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LEONID Industrial Suburb
CHEMICALS
CONTACT :
62/A-2 2nd Stage,
Ashokpuram School Road, Yeshwanthpur
MATERIAL SAFETY DATA SHEET Bangalore-560 022, INDIA
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Ph: +91-80-2337 8354, Fax: +91-80-2357
1H-Benzotriazole
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SECTION 1- CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
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MSDS Name:
1H-Benzotriazole .
Catalog Numbers:
10567-0000, 10567-1000, 10567-5000, 18388-0000, 18388-1000, 18388-5000
Synonyms:
1,2,3-Benzotriazole
Company Information:
LEONID CHEMICALS
62/A-2 1st Stage, Yeshwanthpur Industrial Suburb
Ashokpuram School Road
Bangalore-560 022, Karnataka, INDIA
Ph: +91-80-2337 8354, Fax: +91-80-2357 4827
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SECTION 2- COMPOSITION, INFORMATION ON INGREDIENTS
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CAS # : 95-14-7
Chemical Name : 1H-Benzotriazole
% : >98%
EINECS# : 202-394-1
Hazard Symbols : XN F
Risk Phrases : 11 20/21/22 36/37/38 5
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SECTION 3- HAZARDS IDENTIFICATION
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EMERGENCY OVERVIEW
Highly flammable. Harmful by inhalation, in contact with skin and if swallowed.
Irritating to eyes, respiratory system and skin. Heating may cause an explosion.
Potential Health Effects
Eye:
Causes eye irritation. May cause redness, pain, blurred vision and possible eye
damage.
Skin:
Causes skin irritation. Harmful if absorbed through the skin. Causes redness and pain.
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1 62/A-2 2nd Stage, Industrial Suburb
Ashokpuram School Road, Yeshwanthpur
Bangalore-560 022, INDIA
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Ingestion:
Harmful if swallowed. May cause irritation of the digestive tract. May cause central
nervous system effects. May cause headache, nausea, fatigue, and dizziness.
Inhalation:
Harmful if inhaled. Causes respiratory tract irritation. May cause headache. Chronic:
Chronic:
No information available.
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SECTION 4 - FIRST AID MEASURES
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Eyes:
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper
and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes.
Ingestion:
Get medical aid immediately. Wash mouth out with water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air
immediately. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen.
Notes to Physician:
Treat symptomatically and supportively.
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SECTION 5 - FIRE FIGHTING MEASURES
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General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand,
MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire,
irritating and highly toxic gases may be generated by thermal decomposition or
combustion. Will burn if involved in a fire. Dust can be an explosion hazard when
exposed to heat or flame. This material in sufficient quantity and reduced particle
size is capable of creating a dust explosion. Flammable solid. May decompose
explosively when heated or involved in a fire. Containers may explode if exposed to
fire. May explode on distillation.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Use water spray, dry chemical,
carbon dioxide, or chemical foam.
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2 62/A-2 2nd Stage, Industrial Suburb
Ashokpuram School Road, Yeshwanthpur
Bangalore-560 022, INDIA
Ph: +91-80-2337 8354, Fax: +91-80-2357 4827
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SECTION 6 - ACCIDENTAL RELEASE MEASURES
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General Information:
Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Do not flush
into a sewer. Remove all sources of ignition. Use a spark-proof tool.
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SECTION 7 - HANDLING AND STORAGE
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Handling:
Use spark-proof tools and explosion proof equipment. Do not breathe dust, vapor,
mist, or gas. Do not get in eyes, on skin, or on clothing. Use only in a chemical fume
hood.
Storage:
Keep away from sources of ignition. Store in a cool, dry place. Store in a tightly closed
container. Flammables-area.
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SECTION 8 - Exposure Controls, Personal Protection
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Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility
and a safety shower. Use adequate general or local explosion-proof ventilation to keep
airborne levels to acceptable levels.
Personal Protective Equipment
Eyes:
Wear chemical goggles.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard
EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when
necessary.
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3 62/A-2 2nd Stage, Industrial Suburb
Ashokpuram School Road, Yeshwanthpur
Bangalore-560 022, INDIA
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SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
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Physical State : Flakes
Color : White to yellow-beige
Odor : odorless
PH : 5 (25 g/l aq.sol.)
Vapor Pressure : 0.04mmHg @20 deg C
Viscosity : No information available.
