contains the following chemicals which are known to the State of California to cause cancer,
birth defects or other reproductive harm, and are subject to the requirements of California Proposition 65 (CA Health
& Safety Code Section 25249.5):
--None Known--
Carcinogen Identification:
This material has not been identified as a carcinogen by NTP, IARC, or OSHA.
EPA (CERCLA) Reportable Quantity:
--None--
Canada - Domestic Substances List: Listed
WHMIS Class:
Not regulated
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations
(CPR) and the MSDS contains all the information required by the CPR.
This material is listed on the following inventories:
Australian (AICS)
Canadian (DSL)
Chinese
European EC/EINECS
Japanese ENCS
Korean (ECL)
Philippine (PICCS)
16. OTHER INFORMATION
Issue Date: 04/09/03
Previous Issue Date: 07/26/01
Revised Sections: New Format
MSDS Number: 776507
Status: Final
Disclaimer of Expressed and Implied Warranties:
The information presented in this Material Safety Data Sheet is based on data believed to be accurate as of the date this Material Safety Data
Sheet was prepared. HOWEVER, NO WARRANTY OF MERCHANTABILITY, FITNESS FOR ANY PARTICULAR PURPOSE, OR ANY OTHER
WARRANTY IS EXPRESSED OR IS TO BE IMPLIED REGARDING THE ACCURACY OR COMPLETENESS OF THE INFORMATION
PROVIDED ABOVE, THE RESULTS TO BE OBTAINED FROM THE USE OF THIS INFORMATION OR THE PRODUCT, THE SAFETY OF
THIS PRODUCT, OR THE HAZARDS RELATED TO ITS USE. No responsibility is assumed for any damage or injury resulting from abnormal
use or from any failure to adhere to recommended practices. The information provided above, and the product, are furnished on the condition
that the person receiving them shall make their own determination as to the suitability of the product for their particular purpose and on the
condition that they assume the risk of their use. In addition, no authorization is given nor implied to practice any patented invention without a
license.
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