Boiling Point : 204 deg C @15mmHg
Freezing/Melting Point : 95 - 99 deg C
Autoignition Temperature : 210 deg C ( 410.00 deg F)
Flash Point : 170 deg C ( 338.00 deg F)
Explosion Limits, lower : 2.4 Vol %
Explosion Limits, upper : No information available.
Decomposition Temperature : >160 deg C
Solubility in water : 25 g/l (20癈)
Specific Gravity/Density : No information available.
Molecular Formula : C6H5N3
Molecular Weight : 119.13
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SECTION 10 - STABILITY AND REACTIVITY
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Chemical Stability:
Heating may cause an explosion. Dusts may form an explosion hazard.
Conditions to Avoid:
Incompatible materials, ignition sources, heat.
Incompatibilities with Other Materials:
Strong oxidizing agents, heavy metals.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization:
Has not been reported
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4 62/A-2 2nd Stage, Industrial Suburb
Ashokpuram School Road, Yeshwanthpur
Bangalore-560 022, INDIA
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SECTION 11 - TOXICOLOGICAL INFORMATION
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RTECS#:
CAS# 95-14-7: Dm1225000
LD50/LC50:
CAS# 95-14-7: Inhalation, rat: LC50 = 1910 mg/m3/3H; Oral, mouse: LD50 = 615
mg/kg; Oral, rat: LD50 = 560 mg/kg; Skin, rat: LD50 = >1 gm/kg. Not available.
Carcinogenicity:
1H-Benzotriazole - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA. See actual entry
in RTECS for complete information.
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SECTION 12 -ECOLOGICAL INFORMATION
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Other
Avoid entering into waters or underground water. Do not empty into drains. Non-
biodegradable.
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SECTION 13 -DISPOSAL CONSIDERATIONS
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Dispose of in a manner consistent with federal, state, and local regulations.
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SECTION 14 - TRANSPORT INFORMATION
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IATA
Shipping Name : FLAMMABLE SOLID, TOXIC, ORGANIC, N.O.S.*
Hazard Class : 4.1
UN Number : 2926
Packing Group : II
IMO
Shipping Name : FLAMMABLE SOLID, TOXIC, ORGANIC, N.O.S.*
Hazard Class : 4.1
UN Number : 2926
Packing Group : II
-
RID/ADR
Shipping Name : FLAMMABLE SOLID, TOXIC, ORGANIC, N.O.S.*
Hazard Class : 4.1
UN Number : 2926
Packing Group : II
TM
5 62/A-2 2nd Stage, Industrial Suburb
Ashokpuram School Road, Yeshwanthpur
Bangalore-560 022, INDIA
Ph: +91-80-2337 8354, Fax: +91-80-2357 4827
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SECTION 15 - REGULATORY INFORMATION
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European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
XN F
Risk Phrases:
R 11 Highly flammable. R 20/21/22 Harmful by inhalation, in contact with skin and if
swallowed. R 36/37/38 Irritating to eyes, respiratory system and skin. R 5 Heating may
cause an explosion.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately with plenty of water and seek
medical advice. S 28A After contact with skin, wash immediately with plenty of water.
S 36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S 45 In
case of accident or if you feel unwell, seek medical advice immediately (show the
label where possible).
WGK (Water Danger/Protection)
CAS# 95-14-7: 2
United Kingdom Occupational Exposure Limits
No information available.
United Kingdom Maximum Exposure Limits
No information available.
Canada
CAS# 95-14-7 is listed on Canada's DSL List.
CAS# 95-14-7 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 95-14-7: OEL-RUSSIA:STEL 5 mg/m3;Skin
US FEDERAL
TSCA
CAS# 95-14-7 is listed on the TSCA inventory. rous form is on the inventory
(40CFR720.3(u)(2)).
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SECTION 16 - ADDITIONAL INFORMATION
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The information above is believed to be accurate and represents the best information
currently available to us. However, we make no warranty of merchantability or any
other warranty, express or implied, with respect to such information, and we assume
no liability resulting from its use. Users should make their own investigations to
determine the suitability of the information for their particular purposes. In no way
shall the company be liable for any claims, losses, or damages of any third party or for
lost profits or any special, indirect, incidental, consequential or exemplary damages,
howsoever arising, even if the company has been advised of the possibility of such
damages.
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6 62/A-2 2nd Stage, Industrial Suburb
Ashokpuram School Road, Yeshwanthpur
Bangalore-560 022, INDIA
Ph: +91-80-2337 8354, Fax: +91-80-2357 4827
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